CN106087421B - Soil-releasing finishing agent and its preparation method and application - Google Patents
Soil-releasing finishing agent and its preparation method and application Download PDFInfo
- Publication number
- CN106087421B CN106087421B CN201610444324.3A CN201610444324A CN106087421B CN 106087421 B CN106087421 B CN 106087421B CN 201610444324 A CN201610444324 A CN 201610444324A CN 106087421 B CN106087421 B CN 106087421B
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- China
- Prior art keywords
- soil
- parts
- finishing agent
- releasing finishing
- acid
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- Expired - Fee Related
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 40
- 239000002689 soil Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000002148 esters Chemical class 0.000 claims abstract description 24
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 23
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims description 29
- 239000004753 textile Substances 0.000 claims description 24
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 21
- 235000011090 malic acid Nutrition 0.000 claims description 21
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 20
- 239000001630 malic acid Substances 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 16
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- -1 silicane alkane Chemical class 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 3
- 230000000740 bleeding effect Effects 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 239000003921 oil Substances 0.000 description 20
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 11
- 235000004883 caffeic acid Nutrition 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- FXMBKAAULHJRKL-UHFFFAOYSA-N [amino(dimethoxy)silyl]oxymethane Chemical compound CO[Si](N)(OC)OC FXMBKAAULHJRKL-UHFFFAOYSA-N 0.000 description 9
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 description 4
- 108010059892 Cellulase Proteins 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 229940074360 caffeic acid Drugs 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000011032 tourmaline Substances 0.000 description 3
- 229940070527 tourmaline Drugs 0.000 description 3
- 229910052613 tourmaline Inorganic materials 0.000 description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
- D06B23/22—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for heating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of soil-releasing finishing agents, include the component of following parts by weight：20 ~ 30 parts of esters of acrylic acid, 10 ~ 20 parts of organosilicon containing double bond, 5 ~ 10 parts of active organic acid, 1 ~ 3 part of silane coupling agent, 3 ~ 5 parts of dispersant.The soil-releasing finishing agent prepared through the application is widely portable to every field, of low cost, has higher activity, and clean effect is splendid.
Description
Technical field
The present invention relates to the afterfinish method of textile, more particularly to a kind of soil-releasing finishing agent and preparation method thereof and should
With.
Background technology
Young parents have such worry mostly：When being taken every time to child's laundry, oil stain, spot on clothes need
Will be after oil stain, spot to place the surfactants such as more liquid detergents and are subject to cautious rubbing, oil stain, spot are
It can be cleaned, in special circumstances, remain to see sharp trace；The rag of household wiping kitchen tools, dining table, uses a period of time
Afterwards, it may appear that the greasy feeling on rag significantly increases, and needs to be replaced frequently, and causes the waste of cost；In some special dimensions, than
In oil recovery, drilling well, oil refining industry, a large amount of oil stain is inevitably rubbed in the tooling of workpeople, so, research and development are fuel-displaced
The soil-releasing finishing agent that stain is easily washed becomes scholars at this stage and is keen to one of subject of research and development.
At present, it is easy that the Chinese patent that application publication number is CN105603747A in existing patent discloses a kind of novel hydrophilic
Soil release finishing agent and preparation method thereof uses esters of acrylic acid as base-material, water-soluble silicon oil, carboxymethyl cellulose and Tourmaline powder
Etc. being prepared, through the soil release finishing agent treated fabric easy-detergency significant effect, still, Tourmaline powder is by ore mostly
Particle or fiber tourmaline be prepared, mostly with heavier color and luster, make the use of the soil release finishing agent there is limitation
Property；The Wu Ying Zhe of Institutes Of Technology Of Zhejiang is had studied using influence of the cellulase washing to raising polyester-cotton fabric soil release performance, is ground
The color and luster of fabric will not be impacted by studying carefully the technique for showing to handle through cellulase, and wash after fabric decontaminating effect compared with
Good, still, cellulase needs are extracted from cellulose, and extraction cost is higher, and washing times are more, the usage amount of cellulase
It is bigger, caused by cost it is higher.
Invention content
The object of the present invention is to provide a kind of soil-releasing finishing agents of low cost, applicability is extensive and clean effect is good.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of soil-releasing finishing agent includes the component of following parts by weight：
By using above-mentioned technical proposal, esters of acrylic acid has excellent weatherability, film forming and caking property, but it is deposited
Water resistance, penetrability and resistance to soiling are poor the shortcomings of；Active organic acid is a kind of active and acid organic compound, will
Esters of acrylic acid is mixed with active organic acid, and esters of acrylic acid surface is made to have higher activity, is contributed to and other components
The reaction was continued；Organosilicon containing double bond has stronger activity, is chemically reacted with esters of acrylic acid, the main polymer chain of generation
In containing Si-O-Si keys, Si-C keys, Si-O keys, their bond energy is much larger than the bond energy of C-O keys, the compliance, excellent with height
Different high and low temperature resistance, weatherability, water resistance and good gas permeability substantially increases the solvent resistant of esters of acrylic acid
Property, high and low temperature resistance, durability in oxidative degradation energy, while the surface for having pure propylene acid esters concurrently can low, hydrophobic, pollution resistance and electricity
The good characteristics such as insulating properties and elasticity efficiently solve the disadvantage that existing rigidity when acrylate film and Ludox film
By force, glossiness is low, is easily cracked, the defects of low temperature drying is rapid, and the two can reach the mutual supplement with each other's advantages in performance；Acrylate
Class, organic acid and organosilicon containing double bond dispersant, silane coupling agent collective effect under the soil-releasing finishing agent that generates be nothing
Color or light-coloured transparent shape liquid are widely portable to every field, and used raw material price is cheap, suitable for giving birth on a large scale
Production, and the soil-releasing finishing agent prepared, coated in textile surface after textile surface, is made to have higher activity, decontamination is imitated
Fruit is splendid.
The present invention is further arranged to：The esters of acrylic acid selects methyl acrylate, ethyl acrylate and metering system
One kind in sour hydroxyl ethyl ester.
By using above-mentioned technical proposal, methyl acrylate is colourless liquid, is dissolved in ethyl alcohol, ether, acetone and benzene, is
A kind of common monomer of volatile unsaturated methyl ester and synthesising macromolecule copolymer；Ethyl acrylate is colourless liquid,
It is soluble in ethyl alcohol, ether, easily polymerize, can be copolymerized with other monomers, be the monomer of common high molecular synthetic material, be used in combination
In manufacture coating, adhesive, leather processing auxiliary agent, textile auxiliary, oil paint additive etc.；Hydroxyethyl methacrylate is colourless
Bright mobile liquid has higher activity, for the modification of resin and coating, the propylene that side chain contains activity hydroxy can be made
Acid resin, for manufacturing the adhesive of fabric in textile industry, using methyl acrylate, ethyl acrylate or methacrylic acid
A kind of raw material as esters of acrylic acid in hydroxyl ethyl ester is all common synthon, has and derives from a wealth of sources, is low-cost
Characteristic, and reaction process is simple, quick, it is efficient.
The present invention is further arranged to：The organosilicon containing double bond selects vinyltrimethoxysilane, three second of vinyl
One kind in oxysilane, γ-methacryloxy trimethoxy silane.
By using above-mentioned technical proposal, vinyltrimethoxysilane is colourless transparent liquid, is universal containing double bond
Organosilicon is copolymerized with acrylic monomers, and the coating of formation has many advantages, such as excellent weatherability, resistant to dust and washable；Ethylene
Ethyl triethoxy silicane alkane is colourless transparent liquid, can be copolymerized with various of monomer, and the coating of preparation has excellent electrical property,
Prevent damp and hot, salt spray proof, mould proof NBC protective performance；γ-methacryloxy trimethoxy silane is colourless transparent liquid, due to
Containing methacryloxy functional groups, it can be widely applied to the modification of unsaturated-resin and used as coating, by itself and its
During his monomer copolymerization, prepared coating has stronger activity, and being impregnated in textile surface has the characteristic for being easier to clean,
Meanwhile with excellent weatherability, resistant of high or low temperature and dust-proof, anti-gray characteristic.
The present invention is further arranged to：The active organic acid is malic acid and caffeinic mixture, wherein malic acid
Weight percent in malic acid and caffeinic mixture is 40~60%.
By using above-mentioned technical proposal, malic acid also known as 2- hydroxysuccinic acids have excellent hydrophilicity, and fourth two
Acid has there are two carboxyl, and malic acid has polyfunctional group, hydroxyl and carboxyl, to make it have higher activity；Caffeic acid also known as 3,
4- dihydroxycinnamic acids, polyhydroxy make it have higher activity, and caffeic acid has the functional groups such as hydroxyl, phenyl, double bond, has
Higher activity by malic acid and during caffeic acid collective effect, can generate synergistic effect, by esters of acrylic acid with this mix it is organic
When acid is blended, the surface-active of esters of acrylic acid substance is helped to improve, is more advantageous to being reacted with other components, and
And wherein being mixed by 40~60% ratio of the weight percent of malic acid, the activity for making the organic acid of mixing is best.
The present invention is further arranged to：The silane coupling agent selects γ aminopropyltriethoxy silane and aminopropan
The mixture of base trimethoxy silane, wherein γ aminopropyltriethoxy silane in γ aminopropyltriethoxy silane and
Weight percent in the mixture of TSL 8330 is 40~60%.
By using above-mentioned technical proposal, γ aminopropyltriethoxy silane is colourless transparent liquid, inside contains ammonia
Base and ethyoxyl for being coupled organic polymer and inorganic filler, enhance its caking property, improve the mechanical, water-fast, anti-ageing of product
The performances such as change, are usually used in textile fabric auxiliary agent, insulating materials, adhesive industry；Amino in TSL 8330
Coupling organic polymer and inorganic filler are respectively intended to methoxyl group, the organic compatibility with inorganic filler of enhancing improves filler
Wetability and dispersibility in the polymer are usually used in textile fabric auxiliary agent, insulating materials, adhesive industry, by gamma-amino third
Ethyl triethoxy silicane alkane and TSL 8330 collective effect, the two can generate synergistic effect, make silane coupling agent
The active bigger that has of mixture, be conducive to organic matter and inorganic matter be preferably compatible.
The present invention is further arranged to：The dispersant selects triethyl group hexyl phosphoric acid or methyl anyl alcohol.
By using above-mentioned technical proposal, triethyl group hexyl phosphoric acid and methyl anyl alcohol are the dispersants haveing excellent performance, energy
Enough reduce solid or the substance of liquid particle aggregation in dispersion, the stability in holding system, triethyl group hexyl phosphoric acid or
Person's methyl anyl alcohol is added in reaction system, and each component in reaction system is enable more uniformly to be disperseed, and contributes to anti-
Answer ground more fully, thoroughly.
The invention also discloses a kind of preparation methods of soil-releasing finishing agent, include the following steps：
(1) esters of acrylic acid, active organic acid are added in reaction vessel successively, the temperature in slow increase container is extremely
60~70 DEG C；
(2) organosilicon containing double bond is added in reaction vessel and reacted, mixing speed is 100~120r/min；
(3) silane coupling agent is added in into reaction vessel；
(4) dispersant is added in into reaction vessel, addition speed is 10~20ml/min, reacts 2~4h.
By using above-mentioned technical proposal, esters of acrylic acid is subjected to activation process using active organic acid, makes acrylic acid
Esters have larger activity, can more easily be reacted with organosilicon containing double bond, and be slowly added to dispersant and silicon
Alkane coupling agent, dispersant contribute to more component more uniformly to merge, and make reaction system uniform, stable, silane coupling agent can promote
It is reacted into esters of acrylic acid with organosilicon containing double bond, so as to ensure that reaction carries out more abundant, thorough.
The invention also discloses a kind of application of soil-releasing finishing agent, using above-mentioned 5~10% soil-releasing finishing agent and
0.3~1% bleeding agent, 1~3% softening agent, 1~3% smooth agent, remaining be water, using pad or dip finishing technique to spin
Fabric is arranged.
By using above-mentioned technical proposal, using above-mentioned soil-releasing finishing agent and other auxiliary addition agents, bleeding agent, softening agent
With smooth agent collective effect, using padding or dip finishing technique arranges textile, water, softness are used instead of tradition
The formula of the soil-releasing finishing agent of agent and smooth agent, the soil-releasing finishing agent processing spot of the application is more efficient, thorough, decontamination
Excellent effect.
The present invention is further arranged to：Finishing technique parameter：Textile liquid carrying rate is 60~80%, 110~120 DEG C of preliminary dryings
120~180s, 160~180 DEG C bake 60~100s.
By using above-mentioned technical proposal, above-mentioned technological parameter is controlled, textile surface humidity is moderate, to above-mentioned easy decontamination
Finishing agent has stronger adhesive force, soil-releasing finishing agent and its auxiliary addition agent is made relatively easily to be attached to textile surface, together
When, using preliminary drying and two step heatings are baked, make textile surface that there is dust to be not easy attachment on the surface thereof, and are washed
When the oil stain on surface, spot can washes clean easily.
In conclusion the invention has the advantages that：
1st, activation process is carried out to esters of acrylic acid using malic acid and caffeinic blend, makes esters of acrylic acid surface
Activity with bigger is conducive to reacting for esters of acrylic acid and the organosilicon containing double bond, improves the viscosity of product, make the product
It is easier to be attached to product surface；
2nd, in the mixture to reaction system for adding γ aminopropyltriethoxy silane and amino trimethoxy silane,
The mixture can fully be reacted with esters of acrylic acid remaining in reaction system, and the easy decontamination for considerably improving product is whole
Rationality energy；
3rd, through pad or the textile surface of dip finishing process and by preliminary drying and bake two steps heat treatment
Afterwards, dust can be substantially reduced and fall the fungus resistance, stain on the surface thereof, improving textile surface.
Specific embodiment
The present invention is described in further detail with reference to embodiments.
Esters of acrylic acid raw material is bought from Tianjin Jin Heng coating Co., Ltd；
The purchase of organosilicon containing double bond is from Nanjing through Tian Wei Chemical Co., Ltd.s；
Silane coupling agent purchase is from Nanjing through Tian Wei Chemical Co., Ltd.s；
Caffeic acid is bought from Henan Lai Er mattresses bio tech ltd；
Malic acid is bought from Nantong Fei Yu fine chemicals Co., Ltd.
Embodiment one：
(1) 2 parts of malic acid, 3 parts of caffeic acids and 20 parts of methyl acrylates are sequentially added into three-necked flask, through oil under stirring
Bath is heated to 60 DEG C, mixing speed 70r/min；
(2) 10 parts of vinyltrimethoxysilanes, mixing speed 100r/min, mixing time are added in into three-necked flask
For 30min；
(3) 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silicon are added in into three-necked flask
Alkane；
(4) 3 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 2h.
Embodiment two：
(1) 4 parts of malic acid, 4 parts of caffeic acids and 25 parts of ethyl acrylates are sequentially added into three-necked flask, through oil under stirring
Bath is heated to 65 DEG C, mixing speed 75r/min；
(2) 10 parts of acrylic trimethoxy silanes, mixing speed 110r/min, stirring are added in into three-necked flask
30min；
(3) 0.6 part of γ aminopropyltriethoxy silane and 0.9 part of amino trimethoxy silicon are added in into three-necked flask
Alkane；
(4) 4 parts of methyl anyl alcohols are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min, is reacted
3h。
Embodiment three：
(1) 6 parts of malic acid, 4 parts of caffeic acids and 30 parts of hydroxyethyl methacrylates are sequentially added into three-necked flask, are stirred
It is lower through oil bath heating to 70 DEG C, mixing speed 80r/min；
(2) 20 parts of γ-metering system phthalein oxygroup trimethoxy silane, mixing speed 120r/ are added in into three-necked flask
Min, mixing time 30min；
(3) 1 part of γ aminopropyltriethoxy silane and 1 part of amino trimethoxy silane are added in into three-necked flask；
(4) 5 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 4h.
Example IV：
(1) 5 parts of malic acid, 5 parts of caffeic acids and 25 parts of hydroxyethyl methacrylates are sequentially added into three-necked flask, are stirred
It is lower through oil bath heating to 66 DEG C, mixing speed 72r/min；
(2) 16 parts of vinyltrimethoxysilanes, mixing speed 115r/min, mixing time are added in into three-necked flask
For 30min；
(3) 1 part of γ aminopropyltriethoxy silane and 1 part of amino trimethoxy silane are added in into three-necked flask；
(4) 4.5 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, control the flow velocity of separatory funnel for 1 part/
Min reacts 3h.
Embodiment five：
(1) 6 parts of malic acid, 4 parts of caffeic acids and 25 parts of ethyl acrylates are sequentially added into three-necked flask, through oil under stirring
Bath is heated to 70 DEG C, mixing speed 77r/min；
(2) 18 parts of γ-metering system phthalein oxygroup trimethoxy silane, mixing speed 112r/ are added in into three-necked flask
Min, mixing time 30min；
(3) 1 part of γ aminopropyltriethoxy silane and 1.5 parts of amino trimethoxy silanes are added in into three-necked flask；
(4) 3.5 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, control the flow velocity of separatory funnel for 1 part/
Min reacts 3.5h.
Comparative example one：
(1) 20 parts of methyl acrylates into three-necked flask, through oil bath heating to 60 DEG C under stirring, mixing speed 70r/
min；
(2) 10 parts of vinyltrimethoxysilanes, mixing speed 100r/min, mixing time are added in into three-necked flask
For 30min；
(3) 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silicon are added in into three-necked flask
Alkane；
(4) 3 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 2h.
Comparative example two：
(1) 5 parts of malic acid, 20 parts of methyl acrylates are sequentially added into three-necked flask, through oil bath heating to 60 under stirring
DEG C, mixing speed 70r/min；
(2) 10 parts of vinyltrimethoxysilanes, mixing speed 100r/min, mixing time are added in into three-necked flask
For 30min；
(3) 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silicon are added in into three-necked flask
Alkane；
(4) 3 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 2h.
Comparative example three：
(1) 2 parts of malic acid, 3 parts of caffeic acids and 20 parts of methyl acrylates are sequentially added into three-necked flask, through oil under stirring
Bath is heated to 60 DEG C, mixing speed 70r/min；
(2) 10 parts of vinyltrimethoxysilanes, mixing speed 100r/min, mixing time are added in into three-necked flask
For 30min；
(3) 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silicon are added in into three-necked flask
Alkane；
(4) 3 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 2h.
Comparative example four：
(1) 2 parts of malic acid, 3 parts of caffeic acids and 20 parts of methyl acrylates are sequentially added into three-necked flask, through oil under stirring
Bath is heated to 60 DEG C, mixing speed 70r/min；
(2) 10 parts of vinyltrimethoxysilanes, mixing speed 100r/min, mixing time are added in into three-necked flask
For 30min；
(3) 3 parts of triethyl group hexyl phosphoric acids are slowly added into three-necked flask, the flow velocity for controlling separatory funnel is 1 part/min,
React 2h.
Detection method：
(1) viscosity：Leach mill solution is detected using rotational viscometer；
(2) soil release performance：Through padding that treated, textile is washed through aqueous solution soaking, is observed and is washed under the conditions of different time
Situation；
(3) fungus resistance：Using three mesh zoom-stereo microscope of VMS300A scientific researches grade in different times under the conditions of it is right
Textile surface is observed, and amplification factor is 500 times.
The results are shown in table below for the viscosity measurements of leach mill solution
| Sample | Viscosity (mpas) |
| Embodiment one | 78 |
| Embodiment two | 81 |
| Embodiment three | 82 |
| Example IV | 80 |
| Embodiment five | 79 |
| Comparative example one | 20 |
| Comparative example two | 32 |
| Comparative example three | 27 |
As seen from the above table, for comparative example, the viscosity of the leach mill solution of embodiment is about 80mpas, and viscosity is big
It is big to improve, soil-releasing finishing agent can be made relatively easily to be attached on the surface of textile.
The testing result of soil release performance is as shown in the table
As seen from the above table, the processed textile of embodiment can significantly disappear in immersion 1h, the oil stain adhered to thereon, and
Oil stain in comparative example is then not easy washed clean.
The testing result of fungus resistance is as shown in the table
As seen from the above table, there is excellent fungus resistance, stain through the processed textile surface of embodiment, is not added with silicon
The textile surface of the comparative example of alkane coupling agent is easily adhered bacterium, and textile surface is easily dirty.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, people in the art
Member can as needed make the present embodiment the modification of no creative contribution after this specification is read, but as long as at this
It is all protected in the right of invention by Patent Law.
Claims (7)
1. a kind of soil-releasing finishing agent, it is characterised in that include the component of following parts by weight：
20 ~ 30 parts of esters of acrylic acid
10 ~ 20 parts of organosilicon containing double bond
5 ~ 10 parts of active organic acid
1 ~ 3 part of silane coupling agent
3 ~ 5 parts of dispersant；
The active organic acid is malic acid and caffeinic mixture, and wherein malic acid is in malic acid and caffeinic mixture
In weight percent be 40 ~ 60%；
The dispersant selects triethyl group hexyl phosphoric acid or methyl anyl alcohol.
2. soil-releasing finishing agent according to claim 1, it is characterised in that：The esters of acrylic acid selects acrylic acid first
One kind in ester, ethyl acrylate and hydroxyethyl methacrylate.
3. soil-releasing finishing agent according to claim 1, it is characterised in that：The organosilicon containing double bond selects vinyl three
One kind in methoxy silane, vinyltriethoxysilane, γ-methacryloxy trimethoxy silane.
4. soil-releasing finishing agent according to claim 1, it is characterised in that：The silane coupling agent selects gamma-amino third
The mixture of ethyl triethoxy silicane alkane and TSL 8330, wherein γ aminopropyltriethoxy silane γ-
Weight percent in the mixture of aminopropyltriethoxywerene werene and TSL 8330 is 40 ~ 60%.
A kind of 5. method for preparing the soil-releasing finishing agent as described in claim 1 ~ 4 any one, it is characterised in that including such as
Lower step：
（1）Esters of acrylic acid, active organic acid are added in reaction vessel successively, the temperature in slow increase container to 60 ~
70℃；
（2）Organosilicon containing double bond is added in reaction vessel and is reacted, mixing speed is 100 ~ 120r/min；
（3）Silane coupling agent is added in into reaction vessel；
（4）Dispersant is added in into reaction vessel, addition speed is 10 ~ 20ml/min, reacts 2 ~ 4h.
6. a kind of application of soil-releasing finishing agent as described in claim 1 ~ 4 any one, it is characterised in that：Using above-mentioned 5 ~
10% soil-releasing finishing agent and 0.3 ~ 1% bleeding agent, 1 ~ 3% softening agent, 1 ~ 3% smooth agent, remaining be water, using padding or impregnate
Finishing technique arranges textile.
7. the application of soil-releasing finishing agent according to claim 6, it is characterised in that：Finishing technique parameter：Textile band
Liquid rate is 60 ~ 80%, 110 ~ 120 DEG C of 120 ~ 180s of preliminary drying, and 160 ~ 180 DEG C bake 60 ~ 100s.
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| CN108691030A (en) * | 2018-05-24 | 2018-10-23 | 王德文 | The antifouling aquiculture net cage of sterilizing and anti-virus |
| CN108587273A (en) * | 2018-05-24 | 2018-09-28 | 南京中森挤出机械有限公司 | Ship outer layer antifouling paint and preparation method thereof |
| CN108838042A (en) * | 2018-08-02 | 2018-11-20 | 南京大石电子科技有限公司 | A kind of waterproof gluing process suitable for electric vehicle instrument |
| CN109044009A (en) * | 2018-09-03 | 2018-12-21 | 南通市新纪元宾馆用品有限公司 | Multifunctional cervical vertebra health care pillow |
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