CN106084717B - High heat-resisting high tenacity polycarbonate composite and preparation method thereof - Google Patents
High heat-resisting high tenacity polycarbonate composite and preparation method thereof Download PDFInfo
- Publication number
- CN106084717B CN106084717B CN201610414756.XA CN201610414756A CN106084717B CN 106084717 B CN106084717 B CN 106084717B CN 201610414756 A CN201610414756 A CN 201610414756A CN 106084717 B CN106084717 B CN 106084717B
- Authority
- CN
- China
- Prior art keywords
- polycarbonate
- parts
- copolymer
- butadiene
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 95
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 91
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 claims abstract description 53
- 229920001519 homopolymer Polymers 0.000 claims abstract description 29
- 239000012745 toughening agent Substances 0.000 claims abstract description 27
- 229920001577 copolymer Polymers 0.000 claims abstract description 26
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 28
- 239000010452 phosphate Substances 0.000 claims description 28
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 27
- -1 C1-C8-alkyl methacrylate Chemical compound 0.000 claims description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 13
- 229920000578 graft copolymer Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 11
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 11
- 239000005062 Polybutadiene Substances 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 229920002857 polybutadiene Polymers 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 229920001400 block copolymer Polymers 0.000 claims description 6
- 229920012128 methyl methacrylate acrylonitrile butadiene styrene Polymers 0.000 claims description 6
- 229920005604 random copolymer Polymers 0.000 claims description 6
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 6
- 229920001897 terpolymer Polymers 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- 239000004611 light stabiliser Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 3
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
- BZDKYAZTCWRUDZ-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC=C.C=CC#N.COC(=O)C(C)=C.C=CC1=CC=CC=C1 BZDKYAZTCWRUDZ-UHFFFAOYSA-N 0.000 claims description 3
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 claims description 3
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 3
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 3
- 239000005043 ethylene-methyl acrylate Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- NOKUWSXLHXMAOM-UHFFFAOYSA-N hydroxy(phenyl)silicon Chemical compound O[Si]C1=CC=CC=C1 NOKUWSXLHXMAOM-UHFFFAOYSA-N 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- BKLGNGGEJNHIQT-UHFFFAOYSA-N prop-2-enoic acid;silicon Chemical compound [Si].OC(=O)C=C BKLGNGGEJNHIQT-UHFFFAOYSA-N 0.000 claims description 3
- 229920002379 silicone rubber Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 150000003440 styrenes Chemical class 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 abstract description 29
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 28
- 239000000956 alloy Substances 0.000 abstract description 5
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 239000004425 Makrolon Substances 0.000 abstract 3
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 230000007547 defect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000004431 polycarbonate resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 229920007019 PC/ABS Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- QSOMQGJOPSLUAZ-UHFFFAOYSA-N 2-ethenylbuta-1,3-dienylbenzene Chemical compound C=CC(C=C)=CC1=CC=CC=C1 QSOMQGJOPSLUAZ-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- BLXLSQIOCCHAHJ-UHFFFAOYSA-N [2,3,4-tri(nonyl)phenyl] dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=C(OP(O)O)C(CCCCCCCCC)=C1CCCCCCCCC BLXLSQIOCCHAHJ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 125000000000 cycloalkoxy group Chemical group 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- OXDOANYFRLHSML-UHFFFAOYSA-N dimethoxyphosphorylbenzene Chemical compound COP(=O)(OC)C1=CC=CC=C1 OXDOANYFRLHSML-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- YJLVKRVGSARISS-UHFFFAOYSA-N tris(2,6-dimethylphenyl) phosphite Chemical compound CC1=CC=CC(C)=C1OP(OC=1C(=CC=CC=1C)C)OC1=C(C)C=CC=C1C YJLVKRVGSARISS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of high heat-resisting high tenacity polycarbonate composite and preparation method thereof, by weight, there is the following raw material formula：60~90 parts of makrolon, 1~20 part of butadiene copolymer, 5~25 parts of phosphoric acid ester homopolymer, 0~8 part of toughener, 0~9.6 part of other auxiliary agents；The sum of parts by weight of each component are 100 parts；Compared to the prior art, the present invention adds phosphoric acid ester homopolymer in composition of raw materials, on the one hand the drawbacks of overcoming existing organophosphate ester flame retardant that makrolon heat distortion temperature and toughness can be greatly reduced well, effectively lift the heat resistance and toughness of polycarbonate compositions；On the other hand also there is good fire retardation, can effectively lifts the flame retardant rating of polycarbonate compositions；In addition, the phosphoric acid ester homopolymer also has fabulous compatibility with makrolon, there will not be plasticization to alloy, can be in the case where not influencing polycarbonate compositions flame retardant rating, toughness, hence it is evident that improve the heat resistance of polycarbonate compositions.
Description
Technical Field
The invention relates to the technical field of engineering plastics, in particular to a high-heat-resistance high-toughness polycarbonate composition and a preparation method thereof.
Background
Polycarbonate PC has the advantages of high impact resistance, heat resistance, good dimensional stability, electric insulation performance and the like, but simultaneously PC has the defects of notch sensitivity, poor processability and the like. In order to improve the defects, a rubber modified polymer can be added, and particularly, PC/ABS alloy which takes PC and ABS as main raw materials is an important engineering plastic, so that the heat resistance and the tensile strength of ABS can be improved, the melt viscosity of PC can be reduced, the processability can be improved, and the sensitivity of the internal stress and the impact strength of a product to the thickness of the product can be reduced.
In addition, in order to meet the high requirement of flame retardancy of the material, an aromatic phosphate flame retardant is also usually added, but the addition thereof usually produces a plasticizing effect on the PC/ABS alloy, and affects the impact strength and heat resistance of the polycarbonate resin. In practical application, the ultra-thin and heat-resistant products are the development direction of market demands. Therefore, the use of aromatic phosphoric acid ester flame retardants is greatly limited.
Chinese patent CN104583316 discloses a method for preparing a flame-retardant high heat-resistant high-toughness polycarbonate composition, which adopts PC with a special structure and a phosphazene flame retardant added to improve the heat distortion temperature of the high heat-resistant high-toughness polycarbonate composition, but the PC with the special structure limits the large-area application of the method to a great extent, and the application of the method is also limited by the high price of the phosphazene flame retardant.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
In order to overcome the defects, the invention provides a high-heat-resistance high-toughness polycarbonate composition and a preparation method thereof, the preparation method is simple and safe to operate, and the polycarbonate composition prepared by the preparation method has excellent toughness, heat resistance and flame retardant grade, and is particularly suitable for occasions with higher requirements on use environments.
The technical scheme adopted by the invention for solving the technical problem is as follows: the high-heat-resistance high-toughness polycarbonate composition comprises the following raw materials in parts by weight: 60-90 parts of polycarbonate, 1-20 parts of butadiene copolymer, 5-25 parts of phosphate homopolymer, 0-8 parts of toughening agent and 0-9.6 parts of other auxiliary agents; and the sum of the parts by weight of the components is 100 parts.
In a further improvement of the present invention, the polycarbonate is at least one selected from the group consisting of an aromatic polycarbonate, an aliphatic polycarbonate, an aromatic-aliphatic polycarbonate, and a branched polycarbonate.
As a further improvement of the invention, the polycarbonate is aromatic polycarbonate with viscosity average molecular weight of 13000-40000.
As a further improvement of the invention, the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts by weight of component A with 5-95 parts by weight of component B,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is formed by mixing 50-95 parts of component B1 and 5-50 parts of component B2 by taking the total weight of the component B as a basis, wherein the component B1 is selected from at least one of styrene, styrene derivatives, C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is selected from at least one of acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
As a further improvement of the present invention, the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS, methyl methacrylate-butadiene-styrene graft copolymer MBS.
As a further improvement of the invention, the weight average molecular weight of the phosphate homopolymer is 35000-50000.
As a further improvement of the invention, the toughening agent is at least one selected from methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride; the grain size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
As a further improvement of the invention, the other auxiliary agent is at least one selected from the group consisting of heat stabilizers, antioxidants, anti-dripping agents, light stabilizers, plasticizers, fillers and colorants.
The invention also provides a preparation method for preparing the high-heat-resistance high-toughness polycarbonate composition, which comprises the following preparation steps: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents according to the formula ratio, putting the polycarbonate, the butadiene copolymer, the phosphate homopolymer, the toughening agent and the other auxiliary agents into a mixer for blending, uniformly mixing, then putting the mixture into a double-screw extruder for melt mixing, and extruding and granulating to obtain the high-heat-resistance high-toughness polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
The invention has the beneficial effects that: compared with the prior art, the phosphate homopolymer is added into the raw material formula, and on one hand, the phosphate homopolymer can well overcome the defect that the existing organic phosphate flame retardant can greatly reduce the thermal deformation temperature and the toughness of the polycarbonate, and effectively improve the heat resistance and the toughness of the polycarbonate composition; on the other hand, the phosphate homopolymer also has a good flame retardant effect, and the flame retardant grade of the polycarbonate composition can be effectively improved; in addition, the phosphate homopolymer has excellent compatibility with polycarbonate, does not have a plasticizing effect on alloy, can obviously improve the heat resistance of the polycarbonate composition under the condition of not influencing the flame-retardant grade and the toughness of the polycarbonate composition, and is particularly suitable for occasions with higher requirements on use environments.
Detailed Description
The present invention will be described in further detail with reference to specific examples, but the present invention is not limited to these examples.
As is well known, the selection of materials, the formulation of raw materials, and the preparation process are three major factors that determine the quality of the product, and the three factors affect each other. Therefore, in order to better illustrate the advantages and innovativeness of the high heat-resistant high-toughness polycarbonate composition product obtained in the present invention, the materials, raw material formula and preparation method of the high heat-resistant high-toughness polycarbonate composition product obtained in the present invention will be described in detail below.
(1) The invention adopts the following materials:
the invention discloses a high heat-resistant high-toughness polycarbonate composition, which mainly comprises polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents, wherein the selection conditions of the raw materials are as follows:
(1a) polycarbonate (C):
in the present invention, the polycarbonate is at least one selected from polycarbonates produced by an interfacial polymerization method, a melt transesterification method, a pyridine method, a ring-opening polymerization method of a cyclic carbonate compound, and a solid-phase transesterification method of a prepolymer. The preparation method of the polycarbonate is described in more detail in the Chinese patent CN104987688A, and thus, the detailed description thereof is omitted.
Preferably, the polycarbonate of the present invention is at least one selected from the group consisting of aromatic polycarbonate, aliphatic polycarbonate, aromatic-aliphatic polycarbonate, and branched polycarbonate prepared by the above preparation method; more preferably, the polycarbonate is an aromatic polycarbonate with a viscosity average molecular weight of 13000-40000, even more preferably 17000-24000, and has good mechanical strength and excellent moldability when the viscosity average molecular weight of the aromatic polycarbonate is 17000-24000.
(1b) Butadiene copolymer:
in the present invention, the butadiene copolymer is prepared by a bulk polymerization method, an emulsion polymerization method, or a bulk-suspension polymerization method. The method specifically comprises the following steps: the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts of component A with 5-95 parts of component B in parts by weight, and the sum of the parts by weight of the component A and the component B is 100 parts; wherein,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is prepared by mixing 50-95 parts of component B1 and 5-50 parts of component B2, wherein the sum of the parts by weight of the component B1 and the component B2 is 100 parts, the component B1 is at least one selected from styrene, styrene derivatives (such as α -methyl styrene, p-methyl styrene and divinyl styrene), C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is at least one selected from acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
Preferably, the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS, methyl methacrylate-butadiene-styrene graft copolymer MBS.
Further preferably, the acrylonitrile-butadiene-styrene graft copolymer ABS is selected from a mixture of a thermoplastic graft copolymer and an acrylonitrile-styrene copolymer, wherein the thermoplastic graft copolymer is obtained by graft polymerizing 5-28 parts by weight of a butadiene rubber component with 15-30 parts by weight of acrylonitrile and 40-70 parts by weight of styrene, and the formula is particularly preferably as follows: a mixture of a thermoplastic graft copolymer obtained by graft-polymerizing 20 parts by weight of a butadiene rubber component with 22 parts by weight of acrylonitrile and 58 parts by weight of styrene and an acrylonitrile-styrene copolymer.
(1c) Phosphate homopolymer:
the phosphate homopolymer is a homopolymer made of phosphate units having a weight average molecular weight of more than 10000, represented by the following chemical formula (1).
In the chemical formula (1), Y is an alkyl group having 1 to 10 carbon atoms, an alkylene group having 1 to 10 carbon atoms, or a cycloalkoxy group having 5 to 12 carbon atoms, and R represents an alkyl group having 1 to 10 carbon atoms.
In the chemical formula (1), Y can be a straight-chain carbon with 1-10 carbon atoms or an alkylene with a branched chain, the branched chain can comprise ethyl, isopropyl, butyl, hexyl and the like, and the alkylene with 1-10 carbon atoms is particularly preferred; in particular, Y is cyclohexylene, preferably 2, 2-propylene, and particularly preferably 2, 2-propyleneoxy. In the chemical formula (1), 2, 2-bis (4-hydroxyphenyl) propane (i.e., bisphenol A) and a phosphate group are particularly preferable.
R in formula (1), as mentioned above, the alkyl group on the phosphoric acid may be 10 carbon atoms, and the branched chain may include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptylbutyl, octyl, nonyl, decyl, etc. The alkyl group preferably has 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, still more preferably 1 to 4 carbon atoms, and particularly preferably a methyl group, an ethyl group, and a propyl group, among which the methyl group and the ethyl group are preferable, and the most preferable is the methyl group.
The weight average molecular weight of the phosphate homopolymer is 10000 or more, preferably 15000 or more, and more preferably 20000 or more; meanwhile, the weight average molecular weight of the phosphate homopolymer is preferably 300000 or less, more preferably 200000 or less. This is because: the heat resistance of the polycarbonate resin composition having a weight average molecular weight of 10000 or less is lowered, and if the weight average molecular weight exceeds 300000, the polycarbonate resin composition may have defects such as degradation and poor appearance of compatibility. In order to avoid the defects, the phosphate ester homopolymer with the weight-average molecular weight of 35000-50000 is preferably used in the invention.
(1d) A toughening agent:
in the invention, the toughening agent is selected from at least one of methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride; the grain size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
(1e) Other auxiliary agents:
in the present invention, when the polycarbonate, the butadiene copolymer, the phosphate homopolymer and the toughening agent are mixed, other additives selected from at least one of a heat stabilizer, an antioxidant, an anti-dripping agent, a light stabilizer, a plasticizer, a filler and a colorant may be added as needed. Wherein,
suitable heat stabilizers include: organic phosphites such as triphenyl phosphite, tris- (2, 6-dimethylphenyl) phosphite, tris-nonylphenyl phosphite, dimethylbenzene phosphonate, trimethyl phosphate, and the like.
Suitable antioxidants include: organophosphites, alkylated monophenols or polyphenols, alkylated reaction products of polyphenols and dienes, butylated reaction products of p-cresol or dicyclopentadiene, alkylated hydroquinones, hydroxylated thiodiphenyl ethers, alkylene-bisphenols, benzyl compounds, polyol esters and the like.
Suitable anti-dripping agents are preferably fluorinated polyolefins, which are generally polymers or copolymers containing a fluorine-containing ethylene structure, and may be specifically exemplified by vinylidene fluoride resins, tetrafluoroethylene resins, and tetrafluoroethylene/hexafluoropropylene copolymer resins, with tetrafluoroethylene resins being preferred.
Suitable light stabilizers include at least one of benzotriazoles, benzophenones.
Suitable plasticizers are phthalates.
Suitable fillers include titanium dioxide, talc, mica, barium sulfate, and the like.
Suitable colorants include various pigments, dyes.
(2) The high heat-resistant high-toughness polycarbonate composition is prepared
Examples 1 to 6 and comparative examples 1 to 3 were prepared according to the following preparation steps, based on the parts by weight of the raw materials shown in Table 1: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer (or flame retardant), toughening agent and other auxiliaries according to the formula ratio, putting the materials into a mixer for blending, uniformly mixing, putting the materials into a double-screw extruder for melt mixing, and extruding and granulating to obtain a polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
Table 1: unit: parts by weight
Note that polycarbonate PC S-2000F, viscosity average molecular weight 25000 (Mitsubishi, Japan), butadiene copolymer ABS, PA-757 (Taiwan Chimei), was prepared by emulsion polymerization, phosphate homopolymer, Nofia HM1100(FRX), weight average molecular weight 43000, toughening agent, EM500 (Korean LG), flame retardant, Phireguard BDP (Jiangsu Yake), antioxidant AO 1076: β - (3, 5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate (CAS No.: 2082-79-3), anti-dripping agent:30N PTFE(DuPont)。
(3) product physical Property test
According to the industry standard, the nine polycarbonate compositions prepared in the above examples 1-6 and comparative examples 1-3 were subjected to a plurality of basic physical property tests. The test standards or methods for multiple basic physical property tests are as follows:
① UL94 flame retardancy test method:
the flammability test was carried out according to the protocol "flammability test of plastic materials, UL 94". Flame retardant ratings were derived based on the burn rate, extinguishing time, ability to resist dripping, and whether dripping (drip) was burning. Samples used for the test: bars having dimensions of 125mm length x 13mm width x no greater than 13mm thickness, the thickness of the bars when tested according to the invention being selected to be 1.5 mm. According to the UL94 protocol, and based on the test results obtained for five samples, the material flame retardant rating can be classified as (UL 94-HB): v0, V1, V2, 5VA and/or 5 VB; in the present invention, however, only the flame retardant rating of the material is classified as: v0, V1 and V2, and the classification criteria for each flame retardant rating are:
v0: in a sample placed so that its long axis is 180 degrees with respect to the flame, the period of burning and/or smoldering does not exceed 10 seconds after the ignition flame is removed, and the vertically placed sample does not produce dripping of combustion particles that ignite cotton wool. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the flame holding time for the first light (t1) and the flame holding time for the second light (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 50 seconds.
V1: in a sample placed so that its long axis is 180 degrees relative to the flame, the period of burning and/or smoldering does not exceed 30 seconds after the ignition flame is removed, and the vertically placed sample does not produce dripping of burning particles that ignite cotton wool. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the first lit flame holding time (t1) and the second lit flame holding time (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 250 seconds.
V2: in a sample placed so that its long axis is 180 degrees relative to the flame, the average period of burning and/or smoldering after removal of the ignition flame does not exceed 30 seconds, but a vertically placed sample produces dripping of burning particles that ignite cotton. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the first lit flame holding time (t1) and the second lit flame holding time (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 250 seconds.
② Heat Deflection Temperature (HDT) determination method HDT is determined according to test standard ASTM D648 under a load of 1.82MPa, flat with bars of 3.2mm and/or 6.4mm thickness, the results being recorded in ℃ C.
③ notched Izod impact strength was measured using a 3.2mm thick molded notched Izod impact bar at 23 ℃ the notched Izod impact strength was measured according to ASTM D256 and the results were recorded in joules/meter and tested at room temperature (23 ℃).
The nine polycarbonate compositions prepared in examples 1 to 6 of the present invention and comparative examples 1 to 3 were subjected to the above physical property tests, and the test results are shown in Table 2, by taking the average value:
table 2: basic physical properties of the polycarbonate compositions prepared in examples 1 to 6 of the present invention and comparative examples 1 to 3
Test results
As can be seen from Table 2, the polycarbonate compositions prepared in comparative examples 1 to 3 have better flame retardant rating, but the polycarbonate compositions prepared in comparative examples 1 to 3 have poor heat resistance and/or toughness, especially in comparative example 1. Different from comparative examples 1 to 3, the high heat-resistant high-toughness polycarbonate composition prepared in the embodiment of the invention has excellent toughness and heat resistance while having excellent flame retardant rating, and particularly, the embodiment of the invention does not improve the flame retardant rating of the polycarbonate composition by adding a flame retardant in a raw material formula, and the principle of improving the flame retardant rating of the polycarbonate composition obtained in the invention is essentially different from that of comparative examples 1 to 3.
The polycarbonate composition prepared by the invention has advantages in toughness, heat resistance and flame retardant grade, and is mainly benefited from the optimization and improvement of raw material formula, which is specifically represented as follows: according to the invention, the phosphate homopolymer is added into the raw material formula, and on one hand, the phosphate homopolymer can well overcome the defect that the thermal deformation temperature and the toughness of polycarbonate are greatly reduced due to the addition of an organic phosphate flame retardant in the prior art, and the heat resistance and the toughness of the polycarbonate composition are effectively improved; on the other hand, the phosphate homopolymer also has a good flame retardant effect, and the flame retardant grade of the polycarbonate composition can be effectively improved; in addition, the phosphate homopolymer has excellent compatibility with polycarbonate, does not have a plasticizing effect on alloy, can obviously improve the heat resistance of the polycarbonate composition under the condition of not influencing the flame-retardant grade and the toughness of the polycarbonate composition, and is particularly suitable for occasions with higher requirements on use environments.
The high heat-resistant high-toughness polycarbonate composition product prepared by the invention can be widely applied to mobile phones, MP3 players, computers, notebook computers, cameras, video recorders, tablet computers, hand receivers, parts of kitchen appliances or electric shells, automobile parts, shells or covers in the building field, shells and frames of electric appliances, and the like; has wide market prospect and market benefit.
The present invention has been described in detail in order to enable those skilled in the art to understand the invention and to practice it, and it is not intended to limit the scope of the invention, and all equivalent changes and modifications made according to the spirit of the present invention should be covered by the present invention.
Claims (8)
1. A polycarbonate composition with high heat resistance and high toughness is characterized in that: the formula comprises the following raw materials in parts by weight: 60-90 parts of polycarbonate, 1-20 parts of butadiene copolymer, 5-25 parts of phosphate homopolymer, 0-8 parts of toughening agent and 0-9.6 parts of other auxiliary agents, wherein the sum of the parts by weight of the components is 100 parts;
the weight average molecular weight of the phosphate homopolymer is 35000-50000, the particle size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
2. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the polycarbonate is at least one selected from aromatic polycarbonate, aliphatic polycarbonate, aromatic-aliphatic polycarbonate and branched polycarbonate.
3. The high heat resistance and high toughness polycarbonate composition according to claim 2, wherein: the polycarbonate is aromatic polycarbonate with the viscosity average molecular weight of 13000-40000.
4. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts by weight of a component A with 5-95 parts by weight of a component B, wherein,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is formed by mixing 50-95 parts of component B1 and 5-50 parts of component B2 by taking the total weight of the component B as a basis, wherein the component B1 is selected from at least one of styrene, styrene derivatives, C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is selected from at least one of acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
5. The polycarbonate composition with high heat resistance and high toughness as claimed in claim 4, wherein: the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS and methyl methacrylate-butadiene-styrene graft copolymer MBS.
6. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the toughening agent is at least one selected from methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride.
7. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the other auxiliary agent is selected from at least one of a heat stabilizer, an antioxidant, an anti-dripping agent, a light stabilizer, a plasticizer, a filler and a coloring agent.
8. The method for preparing a high heat-resistant high toughness polycarbonate composition according to any one of claims 1 to 7, wherein: the preparation method comprises the following preparation steps: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents according to the formula ratio, putting the polycarbonate, the butadiene copolymer, the phosphate homopolymer, the toughening agent and the other auxiliary agents into a mixer for blending, uniformly mixing, then putting the mixture into a double-screw extruder for melt mixing, and extruding and granulating to obtain the high-heat-resistance high-toughness polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414756.XA CN106084717B (en) | 2016-06-14 | 2016-06-14 | High heat-resisting high tenacity polycarbonate composite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414756.XA CN106084717B (en) | 2016-06-14 | 2016-06-14 | High heat-resisting high tenacity polycarbonate composite and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106084717A CN106084717A (en) | 2016-11-09 |
| CN106084717B true CN106084717B (en) | 2018-05-15 |
Family
ID=57846542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610414756.XA Active CN106084717B (en) | 2016-06-14 | 2016-06-14 | High heat-resisting high tenacity polycarbonate composite and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106084717B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112625417B (en) * | 2020-11-11 | 2022-09-20 | 万华化学(四川)有限公司 | High-heat-resistance thin-wall flame-retardant polycarbonate alloy, method and application |
| CN113736240B (en) * | 2021-08-17 | 2023-03-31 | 金发科技股份有限公司 | High-toughness flame-retardant polycarbonate alloy composition and preparation method and application thereof |
| CN113999511B (en) * | 2021-10-18 | 2023-06-06 | 金发科技股份有限公司 | Flame-retardant polycarbonate alloy composition resistant to damp-heat as well as preparation method and application thereof |
| CN114539755A (en) * | 2022-02-25 | 2022-05-27 | 金发科技股份有限公司 | Polycarbonate composition and preparation method and application thereof |
| CN114573972B (en) * | 2022-03-31 | 2023-11-14 | 金发科技股份有限公司 | Polycarbonate composite material and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448758A (en) * | 2014-11-27 | 2015-03-25 | 五行材料科技（江苏）有限公司 | Flame-retardant polycarbonate enhanced high-modulus molding combination and preparation method thereof |
| CN104987691A (en) * | 2015-06-09 | 2015-10-21 | 金发科技股份有限公司 | Polycarbonate composition and preparation method thereof |
| CN105283507A (en) * | 2013-06-13 | 2016-01-27 | 普立万公司 | Completely non-halogenated flame retardant polycarbonate compounds |
| CN105462224A (en) * | 2015-12-28 | 2016-04-06 | 江苏金发科技新材料有限公司 | Stress-cracking-resistant polycarbonate composite material and preparation method thereof |
-
2016
- 2016-06-14 CN CN201610414756.XA patent/CN106084717B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105283507A (en) * | 2013-06-13 | 2016-01-27 | 普立万公司 | Completely non-halogenated flame retardant polycarbonate compounds |
| CN104448758A (en) * | 2014-11-27 | 2015-03-25 | 五行材料科技（江苏）有限公司 | Flame-retardant polycarbonate enhanced high-modulus molding combination and preparation method thereof |
| CN104987691A (en) * | 2015-06-09 | 2015-10-21 | 金发科技股份有限公司 | Polycarbonate composition and preparation method thereof |
| CN105462224A (en) * | 2015-12-28 | 2016-04-06 | 江苏金发科技新材料有限公司 | Stress-cracking-resistant polycarbonate composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106084717A (en) | 2016-11-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106084717B (en) | High heat-resisting high tenacity polycarbonate composite and preparation method thereof | |
| US7608654B2 (en) | Halogen-free flame retardant polycarbonate compositions | |
| US6630524B1 (en) | Flame retardant thermoplastic resin composition | |
| EP0970997B1 (en) | Flame retardant polycarbonate/abs composition | |
| KR100804173B1 (en) | Flameproof thermoplastic resin composition | |
| US20070249768A1 (en) | Flame Retardant Polycarbonate Resin Composition | |
| CN112322014B (en) | Low-temperature-resistant PC alloy material and preparation method thereof | |
| EP1799766B1 (en) | Flame retardant thermoplastic resin composition | |
| CN102617972A (en) | Halogen-free flame-retardant styrene-series resin composition and preparation method thereof | |
| EP2660291A2 (en) | Flame retardant thermoplastic resin composition | |
| CN110577730A (en) | Polycarbonate composition for high-gloss oil-resistant switch panel and preparation method thereof | |
| KR20120069865A (en) | Polycarbonate resin composition and molded article thereof | |
| JP6942233B1 (en) | Resin composition and molded product | |
| CN106009587A (en) | High-CTI-value and high-heat-resistance polycarbonate composition and preparation method thereof | |
| EP2336232B1 (en) | Non-halogen flameproof polycarbonate resin composition | |
| JP5008224B2 (en) | Housing material comprising polycarbonate-based colored flame retardant resin composition and process for producing the same | |
| KR101261452B1 (en) | Flameproof Thermoplastic Resin Composition having High Flow-ability and High Impact Strength | |
| KR20120078572A (en) | Flameproof thermoplastic resin composition | |
| KR101140516B1 (en) | Thermoplastic flame retardant resin composition | |
| KR101847249B1 (en) | Flame retardant thermoplastic resin composition and article comprising the same | |
| CN105838055A (en) | Transparent halogen-free flame-retardant polycarbonate composition and preparation method thereof | |
| JP2003020396A (en) | Colored polycarbonate flame-retardant resin composition and its preparation process | |
| KR20110075977A (en) | Flameproof polycarbonate resin composition | |
| JP4201906B2 (en) | Flame retardant resin composition with low mold deposit | |
| CN103183899A (en) | Thermoplastic resin composition having excellent flame retardancy, colorability and thermal stability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |