CN106084844A - A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof - Google Patents

A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof Download PDF

Info

Publication number
CN106084844A
CN106084844A CN201610546860.4A CN201610546860A CN106084844A CN 106084844 A CN106084844 A CN 106084844A CN 201610546860 A CN201610546860 A CN 201610546860A CN 106084844 A CN106084844 A CN 106084844A
Authority
CN
China
Prior art keywords
bamboo
phenolic resin
graphene oxide
heat insulation
temperature resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610546860.4A
Other languages
Chinese (zh)
Inventor
夏大庆
孔令根
王平
王安勇
戚明永
王丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhibang Kitchen Cabinet Co Ltd
Original Assignee
Zhibang Kitchen Cabinet Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhibang Kitchen Cabinet Co Ltd filed Critical Zhibang Kitchen Cabinet Co Ltd
Priority to CN201610546860.4A priority Critical patent/CN106084844A/en
Publication of CN106084844A publication Critical patent/CN106084844A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B29C2043/5808—Measuring, controlling or regulating pressure or compressing force
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B29C2043/5816—Measuring, controlling or regulating temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

Abstract

The invention discloses a kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation and mould cabinet slab, this Bamboo plastic plate material is made up of the raw material of following weight portion: bamboo powder 70 80, organic silicon modified thermal plastic phenolic resin particle 15 25, ten dihydroxystearic acid 12, polymine 45, dehydrated alcohol are appropriate, naphthenic rubber is oily 35, silane coupler 12, antioxidant 0.1 0.2, Polyetherimide 10 15, graphene oxide graft phenylethene acrylate copolymer bulking agent 46, nano carbon black 23.

Description

A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof
Technical field
The present invention relates to bamboo moulding material technical field, particularly relate to a kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation and mould cupboard Cabinet sheet material and preparation method thereof.
Background technology
Cabinet is a class storage closet the most common in daily household, is also the material that in household building materials, market is quite varied Material, along with the change of the demand property of consumer's age level, the requirement to cabinet is the most durable, the environmental protection of product Property, texture etc. are increasingly becoming consumer's focus of attention, make rational use of resources, it is achieved the sustainable development of industry simultaneously Also it is the developing direction producing industry.
Cabinet slab is a ring particularly important in cabinet assembly, directly influences consumer and buys selection, current cabinet Sheet material mainly has solid wood board, particieboard, density board etc., and wherein solid wood board is expensive, needs frequent maintaining, and resistance to water Not enough；Though particieboard low cost, its intensity is low, and content of formaldehyde is high；Density board is smashed after mainly being soaked by timber etc. High pressure compacting forms, and combination property is the most excellent, but its quality is still waited to improve, and uses the non-renewable resources such as timber.
China has extremely abundant bamboo resource, and bamboo wood has a good mechanical property, fast growth, uniqueness attractive in appearance, Being the important substitution material of timber, be the sustainable resource of a kind of environment-friendly and green, it is come by more as a kind of emerging building materials The most concerns.Bamboo moulding material is that bamboo powder is obtained by a class with plastics mixing co-extrusion, its texture having solid wood concurrently and plastics anti- Water, water-fast, advantage, the performance requirement of cabinet slab of especially fitting such as be unlikely to deform.In actual production process, due to bamboo powder with The compatibility of plastics is poor, and the requirement to production technology and auxiliary agent is very strict, is directly connected to the mechanical property of composite, Also it is the key factor of restriction bamboo molding product quality." heat pressing process of bamboo powder/high density polyethylene (HDPE) (HDPE) composite grinds Study carefully " literary composition is with maleic anhydride grafted polyethylene as compatilizer, and under the conditions of 180 DEG C, hot-pressing processing has obtained a kind of bamboo and has moulded proportioning relatively High material, but the material comprehensive mechanical property obtained is poor, still is apparent not enough in processing characteristics as cabinet slab..
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of high temperature resistant heat insulation is modification phenolic resin-based Bamboo moulds cabinet slab and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab, and this Bamboo plastic plate material is by the raw material of following weight portion Make: bamboo powder 70-80, organic silicon modified thermal plastic phenolic resin particle 15-25, ten dihydroxystearic acid 1-2, polymine 4-5, dehydrated alcohol are appropriate, the oily 3-5 of naphthenic rubber, silane coupler 1-2, antioxidant 0.1-0.2, Polyetherimide 10- 15, graphene oxide graft phenylethene-acrylate copolymer bulking agent 4-6, nano carbon black 2-3.
Described graphene oxide graft phenylethene-acrylate copolymer bulking agent is prepared by the raw material of following weight portion Obtain: graphene oxide 1-2, copolymer in cinnamic acrylic ester 12-15, Silane coupling agent KH550 0.1-0.2, dehydrated alcohol 5-8, preparation method is: first put in dehydrated alcohol by Silane coupling agent KH550, adds graphite oxide after being uniformly mixed Alkene, system is heated to 60-80 DEG C, and ultrasonic disperse 1.5-2h, and reaction terminates rear sucking filtration, is dried, must change after products therefrom washing Property graphene oxide, then puts into modified graphene oxide in high-speed mixer together with copolymer in cinnamic acrylic ester, Put into melt blending pelletize in double screw extruder after being uniformly mixed, obtain described graphene oxide graft phenylethene- Acrylate copolymer bulking agent.
The described modification phenolic resin-based bamboo of a kind of high temperature resistant heat insulation moulds the preparation method of cabinet slab:
(1) first bamboo powder is processed through dehydrate, put into by silane coupler, ten dihydroxystearic acids subsequently, gather Aziridine, dehydrated alcohol mixed preparing solution in soak reaction 2-3h, then pass through filter, dried obtain modified bamboo powder standby With；
(2) melt after organic silicon modified thermal plastic phenolic resin particle being mixed homogeneously with Polyetherimide, nano carbon black Pelletize, obtains modified composite phenolic resin basal granule standby；
(3) modification bamboo powder, modified composite phenolic resin basal granule are put in high-speed mixer and be preheated to 60-80 DEG C, mixing Stirring 20-30min, adds other leftover materials subsequently, is warming up to 80-100 DEG C, continues mix and blend 10-20min, mixing Preparing sheet material by die pressing after uniformly, wherein mold pressing preheating time is 20-30min, and molding temperature is 150-180 DEG C, pressurize Time is 4-5min, and pressure is 10-12MPa, and cold pressing time 3-5min, and cold pressing pressure 10-15MPa, obtains described Bamboo plastic plate material.
Bamboo moulding material feature prepared by the present invention is:
(1) bamboo powder is put into after processed silane coupler, ten dihydroxystearic acids, polymine mixed preparing Ethanol solution in modification, bamboo powder surface introduce organic group, its polarity reduce, the compatibility with resin carries Height, the mechanical property of bamboo powder is improved simultaneously.
(2) it is prepared for a kind of graphene oxide graft phenylethene-acrylate copolymer bulking agent, utilizes graphene oxide Unique is amphipathic, bridging is blended for bamboo powder with organic facies, reduces interface-potential, improves the adhesion of storeroom, can be with tradition Maleic anhydride series bulking agent compare favourably, and more environmental protection.
(3) in advance by organic silicon modified thermal plastic phenolic resin particle and Polyetherimide, pelletize of nano carbon black, obtain Obtain the high-intensity resin basal granule that melt fluidity is good.
To sum up, the bamboo prepared with present invention process is moulded product and has of a relatively high bamboo and mould ratio, and production cost is had Effect reduces, and the material prepared has good mechanical property, durable, impact resistant, has flame-resistant high-temperature-resistant performance excellent especially, Its thermal insulation is good simultaneously, product environment-protecting asepsis, has a good application prospect in terms of making high-end cabinet.
Detailed description of the invention
This embodiment Bamboo plastic plate material is made up of the raw material of following weight portion: bamboo powder 70, organic-silicon-modified thermoplastic phenolic resin Fat granule 15, ten dihydroxystearic acid 1, polymine 4, dehydrated alcohol are appropriate, naphthenic rubber is oily 3, silane coupler 1, Antioxidant 0.1, Polyetherimide 10, graphene oxide graft phenylethene-acrylate copolymer bulking agent 4, nano carbon black 2。
Wherein graphene oxide graft phenylethene-acrylate copolymer bulking agent is prepared into by the raw material of following weight portion Arrive: graphene oxide 1, copolymer in cinnamic acrylic ester 12, Silane coupling agent KH550 0.1, dehydrated alcohol 5, preparation method For: first putting in dehydrated alcohol by Silane coupling agent KH550, add graphene oxide after being uniformly mixed, system is heated to 60 DEG C, and ultrasonic disperse 1.5h, reaction terminates rear sucking filtration, is dried, obtains modified graphene oxide after products therefrom washing, then will Modified graphene oxide puts in high-speed mixer together with copolymer in cinnamic acrylic ester, puts into after being uniformly mixed Melt blending pelletize in double screw extruder, obtains described graphene oxide graft phenylethene-acrylate copolymer increase-volume Agent.
This embodiment preparation of plates method is:
(1) first bamboo powder is processed through dehydrate, put into by silane coupler, ten dihydroxystearic acids subsequently, gather Aziridine, dehydrated alcohol mixed preparing solution in soak reaction 2h, then pass through filter, dried obtain modified bamboo powder standby；
(2) melt after organic silicon modified thermal plastic phenolic resin particle being mixed homogeneously with Polyetherimide, nano carbon black Pelletize, obtains modified composite phenolic resin basal granule standby；
(3) modification bamboo powder, modified composite phenolic resin basal granule are put in high-speed mixer and be preheated to 60 DEG C, mix and blend 20min, adds other leftover materials subsequently, is warming up to 80 DEG C, continues mix and blend 10min, by molding after mix homogeneously Legal system obtains sheet material, wherein mold preheating time be 20min, molding temperature is 150 DEG C, and the dwell time is 4min, and pressure is 10MPa, cold pressing time 3min, and cold pressing pressure 10MPa, obtains described Bamboo plastic plate material.
Above-mentioned prepared Bamboo plastic plate material is made test strip and is carried out performance measurement, and test result is as follows:
Detection project Testing result
Hot strength (MPa) 35.0
Bending strength (MPa) 42.5
Elongation at break (%) 16.2
Bending modulus (GPa) 2.68
24h thickness swelling rate (%) ≤1.5
Impact strength (KJ/m<sup>2</sup>) 12.2

Claims (3)

1. the modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab, it is characterised in that this Bamboo plastic plate material is by following heavy Amount part raw material make: bamboo powder 70-80, organic silicon modified thermal plastic phenolic resin particle 15-25, ten dihydroxystearic acid 1-2, Polymine 4-5, dehydrated alcohol are appropriate, the oily 3-5 of naphthenic rubber, silane coupler 1-2, antioxidant 0.1-0.2, polyethers Acid imide 10-15, graphene oxide graft phenylethene-acrylate copolymer bulking agent 4-6, nano carbon black 2-3.
2. a kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation as claimed in claim 1 moulds cabinet slab, it is characterised in that institute Graphene oxide graft phenylethene-acrylate copolymer the bulking agent stated is prepared by the raw material of following weight portion: oxidation Graphene 1-2, copolymer in cinnamic acrylic ester 12-15, Silane coupling agent KH550 0.1-0.2, dehydrated alcohol 5-8, preparation Method is: first put in dehydrated alcohol by Silane coupling agent KH550, adds graphene oxide after being uniformly mixed, and system adds Heat is to 60-80 DEG C, and ultrasonic disperse 1.5-2h, and reaction terminates rear sucking filtration, is dried, obtains modified graphite oxide after products therefrom washing Alkene, then puts into modified graphene oxide in high-speed mixer together with copolymer in cinnamic acrylic ester, and stirring mixing is all Put into melt blending pelletize in double screw extruder after even, obtain described graphene oxide graft phenylethene-acrylate common Polymers bulking agent.
The modification phenolic resin-based bamboo of a kind of high temperature resistant heat insulation the most as claimed in claim 1 moulds the preparation method of cabinet slab, its Being characterised by, its preparation method is:
(1) first bamboo powder is processed through dehydrate, put into subsequently by silane coupler, ten dihydroxystearic acids, polyethylene Imines, dehydrated alcohol mixed preparing solution in soak reaction 2-3h, then pass through filter, dried obtain modified bamboo powder standby；
(2) melt pelletization after organic silicon modified thermal plastic phenolic resin particle being mixed homogeneously with Polyetherimide, nano carbon black, Obtain modified composite phenolic resin basal granule standby；
(3) modification bamboo powder, modified composite phenolic resin basal granule are put in high-speed mixer and be preheated to 60-80 DEG C, mix and blend 20-30min, adds other leftover materials subsequently, is warming up to 80-100 DEG C, continues mix and blend 10-20min, mix homogeneously Prepare sheet material by die pressing afterwards, wherein mold preheating time be 20-30min, molding temperature is 150-180 DEG C, the dwell time For 4-5min, pressure is 10-12MPa, and cold pressing time 3-5min, and cold pressing pressure 10-15MPa, obtains described Bamboo plastic plate material.
CN201610546860.4A 2016-07-12 2016-07-12 A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof Pending CN106084844A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610546860.4A CN106084844A (en) 2016-07-12 2016-07-12 A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610546860.4A CN106084844A (en) 2016-07-12 2016-07-12 A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106084844A true CN106084844A (en) 2016-11-09

Family

ID=57221264

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610546860.4A Pending CN106084844A (en) 2016-07-12 2016-07-12 A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106084844A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214444A (en) * 2021-05-13 2021-08-06 建滔（佛冈）积层纸板有限公司 PEG-400 modified phenolic resin glue solution and application thereof
CN115536979A (en) * 2022-08-17 2022-12-30 杭州巨星科技股份有限公司 Wear-resistant self-lubricating material, preparation method thereof and application thereof in pneumatic tools

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153877A (en) * 2011-02-22 2011-08-17 中国科学技术大学 Graphene composite material and preparation method thereof
CN103588991A (en) * 2013-11-20 2014-02-19 桂林理工大学 Method for preparing hyperdispersant by adopting oxidized graphene and application thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153877A (en) * 2011-02-22 2011-08-17 中国科学技术大学 Graphene composite material and preparation method thereof
CN103588991A (en) * 2013-11-20 2014-02-19 桂林理工大学 Method for preparing hyperdispersant by adopting oxidized graphene and application thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214444A (en) * 2021-05-13 2021-08-06 建滔（佛冈）积层纸板有限公司 PEG-400 modified phenolic resin glue solution and application thereof
CN113214444B (en) * 2021-05-13 2021-11-19 建滔（佛冈）积层纸板有限公司 PEG-400 modified phenolic resin glue solution and application thereof
CN115536979A (en) * 2022-08-17 2022-12-30 杭州巨星科技股份有限公司 Wear-resistant self-lubricating material, preparation method thereof and application thereof in pneumatic tools

Similar Documents

Publication Publication Date Title
CN103087400B (en) A kind of wood plastic composite and preparation method thereof
CN101580640B (en) Method for preparing wood-plastic composite by blending heat-treated plant fiber with plastic
CN102977624B (en) A kind of degradable type bamboo-plastic composite material with superhigh tenacity and preparation method thereof
CN103849018A (en) Rice hull ash/macromolecular composite material, preparation method and application thereof
CN101921491A (en) Wood plastic composite material
CN103044944A (en) Method for preparing high-performance wood-plastic composite material
CN103709519A (en) Modified polypropylene material and preparation method thereof
CN102558679A (en) Novel bamboo fiber/polypropylene composite material and method for preparing same
CN105713403A (en) Wood-plastic composite and preparation method for special-shape molded member thereof
CN105566937A (en) Fiberglass reinforced wood-plastic composite material and preparation method thereof
CN106189326B (en) Furfural dregs are preparing the application in Wood-plastic material
CN101418101B (en) Polypropylene wood-plastic slab and preparation method thereof
CN103289427A (en) Hemp/polymer composite material and preparation method thereof
CN101717563A (en) Polylactic acid material filled with glass microballons and preparation method thereof
CN106147268A (en) A kind of bamboo modified with graphene oxide graft phenylethene acrylonitrile copolymer bulking agent moulds cabinet slab and preparation method thereof
CN105694230A (en) Environment-friendly plastifying biomass composite and preparation method thereof
CN101698728A (en) Bright and injection-molding wood plastic composite and method for preparing the same
CN106084842A (en) A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof
CN106189304A (en) A kind of antimicrobial form high-density polyethylene thiazolinyl bamboo blending nano-metallic copper moulds cabinet slab and preparation method thereof
CN106084844A (en) A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof
CN104194288A (en) Water bamboo shell fiber modified poly adipic acid/butylene terephthalate composite material and preparation method thereof
CN106084845A (en) A kind of light heat-resisting flame-retardant modified chlorinated polyethylene thiazolinyl bamboo moulds cabinet slab and preparation method thereof
CN104530738B (en) PP/ABS wood-plastic composite plate and manufacturing method thereof
CN106189307A (en) A kind of high-strength polyethylene base bamboo containing carbon nano-fiber moulds cabinet slab and preparation method thereof
CN104371196A (en) High-temperature-resistant high-polymer fiber material with inorganic nano material and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161109

RJ01 Rejection of invention patent application after publication