CN106085137A - A kind of novel high rigidity anticorrosive paint - Google Patents
A kind of novel high rigidity anticorrosive paint Download PDFInfo
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- CN106085137A CN106085137A CN201610638558.1A CN201610638558A CN106085137A CN 106085137 A CN106085137 A CN 106085137A CN 201610638558 A CN201610638558 A CN 201610638558A CN 106085137 A CN106085137 A CN 106085137A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The invention discloses the preparation method of a kind of novel high rigidity anticorrosive paint: the preparation of (1) nano dispersion fluid: take Nano carbon white, nano alumina powder, nano barium sulfate, make medium with isopropanol and be configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C and stir in thermostatical oil bath, make coupling reaction 2h, prepare nano dispersion fluid with standby；(2) component A is prepared；(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel high rigidity anticorrosive paint.
Description
Technical field
The present invention relates to a kind of novel high rigidity anticorrosive paint, belong to coating manufacture field.
Background technology
Hardware anticorrosion is most effective, one of most common method is to coat anticorrosion organic coating in metal surface,
With isolation metallic matrix and corrosive medium.The domestic research to anticorrosive paint achieves more achievement, but there is also research side
Method falls behind, and corrosion-inhibiting coating thickness is big, has substantial amounts of inflammable, explosive, poisonous organic solvent to escape, has bigger to human body and environment
The deficiency such as harm.At present, anticorrosive coating market used is still based on traditional solvent-borne anticorrosive coating.But in recent years
Come, countries in the world released one after another relevant environmental pollution limit laws and regulations, be directed to coating industry just has in coating
The content of organic volatile and harmful air pollutants two large problems, so account for the molten of All Around The World coating industry 53% by making
The production of dosage form coating is restricted.Therefore, develop low VOC anticorrosive coating necessary, and solvent-free new coating is real
One of approach of the lowest VOC.
Anticorrosive paint refers to play a class high-performance coating of protection base material effect, protection under harsh corrosive environment
Life-span is generally more than 15 years.The kind of anticorrosive paint is more, such as epoxy resin, polyurethanes, chlorinated polyolefin hydro carbons and chlorine
Change rubber-like etc..Epoxy resin owing to having that adhesive force preferable to various grounds, alkali resistance be especially prominent, good toughness, can expire
The foot advantage such as multiple construction requirement and favored.Epoxy coating is used widely at the corrosion-resistant field such as oil, chemical industry, and
Achieved with good anticorrosion ability.
It is desirable to provide a kind of novel high rigidity anticorrosive paint, its natural environmental-protective, there is again good antiseptic property,
The most superpower pencil hardness.
Summary of the invention
The shortcoming that the present invention is directed to prior art, it is provided that a kind of novel high rigidity anticorrosive paint, its natural environmental-protective, again
There is good antiseptic property, the most superpower pencil hardness.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 2-4 part, nano alumina powder 2 parts, nano barium sulfate 1 part, make to be situated between with isopropanol
Matter is configured to suspension, and high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 10-12 part, zinc phosphate 2 parts, pigment 8 parts, slides
Stone powder 18 parts, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating
The ratio of 1: 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
The invention have benefit that:
The present invention provides a kind of novel high rigidity anticorrosive paint, its natural environmental-protective, has again good antiseptic property and mechanical property
Can, shelf characteric is stable, not free settling, and adhesive force is good, the most also the pencil hardness of superelevation.
Detailed description of the invention
Embodiment 1:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 2 parts, nano alumina powder 2 parts, nano barium sulfate 1 part, make medium with isopropanol
Being configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 12 parts, zinc phosphate 2 parts, pigment 8 parts, Talcum
18 parts of powder, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating 1:
The ratio of 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
Embodiment 2:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 4 parts, nano alumina powder 2 parts, nano barium sulfate 1 part, make medium with isopropanol
Being configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 10 parts, zinc phosphate 2 parts, pigment 8 parts, Talcum
18 parts of powder, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating 1:
The ratio of 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
Embodiment 3:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 3 parts, nano alumina powder 2 parts, nano barium sulfate 1 part, make medium with isopropanol
Being configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 11 parts, zinc phosphate 2 parts, pigment 8 parts, Talcum
18 parts of powder, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating 1:
The ratio of 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
Embodiment 4:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 2 parts, nano alumina powder 2 parts, nano barium sulfate 1 part, make medium with isopropanol
Being configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 10 parts, zinc phosphate 2 parts, pigment 8 parts, Talcum
18 parts of powder, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating 1:
The ratio of 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
Embodiment 5:
A kind of preparation method of novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
According to parts by weight, take Nano carbon white 4 parts, nano alumina powder 2 parts, nano barium sulfate 1 part, make medium with isopropanol
Being configured to suspension, high speed dispersion is uniform, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
Mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in thermostatical oil
In bath, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 12 parts, zinc phosphate 2 parts, pigment 8 parts, Talcum
18 parts of powder, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating 1:
The ratio of 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares component A；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, obtain novel
High rigidity anticorrosive paint.
Embodiment 6: effect is tested and assessed
According to GB/T 1,727 1992 " paint film is typically prepared method ", brush with hairbrush that economy-combat abrades rust, oil removal treatment is crossed
Tinplate (tinplate) is upper [specification 50mm × 100mm × (0.2-0.3) mm], and thickness is more than 100 μm, treats that coating is complete at 25 DEG C
Relevant rudimentary quantitative measurement is carried out after solidification.
The anticorrosive paint preparing embodiment 1-5 carries out the test of performance according to relevant criterion, result such as table 1 institute
Show:
Table 1
As can be seen here, the present invention provides a kind of novel high rigidity anticorrosive paint, its natural environmental-protective, has again good antiseptic property
And mechanical property, shelf characteric is stable, not free settling, and adhesive force is good, the most also the pencil hardness of superelevation.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (4)
1. a preparation method for novel high rigidity anticorrosive paint, its step is as follows:
(1) preparation of nano dispersion fluid:
Take Nano carbon white, nano alumina powder, nano barium sulfate, make medium with isopropanol and be configured to suspension, at a high speed
It is uniformly dispersed, then ultrasonic disperse 20min；
A certain amount of silane coupler is dissolved in isopropanol medium, high-speed stirred 20min under room temperature.
2. mix above-mentioned 2 kinds of solution, ultrasonic disperse 25min according to the ratio of weight ratio 1:1, then keep 30 DEG C in constant temperature oil bath
In pot, stirring, makes coupling reaction 2h, prepares nano dispersion fluid with standby；
(2) component A is prepared:
According to parts by weight, 50 parts of epoxy resin liquid adds nano dispersion fluid 10-12 part, zinc phosphate 2 parts, pigment 8 parts, slides
Stone powder 18 parts, calcium silicates 3 parts, mullite part 0.8 part, 0.5 part of mafic spinel brick 200 mesh powder, solvent 20 parts, according to coating
The ratio of 1: 1 adds abrasive media, carries out ball milling with high-speed grinder, until coating fineness is less than 80 μm, prepares A group
Point；
(3) using cashew shell oil firming agent as B component, under room temperature, both in mass ratio 2: 1 mechanical agitation are to uniformly, to obtain final product
Novel high rigidity anticorrosive paint.
3. the preparation method described in claim 1, it is characterised in that:
Described step (1) is: according to parts by weight, takes Nano carbon white 2-4 part, nano alumina powder 2 parts, nano barium sulfate 1
Part.
4. the novel high rigidity anticorrosive paint that the preparation method described in claim 1 or 2 obtains.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610638558.1A CN106085137A (en) | 2016-08-04 | 2016-08-04 | A kind of novel high rigidity anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610638558.1A CN106085137A (en) | 2016-08-04 | 2016-08-04 | A kind of novel high rigidity anticorrosive paint |
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| CN106085137A true CN106085137A (en) | 2016-11-09 |
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| CN201610638558.1A Pending CN106085137A (en) | 2016-08-04 | 2016-08-04 | A kind of novel high rigidity anticorrosive paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373610A (en) * | 2016-11-14 | 2018-08-07 | 中国科学院化学研究所 | Micro-nano structure surface constructs the method for nano coating and its application in antireflective |
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|---|---|---|---|---|
| CN1887992A (en) * | 2006-07-19 | 2007-01-03 | 江苏中矿大正表面工程技术有限公司 | Nanometer modified epoxy sealing paint and its prepn |
| EP2011838A1 (en) * | 2006-04-27 | 2009-01-07 | Takenaka Seisakusho Co., Ltd. | Coating composition and coated article |
| CN101845264A (en) * | 2010-06-03 | 2010-09-29 | 上海大学 | Anticorrosive high-rigidity ceramic coating |
| CN103232786A (en) * | 2013-04-02 | 2013-08-07 | 华南理工大学 | Solvent-free nanometer epoxy anticorrosive paint and preparation method thereof |
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2016
- 2016-08-04 CN CN201610638558.1A patent/CN106085137A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2011838A1 (en) * | 2006-04-27 | 2009-01-07 | Takenaka Seisakusho Co., Ltd. | Coating composition and coated article |
| CN1887992A (en) * | 2006-07-19 | 2007-01-03 | 江苏中矿大正表面工程技术有限公司 | Nanometer modified epoxy sealing paint and its prepn |
| CN101845264A (en) * | 2010-06-03 | 2010-09-29 | 上海大学 | Anticorrosive high-rigidity ceramic coating |
| CN103232786A (en) * | 2013-04-02 | 2013-08-07 | 华南理工大学 | Solvent-free nanometer epoxy anticorrosive paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 胡传炘等: "《特种功能涂层》", 30 September 2009, 北京工业大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373610A (en) * | 2016-11-14 | 2018-08-07 | 中国科学院化学研究所 | Micro-nano structure surface constructs the method for nano coating and its application in antireflective |
| CN108373610B (en) * | 2016-11-14 | 2019-11-12 | 中国科学院化学研究所 | Micro-nano structure surface constructs the method for nano coating and its application in antireflective |
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