CN106111691A - A kind of soil remediation adsorption net and restorative procedure thereof - Google Patents

A kind of soil remediation adsorption net and restorative procedure thereof Download PDF

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Publication number
CN106111691A
CN106111691A CN201610486922.7A CN201610486922A CN106111691A CN 106111691 A CN106111691 A CN 106111691A CN 201610486922 A CN201610486922 A CN 201610486922A CN 106111691 A CN106111691 A CN 106111691A
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CN
China
Prior art keywords
soil
web plate
adsorption net
soil remediation
restorative procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610486922.7A
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Chinese (zh)
Inventor
秦月琴
任飞
孙忠伟
明桂林
吴海东
王前
张传琦
牛杏杏
王赞
王代飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd
Original Assignee
ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd filed Critical ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd
Priority to CN201610486922.7A priority Critical patent/CN106111691A/en
Publication of CN106111691A publication Critical patent/CN106111691A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ

Abstract

The invention discloses a kind of soil remediation adsorption net and restorative procedure thereof, including web plate, this web plate is compressing, for wavy shape by adsorbing material;Described web plate thickness is 2 5mm, uniform on its surface have bar shaped and considers hole, and bar shaped is considered the wave flanging of hole and web plate and formed the inclination angle of 10 15 degree;Described adsorbing material is added attapulgite body by ion-exchange fibre by the weight ratio of 2 4:1 1.5 and prepares.The restorative procedure degree of depth that includes nuzzling adsorption net is in 15 25cm soil 15 30 days.The present invention prepares adsorption net by attapulgite powder body and exchange fiber, it is applied to the improvement reparation of soil pollution, restorative procedure is simple, quick, it is suitable for industrialized production, and can forever remove the harmful substance in soil by absorption, exchange, reach the purpose that rehabilitating soil pollutes, reduce the leaching concentration of harmful substance in soil and heavy metal animal migration in soil and the degree of murder by poisoning.

Description

A kind of soil remediation adsorption net and restorative procedure thereof
Technical field
The invention belongs to attapulgite material technical field, relate to a kind of soil remediation adsorption net and restorative procedure thereof.
Background technology
Soil pollution has pollutant poor mobility, holdup time length, feature such as irreversible in soil, causes soil Fertility declines, and crop yield and quality decline, and can be by runoff and leaching polluted underground water and surface water.
Adsorption filtration is the important technology during current soil deep purifying processes.The most conventional adsorbing material is active Charcoal, activated alumina and ion exchange resin etc., though they can adsorb various pollutant effectively, but due to its relatively low absorption Capacity, slower adsorption rate and poor mechanical stability etc. so that it is extensively application is restricted.
Combine exchange fiber and attapulgite material at present and carry out the technology of repair process soil, the most not Can meet, in order to meet existing situation, soil remediation be needed further exist for, a kind of scheme of existing offer.
Summary of the invention
It is an object of the invention to provide a kind of soil remediation adsorption net and restorative procedure thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of soil remediation adsorption net, including web plate, this web plate is compressing, for wavy shape by adsorbing material; Described web plate thickness is 2-5mm, and on its surface the uniform bar shaped worry hole that has, and bar shaped worry hole is formed with the wave flanging of web plate The inclination angle of 10-15 degree;The weight ratio that described adsorbing material is pressed 2-4:1-1.5 by ion-exchange fibre adds attapulgite powder body Prepare.
Described ion-exchange fibre preparation method is: be sequentially added in a certain amount of vinal ethylene glycol with Ethylenediamine, back flow reaction under stirring, obtain intermediate product;After intermediate product washes with water, add aminopyridine and chloroethene Alkane mixed solution, reacts under stirring at normal temperature, successively by water, hydrochloric acid, water wash products extremely neutrality after terminating, obtains ion exchange fibre Dimension.
Described web plate is the bulk of 1.5m*1.5m, or is the strip of 2m*1m, or is the circle of 1.5-2m for diameter.
The restorative procedure of a kind of soil remediation adsorption net, the method degree of depth that includes nuzzling adsorption net is 15-25cm soil Middle 15-30 days.
Beneficial effects of the present invention: the present invention prepares adsorption net by attapulgite powder body and exchange fiber, is applied to soil The improvement reparation polluted, restorative procedure is simple, quick, is suitable for industrialized production, and can forever remove soil by absorption, exchange In harmful substance, reach the purpose that rehabilitating soil pollutes, reduce the leaching concentration of harmful substance in soil and heavy metal at soil Animal migration in earth and the degree of murder by poisoning.
Accompanying drawing explanation
For the ease of it will be appreciated by those skilled in the art that the present invention is further illustrated below in conjunction with the accompanying drawings.
Fig. 1 is one soil remediation adsorption net structural representation of the present invention;
Fig. 2 is enlarged diagram at B in Fig. 1.
Detailed description of the invention
Embodiment 1
A kind of soil remediation adsorption net, sees Fig. 1, Fig. 2, and including web plate 1, this web plate 1 makes 1.5m* by adsorbing material The bulk of 1.5m, and embossing shape;Web plate 1 thickness is 5mm, on its surface uniform have bar shaped consider hole 101, bar shaped Consider the inclination angle in hole 101 and the wave flanging formation 15 degree of web plate 1;Adsorbing material is pressed the weight of 4:1.5 by ion-exchange fibre Prepare than adding the attapulgite body that particle diameter is 350mm;
Ion-exchange fibre preparation method is: be sequentially added in 3.22kg vinal 4.5kg ethylene glycol with 2.5kg ethylenediamine, back flow reaction 1h under stirring, obtain intermediate product;After intermediate product washes with water, add 1.5kg second Glycol, 6.75kg aminopyridine and 1.25kg ethyl chloride mixed solution, react 30min under stirring at normal temperature, after terminating successively with water, Hydrochloric acid, water wash products, to neutral, obtain ion-exchange fibre;
The degree of depth of above-mentioned prepared adsorption net being nuzzled is in 25cm soil 30 days, adsorb, exchange after remove from soil again, The present invention prepares adsorption net by attapulgite powder body and exchange fiber, is applied to the improvement reparation of soil pollution, restorative procedure letter Single, quick, it is suitable for industrialized production, and can forever remove the harmful substance in soil by absorption, exchange, reach rehabilitating soil The purpose polluted, reduces the leaching concentration of harmful substance in soil and heavy metal animal migration in soil and the degree of murder by poisoning.
Embodiment 2
A kind of soil remediation adsorption net, including web plate 1, this web plate 1 is pressed into the strip of 2m*1m by adsorbing material;Net Plate 1 thickness is 2mm, and on its surface the uniform bar shaped worry hole 101 that has, and bar shaped worry hole 101 forms 10 degree with the wave flanging of web plate 1 Inclination angle;Adsorbing material is added attapulgite body by ion-exchange fibre by the weight ratio of 2:1 and prepares;Ion-exchange fibre system Preparation Method is with embodiment 1.
The degree of depth of above-mentioned prepared adsorption net being nuzzled is in 15cm soil 15 days, adsorb, exchange after remove from soil again.
Above content is only to present configuration example and explanation, affiliated those skilled in the art couple Described specific embodiment makes various amendment or supplements or use similar mode to substitute, without departing from invention Structure or surmount scope defined in the claims, all should belong to protection scope of the present invention.

Claims (4)

1. a soil remediation adsorption net, including web plate, it is characterised in that this web plate is compressing, for ripple by adsorbing material Shape wave shape;Described web plate thickness is 2-5mm, uniform on its surface have bar shaped and considers hole, and the wave of hole and web plate is considered in bar shaped Flanging forms the inclination angle of 10-15 degree;The weight ratio that described adsorbing material is pressed 2-4:1-1.5 by ion-exchange fibre adds recessed Convex rod powder body prepares.
A kind of soil remediation adsorption net the most according to claim 1, it is characterised in that prepared by described ion-exchange fibre Method is: be sequentially added into ethylene glycol and ethylenediamine in a certain amount of vinal, and back flow reaction under stirring obtains Intermediate product;After intermediate product washes with water, add aminopyridine and ethyl chloride mixed solution, react under stirring at normal temperature, terminate After successively by water, hydrochloric acid, water wash products to neutral, obtain ion-exchange fibre.
A kind of soil remediation adsorption net the most according to claim 1, it is characterised in that described web plate is 1.5m*1.5m Bulk, or be the strip of 2m*1m, or be the circle of 1.5-2m for diameter.
4. the restorative procedure of a soil remediation adsorption net, it is characterised in that the method degree of depth that includes nuzzling adsorption net is 15- In 25cm soil 15-30 days.
CN201610486922.7A 2016-06-27 2016-06-27 A kind of soil remediation adsorption net and restorative procedure thereof Pending CN106111691A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610486922.7A CN106111691A (en) 2016-06-27 2016-06-27 A kind of soil remediation adsorption net and restorative procedure thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610486922.7A CN106111691A (en) 2016-06-27 2016-06-27 A kind of soil remediation adsorption net and restorative procedure thereof

Publications (1)

Publication Number Publication Date
CN106111691A true CN106111691A (en) 2016-11-16

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CN (1) CN106111691A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107457252A (en) * 2017-08-04 2017-12-12 蓝畅 One heavy metal species and(Or)The restorative procedure of organic hydrocarbon contaminated soil
CN107931322A (en) * 2017-11-23 2018-04-20 成都新柯力化工科技有限公司 A kind of method using zeroth order Nanoscale Iron original position continuous repair soil
CN108246793A (en) * 2018-02-27 2018-07-06 苏州逸纪杰电子科技有限公司 A kind of heavy-metal contaminated soil renovation agent and preparation method thereof
CN110076192A (en) * 2019-05-31 2019-08-02 华南理工大学 A kind of in-situ remediation method of heavy-metal contaminated soil
CN112474775A (en) * 2020-11-09 2021-03-12 王书敏 Soil treatment rod with array distribution
CN113814266A (en) * 2021-09-13 2021-12-21 生态环境部华南环境科学研究所 Reclaimed aluminum pile point soil pollution risk management and control method based on vertical barrier

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CN102276075A (en) * 2011-06-09 2011-12-14 上海大学 Combined type sewage treatment apparatus
CN102690027A (en) * 2012-06-19 2012-09-26 安树青 Ecological infiltration treatment method
CN102886375A (en) * 2012-09-29 2013-01-23 广西大学 Method for processing heavy metal Cd (Cadmium) contaminated soil
CN203355732U (en) * 2013-07-02 2013-12-25 珠海国佳高分子新材料有限公司 Recyclable heavy-metal adsorption gel ball

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CN102276075A (en) * 2011-06-09 2011-12-14 上海大学 Combined type sewage treatment apparatus
CN102690027A (en) * 2012-06-19 2012-09-26 安树青 Ecological infiltration treatment method
CN102886375A (en) * 2012-09-29 2013-01-23 广西大学 Method for processing heavy metal Cd (Cadmium) contaminated soil
CN203355732U (en) * 2013-07-02 2013-12-25 珠海国佳高分子新材料有限公司 Recyclable heavy-metal adsorption gel ball

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107457252A (en) * 2017-08-04 2017-12-12 蓝畅 One heavy metal species and(Or)The restorative procedure of organic hydrocarbon contaminated soil
CN107931322A (en) * 2017-11-23 2018-04-20 成都新柯力化工科技有限公司 A kind of method using zeroth order Nanoscale Iron original position continuous repair soil
CN107931322B (en) * 2017-11-23 2019-03-01 浙江一龙环保科技有限公司 A method of utilizing zeroth order Nanoscale Iron original position continuous repair soil
CN108246793A (en) * 2018-02-27 2018-07-06 苏州逸纪杰电子科技有限公司 A kind of heavy-metal contaminated soil renovation agent and preparation method thereof
CN110076192A (en) * 2019-05-31 2019-08-02 华南理工大学 A kind of in-situ remediation method of heavy-metal contaminated soil
CN110076192B (en) * 2019-05-31 2022-02-15 华南理工大学 In-situ remediation method for heavy metal contaminated soil
CN112474775A (en) * 2020-11-09 2021-03-12 王书敏 Soil treatment rod with array distribution
CN113814266A (en) * 2021-09-13 2021-12-21 生态环境部华南环境科学研究所 Reclaimed aluminum pile point soil pollution risk management and control method based on vertical barrier

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