CN106092960A - A kind of quick correction near infrared gear also detects the method for chemical composition in agricultural product - Google Patents

A kind of quick correction near infrared gear also detects the method for chemical composition in agricultural product Download PDF

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Publication number
CN106092960A
CN106092960A CN201610604333.4A CN201610604333A CN106092960A CN 106092960 A CN106092960 A CN 106092960A CN 201610604333 A CN201610604333 A CN 201610604333A CN 106092960 A CN106092960 A CN 106092960A
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CN
China
Prior art keywords
near infrared
agricultural product
data
verification
standard
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Pending
Application number
CN201610604333.4A
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Chinese (zh)
Inventor
朱湘飞
刘毅
刘法安
谭占鳌
陈剑
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Shenzhen Batian Ecotypic Engineering Co Ltd
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Shenzhen Batian Ecotypic Engineering Co Ltd
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Priority to CN201610604333.4A priority Critical patent/CN106092960A/en
Publication of CN106092960A publication Critical patent/CN106092960A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • G01N21/274Calibration, base line adjustment, drift correction
    • G01N21/278Constitution of standards

Abstract

The present invention relates to a kind of quick correction near infrared spectrum detection equipment and detect the method for chemical composition in agricultural product, the method standard near infrared detection equipment carries out near-infrared data acquisition to agricultural product standard sample, chemically detect the chemical composition data of agricultural product standard sample, according to standard near infrared spectrum data storehouse and standard chemical compositional data storehouse Criterion mapping model;Gather the near infrared spectrum data of agricultural product verification sample with the actual near infrared detection equipment of detection agricultural product and chemically detect the chemical composition data of agricultural product verification sample, comparing with Standard Map model and obtain verification mapping model, the near infrared spectrum data of fresh sample obtains chemical composition data by verification mapping model.By verification mapping model, solve place the most relatively far apart and use new near infrared detection equipment quickly to check the chemical composition data the most quickly detecting agricultural product.

Description

A kind of quick correction near infrared gear also detects the method for chemical composition in agricultural product
Technical field
The invention belongs to detection of agricultural products field, particularly relate to a kind of quickly correction near infrared spectrum detection equipment and detect The method of chemical composition in agricultural product.
Background technology
The method quickly being detected agricultural production chemical composition by near-infrared increasingly obtains researcher and agricultural production consumer Concern, the differentiation of the most the most key is near infrared detection equipment causes the inaccurate of testing result, often occurs a kind of new Detection unit type all can cause the situation that data with existing storehouse is difficult by, there is presently no preferable solution.
The patent of Publication No. CN102305772A disclose a kind of for food and quality of agricultural product detect based on something lost Pass the characteristic wavelength of near-infrared spectrum screening technique of kernel partial least squares, utilize physico-chemical analysis method to measure all samples to be tested Concentration of component value to be measured after divide calibration set and the forecast set of sample;Utilize genetic algorithm to pretreated calibration set spectrum Data point carries out global search, according to validation-cross root-mean-square error value minimum in kernel partial least squares interactive verification process Determine the final characteristic variable number participating in modeling, and characteristic variable genetic algorithm screened reformulates new data Matrix is as the input of model;Using the calibration set sample concentration of component to be measured matrix that records as the standard output of model, set up Optimal correction analysis model.
The patent of Publication No. CN102879353A discloses and a kind of detects the method for content of protein components in Semen arachidis hypogaeae, bag Include 1) the Standard for Peanuts product of known content of protein components are carried out near infrared spectrum scanning, it is thus achieved that described known protein component The Standard for Peanuts product of content, at all spectral informations of near-infrared wavelength, obtain the calculating meansigma methods of calibration set sample spectrum;2) To described step 1) gained calibration set sample spectrum carries out pretreatment;3) by described step 2) pretreated calibration set sample light Information data in spectrum carries out principal component analysis, characteristic information extraction data;4) with the protein component of described Standard for Peanuts product The chemical measurements of content is corrected value, using described step 3) gained characteristic information data is as independent variable, and described corrected value is made For dependent variable, set up the calibration model between described independent variable and described dependent variable with Chemical Measurement Multivariate Correction algorithm;5) By described step 1) the Standard for Peanuts product of described known content of protein components replace with peanut sample to be measured, repeating said steps 1) to step 3), by described step 3) gained characteristic information data input described step 4) calibration model, obtain described to be measured Content of protein components in peanut sample.
The patent of Publication No. CN101907564A discloses the near infrared spectrum quickly side of detection of a kind of rapeseed quality Method: first take different in moisture and fat the some parts of Semen Brassicae campestris sample, a part as calibration set, another part as forecast set, Remainder is as testing sample, and the water content of employing National Standard Method mensuration all samples and fat content are as measured value;Use again Near infrared detection instrument acquisition correction collection sample of the present invention, forecast set sample and the spectrum information that diffuses of testing sample, use school Relation between the spectroscopic data just collected and its water content and fat content measured value sets up calibration model;By the spectrum number of forecast set Be predicted according to being brought in calibration model, obtain the sample moisture content of forecast set and fat content predict the outcome and analyze with The difference of its measured value, chooses precision of prediction and reaches the calibration model of requirement;Finally model parameter is imported in microprocessor, The spectral information of testing sample is called in the calibration model chosen simultaneously, testing sample water content and fat content are counted Calculating, the water content obtained and fat content predictive value are testing sample water content and determination of fat result.
But the method for being capable of quickly detecting in prior art does not the most solve different detecting instrument to be caused There is the problem that data base is difficult by, it is impossible to realize utilizing new instrument that sample is used for quickly detecting.
Summary of the invention
For solving above-mentioned technical problem, the invention provides a kind of quickly correction near infrared spectrum detection equipment and detect agriculture The method of chemical composition in product, it is characterised in that the method comprises the steps:
Step A: with standard near infrared detection equipment, n agricultural product standard sample is carried out near-infrared data acquisition, obtain Standard near infrared spectrum data storehouse;
Step B: the chemically chemical composition data of n agricultural product standard sample in detecting step A, forms standard Chemical composition data storehouse;
Step C: set up according to the standard near infrared spectrum data storehouse of step A and the standard chemical compositional data storehouse of step B Standard Map model;
Step D: gather the near infrared light of m agricultural product verification sample with the actual near infrared detection equipment of detection agricultural product Modal data, forms verification near infrared spectrum data storehouse;
Step E: the chemically chemical composition data of m agricultural product verification sample in detecting step D, forms verification Chemical composition data storehouse;
Step F: verification near infrared spectrum data storehouse and verification chemical composition data storehouse are compared with Standard Map model Right, it is thus achieved that the near infrared spectrum that actual near infrared detection equipment is gathered and the verification mapping model of chemical composition relation;
Step G: gather the near infrared spectrum data of agricultural product fresh sample with actual near infrared detection equipment, reflected by verification Penetrate model and be calculated the chemical composition data of agricultural product fresh sample;
Wherein the agricultural product in step A, step D and step G belong to same on botany;
Wherein n and m is integer, and n > 50 > m > 5.
Preferably, in said method, standard near infrared detection equipment is stable full spectral coverage infrared spectrum instrument.
Preferably, in said method, actual near infrared detection equipment is continuous portable infrared spectrograph, single-point type hands Hold the spectral measuring devices of spectrogrph or other forms.
Preferably, in said method, Standard Map model and verification mapping model can apply appointing of data construct model Meaning method builds, and is constantly verified by standard chemical compositional data and verification chemical composition data in building process, Finally realize Standard Map model and verification mapping model is capable of actual near infrared detection equipment and standard near infrared detection At the relatively accurate corresponding relation calculated between chemical composition content between equipment.
Preferably, in said method, agricultural product are veterinary antibiotics or grain etc., and agricultural product can also replace with food and exist Said method is detected.
Present invention also offers a kind of quick correction near infrared spectrum detection equipment and detect chemical composition in agricultural product System, it is characterised in that this system includes data input pin, Cloud Server and data output end, it is characterised in that data input pin Having standardized agricultural products near infrared spectrum data input interface and standardized agricultural products chemical data input interface, same data input End or another data database also have verification near infrared spectrum data input structure and verification chemistry agricultural product data input knot Structure, Cloud Server includes Standard Map model and verification mapping model, and data output end has agricultural product chemical data outfan Mouthful, data input pin is bi-directionally connected with Cloud Server, and Cloud Server is connected with data output end.
Beneficial effect:
1, the Standard Map model of specific agricultural product is set up, then in conjunction with the near infrared spectrum of other near infrared detection instruments Data and chemical composition data set up verification mapping model, it is possible to realize quickly correcting and fast new near infrared detection equipment Speed detection chemical composition.
2, by verification mapping model, solve place the most relatively far apart and use new near infrared detection equipment fast Speed inspection the most quickly detects the chemical composition data of agricultural product.
3, standard near infrared spectrum detection equipment and actual near infrared spectrum detection equipment can arbitrarily select, the most in fact Border near infrared detection equipment, in the case of needs quickly detection agricultural product chemical composition, it is thus only necessary to the chemistry of a small amount of sample Detection can be realized as the rapid verification of new equipment and comes into operation.
4, Standard Map model is embedded in high in the clouds, verification spectra database and verification chemical composition data storehouse and is transferred to high in the clouds After, it becomes possible to realize setting up new verification mapping model, then the near infrared spectrum data that actual sample detects is transferred to verification Mapping model can obtain the chemical composition data of sample.
Accompanying drawing explanation
Fig. 1 is that block diagram set up by Standard Map model;
Fig. 2 sets up block diagram for verification mapping model;
Fig. 3 is that actual sample chemical composition detects block diagram.
Detailed description of the invention
Embodiment 1
Step A: with stable full spectral coverage infrared spectrum instrument (as standard near infrared detection equipment) to 150 Fructus Cucumidis sativi marks Quasi-sample carries out near-infrared data acquisition, obtains Fructus Cucumidis sativi standard near infrared spectrum data storehouse;
Step B: the chemically chemical composition data of 150 Fructus Cucumidis sativi standard sample in detecting step A, forms Fructus Cucumidis sativi Standard chemical compositional data storehouse;
Step C: according to Fructus Cucumidis sativi standard near infrared spectrum data storehouse and the Fructus Cucumidis sativi standard chemical component number of step B of step A Fructus Cucumidis sativi Standard Map model is set up according to storehouse;
Step D: gather 20 with the hand-held spectrogrph of single-point type (as the actual near infrared detection equipment of detection agricultural product) The near infrared spectrum data of Fructus Cucumidis sativi verification sample, forms Fructus Cucumidis sativi verification near infrared spectrum data storehouse;
Step E: the chemically chemical composition data of 20 Fructus Cucumidis sativi verification samples in detecting step D, forms Fructus Cucumidis sativi Verification chemical composition data storehouse;
Step F: Fructus Cucumidis sativi is verified near infrared spectrum data storehouse and Fructus Cucumidis sativi verification chemical composition data storehouse and reflects with Fructus Cucumidis sativi standard Penetrate model to compare, it is thus achieved that verification mapping model;
Step G: by the near infrared spectrum data of single-point type hand-held spectrometer collection Fructus Cucumidis sativi fresh sample, map mould by verification Type is calculated the chemical composition data of Fructus Cucumidis sativi fresh sample.
Embodiment 2
Step A: with stable full spectral coverage infrared spectrum instrument (as standard near infrared detection equipment) to 120 Fructus Lycopersici esculenti Standard sample carries out near-infrared data acquisition, obtains Fructus Lycopersici esculenti standard near infrared spectrum data storehouse;
Step B: the chemically chemical composition data of 120 Fructus Lycopersici esculenti standard sample in detecting step A, forms west Red Fructus Kaki standard chemical compositional data storehouse;
Step C: study according to the Fructus Lycopersici esculenti standard near infrared spectrum data storehouse of step A and the Fructus Lycopersici esculenti standardization of step B Fructus Lycopersici esculenti Standard Map model is set up in divided data storehouse;
Step D: adopt with continuous portable infrared spectrograph (as the actual near infrared detection equipment of detection agricultural product) Collect the near infrared spectrum data of 10 Fructus Lycopersici esculenti verification samples, form Fructus Lycopersici esculenti verification near infrared spectrum data storehouse;
Step E: the chemically chemical composition data of 10 Fructus Lycopersici esculenti verification samples in detecting step D, forms west Red Fructus Kaki verification chemical composition data storehouse;
Step F: Fructus Lycopersici esculenti is verified near infrared spectrum data storehouse and Fructus Lycopersici esculenti verification chemical composition data storehouse and Fructus Lycopersici esculenti Standard Map model is compared, it is thus achieved that verification mapping model;
Step G: gather the near infrared spectrum data of Fructus Lycopersici esculenti fresh sample with continuous portable infrared spectrograph, by school Test mapping model and be calculated the chemical composition data of Fructus Lycopersici esculenti fresh sample.

Claims (5)

1. a quick correction near infrared spectrum detects equipment and detects the method for chemical composition in agricultural product, it is characterised in that should Method comprises the steps:
Step A: with standard near infrared detection equipment, n agricultural product standard sample is carried out near-infrared data acquisition, obtain standard Near infrared spectrum data storehouse;
Step B: the chemically chemical composition data of n agricultural product standard sample in detecting step A, forms standard chemical Compositional data storehouse;
Step C: according to standard near infrared spectrum data storehouse and the standard chemical compositional data storehouse Criterion of step B of step A Mapping model;
Step D: gather the near infrared spectrum number of m agricultural product verification sample with the actual near infrared detection equipment of detection agricultural product According to, form verification near infrared spectrum data storehouse;
Step E: the chemically chemical composition data of m agricultural product verification sample in detecting step D, forms verification chemistry Compositional data storehouse;
Step F: compared with Standard Map model in verification near infrared spectrum data storehouse and verification chemical composition data storehouse, obtain Obtain near infrared spectrum and the verification mapping model of chemical composition relation that actual near infrared detection equipment is gathered;
Step G: gather the near infrared spectrum data of agricultural product fresh sample with actual near infrared detection equipment, maps mould by verification Type is calculated the chemical composition data of agricultural product fresh sample;
Wherein the agricultural product in step A, step D and step G belong to same on botany;
Wherein n and m is integer, and n > 50 > m > 5.
Method the most according to claim 1, its Plays near infrared detection equipment is stable full spectral coverage infrared spectrometer Device.
Method the most according to claim 1, actual near infrared detection equipment be continuous portable infrared spectrograph, The hand-held spectrogrph of single-point type or the spectral measuring devices of other forms.
Method the most according to claim 1, wherein agricultural product are veterinary antibiotics or grain.
5. a quick correction near infrared spectrum detects equipment and detects the system of chemical composition in agricultural product, it is characterised in that should System includes data input pin, Cloud Server and data output end, it is characterised in that it is near that data input pin has standardized agricultural products Ir data input interface and standardized agricultural products chemical data input interface, same data input pin or another Data Data Storehouse also has verification near infrared spectrum data input structure and verification chemistry agricultural product data input structure, and Cloud Server includes mark Quasi-mapping model and verification mapping model, data output end has agricultural product chemical data output port, data input pin and cloud Server is bi-directionally connected, and Cloud Server is connected with data output end.
CN201610604333.4A 2016-07-28 2016-07-28 A kind of quick correction near infrared gear also detects the method for chemical composition in agricultural product Pending CN106092960A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106872397A (en) * 2016-12-29 2017-06-20 深圳市芭田生态工程股份有限公司 A kind of method based on existing calibration model quick detection agricultural product chemical constituent
CN106970042A (en) * 2017-04-12 2017-07-21 防城港出入境检验检疫局综合技术服务中心(广西国际旅行卫生保健中心防城港分中心) A kind of carragheen impurity, moisture detection method

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CN102103079A (en) * 2010-12-31 2011-06-22 聚光科技(杭州)股份有限公司 Spectrum analysis method
US8119991B2 (en) * 2004-08-11 2012-02-21 Jordan Valley Semiconductors Ltd. Method and apparatus for accurate calibration of VUV reflectometer
CN105699304A (en) * 2016-01-28 2016-06-22 深圳市芭田生态工程股份有限公司 Method for acquiring matter information represented by spectral information

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Publication number Priority date Publication date Assignee Title
US8119991B2 (en) * 2004-08-11 2012-02-21 Jordan Valley Semiconductors Ltd. Method and apparatus for accurate calibration of VUV reflectometer
CN101865828A (en) * 2010-05-31 2010-10-20 湖南大学 Method for maintaining predication capability of spectrum correction model of complex system
CN102103079A (en) * 2010-12-31 2011-06-22 聚光科技(杭州)股份有限公司 Spectrum analysis method
CN105699304A (en) * 2016-01-28 2016-06-22 深圳市芭田生态工程股份有限公司 Method for acquiring matter information represented by spectral information

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106872397A (en) * 2016-12-29 2017-06-20 深圳市芭田生态工程股份有限公司 A kind of method based on existing calibration model quick detection agricultural product chemical constituent
CN106970042A (en) * 2017-04-12 2017-07-21 防城港出入境检验检疫局综合技术服务中心(广西国际旅行卫生保健中心防城港分中心) A kind of carragheen impurity, moisture detection method
CN106970042B (en) * 2017-04-12 2020-07-28 防城港出入境检验检疫局综合技术服务中心(广西国际旅行卫生保健中心防城港分中心) Method for detecting impurity and moisture content of carrageenin

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Application publication date: 20161109