CN106084511A - A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof - Google Patents
A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof Download PDFInfo
- Publication number
- CN106084511A CN106084511A CN201610414869.XA CN201610414869A CN106084511A CN 106084511 A CN106084511 A CN 106084511A CN 201610414869 A CN201610414869 A CN 201610414869A CN 106084511 A CN106084511 A CN 106084511A
- Authority
- CN
- China
- Prior art keywords
- rubber
- oil
- high temperature
- delivery hose
- resistant high
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The invention discloses a kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof, it is made up of the raw material of following weight portion: fluorinated ethylene propylene rubber 27 43, fluorosioloxane rubber 22 36, homopolymerization chlorohydrin rubber 20 30, phenolic moulding powder 13 26, cumyl peroxide 34, polypropylene glycol adipate 11 19, rock wool powder 19 28, kyanite 10 15, cobalt iso-octoate 23, naphthenic oil 68, cast waste sand 14 28, methoxyethyl acrylate 10 15, the double oleamide 35 of ethylene, triallyl cyanurate 23, zinc carbonate 36, vinyl three (β methoxy ethoxy) silane 12, auxiliary agent 34.Elastomeric material of the present invention has high temperature resistant, the oil resistance of excellence, has good mechanical strength and resistance to ag(e)ing simultaneously, improves petroleum pipeline service life under high temperature oil environment.
Description
Technical field
The present invention relates to a kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof, belong to rubber material
Material field.
Background technology
Rubber is with natural and that synthetic rubber is as raw material production various rubbers, also includes utilizing scrap rubber again
The rubber produced.Rubber is of a great variety, and physical and mechanical properties is good, elastic high, is widely used in various zero of automobile
Part, including tire, sebific duct, transmission band, sealing article, yielding rubber part and security article etc., the rubber that an automobile uses
Glue accessory has 100-200 kind, quantity up to 200-500 more than.In recent years, along with the fast development of auto industry, to rubber
The performance requirement of goods is more and more higher, and the heat-resisting quantity of oil delivery hose elastomeric material is got on the car in existing market and oil resistivity is more come
More carry out to meet the demand in market, shorten its service life.Therefore, a kind of automobile oil delivery hose oil resistant of exploitation it is badly in need of resistance to
Super heated rubber material.
Summary of the invention
Present invention aims to the deficiencies in the prior art, it is provided that a kind of automobile oil delivery hose uses oil-resistant high-temperature rubber
Glue material and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material, is made up of the raw material of following weight portion: fluorinated ethylene-propylene
Rubber 27-43, fluorosioloxane rubber 22-36, homopolymerization chlorohydrin rubber 20-30, phenolic moulding powder 13-26, cumyl peroxide 3-4, poly-oneself
Two acid propylene glycol ester 11-19, rock wool powder 19-28, kyanite 10-15, cobalt iso-octoate 2-3, naphthenic oil 6-8, cast waste sand 14-
28, methoxyethyl acrylate 10-15, ethylene double oleamide 3-5, triallyl cyanurate 2-3, zinc carbonate 3-6, ethylene
Base three ('beta '-methoxy ethyoxyl) silane 1-2, auxiliary agent 3-4；
Described auxiliary agent is made up of the raw material of following weight portion: nanometer palygorskite 8-14,2-mercaptobenzothiazole 3-6,2,2'-
Dibenzamidodiphenyl disulfide 2-4, ferrocene 1-3, bamboo charcoal powder 4-8, zinc ricinate 1-3, m-xylene diamine 5-
7, zeolite molecular sieve 10-15, PCMX 6-9, N nitrosodiphenyl amine 3-5, super Telloy 7-11,2-sulfydryl benzene
And imidazoles 2-4,2,2,4-trimethyl-1,2-dihyaroquinoline polymer 1.5-2.5.
The preparation method of a kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material, comprises the following steps:
(1) fluorinated ethylene propylene rubber, fluorosioloxane rubber, homopolymerization chlorohydrin rubber, polypropylene glycol adipate are added in banbury,
Plasticate at 60-80 DEG C 14-22min, parks more than 8h, discharging；
(2) sizing material that obtains of step (1) being plasticated adds in mill thin logical 3-4 time, then tunes up roll spacing, allows sizing material bag
Roller, after glue-line is uniform, adds cobalt iso-octoate, bisphenol AF, zinc carbonate, vinyl three ('beta '-methoxy ethyoxyl) silane, casting
Antiquated sand, rock wool powder, naphthenic oil, adjustment roll spacing is 2-3mm, and roller temperature is 70-80 DEG C, mixing 8-12min, is subsequently adding remaining former
Material, adjustment roll spacing is 2-3mm, and roller temperature is 65-75 DEG C, and mixing 10-15min parks 15-20h, discharging；
(3) being sent on vulcanizing press vulcanize by mixing for step (2) sizing material obtained, one step cure condition is
(140-160 DEG C) × (30-40min), post vulcanization condition is (250-270 DEG C) × (2-3h).
Beneficial effects of the present invention:
The present invention is the most multiple with the excellent fluorinated ethylene propylene rubber of thermostability and oil resistivity, fluorosioloxane rubber, homopolymerization chlorohydrin rubber
Cooperation is primary raw material, and with the addition of the raw materials such as phenolic moulding powder, rock wool powder, kyanite, cast waste sand, makes the rubber material prepared
Material has high temperature resistant, the oil resistance of excellence, has good mechanical strength and resistance to ag(e)ing simultaneously, improves petroleum pipeline at height
Service life under temperature oil environment.
Detailed description of the invention
Embodiment
A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material, is made up of the raw material of following weight (kg): fluorination second
Third rubber 36, fluorosioloxane rubber 32, homopolymerization chlorohydrin rubber 25, phenolic moulding powder 21, cumyl peroxide 3.5, polyadipate propylene glycol
Ester 14, rock wool powder 23, kyanite 12, cobalt iso-octoate 2.5, naphthenic oil 7, cast waste sand 24, methoxyethyl acrylate 12, ethylene
Double oleamides 4.5, triallyl cyanurate 2.5, zinc carbonate 4.5, vinyl three ('beta '-methoxy ethyoxyl) silane 1.5,
Auxiliary agent 3.5；
Described auxiliary agent is made up of the raw material of following weight (kg): nanometer palygorskite 13,2-mercaptobenzothiazole 5,2,2'-bis-
Benzamido diphenyl disulfide 3.5, ferrocene 2.5, bamboo charcoal powder 7, zinc ricinate 2.5, m-xylene diamine 6, zeolite
Molecular sieve 14, PCMX 8, N nitrosodiphenyl amine 4.5, super Telloy 10,2-mercaptobenzimidazole 3,2,2,
4-trimethyl-1,2-dihyaroquinoline polymer 2.
The preparation method of a kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material, comprises the following steps:
(1) fluorinated ethylene propylene rubber, fluorosioloxane rubber, homopolymerization chlorohydrin rubber, polypropylene glycol adipate are added in banbury,
Plasticate at 60-80 DEG C 14-22min, parks more than 8h, discharging；
(2) sizing material that obtains of step (1) being plasticated adds in mill thin logical 3-4 time, then tunes up roll spacing, allows sizing material
Bag roller, after glue-line is uniform, adds cobalt iso-octoate, bisphenol AF, zinc carbonate, vinyl three ('beta '-methoxy ethyoxyl) silane, casting
Making antiquated sand, rock wool powder, naphthenic oil, adjustment roll spacing is 2-3mm, and roller temperature is 70-80 DEG C, mixing 8-12min, is subsequently adding remaining former
Material, adjustment roll spacing is 2-3mm, and roller temperature is 65-75 DEG C, and mixing 10-15min parks 15-20h, discharging；
(3) being sent on vulcanizing press vulcanize by mixing for step (2) sizing material obtained, one step cure condition is
(140-160 DEG C) × (30-40min), post vulcanization condition is (250-270 DEG C) × (2-3h).
The performance test results of the elastomeric material that above-described embodiment prepares is as shown in the table:
The table 1 automobile oil delivery hose main performance testing result of oil-resistant high temperature-resistanrubber rubber material
。
Claims (2)
1. an automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material, it is characterised in that be made up of the raw material of following weight portion:
Fluorinated ethylene propylene rubber 27-43, fluorosioloxane rubber 22-36, homopolymerization chlorohydrin rubber 20-30, phenolic moulding powder 13-26, peroxidating two are different
Propyl benzene 3-4, polypropylene glycol adipate 11-19, rock wool powder 19-28, kyanite 10-15, cobalt iso-octoate 2-3, naphthenic oil
6-8, cast waste sand 14-28, methoxyethyl acrylate 10-15, ethylene double oleamide 3-5, triallyl cyanurate
2-3, zinc carbonate 3-6, vinyl three ('beta '-methoxy ethyoxyl) silane 1-2, auxiliary agent 3-4；
Described auxiliary agent is made up of the raw material of following weight portion: nanometer palygorskite 8-14,2-mercaptobenzothiazole 3-6,2,2'-bis-
Benzamido diphenyl disulfide 2-4, ferrocene 1-3, bamboo charcoal powder 4-8, zinc ricinate 1-3, m-xylene diamine
5-7, zeolite molecular sieve 10-15, PCMX 6-9, N nitrosodiphenyl amine 3-5, super Telloy 7-11,2-
Mercaptobenzimidazole 2-4,2,2,4-trimethyl-1,2-dihyaroquinoline polymer 1.5-2.5.
The preparation method of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material the most according to claim 1, its feature exists
In, comprise the following steps:
(1) fluorinated ethylene propylene rubber, fluorosioloxane rubber, homopolymerization chlorohydrin rubber, polypropylene glycol adipate are added in banbury,
Plasticate at 60-80 DEG C 14-22min, parks more than 8h, discharging；
(2) sizing material that obtains of step (1) being plasticated adds in mill thin logical 3-4 time, then tunes up roll spacing, allows sizing material bag roller,
After glue-line is uniform, adds cobalt iso-octoate, bisphenol AF, zinc carbonate, vinyl three ('beta '-methoxy ethyoxyl) silane, cast and give up
Sand, rock wool powder, naphthenic oil, adjustment roll spacing is 2-3mm, and roller temperature is 70-80 DEG C, mixing 8-12min, is subsequently adding remaining raw material,
Adjustment roll spacing is 2-3mm, and roller temperature is 65-75 DEG C, and mixing 10-15min parks 15-20h, discharging；
(3) being sent on vulcanizing press vulcanize by mixing for step (2) sizing material obtained, one step cure condition is (140-
160 DEG C) × (30-40min), post vulcanization condition is (250-270 DEG C) × (2-3h).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414869.XA CN106084511A (en) | 2016-06-06 | 2016-06-06 | A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414869.XA CN106084511A (en) | 2016-06-06 | 2016-06-06 | A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106084511A true CN106084511A (en) | 2016-11-09 |
Family
ID=57846495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610414869.XA Pending CN106084511A (en) | 2016-06-06 | 2016-06-06 | A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106084511A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103012892A (en) * | 2012-11-25 | 2013-04-03 | 安徽六方重联机械股份有限公司 | Automobile framework oil seal rubber and preparation method thereof |
-
2016
- 2016-06-06 CN CN201610414869.XA patent/CN106084511A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103012892A (en) * | 2012-11-25 | 2013-04-03 | 安徽六方重联机械股份有限公司 | Automobile framework oil seal rubber and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9840611B2 (en) | Rubber compositions and uses thereof | |
| CN105848923B (en) | Tire production Rubber compound | |
| CN104017280B (en) | The production technique of ageing-resistant tyre capsule sizing material | |
| US9663640B2 (en) | Rubber compositions and uses thereof | |
| CN103131060A (en) | Rubber material and method for machining automobile front auxiliary frame lining with rubber material | |
| CN103834113A (en) | Formula of EPDM (ethylene propylene diene monomer) material applied to dynamic-fatigue-resistant products and preparation method of EPDM material | |
| CN109627580B (en) | Light-colored permanent antistatic modified polypropylene material and preparation method thereof | |
| CN109762212A (en) | A kind of super abrasive conveyer belt and its preparation process | |
| CN104530550B (en) | A kind of thermoplastic elastomer (TPE) and preparation method thereof and the moulding process for conveyer belt | |
| CN101412823A (en) | Rubber composition and tire having component containing combination of emulsion SBR and tackifying resin | |
| CN105860533A (en) | High and low temperature resisting rubber material for automotive air conditioner rubber tube and preparing method thereof | |
| CN106084511A (en) | A kind of automobile oil delivery hose oil-resistant high temperature-resistanrubber rubber material and preparation method thereof | |
| CN105924934A (en) | Wear-resistant rubber material and preparation method thereof for automobile tires | |
| CN105670146A (en) | High-performance vulcanized rubber jacket for transmission belts | |
| CN109705408A (en) | A kind of high-intensitive conveyer belt and its preparation process of resisting cold | |
| CN105860393A (en) | Low-compression-set rubber material for automobile transmission oil seal and preparing method thereof | |
| CN110655690A (en) | High-hardness low-heat-generation low-rolling-resistance solid tire tread rubber material and preparation method thereof | |
| CN102558646B (en) | Anti-impact and wear-resistant high-molecular-weight polyethylene composite lining plate and preparation method for same | |
| CN104804263A (en) | Low-friction butylbenzene/natural rubber composite material and preparation method thereof | |
| CN105646954A (en) | Tire sidewall rubber without mold release agent | |
| CN102140191B (en) | High-wear resistance skirt rubber material for reconstruction of conveyer belt on damage site and skirt on-site reconstruction method | |
| CN116160736B (en) | Super wear-resistant rubber conveyer belt and preparation method thereof | |
| CN106084317A (en) | A kind of automobile conveyer belt high-strength tear-resistant splits elastomeric material and preparation method thereof | |
| CN109762217A (en) | A kind of large junk dedicated conveyer belt and its preparation process | |
| CN105936746A (en) | Wear resistant and antifatigue rubber material for automobile bearing seal rings and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |
|
| RJ01 | Rejection of invention patent application after publication |