CN106086576A - A kind of Ni60A TiO2mo nano coating and preparation method thereof - Google Patents

A kind of Ni60A TiO2mo nano coating and preparation method thereof Download PDF

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Publication number
CN106086576A
CN106086576A CN201610662441.7A CN201610662441A CN106086576A CN 106086576 A CN106086576 A CN 106086576A CN 201610662441 A CN201610662441 A CN 201610662441A CN 106086576 A CN106086576 A CN 106086576A
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CN
China
Prior art keywords
ni60a
tio
parts
prepare
nano coating
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Withdrawn
Application number
CN201610662441.7A
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Chinese (zh)
Inventor
程敬卿
周乾坤
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Wuhu Dinghan Remanufacturing Technology Co Ltd
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Wuhu Dinghan Remanufacturing Technology Co Ltd
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Application filed by Wuhu Dinghan Remanufacturing Technology Co Ltd filed Critical Wuhu Dinghan Remanufacturing Technology Co Ltd
Priority to CN201610662441.7A priority Critical patent/CN106086576A/en
Publication of CN106086576A publication Critical patent/CN106086576A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/12Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

The present invention relates to a kind of Ni60A TiO2Mo nano coating and preparation method thereof, the mass fraction of its component and each component is that Ni60A accounts for 5 25 parts, TiO2Account for 45 65 parts, Mo account for 5 15 parts, trace element account for 12 parts;Preparation method comprises the following steps: (1) uses dry type comminuting method to prepare Ni60A TiO2The nanosphere of Mo;(2) prepared nanosphere use surfactant Protection Code mixing B, Fe, Mo prepare nanometer powder;(3) plasma spray coating process is used to prepare Ni60A TiO at 4Cr13 mould steel matrix surface in prepared mixture2Mo nano coating.Nano material is utilized the technology of welding to form nanometer layer at component surface by the present invention, greatly improves the bond strength of nanometer layer, not only achieves the reparation to worn-out parts, also extend the service life of parts.

Description

A kind of Ni60A-TiO2-Mo nano coating and preparation method thereof
Technical field
The present invention relates to thermal spraying material technical field, a kind of Ni60A-TiO2-Mo nano coating and system thereof Preparation Method.
Background technology
Thermal spraying refers to a series of process, during these, and trickle and scattered metal or nonmetallic coating material, With one fusing or semi-molten state, deposit to a kind of matrix surface through preparation, form certain spray deposited layer.
Along with people are in the production operation of various extreme environments, the use condition of workpiece device is further severe, existing Usual spray material is difficult to the use requirement meeting under adverse circumstances, and therefore people need proportioning more scientific and reasonable, product Sprayed on material that can be more excellent and spraying coating process.
Summary of the invention
Poor in order to solve conventional coatings wearability, the problems such as hardness is relatively low, the present invention provides a kind of Ni60A-TiO2-Mo Nano coating and preparation method thereof.
The technical problem to be solved realizes by the following technical solutions:
A kind of Ni60A-TiO2-Mo nano coating, the mass fraction of its component and each component is that Ni60A accounts for 5-25 part, TiO2 Account for 45-65 part, Mo accounts for 5-15 part, trace element accounts for 1-2 part.
Described trace element is B, Fe, Mo.
A kind of Ni60A-TiO2The preparation method of-Mo nano coating, comprises the following steps:
(1) dry type comminuting method is used to prepare Ni60A-TiO2The nanosphere of-Mo.
(2) nanosphere prepared in step (1) use surfactant Protection Code mixing B, Fe, Mo prepare nano powder End.
(3) plasma spray coating process is used to prepare at 4Cr13 mould steel matrix surface in the mixture prepared in step (2) Ni60A-TiO2-Mo nano coating.
The invention has the beneficial effects as follows: nano material is utilized the technology of welding to form nanometer at component surface by the present invention Layer, greatly improves the bond strength of nanometer layer, not only achieves the reparation to worn-out parts, also utilizes nanometer The high-wearing feature of material self, highly corrosion resistant improve the serviceability of parts, extend the service life of parts.
Detailed description of the invention
In order to make technological means that the present invention realizes and creation characteristic be easy to understand, below the present invention is explained further State.
Embodiment one:
A kind of Ni60A-TiO2-Mo nano coating, the mass fraction of its component and each component is that Ni60A accounts for 5 parts, TiO2Account for 45 parts, Mo account for 5 parts, trace element account for 1 part.
Described trace element is B, Fe, Mo.
A kind of Ni60A-TiO2The preparation method of-Mo nano coating, comprises the following steps:
(1) dry type comminuting method is used to prepare Ni60A-TiO2The nanosphere of-Mo;
(2) nanosphere prepared in step (1) use surfactant Protection Code mixing B, Fe, Mo prepare nano powder End;
(3) plasma spray coating process is used to prepare at 4Cr13 mould steel matrix surface in the mixture prepared in step (2) Ni60A-TiO2-Mo nano coating.
Embodiment two:
A kind of Ni60A-TiO2-Mo nano coating, the mass fraction of its component and each component is that Ni60A accounts for 25 parts, TiO2Account for 65 parts, Mo account for 15 parts, trace element account for 2 parts.
Described trace element is B, Fe, Mo.
A kind of Ni60A-TiO2The preparation method of-Mo nano coating is identical with embodiment one.
Embodiment three:
A kind of Ni60A-TiO2-Mo nano coating, the mass fraction of its component and each component is that Ni60A accounts for 12 parts, TiO2Account for 53 parts, Mo account for 10 parts, trace element account for 1.8 parts.
Described trace element is B, Fe, Mo.
A kind of Ni60A-TiO2The preparation method of-Mo nano coating is identical with embodiment one.
Plasma spraying technology is used to prepare Ni60A-TiO on 4Cr13 mould steel matrix2-Mo nano coating, band is State matrix and the bond strength of matrix, microhardness, the porosity and the abrasive wear resistance pair without described coating of coating It is shown in Table 1 than experimental result:
Table 1Ni60A-TiO2-Mo nano coating with without coating 4Cr13 mould steel substrate performance contrast and experiment:
Experimental group is numbered Porosity (AREA%) Bond strength (MPa) Microhardness (HV)
1 0.414 79.2 986
2 0.425 78.8 994
3 0.447 81.6 1015
Meansigma methods 0.429 79.9 998
Contrast groups 0.578 62.6 850
Plasma spraying technology is used to prepare Ni60A-TiO on 4Cr13 mould steel matrix2-Mo coating, with described painting The matrix of layer and the wear extent contrast and experiment of matrix without described coating are shown in Table 2:
Table 2Ni60A-TiO2-Mo nano coating and the wear extent contrast and experiment of 4Cr13 mould steel matrix:
Experimental group is numbered Before abrasion (g) After abrasion (g) Wear extent (g)
1 58.5841 58.5816 0.0025
2 58.1876 58.1842 0.0034
3 58.8746 58.8720 0.0026
Contrast groups 58.6968 58.6904 0.0064
From Tables 1 and 2, Ni60A-TiO2The excellent combination property of-Mo nano coating, wearability is good.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry The personnel simply present invention it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description Principle, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these change and Improvement both falls within scope of the claimed invention.Claimed scope is by appending claims and equivalence thereof Thing defines.

Claims (2)

1. a Ni60A-TiO2-Mo nano coating, it is characterised in that: the mass fraction of its component and each component is that Ni60A accounts for 5- 25 parts, TiO2Account for 45-65 part, Mo accounts for 5-15 part, trace element accounts for 1-2 part;
Described trace element is B, Fe, Mo.
2. a Ni60A-TiO2The preparation method of-Mo nano coating, it is characterised in that: comprise the following steps:
(1) dry type comminuting method is used to prepare Ni60A-TiO2The nanosphere of-Mo;
(2) nanosphere prepared in step (1) use surfactant Protection Code mixing B, Fe, Mo prepare nanometer powder;
(3) plasma spray coating process is used to prepare at 4Cr13 mould steel matrix surface in the mixture prepared in step (2) Ni60A-TiO2-Mo nano coating.
CN201610662441.7A 2016-08-13 2016-08-13 A kind of Ni60A TiO2mo nano coating and preparation method thereof Withdrawn CN106086576A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610662441.7A CN106086576A (en) 2016-08-13 2016-08-13 A kind of Ni60A TiO2mo nano coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610662441.7A CN106086576A (en) 2016-08-13 2016-08-13 A kind of Ni60A TiO2mo nano coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106086576A true CN106086576A (en) 2016-11-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610662441.7A Withdrawn CN106086576A (en) 2016-08-13 2016-08-13 A kind of Ni60A TiO2mo nano coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106086576A (en)

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Application publication date: 20161109