CN106085237A - A kind of preparation method of low bulk anti-icing paint - Google Patents
A kind of preparation method of low bulk anti-icing paint Download PDFInfo
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- CN106085237A CN106085237A CN201610508863.9A CN201610508863A CN106085237A CN 106085237 A CN106085237 A CN 106085237A CN 201610508863 A CN201610508863 A CN 201610508863A CN 106085237 A CN106085237 A CN 106085237A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D199/00—Coating compositions based on natural macromolecular compounds or on derivatives thereof, not provided for in groups C09D101/00 - C09D107/00 or C09D189/00 - C09D197/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H99/00—Subject matter not provided for in other groups of this subclass, e.g. flours, kernels
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses the preparation method of a kind of low bulk anti-icing paint, belong to anti-icing paint preparing technical field.For at present preparation with silicone oil for main body anti-icing paint, in use, owing to the thermal coefficient of expansion of silicone oil is bigger, under the sunny or higher environment of temperature, it is easily caused the problem that outer coating ftractures because of expansion, provide a kind of by pig hipbone is prepared as bone meal, by by bone meal and squalane compound grafting lipophilic group, effectively prevent icing from producing, simultaneously because the coefficient of expansion of bone meal own is relatively low, the most there is not cracking phenomena, the present invention replaces silicone oil to continue to prepare ice-covering-proof material by bone meal, effectively reduce the coating coefficient of expansion, the coefficient of expansion is 4.5 × 10‑6/ DEG C, more common silicone oil anti-icing paint thermal coefficient of expansion reduces by 10～15%；And preparation process is simple, environmental protection is pollution-free.
Description
Technical field
The invention discloses the preparation method of a kind of low bulk anti-icing paint, belong to anti-icing paint technology of preparing neck
Territory.
Background technology
At cold district, particularly snow disaster, the multiple country of ice damage, such as Russia, Japan, Canada, Britain, Finland, ice
The state such as island, the U.S., continuous print sleety weather usually makes high tension cable, power equipment large area freeze, causes a large amount of power transmission line
The major accidents such as bar (tower), broken string are fallen on road.China is with a vast territory, northern and Midwest severe cold areas, the most all can occur because of defeated
The security incident that the circuit that electric line icing causes damages and thus causes, brings greatly usually to local life and production
Inconvenience, and cause huge economic loss.Before the Spring Festival in 2008, south number provinces and cities continue sleety weather on a large scale, especially day after day
Making high-tension bus-bar and the serious icing of equipment, cause large area transmission line of electricity to destroy, the direct economy having resulted in more than 1,500 hundred million damages
Lose.More seriously, what ice and snow weather caused cut off the water supply, power-off, interruption of communication, hospital, bank, market are not normally functioning,
Life, work, family and the social stability of people is caused serious harm, and its social influence is huge with economic loss.Therefore,
Carrying out ice-covering-proof coating technology research, the safe operation to improving power system has very important value.Therefore, ice-covering-proof
It is currently a global difficult problem.
The research of anti-icing paint is carried out for many years, predominantly the hydrophobic painting of the material such as organosilicon or fluorocarbon polymer composition
Layer, existing mainly by with miniemulsion techniques, preparing the silicone oil microcapsule emulsion with silicon dioxide as shell, and by it with third
The compound water-based hydrophobic coating of preparing of olefin(e) acid ester emulsion, color stuffing, but the thermal coefficient of expansion of silicone oil is relatively big, in sunny or temperature
Under higher environment, be easily caused outer coating and ftracture because of expansion, thus a kind of low expansion anti-icing paint of preparation have very much must
Want.
Summary of the invention
The technical problem that present invention mainly solves: at present preparation with silicone oil for main body anti-icing paint, using
During, owing to the thermal coefficient of expansion of silicone oil is relatively big, under the sunny or higher environment of temperature, it is easily caused outer coating because of swollen
Swollen and the problem that ftractures, it is provided that a kind of by pig hipbone being prepared as bone meal, by by compound to bone meal and squalane grafting parent
Oil base group, effectively prevents icing from producing, simultaneously because the coefficient of expansion of bone meal own is relatively low, does not ftractures
Phenomenon, effectively solves with silicone oil for main body anti-icing paint, in use, due to silicone oil thermal coefficient of expansion relatively
Greatly, under the sunny or higher environment of temperature, it is easily caused the problem that outer coating ftractures because of expansion.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) collect fresh pig hipbone, cleaned and naturally dry, being crushed to 2～5cm with hydraulic breaker subsequently2Hipbone is little
Block, then 1:10 in mass ratio, mix it with deionized water stirring, then steaming and decocting 25～30min at 100～105 DEG C, collects and steams
Boil pig hipbone fritter, at 65～80 DEG C, be dried 6～8h after naturally drying, mill subsequently and sieve, being prepared into 80～90 mesh pigs
Hipbone powder；
(2) being placed in ball mill device by the pig hipbone powder of above-mentioned preparation, controlling ball milling speed is 250～300r/min, treats ball
After mill 3～5h, collecting powder and sieve, being prepared into 120～140 mesh pig hipbone micropowders, 1:5 the most in mass ratio, by pig hipbone
Micropowder mixes with acetone stirring, then ultrasonic disperse 10～15min under 200～300W, is prepared into pig hipbone micropowder dispersion liquid；
(3) count by weight, weigh the pig hipbone micropowder dispersion liquid of 55～60 parts of above-mentioned preparations, 10～15 part of three isocyanide respectively
Acid esters, 10～15 parts of squalanes, 1～2 part of Pulvis Talci and 5～10 parts of fatty acid esters of sorbitan are placed in there-necked flask, stir
Mix mixing and be placed in heating in water bath 10～15min at 55～60 DEG C, after heating in water bath completes, there-necked flask is dripped squalane
The ethylenediamine of quality 1/2, after being added dropwise to complete, continues Heat preservation 1～2h, to be heated complete after, then at 65～80 DEG C of backspins
Turn and be evaporated to the 1/6 of original volume, be prepared into squalane grafting aggregate microcapsule emulsion；
(4) 1:50 in mass ratio, mixes aerosil with titanium dioxide stirring and is placed in ball grinder, control ball milling speed
It is 450～500r/min, after ball milling completes, collects ball milling mixed-powder, count the most by weight, weigh 55～60 respectively
Part deionized water, 2～3 parts of sodium acrylate, 2～3 parts of isopropyl naphthalene sulfonate, 45～50 parts of ball milling mixed-powders, 35～50 parts
The squalane grafting aggregate microcapsule emulsion of above-mentioned preparation and 25～30 parts of pure-acrylic emulsions are placed in beaker, and stirring mixing can be made
For obtaining a kind of low bulk anti-icing paint.
The application process of the present invention is: by 8# bar, the low bulk anti-icing paint of above-mentioned preparation is coated in rust cleaning oil removing
Layer on surface of metal after process, control coating thickness be 0.5～1.0mm, to be sprayed complete after, stand solidification 20～24h.
The invention has the beneficial effects as follows:
(1) present invention replaces silicone oil to continue to prepare ice-covering-proof material by bone meal, effectively reduces the coating coefficient of expansion, expands system
Number is 4.5 × 10-6/ DEG C, more common silicone oil anti-icing paint thermal coefficient of expansion reduces by 10～15%；
(2) preparation process of the present invention is simple, and environmental protection is pollution-free.
Detailed description of the invention
First collect fresh pig hipbone, cleaned and naturally dry, being crushed to 2～5cm with hydraulic breaker subsequently2Hip
Bone fritter, then 1:10 in mass ratio, mix it with deionized water stirring, then steaming and decocting 25～30min at 100～105 DEG C, receives
Collection steaming and decocting pig hipbone fritter, is dried 6～8h at 65～80 DEG C, mills subsequently and sieve, being prepared into 80～90 after naturally drying
Mesh pig hipbone powder；Being placed in ball mill device by the pig hipbone powder of above-mentioned preparation, controlling ball milling speed is 250～300r/
Min, after ball milling 3～5h, collects powder and also sieves, and is prepared into 120～140 mesh pig hipbone micropowders, 1:5 the most in mass ratio,
Pig hipbone micropowder is mixed with acetone stirring, then ultrasonic disperse 10～15min under 200～300W, it is prepared into pig hipbone micropowder
Dispersion liquid；Count by weight, weigh the pig hipbone micropowder dispersion liquid of 55～60 parts of above-mentioned preparations, 10～15 part of three isocyanide respectively
Acid esters, 10～15 parts of squalanes, 1～2 part of Pulvis Talci and 5～10 parts of fatty acid esters of sorbitan are placed in there-necked flask, stir
Mix mixing and be placed in heating in water bath 10～15min at 55～60 DEG C, after heating in water bath completes, there-necked flask is dripped squalane
The ethylenediamine of quality 1/2, after being added dropwise to complete, continues Heat preservation 1～2h, to be heated complete after, then at 65～80 DEG C of backspins
Turn and be evaporated to the 1/6 of original volume, be prepared into squalane grafting aggregate microcapsule emulsion；1:50 in mass ratio, by gas phase titanium dioxide
Silicon stirs to mix with titanium dioxide and is placed in ball grinder, and controlling ball milling speed is 450～500r/min, after ball milling completes, receives
Collection ball milling mixed-powder, counts the most by weight, weigh respectively 55～60 parts of deionized waters, 2～3 parts of sodium acrylate, 2～3
Part isopropyl naphthalene sulfonate, 45～50 parts of ball milling mixed-powders, the squalane grafting aggregate microcapsule of 35～50 parts of above-mentioned preparations
Emulsion and 25～30 parts of pure-acrylic emulsions are placed in beaker, and stirring mixing can be prepared into a kind of low bulk anti-icing paint.
Example 1
First collect fresh pig hipbone, cleaned and naturally dry, being crushed to 2cm with hydraulic breaker subsequently2Hipbone fritter,
1:10 the most in mass ratio, mixes it with deionized water stirring, then steaming and decocting 25min at 100 DEG C, collects steaming and decocting pig hipbone little
Block, is dried 6h at 65 DEG C, mills subsequently and sieve, being prepared into 80 mesh pig hipbone powder after naturally drying；By above-mentioned preparation
Pig hipbone powder is placed in ball mill device, and control ball milling speed is 250r/min, after ball milling 3h, collects powder and sieves, system
The standby 120 mesh pig hipbone micropowders that obtain, 1:5 the most in mass ratio, pig hipbone micropowder is mixed with acetone stirring, more ultrasonic under 200W
Dispersion 10min, is prepared into pig hipbone micropowder dispersion liquid；Counting by weight, the pig hipbone weighing 55 parts of above-mentioned preparations respectively is micro-
Powder dispersion liquid, 10 parts of triisocyanates, 10 parts of squalanes, 1 part of Pulvis Talci and 5 parts of fatty acid esters of sorbitan are placed in three mouthfuls of burnings
In Ping, stirring mixing is placed in heating in water bath 10min at 55 DEG C, after heating in water bath completes, there-necked flask is dripped squalane
The ethylenediamine of quality 1/2, after being added dropwise to complete, continues Heat preservation 1h, to be heated complete after, then rotate at 65 DEG C and be evaporated to
The 1/6 of original volume, is prepared into squalane grafting aggregate microcapsule emulsion；1:50 in mass ratio, by aerosil and titanium white
Powder stirring mixing is placed in ball grinder, and control ball milling speed is 450r/min, after ball milling completes, collects ball milling mixed powder
End, counts the most by weight, weighs 55 parts of deionized waters, 2 parts of sodium acrylate, 2 parts of isopropyl naphthalene sulfonate, 45 parts of balls respectively
Mill mixed-powder, the squalane grafting aggregate microcapsule emulsion of 35 parts of above-mentioned preparations and 25 parts of pure-acrylic emulsions are placed in beaker, stir
Mix mixing and can be prepared into a kind of low bulk anti-icing paint.
By 8# bar, the low bulk anti-icing paint of above-mentioned preparation is coated in the layer on surface of metal after rust cleaning oil removal treatment,
Control coating thickness is 0.5mm, to be sprayed complete after, stand solidification 20h.
Example 2
First collect fresh pig hipbone, cleaned and naturally dry, being crushed to 3cm with hydraulic breaker subsequently2Hipbone fritter,
1:10 the most in mass ratio, mixes it with deionized water stirring, then steaming and decocting 27min at 102 DEG C, collects steaming and decocting pig hipbone little
Block, is dried 7h at 72 DEG C, mills subsequently and sieve, being prepared into 85 mesh pig hipbone powder after naturally drying；By above-mentioned preparation
Pig hipbone powder is placed in ball mill device, and control ball milling speed is 275r/min, after ball milling 4h, collects powder and sieves, system
The standby 130 mesh pig hipbone micropowders that obtain, 1:5 the most in mass ratio, pig hipbone micropowder is mixed with acetone stirring, more ultrasonic under 250W
Dispersion 12min, is prepared into pig hipbone micropowder dispersion liquid；Counting by weight, the pig hipbone weighing 57 parts of above-mentioned preparations respectively is micro-
Powder dispersion liquid, 12 parts of triisocyanates, 12 parts of squalanes, 1 part of Pulvis Talci and 7 parts of fatty acid esters of sorbitan are placed in three mouthfuls of burnings
In Ping, stirring mixing is placed in heating in water bath 12min at 57 DEG C, after heating in water bath completes, there-necked flask is dripped squalane
The ethylenediamine of quality 1/2, after being added dropwise to complete, continues Heat preservation 1h, to be heated complete after, then rotate at 72 DEG C and be evaporated to
The 1/6 of original volume, is prepared into squalane grafting aggregate microcapsule emulsion；1:50 in mass ratio, by aerosil and titanium white
Powder stirring mixing is placed in ball grinder, and control ball milling speed is 475r/min, after ball milling completes, collects ball milling mixed powder
End, counts the most by weight, weighs 57 parts of deionized waters, 3 parts of sodium acrylate, 3 parts of isopropyl naphthalene sulfonate, 47 parts of balls respectively
Mill mixed-powder, the squalane grafting aggregate microcapsule emulsion of 42 parts of above-mentioned preparations and 27 parts of pure-acrylic emulsions are placed in beaker, stir
Mix mixing and can be prepared into a kind of low bulk anti-icing paint.
By 8# bar, the low bulk anti-icing paint of above-mentioned preparation is coated in the layer on surface of metal after rust cleaning oil removal treatment,
Control coating thickness is 0.7mm, to be sprayed complete after, stand solidification 22h.
Example 3
First collect fresh pig hipbone, cleaned and naturally dry, being crushed to 5cm with hydraulic breaker subsequently2Hipbone fritter,
1:10 the most in mass ratio, mixes it with deionized water stirring, then steaming and decocting 30min at 105 DEG C, collects steaming and decocting pig hipbone little
Block, is dried 8h at 80 DEG C, mills subsequently and sieve, being prepared into 90 mesh pig hipbone powder after naturally drying；By above-mentioned preparation
Pig hipbone powder is placed in ball mill device, and control ball milling speed is 300r/min, after ball milling 5h, collects powder and sieves, system
The standby 140 mesh pig hipbone micropowders that obtain, 1:5 the most in mass ratio, pig hipbone micropowder is mixed with acetone stirring, more ultrasonic under 300W
Dispersion 15min, is prepared into pig hipbone micropowder dispersion liquid；Counting by weight, the pig hipbone weighing 60 parts of above-mentioned preparations respectively is micro-
Powder dispersion liquid, 15 parts of triisocyanates, 15 parts of squalanes, 2 parts of Pulvis Talci and 10 parts of fatty acid esters of sorbitan are placed in three mouthfuls
In flask, stirring mixing is placed in heating in water bath 15min at 60 DEG C, after heating in water bath completes, there-necked flask is dripped spiny dogfish
The ethylenediamine of alkane quality 1/2, after being added dropwise to complete, continues Heat preservation 2h, to be heated complete after, then rotary evaporation at 80 DEG C
To the 1/6 of original volume, it is prepared into squalane grafting aggregate microcapsule emulsion；1:50 in mass ratio, by aerosil and titanium
White lead stirring mixing is placed in ball grinder, and control ball milling speed is 500r/min, after ball milling completes, collects ball milling mixed powder
End, counts the most by weight, weighs 60 parts of deionized waters, 3 parts of sodium acrylate, 3 parts of isopropyl naphthalene sulfonate, 50 parts of balls respectively
Mill mixed-powder, the squalane grafting aggregate microcapsule emulsion of 50 parts of above-mentioned preparations and 30 parts of pure-acrylic emulsions are placed in beaker, stir
Mix mixing and can be prepared into a kind of low bulk anti-icing paint.
By 8# bar, the low bulk anti-icing paint of above-mentioned preparation is coated in the layer on surface of metal after rust cleaning oil removal treatment,
Control coating thickness is 1.0mm, to be sprayed complete after, stand solidification 24h.
Claims (1)
1. the preparation method of a low bulk anti-icing paint, it is characterised in that concrete preparation process is:
(1) collect fresh pig hipbone, cleaned and naturally dry, being crushed to 2～5cm with hydraulic breaker subsequently2Hipbone is little
Block, then 1:10 in mass ratio, mix it with deionized water stirring, then steaming and decocting 25～30min at 100～105 DEG C, collects and steams
Boil pig hipbone fritter, at 65～80 DEG C, be dried 6～8h after naturally drying, mill subsequently and sieve, being prepared into 80～90 mesh pigs
Hipbone powder；
(2) being placed in ball mill device by the pig hipbone powder of above-mentioned preparation, controlling ball milling speed is 250～300r/min, treats ball
After mill 3～5h, collecting powder and sieve, being prepared into 120～140 mesh pig hipbone micropowders, 1:5 the most in mass ratio, by pig hipbone
Micropowder mixes with acetone stirring, then ultrasonic disperse 10～15min under 200～300W, is prepared into pig hipbone micropowder dispersion liquid；
(3) count by weight, weigh the pig hipbone micropowder dispersion liquid of 55～60 parts of above-mentioned preparations, 10～15 part of three isocyanide respectively
Acid esters, 10～15 parts of squalanes, 1～2 part of Pulvis Talci and 5～10 parts of fatty acid esters of sorbitan are placed in there-necked flask, stir
Mix mixing and be placed in heating in water bath 10～15min at 55～60 DEG C, after heating in water bath completes, there-necked flask is dripped squalane
The ethylenediamine of quality 1/2, after being added dropwise to complete, continues Heat preservation 1～2h, to be heated complete after, then at 65～80 DEG C of backspins
Turn and be evaporated to the 1/6 of original volume, be prepared into squalane grafting aggregate microcapsule emulsion；
(4) 1:50 in mass ratio, mixes aerosil with titanium dioxide stirring and is placed in ball grinder, control ball milling speed
It is 450～500r/min, after ball milling completes, collects ball milling mixed-powder, count the most by weight, weigh 55～60 respectively
Part deionized water, 2～3 parts of sodium acrylate, 2～3 parts of isopropyl naphthalene sulfonate, 45～50 parts of ball milling mixed-powders, 35～50 parts
The squalane grafting aggregate microcapsule emulsion of above-mentioned preparation and 25～30 parts of pure-acrylic emulsions are placed in beaker, and stirring mixing can be made
For obtaining a kind of low bulk anti-icing paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610508863.9A CN106085237A (en) | 2016-07-02 | 2016-07-02 | A kind of preparation method of low bulk anti-icing paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610508863.9A CN106085237A (en) | 2016-07-02 | 2016-07-02 | A kind of preparation method of low bulk anti-icing paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109336405A (en) * | 2018-10-29 | 2019-02-15 | 许水仙 | A kind of preparation method of hydrophobic antifog glass |
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| CN1287877A (en) * | 1999-07-27 | 2001-03-21 | 株式会社资生堂 | Micro-capsule and its prepn. method |
| CN102268222A (en) * | 2011-08-17 | 2011-12-07 | 天津大学 | Icing-resisting paint containing alkane phase change microcapsules and preparation method thereof |
| CN104014725A (en) * | 2014-05-09 | 2014-09-03 | 方学军 | Improved pig-bone alcohol-based casting paint and production method thereof |
-
2016
- 2016-07-02 CN CN201610508863.9A patent/CN106085237A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1287877A (en) * | 1999-07-27 | 2001-03-21 | 株式会社资生堂 | Micro-capsule and its prepn. method |
| CN102268222A (en) * | 2011-08-17 | 2011-12-07 | 天津大学 | Icing-resisting paint containing alkane phase change microcapsules and preparation method thereof |
| CN104014725A (en) * | 2014-05-09 | 2014-09-03 | 方学军 | Improved pig-bone alcohol-based casting paint and production method thereof |
Non-Patent Citations (1)
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| 庞宏波等: ""硅油微胶囊及其水性防覆冰涂料的制备与性能"", 《电镀与涂饰》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109336405A (en) * | 2018-10-29 | 2019-02-15 | 许水仙 | A kind of preparation method of hydrophobic antifog glass |
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Application publication date: 20161109 |