CN106087384A - A kind of fabric water-resistant type fluorescent whitening agent - Google Patents
A kind of fabric water-resistant type fluorescent whitening agent Download PDFInfo
- Publication number
- CN106087384A CN106087384A CN201610448042.0A CN201610448042A CN106087384A CN 106087384 A CN106087384 A CN 106087384A CN 201610448042 A CN201610448042 A CN 201610448042A CN 106087384 A CN106087384 A CN 106087384A
- Authority
- CN
- China
- Prior art keywords
- fluorescent whitening
- whitening agent
- resistant type
- fabric
- fabric water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a kind of fabric water-resistant type fluorescent whitening agent, it is made up through mixing through physical admixture of the raw material of following percentage by weight: compound fluorescent whitening agent 96～98%, acid blue 0.03～0.3%, Polyethylene Glycol 0.15～0.3%, remaining is Matrii Sulfas Exsiccatus.One fabric water-resistant type fluorescent whitening agent of the present invention, compound by two kinds of fluorescent whitening agents, be effectively increased its to the whiteness lifting force of fabric and acid resistance, its fabric whiteness after processing is high, and color fastness is good, excellent combination property.
Description
Technical field
The present invention relates to fluorescent whitening agent field, particularly relate to a kind of fabric water-resistant type fluorescent whitening agent.
Background technology
Fluorescent whitening agent is that a class absorbs ultraviolet light, launches blue or indigo fluorescent material.Both compensate for
Blue light defect in yellow coloration object reflection light, too increases intensity of reflected light, makes whiteness and brightness all be significantly increased.Glimmering
The compounding of optical brightener can obtain unexpected effect, can improve by the whiteness of dyeing and weaving thing, the use of reduction fluorescent whitening agent
Amount, improve application performance, change fluorescent colortone, meet the effect such as particular/special requirement of client.Fluorescent whitening agent compound synergic is main
There are following three kinds of methods: the fluorescent whitening agent of analog structure is compounding, the fluorescent whitening agent of different structure is compounding and adds sensitizing dye
Material is compounding.
Existing fabric fluorescent whitening agent exists low low and acidproof with the binding strength of fiber to whiteness lifting values
Property difference problem.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of fabric water-resistant type fluorescent whitening agent, it is possible to solve existing
The problems referred to above that fabric (cloth) exists with fluorescent whitening agent.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of fabric with water-fast
Type fluorescent whitening agent, is made up through mixing through physical admixture of the raw material of following percentage by weight:
Compound fluorescent whitening agent 96～98%, acid blue 0.03～0.3%, Polyethylene Glycol 0.15～0.3%, remaining is Matrii Sulfas Exsiccatus.
In a preferred embodiment of the present invention, described compound fluorescent whitening agent is fluorescent whitening agent 357 and quaternary ammonium salt
Fluorescent whitening agent W5Mixture；Wherein,
The molecular formula of fluorescent whitening agent 357 is:
；
Quaternary ammonium salt fluorescent whitening agent W5Molecular formula be:
。
In a preferred embodiment of the present invention, described fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Mixing
Mass ratio is 1.5～2.5:8～10.
In a preferred embodiment of the present invention, described fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Mixing
Mass ratio is 2:9.
The present invention uses above technical scheme, and fluorescent whitening agent 357 and quaternary ammonium salt fluorescence that selection fabric is suitable for increase
White agent W5, compounding by chemical compounding and acid blue dye, make the fibre plant compositions of fluorescent whitening agents of formation, its
High to the whiteness lifting values of fabric, whiteness value can improve more than 22, and acid resistance is excellent, in the acidity that pH is 0.5～1
Under the conditions of, the whiteness value of its handled fabric is basically unchanged；It addition, fabric is reaching identical whiteness requirement
Time, it is possible to decrease fluorescent whitening agent consumption, cost-effective.
The invention has the beneficial effects as follows: one fabric water-resistant type fluorescent whitening agent of the present invention, by two kinds of fluorescence
Brightening agent compound, be effectively increased its to the whiteness lifting force of fabric and acid resistance, its fiber after processing is knitted
Thing whiteness is high, and color fastness is good, excellent combination property.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
The embodiment of the present invention includes:
Embodiment 1
A kind of fabric water-resistant type fluorescent whitening agent, by the raw material of following percentage by weight through physical admixture through mixing
Make:
Compound fluorescent whitening agent 96%；
Acid blue 0.03%；
Polyethylene Glycol 0.15%；
Remaining is Matrii Sulfas Exsiccatus.
Described compound fluorescent whitening agent is fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Quality with 1.5:8
Than the mixture being；Wherein,
The molecular formula of fluorescent whitening agent 357 is:
；
Quaternary ammonium salt fluorescent whitening agent W5Molecular formula be:
。
Embodiment 2
A kind of fabric water-resistant type fluorescent whitening agent, by the raw material of following percentage by weight through physical admixture through mixing
Make:
Compound fluorescent whitening agent 98%；
Acid blue 0.3%；
Polyethylene Glycol 0.3%；
Remaining is Matrii Sulfas Exsiccatus.
Described compound fluorescent whitening agent is fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Quality with 2.5:10
Than the mixture being；Wherein, fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Molecular formula with embodiment 1.
Embodiment 3
A kind of fabric water-resistant type fluorescent whitening agent, by the raw material of following percentage by weight through physical admixture through mixing
Make:
Compound fluorescent whitening agent 97%；
Acid blue 0.2%；
Polyethylene Glycol 0.2%；
Remaining is Matrii Sulfas Exsiccatus.
Described compound fluorescent whitening agent is fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Mass ratio with 2:9
For mixture；Wherein, fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Molecular formula with embodiment 1.
Embodiment 4
A kind of fabric water-resistant type fluorescent whitening agent, by the raw material of following percentage by weight through physical admixture through mixing
Make:
Compound fluorescent whitening agent 98%；
Acid blue 0.1%；
Polyethylene Glycol 0.25%；
Remaining is Matrii Sulfas Exsiccatus.
Described compound fluorescent whitening agent is fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Mass ratio with 2:10
For mixture；Wherein, fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Molecular formula with embodiment 1.
For showing that the present invention has above advantage, utilize fluorescent whitening agent prepared by the embodiment of the present invention 1～4 to bamboo fibre
Fabric is contaminated, and by dip method in 0.5% ‰ (owf) dye level, bath raio 1:40, contaminates 40 minutes for 60 DEG C, result such as following table
Shown in:
As can be seen from the above table, the fluorescent whitening agent of the present invention is high to the whiteness value lifting force of fabric, and acid resistance is good
Good, the increase of solution acidic on whiteness almost without impact.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this
Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks
Territory, is the most in like manner included in the scope of patent protection of the present invention.
Claims (4)
1. a fabric water-resistant type fluorescent whitening agent, it is characterised in that by the raw material of following percentage by weight through physics
Hybrid mode is made through mixing:
Compound fluorescent whitening agent 96～98%, acid blue 0.03～0.3%, Polyethylene Glycol 0.15～0.3%, remaining is Matrii Sulfas Exsiccatus.
Fabric water-resistant type fluorescent whitening agent the most according to claim 1, it is characterised in that described compound fluorescence
Brightening agent is fluorescent whitening agent 357 and quaternary ammonium salt fluorescent whitening agent W5Mixture；Wherein,
The molecular formula of fluorescent whitening agent 357 is:
；
Quaternary ammonium salt fluorescent whitening agent W5Molecular formula be:
。
Fabric water-resistant type fluorescent whitening agent the most according to claim 2, it is characterised in that described fluorescent whitening agent
357 and quaternary ammonium salt fluorescent whitening agent W5Mixing quality ratio be 1.5～2.5:8～10.
Fabric water-resistant type fluorescent whitening agent the most according to claim 3, it is characterised in that described fluorescent whitening agent
357 and quaternary ammonium salt fluorescent whitening agent W5Mixing quality than for 2:9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610448042.0A CN106087384A (en) | 2016-06-21 | 2016-06-21 | A kind of fabric water-resistant type fluorescent whitening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610448042.0A CN106087384A (en) | 2016-06-21 | 2016-06-21 | A kind of fabric water-resistant type fluorescent whitening agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106087384A true CN106087384A (en) | 2016-11-09 |
Family
ID=57237669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610448042.0A Pending CN106087384A (en) | 2016-06-21 | 2016-06-21 | A kind of fabric water-resistant type fluorescent whitening agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106087384A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107604633A (en) * | 2017-08-31 | 2018-01-19 | 王露 | A kind of underwear whitening treatment methods |
| CN111875981A (en) * | 2020-08-18 | 2020-11-03 | 宁夏峰盛科技有限公司 | Preparation method of bio-based natural fluorescent whitening agent |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179466A (en) * | 1996-10-15 | 1998-04-22 | 希巴特殊化学控股公司 | Fluorescent whitening agent formulation |
| CN1890312A (en) * | 2003-12-09 | 2007-01-03 | 塞拉尼斯国际公司 | Optical brightener and method of preparing it |
| CN101048551A (en) * | 2004-10-27 | 2007-10-03 | 西巴特殊化学品控股有限公司 | Compositions of fluorescent whitening agents |
| CN102093750A (en) * | 2010-11-26 | 2011-06-15 | 山西青山化工有限公司 | Method for preparing disulfonic acid liquid fluorescent brightening agent with low temperature stability |
| CN103314154A (en) * | 2011-01-20 | 2013-09-18 | 亨斯迈先进材料（瑞士）有限公司 | Formulations of fluorescent whitening agents in dispersed form |
| CN105063991A (en) * | 2015-08-31 | 2015-11-18 | 山西青山化工有限公司 | Fluorescent whitening agent for chinlon |
| CN105155344A (en) * | 2015-08-31 | 2015-12-16 | 山西青山化工有限公司 | Papermaking fluorescent whitening agent |
-
2016
- 2016-06-21 CN CN201610448042.0A patent/CN106087384A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179466A (en) * | 1996-10-15 | 1998-04-22 | 希巴特殊化学控股公司 | Fluorescent whitening agent formulation |
| CN1890312A (en) * | 2003-12-09 | 2007-01-03 | 塞拉尼斯国际公司 | Optical brightener and method of preparing it |
| CN101048551A (en) * | 2004-10-27 | 2007-10-03 | 西巴特殊化学品控股有限公司 | Compositions of fluorescent whitening agents |
| CN102093750A (en) * | 2010-11-26 | 2011-06-15 | 山西青山化工有限公司 | Method for preparing disulfonic acid liquid fluorescent brightening agent with low temperature stability |
| CN103314154A (en) * | 2011-01-20 | 2013-09-18 | 亨斯迈先进材料（瑞士）有限公司 | Formulations of fluorescent whitening agents in dispersed form |
| CN105063991A (en) * | 2015-08-31 | 2015-11-18 | 山西青山化工有限公司 | Fluorescent whitening agent for chinlon |
| CN105155344A (en) * | 2015-08-31 | 2015-12-16 | 山西青山化工有限公司 | Papermaking fluorescent whitening agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107604633A (en) * | 2017-08-31 | 2018-01-19 | 王露 | A kind of underwear whitening treatment methods |
| CN111875981A (en) * | 2020-08-18 | 2020-11-03 | 宁夏峰盛科技有限公司 | Preparation method of bio-based natural fluorescent whitening agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103993504B (en) | A kind of multifunctional carbon quantum dot is as the application of fluorescent whitening agent | |
| CN103711011B (en) | Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof | |
| TWI363080B (en) | Disperse dyes for poly(lactic acid) based fibers | |
| CN102898870B (en) | Fluorescent whitening agent composition for cotton cloth | |
| Tepparin et al. | Dyeing of cotton, bombyx mori and eri silk fabrics with the natural dye extracted from tamarind seed | |
| WO2018014476A1 (en) | Method for one-bath dyeing of chinlon/cationic dyeable dacron/dacron fabric | |
| CN106087384A (en) | A kind of fabric water-resistant type fluorescent whitening agent | |
| CN104312195A (en) | Disulfonic acid liquid florescent whitening agent composition, synthesis method and applications thereof | |
| KR101871556B1 (en) | Acid dye composition,and dyeing method using same | |
| KR101503913B1 (en) | Dye composition for textile printing | |
| CN105155344A (en) | Papermaking fluorescent whitening agent | |
| CN105862477A (en) | Textile auxiliary for improving color fixation effect and preparation method thereof | |
| KR101230699B1 (en) | One bath dyeing method of complex fabric with polyester-cotton | |
| CN102807773B (en) | Blue dye composition, and dyeing application of blue dye composition on fiber | |
| CN103290704A (en) | Components of colorant composition | |
| CN101880475B (en) | Active scarlet dye composition | |
| CN104559314B (en) | Black dye composition and application thereof in polyamide microfiber leather dyeing | |
| JP6763927B2 (en) | Use of acid dye composition, acid dye composition, and method of dyeing nylon fiber using acid dye composition | |
| CN111535010A (en) | Fluorescent whitening agent composition for high-light-fastness cotton | |
| CN102585549B (en) | Reactive red dye composition | |
| KR101474326B1 (en) | Liquid alkali buffer for reactive dye and method for making the same | |
| JP6918123B2 (en) | Reactive dye composition and dyeing method using it | |
| CN105063991A (en) | Fluorescent whitening agent for chinlon | |
| CN105544254A (en) | Special cleaning solution for dyed fabrics | |
| CN107956104A (en) | A kind of fluorescent whitening agent composition for cotton cloth |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161109 |