CN106098376A - A kind of vehicles warning lamp - Google Patents
A kind of vehicles warning lamp Download PDFInfo
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- CN106098376A CN106098376A CN201610513590.7A CN201610513590A CN106098376A CN 106098376 A CN106098376 A CN 106098376A CN 201610513590 A CN201610513590 A CN 201610513590A CN 106098376 A CN106098376 A CN 106098376A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0036—Formation of the solid electrolyte layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
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Abstract
The application relates to a kind of vehicles warning lamp, including solar module, switch control module, energy-storage module and light-operated direct-current LED warning lamp module；Described solar module is connected with described energy-storage module, and described switch control module is connected with described energy-storage module, and described light-operated direct-current LED warning lamp module is connected with described energy-storage module；Described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Description
Technical field
The application relates to field of vehicles, particularly relates to a kind of vehicles warning lamp.
Background technology
Vehicles warning lamp is applicable to field of traffic, be used for driver is warned, reminding effect.Existing traffic work
Tool warning lamp typically uses battery operated, is frequently run onto battery and does not has suddenly the situation such as electricity or breaking-up, is just affecting the vehicles
Often use.
It addition, existing solaode is in Rapid development stage, general monocrystaline silicon solar cell opto-electronic conversion is imitated
Rate is higher, but complex process, preparation process pollutes the environment, existing dye-sensitized solar cells is single crystal silicon solar cell
Effective replacement.
Summary of the invention
For overcoming problem present in correlation technique, the application provides a kind of vehicles warning lamp.
The application is achieved through the following technical solutions:
A kind of vehicles warning lamp, including: solar module, switch control module, energy-storage module and light-operated directly
Stream LED warning lamp module；Described solar module is connected with described energy-storage module, described switch control module and described storage
Can module connect, described light-operated direct-current LED warning lamp module is connected with described energy-storage module.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
The technical scheme that embodiments herein provides can include following beneficial effect:
1. the dye-sensitized solar cells in the application vehicles warning lamp, due to conventional dyes sensitization solar battery
Middle employing TiO2 nano-particle is as the carrier of dyestuff, though grain structure has big specific surface area, but due to grain boundary
The existence in face, electronics transmits between particles will be through countless interfaces, and this weakens electronics transfer rate in transmitting procedure；
In the DSSC of the present invention, light anode construction is that direct growth Tungstic anhydride. is three-dimensional on transparent conductive film
Grid nanostructured, it has direct electron transfer pathways, and electronics can be collected on electrode along three-dimensional manometer grid,
Simultaneously because tungsten trioxide nano material belongs to semiconductor material with wide forbidden band, there is high electric conductivity, therefore from structure and material
Aspect all substantially increases the efficiency of transmission of electronics.
2. Tungstic anhydride. three-dimensional grid nanostructured has bigger specific surface area, it is possible to be greatly improved the absorption effect of dyestuff
Rate, dyestuff is optically excited generation electronics, and sufficient dye adsorption amount can produce photon in a large number, increases density of photocurrent, and then
The conversion efficiency of sunlight can be improved.
One layer of Cr metal, its conduct is added between FTO substrate and the tungsten oxide three-dimensional grid nanostructured of the most smooth anode
The transition zone of electronics conduction, it is to avoid contact resistance bigger between nanostructured and substrate, additionally, add in the electrolytic solution
Nano-Ag particles, nano-Ag particles contributes to sunlight scattering in the electrolytic solution, increases the probability that dyestuff absorbs, it is possible to carry
High electricity conversion.
4., in the modified model light anode construction of present invention design, Tungstic anhydride. three-dimensional grid nanostructured uses hydro-thermal legal system
Standby, this preparation method is simple, with low cost, has the potentiality of actual application on a large scale.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
Accompanying drawing herein is merged in description and constitutes the part of this specification, it is shown that meet the enforcement of the present invention
Example, and for explaining the principle of the present invention together with description.
Fig. 1 is herein described vehicles warning lamp structure schematic diagram, wherein, 1-solar module, and 2-switchs
Control module, 3-energy-storage module, 4-light-operated direct-current LED warning lamp module.
Fig. 2 is the flow chart of the manufacture method of dye-sensitized solar cells described in the application vehicles warning lamp.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Following disclosure provides many different embodiments or example for realizing the different structure of the application.For letter
Changing disclosure herein, hereinafter parts and setting to specific examples are described.Certainly, they are the most merely illustrative, and
It is not intended to limit the application.Additionally, the application can in different examples repeat reference numerals and/or letter.This heavy
It is for purposes of simplicity and clarity again, itself is more than the relation between various embodiment being discussed and/or arranging.This
Outward, the various specific technique that this application provides and the example of material, but those of ordinary skill in the art it can be appreciated that
The applicability of other techniques and/or the use of other materials.It addition, fisrt feature described below Second Eigenvalue " on "
Structure can include that the first and second features are formed as the embodiment directly contacted, it is also possible to include that other feature is formed at
Embodiment between first and second features, such first and second features are not likely to be directly contact.
In the description of the present application, it should be noted that unless otherwise prescribed and limit, term " is installed ", " being connected ",
" connect " and should be interpreted broadly, for example, it may be mechanically connected or electrical connection, it is also possible to be the connection of two element internals, can
Being to be joined directly together, it is also possible to be indirectly connected to by intermediary, for the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term.
The energy is the material providing energy to convert to nature, is the material base of mankind's activity.Clean energy resource, also referred to as
Green energy resource, refers to those energy not discharged pollutants, includes water energy, wind energy, solar energy, bioenergy, nuclear energy, underground heat
Can etc., clean energy resource is environmentally friendly, and discharge is few, and pollution level is little.At present, the development and utilization of clean energy resource becomes
The appealing that world is consistent.
Solar energy clean energy resource is that the luminous energy of the sun is converted to the form such as heat energy, electric energy, will not in energy sources conversion
Produce other to pollute.Currently used most be silica-based solar, the efficiency of its opto-electronic conversion is higher, but, silicon purified
Journey can produce environmental pollution, the complex manufacturing technology of silica-based solar cell, expensive.
In the extended family of solaode, DSSC belongs to hybrid inorganic-organic battery, this type electricity
The pond electrolyte by light anode, to electrode and sandwich constitutes class sandwich structure；Wherein, light anode is usually by transparent electrical
The TiO2 nano thin-film on pole and surface thereof is constituted, and this TiO2 nano thin-film is adsorbed with dyestuff, and dyestuff is mainly used to absorb sunlight
Energy；Typically being made up of electrode the catalytic film on electrode and surface thereof, this catalytic film is generally Pt metal.The dye sensitization sun
Can have the advantages such as technology is simple, with low cost by battery.In the research to DSSC, the material of light anode
With structure, the conversion efficiency aspect improving photoelectricity is played a significant role.
Tungsten belongs to transition metal, and Tungstic anhydride. is the highest oxidation state of tungsten, fully meets stoichiometric proportion, three oxidations
Tungsten is a kind of typical wide bandgap semiconductor functional material, the sides such as it is in gas detecting, optical, electrical mutagens color, photocatalysis, electrochemistry
Mask has the performance of excellence.
Below in conjunction with embodiment, the present invention is described further.
Embodiment one:
By Fig. 1, embodiments herein relates to a kind of vehicles warning lamp, including: solar module 1, switch
Control module 2, energy-storage module 3 and light-operated direct-current LED warning lamp module 4；Described solar module 1 and described energy-storage module
3 connect, and described switch control module 2 is connected with described energy-storage module 3, described light-operated direct-current LED warning lamp module 4 and described storage
Can module 3 connect.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module 1 is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, in conjunction with Fig. 2, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
Preferably, in described dye-sensitized solar cells, through Hydrothermal Growth, in FTO substrate, grow one layer of three oxygen
Changing tungsten network, when wherein tungsten hexachloride content is 60mmol, nanometer web thickness is 6 μm.Tungsten oxide nanometer three dimensional structure
In hollow network-like, wherein, a diameter of 40nm of network, hiding a large amount of dye molecule can be adsorbed in centre, dye adsorption
Amount is 0.189 × 10-6mol/cm2.
Dye cell structure of the present invention is carried out opto-electronic conversion test, and test condition is AM1.5 optical power density 100mW/
Cm2, test finds, short circuit current is 15.4mA/cm2, and open-circuit voltage is 0.6V, and photoelectric transformation efficiency reaches 9.4%.Resisting fatigue
Test, in the case of follow-on test 1000h, photoelectric transformation efficiency compares and have dropped 3.1%, better working stability.
By test, the vehicles warning lamp of the present invention, preparation process is simple, and anti-fatigue ability is strong, and opto-electronic conversion is imitated
Rate is higher, possesses certain actual application potential.
Embodiment two:
By Fig. 1, embodiments herein relates to a kind of vehicles warning lamp, including: solar module 1, switch
Control module 2, energy-storage module 3 and light-operated direct-current LED warning lamp module 4；Described solar module 1 and described energy-storage module
3 connect, and described switch control module 2 is connected with described energy-storage module 3, described light-operated direct-current LED warning lamp module 4 and described storage
Can module 3 connect.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module 1 is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, in conjunction with Fig. 2, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
Preferably, in described dye-sensitized solar cells, through Hydrothermal Growth, in FTO substrate, grow one layer of three oxygen
Changing tungsten network, when wherein tungsten hexachloride content is 50mmol, nanometer web thickness is 5 μm.Tungsten oxide nanometer three dimensional structure
In hollow network-like, wherein, a diameter of 40nm of network, hiding a large amount of dye molecule can be adsorbed in centre, dye adsorption
Amount is 0.189 × 10-6mol/cm2.
Dye cell structure of the present invention is carried out opto-electronic conversion test, and test condition is AM1.5 optical power density 100mW/
Cm2, test finds, short circuit current is 15.4mA/cm2, and open-circuit voltage is 0.6V, and photoelectric transformation efficiency reaches 8.3%.Resisting fatigue
Test, in the case of follow-on test 1000h, photoelectric transformation efficiency compares and have dropped 3.5%, better working stability.
By test, the vehicles warning lamp of the present invention, preparation process is simple, and anti-fatigue ability is strong, and opto-electronic conversion is imitated
Rate is higher, possesses certain actual application potential.
Embodiment three:
By Fig. 1, embodiments herein relates to a kind of vehicles warning lamp, including: solar module 1, switch
Control module 2, energy-storage module 3 and light-operated direct-current LED warning lamp module 4；Described solar module 1 and described energy-storage module
3 connect, and described switch control module 2 is connected with described energy-storage module 3, described light-operated direct-current LED warning lamp module 4 and described storage
Can module 3 connect.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module 1 is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, in conjunction with Fig. 2, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
Preferably, in described dye-sensitized solar cells, through Hydrothermal Growth, in FTO substrate, grow one layer of three oxygen
Changing tungsten network, when wherein tungsten hexachloride content is 70mmol, nanometer web thickness is 7 μm.Tungsten oxide nanometer three dimensional structure
In hollow network-like, wherein, a diameter of 40nm of network, hiding a large amount of dye molecule can be adsorbed in centre, dye adsorption
Amount is 0.189 × 10-6mol/cm2.
Dye cell structure of the present invention is carried out opto-electronic conversion test, and test condition is AM1.5 optical power density 100mW/
Cm2, test finds, short circuit current is 15.4mA/cm2, and open-circuit voltage is 0.6V, and photoelectric transformation efficiency reaches 7.8%.Resisting fatigue
Test, in the case of follow-on test 1000h, photoelectric transformation efficiency compares and have dropped 5.1%, better working stability.
By test, the vehicles warning lamp of the present invention, preparation process is simple, and anti-fatigue ability is strong, and opto-electronic conversion is imitated
Rate is higher, possesses certain actual application potential.
Embodiment four:
By Fig. 1, embodiments herein relates to a kind of vehicles warning lamp, including: solar module 1, switch
Control module 2, energy-storage module 3 and light-operated direct-current LED warning lamp module 4；Described solar module 1 and described energy-storage module
3 connect, and described switch control module 2 is connected with described energy-storage module 3, described light-operated direct-current LED warning lamp module 4 and described storage
Can module 3 connect.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module 1 is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, in conjunction with Fig. 2, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
Preferably, in described dye-sensitized solar cells,
Through Hydrothermal Growth, in FTO substrate, grow one layer of Tungstic anhydride. network, wherein tungsten hexachloride content
During for 90mmol, nanometer web thickness is 10 μm.Tungsten oxide nanometer three dimensional structure is hollow network-like, wherein, and network
A diameter of 40nm, centre can adsorb hiding a large amount of dye molecule, and dye adsorption amount is 0.189 × 10-6mol/cm2.
Dye cell structure of the present invention is carried out opto-electronic conversion test, and test condition is AM1.5 optical power density 100mW/
Cm2, test finds, short circuit current is 15.4mA/cm2, and open-circuit voltage is 0.6V, and photoelectric transformation efficiency reaches 7.3%.Resisting fatigue
Test, in the case of follow-on test 1000h, photoelectric transformation efficiency compares and have dropped 3.1%, better working stability.
By test, the vehicles warning lamp of the present invention, preparation process is simple, and anti-fatigue ability is strong, and opto-electronic conversion is imitated
Rate is higher, possesses certain actual application potential.
Embodiment five:
By Fig. 1, embodiments herein relates to a kind of vehicles warning lamp, including: solar module 1, switch
Control module 2, energy-storage module 3 and light-operated direct-current LED warning lamp module 4；Described solar module 1 and described energy-storage module
3 connect, and described switch control module 2 is connected with described energy-storage module 3, described light-operated direct-current LED warning lamp module 4 and described storage
Can module 3 connect.
Preferably, described vehicles warning lamp can carry out free installation settings according to specific requirement, use environment.
Preferably, described solar module 1 is based on dye-sensitized solar cells.
Preferably, described dye-sensitized solar cells is by light anode, constitute electrode and electrolyte；Described smooth anode is by outward
FTO substrate, transition zone, Tungstic anhydride. Seed Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule it is followed successively by and；Institute
Stating transition zone is Cr film transition zone；Described Tungstic anhydride. seed layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nano junction
Structure uses hydro-thermal method to prepare.
Preferably, in conjunction with Fig. 2, the preparation process of described dye-sensitized solar cells is as follows:
S1, prepares light anode
A) FTO substrate is cleaned: FTO conductive glass surface can exist greasy dirt, dust etc. and pollute, and first takes certain size
The FTO electro-conductive glass of (10cm × 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses
Deionized water rinses for several times repeatedly, until being cleaned up by liquid detergent, then, FTO electro-conductive glass is sequentially placed into acetone, second
In alcohol, deionized water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, as Tungstic anhydride.
Three dimensional network structure and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and the anhydrous second of 100ml
Alcoholic solution, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into 80 DEG C of oil baths
Middle magnetic agitation 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered seed molten
In liquid, standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO of pull-out
Electro-conductive glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h, wherein temperature-rise periods in Muffle furnace
Middle heating rate is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: prepare and contain tungsten hexachloride, 30mmol sodium tungstate, 45mmol's
The deionized water mixed solution of hexamethylenetetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to height
In pressure still inner bag；Take and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface court
Lower placement, after sealing, puts in the baking oven being warmed up to 95 DEG C by autoclave, reacts 24h, is naturally down to room after reaction completely
Temperature, takes out FTO electro-conductive glass, uses deionized water rinsing 30s, obtains growing the light sun having Tungstic anhydride. three-dimensional grid nanostructured
Pole；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, adds wherein
Enter the lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge,
It is made fully to dissolve；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve,
Lucifuge stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid
The light anode of nanostructured enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then will be with Pt Catalytic Layer
Same size FTO electro-conductive glass be packaged together with this light anode, encapsulating material use heat-sealing film, by electrolyte to electrode
The aperture of one end injects, and encapsulates aperture, connects wire, forms the modified model DSSC of the present invention.
Preferably, in described dye-sensitized solar cells, through Hydrothermal Growth, in FTO substrate, grow one layer of three oxygen
Changing tungsten network, when wherein tungsten hexachloride content is 120mmol, nanometer web thickness is 15 μm.Tungsten oxide nanometer three-dimensional is tied
Structure is hollow network-like, and wherein, a diameter of 40nm of network, hiding a large amount of dye molecule, dyestuff suction can be adsorbed in centre
Attached amount is 0.189 × 10-6mol/cm2.
Dye cell structure of the present invention is carried out opto-electronic conversion test, and test condition is AM1.5 optical power density 100mW/
Cm2, test finds, short circuit current is 15.4mA/cm2, and open-circuit voltage is 0.6V, and photoelectric transformation efficiency reaches 6.5%.Resisting fatigue
Test, in the case of follow-on test 1000h, photoelectric transformation efficiency compares and have dropped 3.1%, better working stability.
By test, the vehicles warning lamp of the present invention, preparation process is simple, and anti-fatigue ability is strong, and opto-electronic conversion is imitated
Rate is higher, possesses certain actual application potential.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (5)
1. a vehicles warning lamp, it is characterised in that including: solar module, switch control module, energy-storage module
With light-operated direct-current LED warning lamp module；Described solar module is connected with described energy-storage module, described switch control module
Being connected with described energy-storage module, described light-operated direct-current LED warning lamp module is connected with described energy-storage module.
Vehicles warning lamp the most according to claim 1, it is characterised in that described vehicles warning lamp can be according to tool
Body requires, uses environment to carry out free installation settings.
Solar module the most according to claim 1, it is characterised in that described solar module is based on dyestuff
Sensitization solar cell.
Dye-sensitized solar cells the most according to claim 3, it is characterised in that described dye-sensitized solar cells is by light
Anode, electrode and electrolyte are constituted；Described smooth anode is followed successively by FTO substrate, transition zone, Tungstic anhydride. seed from outside to inside
Layer, Tungstic anhydride. three-dimensional grid nanostructured and dye molecule；Described transition zone is Cr film transition zone；Described Tungstic anhydride. seed
Layer thickness is 50nm；Described Tungstic anhydride. three-dimensional grid nanostructured uses hydro-thermal method to prepare.
Dye-sensitized solar cells the most according to claim 4, it is characterised in that the system of described dye-sensitized solar cells
Standby process is as follows:
S1, prepares light anode
A) clean FTO substrate: FTO conductive glass surface can exist greasy dirt, dust etc. pollute, first take certain size (10cm ×
FTO electro-conductive glass 10cm), puts into its conducting surface upward in liquid detergent solution, ultrasonic cleaning 30min, then uses deionization
Water rinses for several times repeatedly, until liquid detergent is cleaned up, then, FTO electro-conductive glass is sequentially placed into acetone, ethanol, go from
In sub-water, difference ultrasonic cleaning 20min, dries up stand-by by nitrogen gun；
B) transition zone is prepared: the one layer of Cr film of FTO conductive glass surface magnetron sputtering after cleaned, three-dimensional as Tungstic anhydride.
Network and the transition zone of FTO electro-conductive glass, Cr film thickness is 50nm；
C) Tungstic anhydride. Seed Layer is prepared: take the sodium tungstate of 0.1mol, the diethanolamine of 0.06mol and 100ml dehydrated alcohol molten
Liquid, puts it in beaker, in room temperature magnetic agitation 30min so that it is be sufficiently mixed, then beaker is put into magnetic in 80 DEG C of oil baths
Power stirring 6h, obtains seed solution；Take cleaned in step one after FTO electro-conductive glass, slowly entered in seed solution,
Standing 3min, the most slowly pull-out FTO electro-conductive glass, keeping pull-out speed is 0.05cm/s, subsequently by the FTO conduction glass of pull-out
Glass is put in baking oven and is dried, and FTO electro-conductive glass is finally put into 300 DEG C of annealing 5h in Muffle furnace, wherein heats up in temperature-rise period
Speed is 5 DEG C/min；
D) growth Tungstic anhydride. three-dimensional grid nanostructured: preparation is containing tungsten hexachloride, 30mmol sodium tungstate, six times of 45mmol
The deionized water mixed solution of tetramine and 200ml, is added dropwise over 5ml ammonia and stirs, transferring it to autoclave
In inner bag；Taking and be covered with the FTO electro-conductive glass of tungsten oxide Seed Layer and tilt to lean against in the solution of autoclave inner bag, conducting surface is towards transferring
Put, after sealing, autoclave put in the baking oven being warmed up to 95 DEG C, react 24h, after reaction completely, be naturally down to room temperature,
Take out FTO electro-conductive glass, use deionized water rinsing 30s, obtain growing the light anode having Tungstic anhydride. three-dimensional grid nanostructured；
S2, preparation electrolyte and dyestuff:
Iodine/iodine three anion electrolyte that electrolyte application is traditional, first weighs the acetonitrile solution of 100ml, is added thereto to
The lithium iodide of 0.1M, 0.1M iodine, 0.6M 4-tert .-butylpyridine and the tetrabutylammonium iodide of 0.6M, the ultrasonic 5min of lucifuge, make
It fully dissolves；Then weigh the nano silver particles of 5g, be added in mixed solution, be sufficiently mixed；
Dye solution: weigh N719 powder 50mg, dehydrated alcohol 30ml, N719 is added in dehydrated alcohol, fully dissolve, lucifuge
Stirring 12h；
S3, encapsulation:
Take the dye solution of preparation in step S2 and put in brown glass ware, then growth is had Tungstic anhydride. three-dimensional grid nanometer
The light anode of structure enters in this brown glass ware, and lucifuge is sensitization 3h at 60 DEG C, takes out, then by the phase with Pt Catalytic Layer
Being packaged together with this light anode with size FTO electro-conductive glass, encapsulating material uses heat-sealing film, by electrolyte to electrode one end
Aperture inject, encapsulate aperture, connect wire, formed the present invention modified model DSSC.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916699A (en) * | 1997-05-13 | 1999-06-29 | Motorola, Inc. | Hybrid energy storage system |
| WO2010099858A2 (en) * | 2009-03-03 | 2010-09-10 | Karlsruher Institut Für Technologie (Kit) | Thin film solar cells |
| CN203882393U (en) * | 2014-06-19 | 2014-10-15 | 天津永明新能源科技有限公司 | Transportation means alarm lamp based on solar energy technology |
| CN104465102A (en) * | 2014-12-29 | 2015-03-25 | 中南大学 | Dye-sensitized solar cell photo-anode and preparing method and application thereof |
| CN204328842U (en) * | 2014-12-29 | 2015-05-13 | 黄登峰 | A kind of novel traffic warning lamp |
-
2016
- 2016-06-28 CN CN201610513590.7A patent/CN106098376B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916699A (en) * | 1997-05-13 | 1999-06-29 | Motorola, Inc. | Hybrid energy storage system |
| WO2010099858A2 (en) * | 2009-03-03 | 2010-09-10 | Karlsruher Institut Für Technologie (Kit) | Thin film solar cells |
| CN203882393U (en) * | 2014-06-19 | 2014-10-15 | 天津永明新能源科技有限公司 | Transportation means alarm lamp based on solar energy technology |
| CN104465102A (en) * | 2014-12-29 | 2015-03-25 | 中南大学 | Dye-sensitized solar cell photo-anode and preparing method and application thereof |
| CN204328842U (en) * | 2014-12-29 | 2015-05-13 | 黄登峰 | A kind of novel traffic warning lamp |
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