CN106085547A - A kind of liquid clean coal additive - Google Patents

A kind of liquid clean coal additive Download PDF

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Publication number
CN106085547A
CN106085547A CN201610629513.8A CN201610629513A CN106085547A CN 106085547 A CN106085547 A CN 106085547A CN 201610629513 A CN201610629513 A CN 201610629513A CN 106085547 A CN106085547 A CN 106085547A
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CN
China
Prior art keywords
coal
additive
liquid
nitrate
liquid clean
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610629513.8A
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Chinese (zh)
Inventor
苏振生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui China Mstar Technology Ltd
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Anhui China Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui China Mstar Technology Ltd filed Critical Anhui China Mstar Technology Ltd
Priority to CN201610629513.8A priority Critical patent/CN106085547A/en
Publication of CN106085547A publication Critical patent/CN106085547A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of liquid clean coal additive, it is made up of following component by mass percentage: cerous nitrate or holmium nitrate 0.5 2%, copper sulfate or copper nitrate 2 8%, potassium permanganate or potassium ferrate 1 5%, dodecylbenzene sodium sulfonate or polyvinylpyrrolidone 2 6%, surplus is deionized water.The liquid clean coal additive that the present invention provides, it can improve ignition temperature and the thermal efficiency, reduce boiler slag carbon content, reduce slag carbon dioxide and the discharge capacity of flue dust, and make full use of discarded coal.Save fat coal resource, thus save the consumption of coal and reduce the coal combustion pollution to environment.Additionally, liquid additive overcomes again the shortcoming that solid adds, it is only necessary to the strength spray equipment that adds on conveying coal belt feeder and spray flux are proportional with upper coal amount, and easy to operate efficiency is high, and spraying is uniform.

Description

A kind of liquid clean coal additive
Technical field
The present invention relates to a kind of fine chemical product, refer specifically to a kind of liquid clean coal additive.
Background technology
Coal is a kind of important energy and raw material, is the main fuel of Industrial Boiler.But traditional coal-fired mode has perhaps Many shortcomings, as fat coal burns endless, colm cannot utilize, and pollutant emission is serious etc. on the impact of environment.In order to overcome Above-mentioned deficiency, present way be the combustion characteristics according to this coal, caloric value, volatility and catch fire, sulphur content, slagging scorification Property, the combustion index such as after-flame, by Coal rank according to a certain ratio, and add forming agent, sulphur-fixing agent, produce different performance, combustion Burn completely, the less Filter Tuber For Clean Coal of pollutant emission.
But, improve burning of coal quality, the fire box temperature of raising Industrial Boiler and the thermal efficiency, minimizing the most further and give up The discharge capacity of slag waste gas, improve the utilization rate of the discarded coal in colm even colliery, be still significant.
Summary of the invention
It is desirable to provide a kind of liquid clean coal additive, it can improve ignition temperature and the thermal efficiency, reduce stove Slag phosphorus content, reduces slag carbon dioxide and the discharge capacity of flue dust, and makes full use of discarded coal.Save fat coal resource, from And save the consumption of coal and reduce the coal combustion pollution to environment.Additionally, liquid additive overcomes again the shortcoming that solid adds, Have only to conveying coal belt feeder on add one strength spray equipment and spray flux proportional with upper coal amount, easy to operate Efficiency is high, and spraying is uniformly.
A kind of liquid clean coal additives technology scheme of the present invention is: liquid clean coal additive, by by percent mass The following component composition of ratio: cerous nitrate or holmium nitrate 0.5-2%, copper sulfate or copper nitrate 2-8%, potassium permanganate or potassium ferrate 1-5%, dodecylbenzene sodium sulfonate or polyvinylpyrrolidone 2-6%, surplus is deionized water.
Preferably, a kind of liquid clean coal additive, it is made up of following component by mass percentage: cerous nitrate 0.5%, Copper sulfate 7%, potassium ferrate 5%, dodecylbenzene sodium sulfonate 2%, deionized water surplus.
Preferably, a kind of liquid clean coal additive, it is made up of following component by mass percentage: holmium nitrate 0.5%, Potassium ferrate 3%, copper sulfate 7%, polyvinylpyrrolidone 2%, deionized water surplus.
Preferably, a kind of liquid clean coal additive, liquid section coal sulfur-fixing agent in use with the mixing ratio of coal Example is 1:2000-4000 in mass ratio.
Preferably, a kind of liquid clean coal additive, liquid section coal sulfur-fixing agent in use with the mixing ratio of coal Example is 1:2000 in mass ratio.
The invention have the benefit that this liquid clean coal additive large-sized boiler power plant, cement plant use on grasp Facilitating, spraying is uniformly.In described copper sulfate or the copper ion of copper nitrate is in complexation steady statue and plays catalytic action, holmium nitrate Or cerous nitrate can reduce burning of coal activation energy, play promoting catalysis.The Main Ingredients and Appearance playing degradation agent effect is ferric acid Potassium or potassium permanganate.Play predominantly cationic surfactant, the nonionic surfactant such as polyethylene of dispersant effect Ketopyrrolidine or dodecylbenzene sodium sulfonate.This liquid clean coal additive not only makes coal fully burn, and can the solid sulfur of environmental protection. Sulfur-fixing rate is also high than prior art.Through on probation, the present invention reduces burning of coal activation energy, to saving coals from boiler more than 5%, Gu sulfur reaches 40-60%.
Detailed description of the invention
In order to be more fully understood that the present invention, describe technical scheme in detail with instantiation below, but this Invention is not limited thereto.
Embodiment 1
Material proportion (mass percent)
Cerous nitrate 0.5%
Copper sulfate 7%
Potassium ferrate 5%
Dodecylbenzene sodium sulfonate 2%
Deionized water surplus.
Compound method: be sequentially added in the deionized water of inventory by above-mentioned raw materials, stirs and i.e. implements for 1 hour.
The usage amount of this liquid section coal sulfur-fixing agent is: liquid section coal sulfur-fixing agent: coal=1:2000 (mass ratio), root during use Dilute with the water of 5 times of weight portions according to the dry and wet degree of coal, in order to spray uniformly.
Embodiment 2
Holmium nitrate 0.5%
Potassium ferrate 3%
Copper sulfate 7%
Polyvinylpyrrolidone 2%
Deionized water surplus.
Compound method: be sequentially added in the deionized water of inventory by above-mentioned raw materials, stirs and i.e. implements for 1 hour.

Claims (5)

1. a liquid clean coal additive, it is characterised in that be made up of following component by mass percentage: cerous nitrate or nitre Acid holmium 0.5-2%, copper sulfate or copper nitrate 2-8%, potassium permanganate or potassium ferrate 1-5%, dodecylbenzene sodium sulfonate or poly- Vinylpyrrolidone 2-6%, surplus is deionized water.
A kind of liquid clean coal additive the most according to claim 1, it is characterised in that below by mass percentage One-tenth is grouped into: cerous nitrate 0.5%, copper sulfate 7%, potassium ferrate 5%, dodecylbenzene sodium sulfonate 2%, deionized water surplus.
A kind of liquid clean coal additive the most according to claim 1, it is characterised in that below by mass percentage One-tenth is grouped into: holmium nitrate 0.5%, potassium ferrate 3%, copper sulfate 7%, polyvinylpyrrolidone 2%, deionized water surplus.
A kind of liquid clean coal additive the most according to claim 1, it is characterised in that liquid section coal sulfur-fixing agent is using During be 1:2000-4000 in mass ratio with the mixed proportion of coal.
A kind of liquid clean coal additive the most according to claim 1, it is characterised in that liquid section coal sulfur-fixing agent is using During be 1:2000 in mass ratio with the mixed proportion of coal.
CN201610629513.8A 2016-08-03 2016-08-03 A kind of liquid clean coal additive Withdrawn CN106085547A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610629513.8A CN106085547A (en) 2016-08-03 2016-08-03 A kind of liquid clean coal additive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610629513.8A CN106085547A (en) 2016-08-03 2016-08-03 A kind of liquid clean coal additive

Publications (1)

Publication Number Publication Date
CN106085547A true CN106085547A (en) 2016-11-09

Family

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Family Applications (1)

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CN201610629513.8A Withdrawn CN106085547A (en) 2016-08-03 2016-08-03 A kind of liquid clean coal additive

Country Status (1)

Country Link
CN (1) CN106085547A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643406A (en) * 2019-09-25 2020-01-03 威海翔泽新材料科技有限公司 Preparation of coal-saving combustion improver
CN115595189A (en) * 2022-10-25 2023-01-13 广州佳卡纳化妆品开发有限公司(Cn) Biomass solid fuel with high combustion efficiency and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725347A (en) * 2014-01-20 2014-04-16 高同柱 Desulfurizing, denitrifying and decoking synergic additive for fire coal and preparation method of additive
CN103881785A (en) * 2014-03-28 2014-06-25 兖州市东方化工有限公司 Liquid coal-saving sulfur-fixing agent
CN105316076A (en) * 2015-11-20 2016-02-10 株洲宏信科技发展有限公司 Liquid fuel-coal sulfur-fixation agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725347A (en) * 2014-01-20 2014-04-16 高同柱 Desulfurizing, denitrifying and decoking synergic additive for fire coal and preparation method of additive
CN103881785A (en) * 2014-03-28 2014-06-25 兖州市东方化工有限公司 Liquid coal-saving sulfur-fixing agent
CN105316076A (en) * 2015-11-20 2016-02-10 株洲宏信科技发展有限公司 Liquid fuel-coal sulfur-fixation agent and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643406A (en) * 2019-09-25 2020-01-03 威海翔泽新材料科技有限公司 Preparation of coal-saving combustion improver
CN115595189A (en) * 2022-10-25 2023-01-13 广州佳卡纳化妆品开发有限公司(Cn) Biomass solid fuel with high combustion efficiency and preparation method thereof
CN115595189B (en) * 2022-10-25 2024-04-26 常山乔叶生物质能源有限公司 Biomass solid fuel with high combustion efficiency and preparation method thereof

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Application publication date: 20161109

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