CN106111073B - A kind of desiccant and preparation method thereof - Google Patents
A kind of desiccant and preparation method thereof Download PDFInfo
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- CN106111073B CN106111073B CN201610439493.8A CN201610439493A CN106111073B CN 106111073 B CN106111073 B CN 106111073B CN 201610439493 A CN201610439493 A CN 201610439493A CN 106111073 B CN106111073 B CN 106111073B
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- essential oil
- desiccant
- lavender
- peppermint
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Fats And Perfumes (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of desiccant and preparation method thereof, contain following components in percentage by weight in the desiccant: magnesium chloride 30~40%, chitosan 45~56%, touches essential oil 3~5%, Peppermint essential oil 1~2%, Lavender 1~3% at active carbon 7~9%;Said components are mixed directly and can be prepared by the desiccant, this desiccant has both moisture absorption, antibacterial, the effect of stacte, under conditions of 30 DEG C of temperature, humidity 90%, the hydroscopicity after 15 days can reach 380% of own wt or more, and infiltrate without liquid water.
Description
Technical field
The present invention relates to a kind of desiccant and preparation method thereof, and in particular to a kind of dry containing the fragrance for touching essential oil
Agent and preparation method thereof.
Background technique
With the raising of industrial manufactureization level, all trades and professions will use desiccant, and economic development promotes people's clothing
Increase and the dependence to tool, need drying in preservation and transport.
There are many method now in the art about production desiccant, can satisfy the needs of people substantially, but for one
A little special articles, high to moisture pick-up properties requirement, the general hydroscopicity of common desiccant is only 40% or less;Chinese patent
CN101249418 discloses a kind of desiccant of high hydroscopicity, maximum although it is under conditions of 40 DEG C of temperature, humidity 90%
Hygroscopic capacity can achieve 200% of own wt or more, but such mineral agent does not have fragrance, some high-grade clothings,
The storage use of leatherware, stamp, camera, piano, computer, audio-visual facility is difficult to meet individual requirements;And it is some with fragrance silicon
Desiccant hydroscopicity based on glue is again inadequate, and cannot be used for a long time again, therefore desiccant of today is no longer satisfied need
It wants.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of desiccant and preparation method thereof, touch perfume (or spice) by being added
Essential oil, Peppermint essential oil and Lavender so that this desiccant can not only meet the requirement of moisture pick-up properties, and have pure and fresh
Pleasant fragrance, while having the function of antibacterial.
The technical scheme adopted by the invention is as follows:
A kind of desiccant contains the following substances ingredient and weight percent:
The partial size of the active carbon is 200~400 mesh.
The desiccant, preferably comprises following material composition and weight percent: anhydrous magnesium chloride 40%, active carbon 5%,
Chitosan 45% touches essential oil 5%, Peppermint essential oil 2%, Lavender 3%.
The desiccant, preferably comprises following material composition and weight percent: anhydrous magnesium chloride 30%, active carbon 9%,
Chitosan 56% touches essential oil 3%, Peppermint essential oil 1%, Lavender 1%.
The desiccant, preferably comprises following material composition and weight percent: anhydrous magnesium chloride 35%, active carbon 7%,
Chitosan 50% touches essential oil 4%, Peppermint essential oil 2%, Lavender 2%.
It is described touch essential oil the preparation method comprises the following steps: touched in perfume (or spice) to fresh, be added and steam according to solid-liquid ratio 1:10~20
Distilled water is impregnated 2~4 hours, and concussion is interrupted in soaking process, and steam distillation is carried out after immersion, terminates to steam after extracting 6 hours
It evaporates, collects essential oil, be dried over anhydrous sodium sulfate, can be prepared by touching essential oil.
The Peppermint essential oil the preparation method comprises the following steps: peppermint is put into container, heated by lower section and generate steam, peppermint
Essential oil follows steam to evaporate, and the vapor containing essential oil becomes liquid after catheter collection is cooling, according to water and essential oil
Specific gravity, the difference of density and separate Peppermint essential oil.
The Lavender the preparation method comprises the following steps: lavender is mixed with distilled water according to the solid-liquid ratio of 1:10~20, boil
Boiling, the essential oil containing lavender ingredient are diffused into vapor, form the azeotropic mixture of water and oil, and azeotropic mixture is cooling, after separation
It can be prepared by Lavender.
The present invention also provides the preparation methods of the desiccant, and the preparation method comprises the following steps: by formula ratio
Anhydrous magnesium chloride, active carbon, chitosan, touch essential oil, Peppermint essential oil and Lavender and be mixed evenly and can make
Obtain desiccant.
The present invention by by anhydrous magnesium chloride, active carbon, chitosan, touch essential oil, Peppermint essential oil and Lavender
Mixing, prepares the fragrance desiccant with high hydroscopicity and fresh scent.
Active carbon is porous adsorbing material, while the noxious materials such as the formaldehyde in air, dimethylbenzene can be absorbed, and is being played
Play the role of air cleaning while its suction-operated, while the shatter value of desiccant can be increased.
Anhydrous magnesium chloride is used as easy moisture absorbing component in the present invention, and anhydrous magnesium chloride is easy to contain with water molecules formation
The hydrate of the different crystallizations water has extremely strong activity of water absorption.
Chitosan is containing a large amount of polar group hydroxyl and amino, these groups can form hydrogen between hydrone
Key, thus fixed hydrone.
It touches in perfume (or spice) containing the various actives volatile components such as limonene, australene, terpinolene, Bronyl acetate, band
There are strong scent, and lasting fragrance, while there is extensive bacteriostasis, essential oil is touched in addition in desiccant, is keeping
Article achievees the purpose that antibacterial stacte while dry.
Peppermint essential oil tool has the effect of refreshing, and the mind that makes one of news rouses oneself, and touches essential oil and Lavender
It is added in desiccant together, the smell of stacte can be made more pure and fresh pleasant.
Lavender is to generally acknowledge most calm, is releived, the plant of syngignoscism, it can releive intense strain, the calm mind,
Pneumostatic is calmed down, just has hospital the volatile oil extracted from lavender for improving the sleep of the elderly in foreign countries;In Xinjiang,
Neurasthenia and insomnia are also treated with lavender herb preparation by many Uygur medicine hospitals;There are also apparent antibacterials to make for lavender
With the linalool contained in lavender is the main component of lavender antibacterial, it can inhibit 17 kinds of bacteriums, and (including Grain-negative is thin
Bacterium and gram-positive bacteria), the growths of 10 kinds of fungies.
Desiccant of the invention is using easy hygroscopic salt, active carbon, chitosan and derived essential oil composition, the mechanism of action are as follows:
Active carbon absorbs moisture as adsorbent material, and easy hygroscopic salt anhydrous magnesium chloride absorbs moisture and forms crystalline hydrate, further inhales
Wet effect will continue to absorb water from environment and form liquid mixture;At this point, polar group hydroxyl and amino in chitosan
Firm hydrogen bond can be formed, so that anhydrous magnesium chloride and activity in conjunction with the hydrone to dissociate in active carbon and liquid mixture
Charcoal restores rapidly water absorbing capacity, while the volatile derived essential oil contained in desiccant can be dealt into air, play stacte
Purpose, after chitosan constantly absorbs water, intramolecular and intermolecular hydrogen bond are constantly formed, and then form stable gel, thus
Moisture is fixed in drier system, avoids the infiltration of moisture, while the diffusion of essential oil can be slowed down, plays it for a long time
Stacte purpose.
It is according to the present invention to be formulated the obtained desiccant for having both the moisture absorption, antibacterial and perfume container, in 30 DEG C of temperature, humidity
Under conditions of 90%, the hydroscopicity after 15 days can reach 380% of own wt or more, significantly larger than existing each dry in the market
The hydroscopicity of drying prescription.
The present invention compared with the existing technology, has following advantages:
1. containing plants essential oil in desiccant, while playing diluting effect, achieve the purpose that stacte;
2. containing active carbon ingredient in desiccant, when carrying out the drying such as furniture, clothing indoors, while playing to nocuousness
The suction-operated of substance;
3. each ingredient in the present invention is simple and easy to get, and the pure plant formula containing there are many, Environmental Safety, while having antibacterial
Effect.
Specific embodiment
Embodiment 1
A kind of desiccant, contain the following substances ingredient and weight percent: anhydrous magnesium chloride 40%, active carbon 5%, shell are poly-
Sugar 45% touches essential oil 5%, Peppermint essential oil 2%, Lavender 3%.
Touch essential oil to fresh the preparation method comprises the following steps: touches in perfume (or spice), and distilled water is added according to solid-liquid ratio 1:10, impregnates
4 hours, concussion is interrupted in soaking process, steam distillation is carried out after immersion, terminates distillation after extracting 6 hours, collects essential oil, warp
Anhydrous sodium sulfate is dry, can be prepared by touching essential oil.
Peppermint essential oil the preparation method comprises the following steps: peppermint is put into container, heated by lower section and generate steam, the essential oil of peppermint
And then steam evaporates, and the vapor containing essential oil becomes liquid after catheter collection is cooling, according to the specific gravity of water and essential oil,
The difference of density and separate Peppermint essential oil.
Lavender the preparation method comprises the following steps: lavender is mixed with distilled water according to 1:10 solid-liquid ratio, boil, containing smoking
The essential oil of clothing grass ingredient is diffused into vapor, forms the azeotropic mixture of water and oil, and azeotropic mixture is cooling, can be prepared by smoking after separation
Clothing grass essential oil.
By the anhydrous magnesium chloride of above-mentioned formula ratio, active carbon, chitosan, touch essential oil, Peppermint essential oil and lavender essence
Oil is mixed evenly, as required with the packaging material quantitative package for having penetrability.
Under conditions of gained desiccant is placed on 30 DEG C of temperature, humidity 90%, the hydroscopicity after 15 days can reach itself weight
The 382% of amount, and oozed out without liquid water;Gained desiccant is placed in wardrobe 3 months, clothing surface smell faint scent.
Embodiment 2
A kind of desiccant, contain the following substances ingredient and weight percent: anhydrous magnesium chloride 30%, active carbon 9%, shell are poly-
Sugar 56% touches essential oil 3%, Peppermint essential oil 1%, Lavender 1%.
Touch essential oil to fresh the preparation method comprises the following steps: touches in perfume (or spice), and distilled water is added according to solid-liquid ratio 1:15, impregnates
3 hours, concussion is interrupted in soaking process, steam distillation is carried out after immersion, terminates distillation after extracting 6 hours, collects essential oil, warp
Anhydrous sodium sulfate is dry, can be prepared by touching essential oil.
Peppermint essential oil the preparation method comprises the following steps: peppermint is put into container, heated by lower section and generate steam, the essential oil of peppermint
And then steam evaporates, and the vapor containing essential oil becomes liquid after catheter collection is cooling, according to the specific gravity of water and essential oil,
The difference of density and separate Peppermint essential oil.
Lavender the preparation method comprises the following steps: lavender is mixed with distilled water according to 1:15 solid-liquid ratio, boil, containing smoking
The essential oil of clothing grass ingredient is diffused into vapor, forms the azeotropic mixture of water and oil, and azeotropic mixture is cooling, can be prepared by smoking after separation
Clothing grass essential oil.
By the anhydrous magnesium chloride of above-mentioned formula ratio, active carbon, chitosan, touch essential oil, Peppermint essential oil and lavender essence
Oil is mixed evenly, as required with the packaging material quantitative package for having penetrability.
Under conditions of gained desiccant is placed on 30 DEG C of temperature, humidity 90%, the hydroscopicity after 15 days can reach itself weight
The 385% of amount, and oozed out without liquid water;Gained desiccant is placed in wardrobe 3 months, clothing surface smell faint scent.
Embodiment 3
A kind of desiccant, contain the following substances ingredient and weight percent: anhydrous magnesium chloride 35%, active carbon 7%, shell are poly-
Sugar 50% touches essential oil 4%, Peppermint essential oil 2%, Lavender 2%.
Touch essential oil to fresh the preparation method comprises the following steps: touches in perfume (or spice), and distilled water is added according to solid-liquid ratio 1:20, impregnates
2 hours, concussion is interrupted in soaking process, steam distillation is carried out after immersion, terminates distillation after extracting 6 hours, collects essential oil, warp
Anhydrous sodium sulfate is dry, can be prepared by touching essential oil.
Peppermint essential oil the preparation method comprises the following steps: peppermint is put into container, heated by lower section and generate steam, the essential oil of peppermint
And then steam evaporates, and the vapor containing essential oil becomes liquid after catheter collection is cooling, according to the specific gravity of water and essential oil,
The difference of density and separate Peppermint essential oil.
Lavender the preparation method comprises the following steps: lavender is mixed with distilled water according to 1:20 solid-liquid ratio, boil, containing smoking
The essential oil of clothing grass ingredient is diffused into vapor, forms the azeotropic mixture of water and oil, and azeotropic mixture is cooling, can be prepared by smoking after separation
Clothing grass essential oil.
By the anhydrous magnesium chloride of above-mentioned formula ratio, active carbon, chitosan, touch essential oil, Peppermint essential oil and lavender essence
Oil is mixed evenly, as required with the packaging material quantitative package for having penetrability.
Under conditions of gained desiccant is placed on 30 DEG C of temperature, humidity 90%, the hydroscopicity after 15 days can reach itself weight
The 380% of amount, and oozed out without liquid water;Gained desiccant is placed in wardrobe 3 months, clothing surface smell faint scent.
Comparative example 1
A kind of desiccant, contain the following substances ingredient and weight percent: anhydrous magnesium chloride 85%, touches active carbon 5%
Essential oil 5%, Peppermint essential oil 2%, Lavender 3%.
It is prepared using method identical with embodiment, under conditions of gained desiccant is placed on 30 DEG C of temperature, humidity 90%,
Hydroscopicity after 15 days can reach the 150% of own wt, have a small amount of liquid water to ooze out.
The above-mentioned detailed description carried out referring to embodiment to desiccant and preparation method thereof is illustrative rather than limits
Property, can enumerate several embodiments according to limited range, thus the variation in the case where not departing from present general inventive concept and
Modification, should belong within protection scope of the present invention.
Claims (8)
1. a kind of desiccant, which is characterized in that contain the following substances ingredient and weight percent:
The partial size of the active carbon is 200~400 mesh;The desiccant is under conditions of 30 DEG C of temperature, humidity 90%, after 15 days
Hydroscopicity can reach 380% of own wt or more.
2. desiccant according to claim 1, which is characterized in that contain the following substances ingredient and weight percent: anhydrous
Magnesium chloride 40%, chitosan 45%, touches essential oil 5%, Peppermint essential oil 2%, Lavender 3% at active carbon 5%.
3. desiccant according to claim 1, which is characterized in that contain the following substances ingredient and weight percent: anhydrous
Magnesium chloride 30%, chitosan 56%, touches essential oil 3%, Peppermint essential oil 1%, Lavender 1% at active carbon 9%.
4. desiccant according to claim 1, which is characterized in that contain the following substances ingredient and weight percent: anhydrous
Magnesium chloride 35%, chitosan 50%, touches essential oil 4%, Peppermint essential oil 2%, Lavender 2% at active carbon 7%.
5. desiccant according to any one of claims 1-4, which is characterized in that the preparation method for touching essential oil
Are as follows: Xiang Xinxian's touches in perfume (or spice), and distilled water is added according to solid-liquid ratio 1:10~20, impregnates 2~4 hours, is interrupted in soaking process
Concussion carries out steam distillation after immersion, terminate distillation after extracting 6 hours, collect essential oil, be dried over anhydrous sodium sulfate
It is made and touches essential oil.
6. desiccant according to any one of claims 1-4, which is characterized in that the preparation method of the Peppermint essential oil
Are as follows: peppermint is put into container, is heated by lower section and generates steam, the essential oil of peppermint follows steam to evaporate, contains essential oil
Vapor become liquid, according to the specific gravity of water and essential oil, the difference of density after catheter collection is cooling and separate peppermint
Essential oil.
7. desiccant according to any one of claims 1-4, which is characterized in that the preparation method of the Lavender
Are as follows: lavender is mixed with distilled water according to the solid-liquid ratio of 1:10~20, is boiled, the essential oil containing lavender ingredient is diffused into water steaming
In gas, the azeotropic mixture of water and oil is formed, azeotropic mixture is cooling, it can be prepared by Lavender after separation.
8. the preparation method of desiccant according to any one of claims 1-4, which is characterized in that the preparation method packet
It includes following steps: by the anhydrous magnesium chloride of formula ratio, active carbon, chitosan, touching essential oil, Peppermint essential oil and Lavender
It is mixed evenly and can be prepared by desiccant.
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CN111450811A (en) * | 2019-01-21 | 2020-07-28 | 广州道源生物医药科技有限公司 | Process for adsorbing essential oil by using silica gel desiccant or molecular sieve desiccant |
CN110280110A (en) * | 2019-07-02 | 2019-09-27 | 陕西中医药大学 | A kind of chemical drier and preparation method thereof |
CN110756021A (en) * | 2019-11-13 | 2020-02-07 | 徐州沿湖粮油储备库 | Drying agent with anti-static function for grain bin |
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CN101417224B (en) * | 2008-11-13 | 2011-11-16 | 华侨大学 | Use of industrial hemp core powder as drier |
CN103638788A (en) * | 2013-11-29 | 2014-03-19 | 大连创达技术交易市场有限公司 | Chemical desiccant |
CN104437427B (en) * | 2014-10-31 | 2017-09-22 | 重庆环驰科技有限公司 | Multi-functional cocoanut active charcoal deodorant cream and preparation method thereof |
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