CN106084717B - High heat-resisting high tenacity polycarbonate composite and preparation method thereof - Google Patents

High heat-resisting high tenacity polycarbonate composite and preparation method thereof Download PDF

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CN106084717B
CN106084717B CN201610414756.XA CN201610414756A CN106084717B CN 106084717 B CN106084717 B CN 106084717B CN 201610414756 A CN201610414756 A CN 201610414756A CN 106084717 B CN106084717 B CN 106084717B
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polycarbonate
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copolymer
butadiene
styrene
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CN106084717A (en
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董相茂
田征宇
刘贤文
张永
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Jiangsu Kingfa New Material Co Ltd
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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Abstract

The invention discloses a kind of high heat-resisting high tenacity polycarbonate composite and preparation method thereof, by weight, there is the following raw material formula:60~90 parts of makrolon, 1~20 part of butadiene copolymer, 5~25 parts of phosphoric acid ester homopolymer, 0~8 part of toughener, 0~9.6 part of other auxiliary agents;The sum of parts by weight of each component are 100 parts;Compared to the prior art, the present invention adds phosphoric acid ester homopolymer in composition of raw materials, on the one hand the drawbacks of overcoming existing organophosphate ester flame retardant that makrolon heat distortion temperature and toughness can be greatly reduced well, effectively lift the heat resistance and toughness of polycarbonate compositions;On the other hand also there is good fire retardation, can effectively lifts the flame retardant rating of polycarbonate compositions;In addition, the phosphoric acid ester homopolymer also has fabulous compatibility with makrolon, there will not be plasticization to alloy, can be in the case where not influencing polycarbonate compositions flame retardant rating, toughness, hence it is evident that improve the heat resistance of polycarbonate compositions.

Description

High-heat-resistance high-toughness polycarbonate composition and preparation method thereof
Technical Field
The invention relates to the technical field of engineering plastics, in particular to a high-heat-resistance high-toughness polycarbonate composition and a preparation method thereof.
Background
Polycarbonate PC has the advantages of high impact resistance, heat resistance, good dimensional stability, electric insulation performance and the like, but simultaneously PC has the defects of notch sensitivity, poor processability and the like. In order to improve the defects, a rubber modified polymer can be added, and particularly, PC/ABS alloy which takes PC and ABS as main raw materials is an important engineering plastic, so that the heat resistance and the tensile strength of ABS can be improved, the melt viscosity of PC can be reduced, the processability can be improved, and the sensitivity of the internal stress and the impact strength of a product to the thickness of the product can be reduced.
In addition, in order to meet the high requirement of flame retardancy of the material, an aromatic phosphate flame retardant is also usually added, but the addition thereof usually produces a plasticizing effect on the PC/ABS alloy, and affects the impact strength and heat resistance of the polycarbonate resin. In practical application, the ultra-thin and heat-resistant products are the development direction of market demands. Therefore, the use of aromatic phosphoric acid ester flame retardants is greatly limited.
Chinese patent CN104583316 discloses a method for preparing a flame-retardant high heat-resistant high-toughness polycarbonate composition, which adopts PC with a special structure and a phosphazene flame retardant added to improve the heat distortion temperature of the high heat-resistant high-toughness polycarbonate composition, but the PC with the special structure limits the large-area application of the method to a great extent, and the application of the method is also limited by the high price of the phosphazene flame retardant.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
In order to overcome the defects, the invention provides a high-heat-resistance high-toughness polycarbonate composition and a preparation method thereof, the preparation method is simple and safe to operate, and the polycarbonate composition prepared by the preparation method has excellent toughness, heat resistance and flame retardant grade, and is particularly suitable for occasions with higher requirements on use environments.
The technical scheme adopted by the invention for solving the technical problem is as follows: the high-heat-resistance high-toughness polycarbonate composition comprises the following raw materials in parts by weight: 60-90 parts of polycarbonate, 1-20 parts of butadiene copolymer, 5-25 parts of phosphate homopolymer, 0-8 parts of toughening agent and 0-9.6 parts of other auxiliary agents; and the sum of the parts by weight of the components is 100 parts.
In a further improvement of the present invention, the polycarbonate is at least one selected from the group consisting of an aromatic polycarbonate, an aliphatic polycarbonate, an aromatic-aliphatic polycarbonate, and a branched polycarbonate.
As a further improvement of the invention, the polycarbonate is aromatic polycarbonate with viscosity average molecular weight of 13000-40000.
As a further improvement of the invention, the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts by weight of component A with 5-95 parts by weight of component B,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is formed by mixing 50-95 parts of component B1 and 5-50 parts of component B2 by taking the total weight of the component B as a basis, wherein the component B1 is selected from at least one of styrene, styrene derivatives, C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is selected from at least one of acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
As a further improvement of the present invention, the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS, methyl methacrylate-butadiene-styrene graft copolymer MBS.
As a further improvement of the invention, the weight average molecular weight of the phosphate homopolymer is 35000-50000.
As a further improvement of the invention, the toughening agent is at least one selected from methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride; the grain size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
As a further improvement of the invention, the other auxiliary agent is at least one selected from the group consisting of heat stabilizers, antioxidants, anti-dripping agents, light stabilizers, plasticizers, fillers and colorants.
The invention also provides a preparation method for preparing the high-heat-resistance high-toughness polycarbonate composition, which comprises the following preparation steps: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents according to the formula ratio, putting the polycarbonate, the butadiene copolymer, the phosphate homopolymer, the toughening agent and the other auxiliary agents into a mixer for blending, uniformly mixing, then putting the mixture into a double-screw extruder for melt mixing, and extruding and granulating to obtain the high-heat-resistance high-toughness polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
The invention has the beneficial effects that: compared with the prior art, the phosphate homopolymer is added into the raw material formula, and on one hand, the phosphate homopolymer can well overcome the defect that the existing organic phosphate flame retardant can greatly reduce the thermal deformation temperature and the toughness of the polycarbonate, and effectively improve the heat resistance and the toughness of the polycarbonate composition; on the other hand, the phosphate homopolymer also has a good flame retardant effect, and the flame retardant grade of the polycarbonate composition can be effectively improved; in addition, the phosphate homopolymer has excellent compatibility with polycarbonate, does not have a plasticizing effect on alloy, can obviously improve the heat resistance of the polycarbonate composition under the condition of not influencing the flame-retardant grade and the toughness of the polycarbonate composition, and is particularly suitable for occasions with higher requirements on use environments.
Detailed Description
The present invention will be described in further detail with reference to specific examples, but the present invention is not limited to these examples.
As is well known, the selection of materials, the formulation of raw materials, and the preparation process are three major factors that determine the quality of the product, and the three factors affect each other. Therefore, in order to better illustrate the advantages and innovativeness of the high heat-resistant high-toughness polycarbonate composition product obtained in the present invention, the materials, raw material formula and preparation method of the high heat-resistant high-toughness polycarbonate composition product obtained in the present invention will be described in detail below.
(1) The invention adopts the following materials:
the invention discloses a high heat-resistant high-toughness polycarbonate composition, which mainly comprises polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents, wherein the selection conditions of the raw materials are as follows:
(1a) polycarbonate (C):
in the present invention, the polycarbonate is at least one selected from polycarbonates produced by an interfacial polymerization method, a melt transesterification method, a pyridine method, a ring-opening polymerization method of a cyclic carbonate compound, and a solid-phase transesterification method of a prepolymer. The preparation method of the polycarbonate is described in more detail in the Chinese patent CN104987688A, and thus, the detailed description thereof is omitted.
Preferably, the polycarbonate of the present invention is at least one selected from the group consisting of aromatic polycarbonate, aliphatic polycarbonate, aromatic-aliphatic polycarbonate, and branched polycarbonate prepared by the above preparation method; more preferably, the polycarbonate is an aromatic polycarbonate with a viscosity average molecular weight of 13000-40000, even more preferably 17000-24000, and has good mechanical strength and excellent moldability when the viscosity average molecular weight of the aromatic polycarbonate is 17000-24000.
(1b) Butadiene copolymer:
in the present invention, the butadiene copolymer is prepared by a bulk polymerization method, an emulsion polymerization method, or a bulk-suspension polymerization method. The method specifically comprises the following steps: the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts of component A with 5-95 parts of component B in parts by weight, and the sum of the parts by weight of the component A and the component B is 100 parts; wherein,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is prepared by mixing 50-95 parts of component B1 and 5-50 parts of component B2, wherein the sum of the parts by weight of the component B1 and the component B2 is 100 parts, the component B1 is at least one selected from styrene, styrene derivatives (such as α -methyl styrene, p-methyl styrene and divinyl styrene), C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is at least one selected from acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
Preferably, the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS, methyl methacrylate-butadiene-styrene graft copolymer MBS.
Further preferably, the acrylonitrile-butadiene-styrene graft copolymer ABS is selected from a mixture of a thermoplastic graft copolymer and an acrylonitrile-styrene copolymer, wherein the thermoplastic graft copolymer is obtained by graft polymerizing 5-28 parts by weight of a butadiene rubber component with 15-30 parts by weight of acrylonitrile and 40-70 parts by weight of styrene, and the formula is particularly preferably as follows: a mixture of a thermoplastic graft copolymer obtained by graft-polymerizing 20 parts by weight of a butadiene rubber component with 22 parts by weight of acrylonitrile and 58 parts by weight of styrene and an acrylonitrile-styrene copolymer.
(1c) Phosphate homopolymer:
the phosphate homopolymer is a homopolymer made of phosphate units having a weight average molecular weight of more than 10000, represented by the following chemical formula (1).
In the chemical formula (1), Y is an alkyl group having 1 to 10 carbon atoms, an alkylene group having 1 to 10 carbon atoms, or a cycloalkoxy group having 5 to 12 carbon atoms, and R represents an alkyl group having 1 to 10 carbon atoms.
In the chemical formula (1), Y can be a straight-chain carbon with 1-10 carbon atoms or an alkylene with a branched chain, the branched chain can comprise ethyl, isopropyl, butyl, hexyl and the like, and the alkylene with 1-10 carbon atoms is particularly preferred; in particular, Y is cyclohexylene, preferably 2, 2-propylene, and particularly preferably 2, 2-propyleneoxy. In the chemical formula (1), 2, 2-bis (4-hydroxyphenyl) propane (i.e., bisphenol A) and a phosphate group are particularly preferable.
R in formula (1), as mentioned above, the alkyl group on the phosphoric acid may be 10 carbon atoms, and the branched chain may include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptylbutyl, octyl, nonyl, decyl, etc. The alkyl group preferably has 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, still more preferably 1 to 4 carbon atoms, and particularly preferably a methyl group, an ethyl group, and a propyl group, among which the methyl group and the ethyl group are preferable, and the most preferable is the methyl group.
The weight average molecular weight of the phosphate homopolymer is 10000 or more, preferably 15000 or more, and more preferably 20000 or more; meanwhile, the weight average molecular weight of the phosphate homopolymer is preferably 300000 or less, more preferably 200000 or less. This is because: the heat resistance of the polycarbonate resin composition having a weight average molecular weight of 10000 or less is lowered, and if the weight average molecular weight exceeds 300000, the polycarbonate resin composition may have defects such as degradation and poor appearance of compatibility. In order to avoid the defects, the phosphate ester homopolymer with the weight-average molecular weight of 35000-50000 is preferably used in the invention.
(1d) A toughening agent:
in the invention, the toughening agent is selected from at least one of methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride; the grain size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
(1e) Other auxiliary agents:
in the present invention, when the polycarbonate, the butadiene copolymer, the phosphate homopolymer and the toughening agent are mixed, other additives selected from at least one of a heat stabilizer, an antioxidant, an anti-dripping agent, a light stabilizer, a plasticizer, a filler and a colorant may be added as needed. Wherein,
suitable heat stabilizers include: organic phosphites such as triphenyl phosphite, tris- (2, 6-dimethylphenyl) phosphite, tris-nonylphenyl phosphite, dimethylbenzene phosphonate, trimethyl phosphate, and the like.
Suitable antioxidants include: organophosphites, alkylated monophenols or polyphenols, alkylated reaction products of polyphenols and dienes, butylated reaction products of p-cresol or dicyclopentadiene, alkylated hydroquinones, hydroxylated thiodiphenyl ethers, alkylene-bisphenols, benzyl compounds, polyol esters and the like.
Suitable anti-dripping agents are preferably fluorinated polyolefins, which are generally polymers or copolymers containing a fluorine-containing ethylene structure, and may be specifically exemplified by vinylidene fluoride resins, tetrafluoroethylene resins, and tetrafluoroethylene/hexafluoropropylene copolymer resins, with tetrafluoroethylene resins being preferred.
Suitable light stabilizers include at least one of benzotriazoles, benzophenones.
Suitable plasticizers are phthalates.
Suitable fillers include titanium dioxide, talc, mica, barium sulfate, and the like.
Suitable colorants include various pigments, dyes.
(2) The high heat-resistant high-toughness polycarbonate composition is prepared
Examples 1 to 6 and comparative examples 1 to 3 were prepared according to the following preparation steps, based on the parts by weight of the raw materials shown in Table 1: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer (or flame retardant), toughening agent and other auxiliaries according to the formula ratio, putting the materials into a mixer for blending, uniformly mixing, putting the materials into a double-screw extruder for melt mixing, and extruding and granulating to obtain a polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
Table 1: unit: parts by weight
Note that polycarbonate PC S-2000F, viscosity average molecular weight 25000 (Mitsubishi, Japan), butadiene copolymer ABS, PA-757 (Taiwan Chimei), was prepared by emulsion polymerization, phosphate homopolymer, Nofia HM1100(FRX), weight average molecular weight 43000, toughening agent, EM500 (Korean LG), flame retardant, Phireguard BDP (Jiangsu Yake), antioxidant AO 1076: β - (3, 5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate (CAS No.: 2082-79-3), anti-dripping agent:30N PTFE(DuPont)。
(3) product physical Property test
According to the industry standard, the nine polycarbonate compositions prepared in the above examples 1-6 and comparative examples 1-3 were subjected to a plurality of basic physical property tests. The test standards or methods for multiple basic physical property tests are as follows:
① UL94 flame retardancy test method:
the flammability test was carried out according to the protocol "flammability test of plastic materials, UL 94". Flame retardant ratings were derived based on the burn rate, extinguishing time, ability to resist dripping, and whether dripping (drip) was burning. Samples used for the test: bars having dimensions of 125mm length x 13mm width x no greater than 13mm thickness, the thickness of the bars when tested according to the invention being selected to be 1.5 mm. According to the UL94 protocol, and based on the test results obtained for five samples, the material flame retardant rating can be classified as (UL 94-HB): v0, V1, V2, 5VA and/or 5 VB; in the present invention, however, only the flame retardant rating of the material is classified as: v0, V1 and V2, and the classification criteria for each flame retardant rating are:
v0: in a sample placed so that its long axis is 180 degrees with respect to the flame, the period of burning and/or smoldering does not exceed 10 seconds after the ignition flame is removed, and the vertically placed sample does not produce dripping of combustion particles that ignite cotton wool. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the flame holding time for the first light (t1) and the flame holding time for the second light (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 50 seconds.
V1: in a sample placed so that its long axis is 180 degrees relative to the flame, the period of burning and/or smoldering does not exceed 30 seconds after the ignition flame is removed, and the vertically placed sample does not produce dripping of burning particles that ignite cotton wool. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the first lit flame holding time (t1) and the second lit flame holding time (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 250 seconds.
V2: in a sample placed so that its long axis is 180 degrees relative to the flame, the average period of burning and/or smoldering after removal of the ignition flame does not exceed 30 seconds, but a vertically placed sample produces dripping of burning particles that ignite cotton. The flame holding time for the fifth bar is the flame holding time for the five bars, each lit twice, wherein the sum of the first lit flame holding time (t1) and the second lit flame holding time (t2), i.e. the maximum flame holding time (t1+ t2), is less than or equal to 250 seconds.
② Heat Deflection Temperature (HDT) determination method HDT is determined according to test standard ASTM D648 under a load of 1.82MPa, flat with bars of 3.2mm and/or 6.4mm thickness, the results being recorded in ℃ C.
③ notched Izod impact strength was measured using a 3.2mm thick molded notched Izod impact bar at 23 ℃ the notched Izod impact strength was measured according to ASTM D256 and the results were recorded in joules/meter and tested at room temperature (23 ℃).
The nine polycarbonate compositions prepared in examples 1 to 6 of the present invention and comparative examples 1 to 3 were subjected to the above physical property tests, and the test results are shown in Table 2, by taking the average value:
table 2: basic physical properties of the polycarbonate compositions prepared in examples 1 to 6 of the present invention and comparative examples 1 to 3
Test results
As can be seen from Table 2, the polycarbonate compositions prepared in comparative examples 1 to 3 have better flame retardant rating, but the polycarbonate compositions prepared in comparative examples 1 to 3 have poor heat resistance and/or toughness, especially in comparative example 1. Different from comparative examples 1 to 3, the high heat-resistant high-toughness polycarbonate composition prepared in the embodiment of the invention has excellent toughness and heat resistance while having excellent flame retardant rating, and particularly, the embodiment of the invention does not improve the flame retardant rating of the polycarbonate composition by adding a flame retardant in a raw material formula, and the principle of improving the flame retardant rating of the polycarbonate composition obtained in the invention is essentially different from that of comparative examples 1 to 3.
The polycarbonate composition prepared by the invention has advantages in toughness, heat resistance and flame retardant grade, and is mainly benefited from the optimization and improvement of raw material formula, which is specifically represented as follows: according to the invention, the phosphate homopolymer is added into the raw material formula, and on one hand, the phosphate homopolymer can well overcome the defect that the thermal deformation temperature and the toughness of polycarbonate are greatly reduced due to the addition of an organic phosphate flame retardant in the prior art, and the heat resistance and the toughness of the polycarbonate composition are effectively improved; on the other hand, the phosphate homopolymer also has a good flame retardant effect, and the flame retardant grade of the polycarbonate composition can be effectively improved; in addition, the phosphate homopolymer has excellent compatibility with polycarbonate, does not have a plasticizing effect on alloy, can obviously improve the heat resistance of the polycarbonate composition under the condition of not influencing the flame-retardant grade and the toughness of the polycarbonate composition, and is particularly suitable for occasions with higher requirements on use environments.
The high heat-resistant high-toughness polycarbonate composition product prepared by the invention can be widely applied to mobile phones, MP3 players, computers, notebook computers, cameras, video recorders, tablet computers, hand receivers, parts of kitchen appliances or electric shells, automobile parts, shells or covers in the building field, shells and frames of electric appliances, and the like; has wide market prospect and market benefit.
The present invention has been described in detail in order to enable those skilled in the art to understand the invention and to practice it, and it is not intended to limit the scope of the invention, and all equivalent changes and modifications made according to the spirit of the present invention should be covered by the present invention.

Claims (8)

1. A polycarbonate composition with high heat resistance and high toughness is characterized in that: the formula comprises the following raw materials in parts by weight: 60-90 parts of polycarbonate, 1-20 parts of butadiene copolymer, 5-25 parts of phosphate homopolymer, 0-8 parts of toughening agent and 0-9.6 parts of other auxiliary agents, wherein the sum of the parts by weight of the components is 100 parts;
the weight average molecular weight of the phosphate homopolymer is 35000-50000, the particle size of the toughening agent is 50-700 nm, and the glue content of the toughening agent is 40-90%.
2. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the polycarbonate is at least one selected from aromatic polycarbonate, aliphatic polycarbonate, aromatic-aliphatic polycarbonate and branched polycarbonate.
3. The high heat resistance and high toughness polycarbonate composition according to claim 2, wherein: the polycarbonate is aromatic polycarbonate with the viscosity average molecular weight of 13000-40000.
4. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the butadiene copolymer is a graft copolymer formed by connecting 5-95 parts by weight of a component A with 5-95 parts by weight of a component B, wherein,
the component A is at least one selected from polybutadiene, styrene-butadiene random copolymer and block copolymer, acrylonitrile-butadiene random copolymer and block copolymer, polybutadiene and polyisoprene copolymer, ethylene and alpha-olefin copolymer, ethylene and alpha-unsaturated carboxylic ester copolymer and ethylene-propylene-non-conjugated diene terpolymer;
the component B is formed by mixing 50-95 parts of component B1 and 5-50 parts of component B2 by taking the total weight of the component B as a basis, wherein the component B1 is selected from at least one of styrene, styrene derivatives, C1-C8-alkyl methacrylate, C1-C8-alkyl acrylate, dimethyl siloxane, phenyl siloxane and polyalkylsiloxane, and the component B2 is selected from at least one of acrylonitrile, methacrylonitrile, C1-C8-alkyl methacrylate and C1-C8-alkyl acrylate.
5. The polycarbonate composition with high heat resistance and high toughness as claimed in claim 4, wherein: the butadiene copolymer is selected from at least one of styrene-butadiene-styrene block copolymer SBS, acrylonitrile-butadiene-styrene graft copolymer ABS, methyl methacrylate-acrylonitrile-butadiene styrene copolymer MABS and methyl methacrylate-butadiene-styrene graft copolymer MBS.
6. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the toughening agent is at least one selected from methyl methacrylate/butadiene/styrene copolymer, methyl methacrylate/acrylic polymer, acrylic toughening agent, acrylic acid-silicon rubber toughening agent, ethylene-methyl acrylate, ethylene-butyl acrylate, ethylene-acrylate-glycidyl methacrylate terpolymer and ethylene-vinyl acetate copolymer-functionalized maleic anhydride.
7. The high heat resistance and high toughness polycarbonate composition according to claim 1, wherein: the other auxiliary agent is selected from at least one of a heat stabilizer, an antioxidant, an anti-dripping agent, a light stabilizer, a plasticizer, a filler and a coloring agent.
8. The method for preparing a high heat-resistant high toughness polycarbonate composition according to any one of claims 1 to 7, wherein: the preparation method comprises the following preparation steps: firstly, weighing polycarbonate, butadiene copolymer, phosphate homopolymer, toughening agent and other auxiliary agents according to the formula ratio, putting the polycarbonate, the butadiene copolymer, the phosphate homopolymer, the toughening agent and the other auxiliary agents into a mixer for blending, uniformly mixing, then putting the mixture into a double-screw extruder for melt mixing, and extruding and granulating to obtain the high-heat-resistance high-toughness polycarbonate composition; the diameter of a screw of the double-screw extruder is 40:1, the temperature of each section of screw cylinder is set to be 250-260 ℃, and the rotating speed of the screw is 400-500 rpm.
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CN112625417B (en) * 2020-11-11 2022-09-20 万华化学(四川)有限公司 High-heat-resistance thin-wall flame-retardant polycarbonate alloy, method and application
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CN113999511B (en) * 2021-10-18 2023-06-06 金发科技股份有限公司 Flame-retardant polycarbonate alloy composition resistant to damp-heat as well as preparation method and application thereof
CN114539755A (en) * 2022-02-25 2022-05-27 金发科技股份有限公司 Polycarbonate composition and preparation method and application thereof
CN114573972B (en) * 2022-03-31 2023-11-14 金发科技股份有限公司 Polycarbonate composite material and preparation method and application thereof

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