CN106084815A - A kind of compound 3D printed material and preparation method thereof - Google Patents

A kind of compound 3D printed material and preparation method thereof Download PDF

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Publication number
CN106084815A
CN106084815A CN201610496570.3A CN201610496570A CN106084815A CN 106084815 A CN106084815 A CN 106084815A CN 201610496570 A CN201610496570 A CN 201610496570A CN 106084815 A CN106084815 A CN 106084815A
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parts
printed material
district
compound
resin
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罗诗根
高保
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Huaying City Height Coude Electronic Science And Technology Co Ltd
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Huaying City Height Coude Electronic Science And Technology Co Ltd
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Priority to CN201610496570.3A priority Critical patent/CN106084815A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04—Rosin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)

Abstract

The present invention relates to a kind of compound 3D printed material, by crosslinked phenolic resin, two nonyl certain herbaceous plants with big flowers base barium sulfonates, silica flour, Brazil wax, polyglycol distearate, vermiculite power, bamboo charcoal powder, polyglycereol, modified potato starch, Tricyclodecenyl acetate, nipagin A sodium, blanc fixe, ATBC, coal tar, nanometer zirconium phosphate, basalt fibre powder, pentalyn resin, carbamide forms, prepared material has higher hot strength and stretch modulus, and remain good toughness, its performance indications such as elongation at break and impact strength are good；Not only having at a relatively high toughness, also have higher thermostability, serviceability is good, it is simple to use as required.

Description

A kind of compound 3D printed material and preparation method thereof
Technical field
The present invention relates to a kind of compound 3D printed material and preparation method thereof, belong to 3D printed material technical field.
Background technology
In recent years, 3D prints and is subject to pay close attention to the most widely because of the processing and forming advantage of its uniqueness.3D prints, also known as Increase material manufacturing technology, generally refer to utilize digitized model file, by programme-control printing head, with the side successively accumulated Formula straight forming goes out the technology of 3D solid.Compared with traditional forming method, 3D prints mould and the operation that need not complexity Technique, the course of processing, by computer program control, handy and safe, substantially reduces the processing and forming cycle, and rapid shaping structure is complicated Part, personalized customization can be realized.Along with going deep into of research, 3D prints gradually in fields such as medical science, aviation, building, automobiles There is the most wide application.Material strand melt extrusion technology, also known as fused glass pellet technology, is in 3D printing technique One of most widely used technology, its principle be by the wire rod of certain specification by oven heats to more than its fusing point, make material Material is expressed on platform by a nozzle after being in certain flow regime, is deposited into 3D solid layer by layer.
Summary of the invention
It is an object of the invention to provide a kind of compound 3D printed material and preparation method thereof, in order to preferably improve 3D and beat Treatment effect prepared by printed material material, conveniently uses as required.
To achieve these goals, technical scheme is as follows.
A kind of compound 3D printed material, is made up of the material of following mass fraction: crosslinked phenolic resin 16～20 parts, two nonyls Certain herbaceous plants with big flowers base barium sulfonate 18～22 parts, silica flour 14～18 parts, Brazil wax 12～16 parts, polyglycol distearate 18～22 Part, vermiculite power 14～18 parts, bamboo charcoal powder 12～16 parts, polyglycereol 18～22 parts, modified potato starch 14～18 parts, acetic acid three Cyclodecene ester 18～22 parts, nipagin A sodium 14～18 parts, blanc fixe 14～18 parts, the positive fourth of acetyl tributyl citrate three Ester 12～16 parts, coal tar 18～22 parts, nanometer zirconium phosphate 14～18 parts, basalt fibre powder 12～16 parts, Colophonium Ji Wusi Alcohol ester resin 18～22 parts, carbamide 14～18 parts.
Further, above-mentioned compound 3D printed material, it is made up of the material of following mass fraction: crosslinked phenolic resin 16 Part, two nonyl certain herbaceous plants with big flowers base barium sulfonates 18 parts, silica flour 14 parts, Brazil wax 12 parts, polyglycol distearate 18 parts, vermiculite power 14 Part, bamboo charcoal powder 12 parts, polyglycereol 18 parts, modified potato starch 14 parts, Tricyclodecenyl acetate 18 parts, P-hydroxybenzoic acid second 14 parts of ester sodium, blanc fixe 14 parts, ATBC 12 parts, 18 parts of coal tar, nanometer zirconium phosphate 14 parts, basalt Fiber powder 12 parts, pentalyn resin 18 parts, 14 parts of carbamide.
Further, above-mentioned compound 3D printed material, it is made up of the material of following mass fraction: crosslinked phenolic resin 18 Part, two nonyl certain herbaceous plants with big flowers base barium sulfonates 20 parts, silica flour 16 parts, Brazil wax 14 parts, polyglycol distearate 20 parts, vermiculite power 16 Part, bamboo charcoal powder 14 parts, polyglycereol 20 parts, modified potato starch 16 parts, Tricyclodecenyl acetate 20 parts, P-hydroxybenzoic acid second 16 parts of ester sodium, blanc fixe 16 parts, ATBC 14 parts, 20 parts of coal tar, nanometer zirconium phosphate 16 parts, basalt Fiber powder 14 parts, pentalyn resin 20 parts, 16 parts of carbamide.
Further, above-mentioned compound 3D printed material, it is made up of the material of following mass fraction: crosslinked phenolic resin 20 Part, two nonyl certain herbaceous plants with big flowers base barium sulfonates 22 parts, silica flour 18 parts, Brazil wax 16 parts, polyglycol distearate 22 parts, vermiculite power 18 Part, bamboo charcoal powder 16 parts, polyglycereol 22 parts, modified potato starch 18 parts, Tricyclodecenyl acetate 22 parts, P-hydroxybenzoic acid second 18 parts of ester sodium, blanc fixe 18 parts, ATBC 16 parts, 22 parts of coal tar, nanometer zirconium phosphate 18 parts, basalt Fiber powder 16 parts, pentalyn resin 22 parts, 18 parts of carbamide.
Further, above-mentioned compound 3D printed material, its preparation method, comprise the steps:
1), after the material of above-mentioned mass fraction being mixed, add and extrude pelletizing after being blended uniformly in double screw extruder, Lay-by material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 160～180 DEG C, 190～210 DEG C, 220～240 DEG C, 260～280 DEG C；Engine speed is 40～200rpm；
2) described lay-by material is joined in single screw extrusion machine, use traction machine drawing-off after extrusion, make and beat for 3D The wire rod of print；The temperature of single screw extrusion machine one district, 2nd district, 3rd district and die head is respectively 230～235 DEG C, 250～255 DEG C, 260～265 DEG C, 250～255 DEG C；Screw speed is 10～30rpm, and the draw ratio of traction machine is 1.1～3.2.
This beneficial effect of the invention is: the compound 3D printed material in the present invention, by crosslinked phenolic resin, two nonyl certain herbaceous plants with big flowers bases Barium sulfonate, silica flour, Brazil wax, polyglycol distearate, vermiculite power, bamboo charcoal powder, polyglycereol, Rhizoma Solani tuber osi degeneration are formed sediment Powder, Tricyclodecenyl acetate, nipagin A sodium, blanc fixe, ATBC, coal tar, nanometer Zirconium phosphate, basalt fibre powder, pentalyn resin, carbamide form, and it is strong that prepared material has higher stretching Degree and stretch modulus, and remain good toughness, its performance indications such as elongation at break and impact strength are good；Not only have Having at a relatively high toughness, also have higher thermostability, serviceability is good, it is simple to use as required.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described, in order to be better understood from the present invention.
Embodiment 1
Compound 3D printed material in the embodiment of the present invention, is made up of the material of following mass fraction: crosslinked phenolic resin 16 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 18 parts, silica flour 14 parts, Brazil wax 12 parts, polyglycol distearate 18 parts, vermiculite power 14 parts, bamboo charcoal powder 12 parts, polyglycereol 18 parts, modified potato starch 14 parts, Tricyclodecenyl acetate 18 parts, P-hydroxybenzoic acid 14 parts of ethyl ester sodium, blanc fixe 14 parts, ATBC 12 parts, 18 parts of coal tar, nanometer zirconium phosphate 14 parts, the Black Warrior Rock fiber powder 12 parts, pentalyn resin 18 parts, 14 parts of carbamide.
Above-mentioned compound 3D printed material, its preparation method, comprise the steps:
1), after the material of above-mentioned mass fraction being mixed, add and extrude pelletizing after being blended uniformly in double screw extruder, Lay-by material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 160 DEG C, 190 DEG C, 220 DEG C, 260 DEG C； Engine speed is 40rpm；
2) described lay-by material is joined in single screw extrusion machine, use traction machine drawing-off after extrusion, make and beat for 3D The wire rod of print；The temperature of single screw extrusion machine one district, 2nd district, 3rd district and die head is respectively 230 DEG C, 250 DEG C, 260 DEG C, 250 DEG C； Screw speed is 10rpm, and the draw ratio of traction machine is 1.1.
Embodiment 2
In the embodiment of the present invention, compound 3D printed material, is made up of the material of following mass fraction: crosslinked phenolic resin 18 Part, two nonyl certain herbaceous plants with big flowers base barium sulfonates 20 parts, silica flour 16 parts, Brazil wax 14 parts, polyglycol distearate 20 parts, vermiculite power 16 Part, bamboo charcoal powder 14 parts, polyglycereol 20 parts, modified potato starch 16 parts, Tricyclodecenyl acetate 20 parts, P-hydroxybenzoic acid second 16 parts of ester sodium, blanc fixe 16 parts, ATBC 14 parts, 20 parts of coal tar, nanometer zirconium phosphate 16 parts, basalt Fiber powder 14 parts, pentalyn resin 20 parts, 16 parts of carbamide.
Above-mentioned compound 3D printed material, its preparation method, comprise the steps:
1), after the material of above-mentioned mass fraction being mixed, add and extrude pelletizing after being blended uniformly in double screw extruder, Lay-by material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 170 DEG C, 200 DEG C, 230 DEG C, 270 DEG C； Engine speed is 120rpm；
2) described lay-by material is joined in single screw extrusion machine, use traction machine drawing-off after extrusion, make and beat for 3D The wire rod of print；The temperature of single screw extrusion machine one district, 2nd district, 3rd district and die head is respectively 232 DEG C, 252 DEG C, 262 DEG C, 252 DEG C； Screw speed is 20rpm, and the draw ratio of traction machine is 2.
Embodiment 3
Compound 3D printed material in the embodiment of the present invention, is made up of the material of following mass fraction: crosslinked phenolic resin 20 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 22 parts, silica flour 18 parts, Brazil wax 16 parts, polyglycol distearate 22 parts, vermiculite power 18 parts, bamboo charcoal powder 16 parts, polyglycereol 22 parts, modified potato starch 18 parts, Tricyclodecenyl acetate 22 parts, P-hydroxybenzoic acid 18 parts of ethyl ester sodium, blanc fixe 18 parts, ATBC 16 parts, 22 parts of coal tar, nanometer zirconium phosphate 18 parts, the Black Warrior Rock fiber powder 16 parts, pentalyn resin 22 parts, 18 parts of carbamide.
Above-mentioned compound 3D printed material, its preparation method, comprise the steps:
1), after the material of above-mentioned mass fraction being mixed, add and extrude pelletizing after being blended uniformly in double screw extruder, Lay-by material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 180 DEG C, 210 DEG C, 240 DEG C, 280 DEG C； Engine speed is 200rpm；
2) described lay-by material is joined in single screw extrusion machine, use traction machine drawing-off after extrusion, make and beat for 3D The wire rod of print；The temperature of single screw extrusion machine one district, 2nd district, 3rd district and die head is respectively 235 DEG C, 255 DEG C, 265 DEG C, 255 DEG C； Screw speed is 30rpm, and the draw ratio of traction machine is 3.2.
Reference examples
This reference examples is combined 3D printed material, and its raw material consists of poly-succinic fourth diester and 1 mass of 100 mass fractions The titanium dioxide of number.
Its preparation process is as follows:
1) poly-succinic fourth diester is dried at 60 DEG C 12h；
2) by the poly-succinic fourth diester of 100 weight portions, after the titanium dioxide premix of 1 part, cut by double screw extruder extrusion After Li, obtain lay-by material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 140～150 DEG C, 165～ 170 DEG C, 180～185 DEG C, 180～185 DEG C, engine speed is 40rpm.
Above-described embodiment 1, embodiment 2, embodiment 3 and matched group material are carried out performance test comparison, in test, draws Stretching performance to measure by ASTMD638, select II pattern bar, during test, draw speed is 50mm/min；Impact strength presses ASTMD648 Measure；Melt viscosity is at 160 DEG C, and strain is to use frequency scanning 0.01～100Hz mensuration for 1% time.
Performance test comparing result is as shown in table 1:
Table 1 performance test comparing result
The performance test results Embodiment 1 Embodiment 2 Embodiment 3 Matched group
Hot strength/MPa 45.6 55.6 48.3 28.6
Stretch modulus/MPa 1559.9 1859.6 1689 628.3
Elongation at break/% 93 94 95 259
Impact strength/kJ m<sup>-2</sup> 17.8 18.4 16.3 7.8
Zero shear viscosity/Pa s 3889 3885 3798 759
From the present embodiment, product of the present invention, its hot strength, stretch modulus and impact strength significantly improve, and 3D beats Printing product buckling deformation significantly improves, and dimensional accuracy improves.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (5)

1. a compound 3D printed material, it is characterised in that: be made up of the material of following mass fraction: crosslinked phenolic resin 16～ 20 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 18～22 parts, silica flour 14～18 parts, Brazil wax 12～16 parts, Polyethylene Glycol stearic acid Ester 18～22 parts, vermiculite power 14～18 parts, bamboo charcoal powder 12～16 parts, polyglycereol 18～22 parts, modified potato starch 14～18 Part, Tricyclodecenyl acetate 18～22 parts, nipagin A sodium 14～18 parts, blanc fixe 14～18 parts, acetyl lemon Lemon acid tri-n-butyl 12～16 parts, coal tar 18～22 parts, nanometer zirconium phosphate 14～18 parts, basalt fibre powder 12～16 parts, Pentalyn resin 18～22 parts, carbamide 14～18 parts.
Compound 3D printed material the most according to claim 1, it is characterised in that: described compound 3D printed material, by following The material composition of mass fraction: crosslinked phenolic resin 16 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 18 parts, silica flour 14 parts, Brazil wax 12 parts, polyglycol distearate 18 parts, vermiculite power 14 parts, bamboo charcoal powder 12 parts, polyglycereol 18 parts, modified potato starch 14 Part, Tricyclodecenyl acetate 18 parts, nipagin A sodium 14 parts, blanc fixe 14 parts, ATBC 12 parts, 18 parts of coal tar, nanometer zirconium phosphate 14 parts, 12 parts of basalt fibre powder, pentalyn resin 18 parts, carbamide 14 Part.
Compound 3D printed material the most according to claim 1, it is characterised in that: described compound 3D printed material, by following The material composition of mass fraction: crosslinked phenolic resin 18 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 20 parts, silica flour 16 parts, Brazil wax 14 parts, polyglycol distearate 20 parts, vermiculite power 16 parts, bamboo charcoal powder 14 parts, polyglycereol 20 parts, modified potato starch 16 Part, Tricyclodecenyl acetate about 20 parts, nipagin A sodium 16 parts, blanc fixe about 16 parts, acetyl tributyl citrate three N-butyl 14 parts, 20 parts of coal tar, nanometer zirconium phosphate 16 parts, 14 parts of basalt fibre powder, pentalyn resin 20 parts, 16 parts of carbamide.
Compound 3D printed material the most according to claim 1, it is characterised in that: described compound 3D printed material, by following The material composition of mass fraction: crosslinked phenolic resin 20 parts, two nonyl certain herbaceous plants with big flowers base barium sulfonates 22 parts, silica flour 18 parts, Brazil wax 16 parts, polyglycol distearate about 22 parts, vermiculite power 18 parts, bamboo charcoal powder 16 parts, polyglycereol 22 parts, modified potato starch 18 parts, Tricyclodecenyl acetate 22 parts, nipagin A sodium 18 parts, blanc fixe 18 parts, the positive fourth of acetyl tributyl citrate three Ester 16 parts, 22 parts of coal tar, nanometer zirconium phosphate 18 parts, 16 parts of basalt fibre powder, pentalyn resin 22 parts, carbamide 18 parts.
Compound 3D printed material the most according to claim 1, it is characterised in that: described compound 3D printed material, it is prepared Method, comprises the steps:
1), after the material of above-mentioned mass fraction being mixed, add and extrude pelletizing after being blended uniformly in double screw extruder, obtain standby Material；The temperature of double screw extruder one district, 2nd district, 3rd district and die head is respectively 160～180 DEG C, 190～210 DEG C, 220～ 240 DEG C, 260～280 DEG C；Engine speed is 40～200rpm；
2) described lay-by material is joined in single screw extrusion machine, after extrusion, use traction machine drawing-off, make for 3D printing Wire rod；The temperature of single screw extrusion machine one district, 2nd district, 3rd district and die head is respectively 230～235 DEG C, 250～255 DEG C, 260～ 265 DEG C, 250～255 DEG C；Screw speed is 10～30rpm, and the draw ratio of traction machine is 1.1～3.2.
CN201610496570.3A 2016-06-28 2016-06-28 A kind of compound 3D printed material and preparation method thereof Pending CN106084815A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523010A (en) * 2017-09-06 2017-12-29 王明江 A kind of high-strength material for 3D flying prints
CN110157168A (en) * 2018-02-08 2019-08-23 肇庆益晟商贸有限公司 A kind of shock resistance 3D printing material and its preparation method and application
CN113387606A (en) * 2021-07-01 2021-09-14 四川谦宜复合材料有限公司 Cement-based basalt fiber aggregate for 3D printing and preparation and use methods thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105462201A (en) * 2015-12-23 2016-04-06 江苏道勤新材料科技有限公司 Polyhydroxybutyrate-based degradable 3D (Three Dimensional) printing supplies
CN105694119A (en) * 2016-05-01 2016-06-22 王璐 Polymer material for 3D printing and preparing method thereof
CN105820509A (en) * 2016-05-09 2016-08-03 李红玉 Polymer material used for 3D printing and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105462201A (en) * 2015-12-23 2016-04-06 江苏道勤新材料科技有限公司 Polyhydroxybutyrate-based degradable 3D (Three Dimensional) printing supplies
CN105694119A (en) * 2016-05-01 2016-06-22 王璐 Polymer material for 3D printing and preparing method thereof
CN105820509A (en) * 2016-05-09 2016-08-03 李红玉 Polymer material used for 3D printing and preparing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523010A (en) * 2017-09-06 2017-12-29 王明江 A kind of high-strength material for 3D flying prints
CN110157168A (en) * 2018-02-08 2019-08-23 肇庆益晟商贸有限公司 A kind of shock resistance 3D printing material and its preparation method and application
CN113387606A (en) * 2021-07-01 2021-09-14 四川谦宜复合材料有限公司 Cement-based basalt fiber aggregate for 3D printing and preparation and use methods thereof

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Application publication date: 20161109