CN106079013A - A kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide - Google Patents

A kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide Download PDF

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Publication number
CN106079013A
CN106079013A CN201610469375.1A CN201610469375A CN106079013A CN 106079013 A CN106079013 A CN 106079013A CN 201610469375 A CN201610469375 A CN 201610469375A CN 106079013 A CN106079013 A CN 106079013A
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China
Prior art keywords
solution
chlorine dioxide
chlorite
chlorate
citric acid
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CN201610469375.1A
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Chinese (zh)
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CN106079013B (en
Inventor
丁四泉
刘志刚
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WANHUA HEXIANG PLATE INDUSTRY (HUAIYUAN) Co.,Ltd.
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Wanhua Ecoboard Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00—Pretreatment of moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/0228—Spraying apparatus, e.g. tunnels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00—Chemical or physical treatment of reed, straw, or similar material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/20—Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention provides a kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide, comprise the following steps: chlorite crystal or chlorate crystal water dissolution are configured to chlorite solution or solution of chlorate；Citric acid crystal water dissolution is configured to citric acid solution；By chlorite solution or solution of chlorate, mix in hermetic container according to the mass ratio of 9～10:5 with citric acid solution, and it is shaken until reacting and terminating, i.e. prepare aqueous solution of chlorine dioxide；Aqueous solution of chlorine dioxide is transferred in the tank of resistance to chemical attack, then uses compressed gas to apply, in straw blank workshop section, the wood shavings particle after chopping to be carried out sterilization in air-stream spraying mode by aqueous solution of chlorine dioxide.The present invention solves deficiency of the prior art, is conducive to the interior quality anti-mildew improving wood-based plate to become, and more can reduce artificial chipboard and bring unsafe pathogenic risk to human health during producing and using.

Description

A kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide
Technical field
The present invention relates to the sterilization of the wood shavings material of a kind of ecological stalk-shaving board, straw wood shavings material of especially lossing In high pathogenic bacterium and virus, reduce high pathogenic bacterium and virus through being broadcast to the risk that human health is brought, belong to Chemical activator Engineering field.
Background technology
At present, the big class of wood shavings material main two of artificial chipboard manufacturing enterprise: wooden shavings and agricultural crop straw wood shavings.It At the links grown up to, gather, transport, store in a warehouse, the time is long, and spatial environments is complicated, and various pathogenic bacterium and virus are easily at plane Middle parasitism and breeding, especially agricultural crop straw is spent to be more easy to contact with the feces of the mankind and poultry, its cross transmission, the chance of infection The highest.Therefore, its wood shavings goods are in plant produced manufacture process, and it is carried out abundant sterilization is necessary.And At present, artificial stalk board manufacturing enterprise is that the straw of purchase is stored a period of time, natural drying in process of production.Post-treatment Stage carries out hot air convective drying, then through applying glue, hot pressing, the production technology of molding.Though the course of processing is through certain high temperature mistake Journey, but blind spot is a lot, can not be thorough to sterilizing and virus killing.Therefore, the manufacture process at wood shavings goods increases the most broken to wood shavings It is necessary that material carries out the operation of special sterilizing and virus killing, is also feasible.
Sterilization effect of chlorine dioxide has been ripe technology." New Type Water Treatment Chemicals-chlorine dioxide technology and should With " book discusses the most detailed, (yellow monarch's gift writes, and Chemical Industry Press publishes), the preparation of chlorine dioxide and accumulating etc. have certain Technical difficulty, its application has certain limitation.
Summary of the invention
The invention provides a kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide, solve existing skill Deficiency in art, this process advan in improve wood-based plate interior quality anti-mildew become, more can reduce artificial chipboard produce and Unsafe pathogenic risk is brought to human health during use.
Realizing the technical scheme that above-mentioned purpose of the present invention used is:
A kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide, comprises the following steps: (1), by chlorite Crystal or chlorate crystal water dissolution, be configured to chlorite solution or solution of chlorate that concentration is 35%～55%；By lemon Lemon acid crystal water dissolution, is configured to the citric acid solution that concentration is 35%～55%；
(2), by chlorite solution or solution of chlorate, with citric acid solution according to 9～10:5 mass ratio at hermetic container In mix, and it is shaken until reacting and terminating, i.e. prepares aqueous solution of chlorine dioxide；
(3), aqueous solution of chlorine dioxide is transferred in the tank of resistance to chemical attack, then uses compressed gas by titanium dioxide Chlorine water solution applies, in straw blank workshop section, the wood shavings particle after chopping to be carried out sterilization in air-stream spraying mode.
Chlorite described in step (1) is sodium chlorite or potassium chlorite, and described chlorate is sodium chlorate or chlorine Acid potassium.
Tank described in step (3) is Teflon coating container or glass steel container.
Compressed gas described in step (3) is compressed air, carbon dioxide or nitrogen.
Chlorine dioxide is the gas that a kind of yellow green to Chinese red has similar chlorine penetrating odor, works as chlorine dioxide concentration As little as during 100mg/L, its abnormal smells from the patient is light grass smell, and concentration is the highest, and its Odor stimulation increases.Chlorine dioxide is in water Being partly dissolved, and exist with stable molecular conformation, darken along with concentration of ordinary dissolution increases its aqueous solution, its aqueous solution is by Huang Green to Chinese red conversion.Chlorine dioxide is a kind of to have the most strongly active oxidant, shows higher, to micro-under illumination condition What bioprotein performance was the strongest penetrates inactivating effect, to many oxidized decomposition reactions of material frowzy, and removes its stench Problem.Resolvating agent hydrone can play catalysis instrumentality, strengthens the infiltration of chlorine dioxide, promotes chlorine dioxide same The inside of wood shavings material is merged, and effectively adds penetrating of chlorine dioxide microorganism in colonizing in wood shavings body, and makes to cause a disease Bacterium and virus are loss or inactivate.
Compared with prior art, based on chlorine dioxide the ecological stalk-shaving board sterilization technique tool that the present invention provides Have the advantage that using the aqueous solution of chlorine dioxide of the present invention that stalk board raw material carries out sterilization processes technique, it is thus achieved that Anti-mildew change, high-quality environment protective healthy ecology straw board without the bacterium that causes a disease.Aqueous solution of chlorine dioxide can also be used for stalk board Material grows the removing of mycete.The present invention has good economic benefit and social benefit.
Detailed description of the invention
Specifically comprising the following steps that of ecological stalk-shaving board sterilization technique based on chlorine dioxide provided by the present invention (1), by chlorite crystal or chlorate crystal water dissolution, it is configured to chlorite solution or chlorine that concentration is 35%～55% Acid salt solution；By Citric acid crystal water dissolution, it is configured to the citric acid solution that concentration is 35%～55%；
(2), by chlorite solution or solution of chlorate, with citric acid solution according to 9～10:5 mass ratio at hermetic container In mix, and it is shaken until reacting and terminating, i.e. prepares aqueous solution of chlorine dioxide；
(3), aqueous solution of chlorine dioxide is transferred in the tank of resistance to chemical attack, then uses compressed gas by titanium dioxide Chlorine water solution applies, in straw blank workshop section, the wood shavings particle after chopping to be carried out sterilization in air-stream spraying mode.
Below in conjunction with specific embodiment the present invention done detailed specific description, but protection scope of the present invention not office It is limited to following example.
Embodiment 1
A, take mass percent concentration identical sodium chlorite aqueous solution 200g and aqueous citric acid solution 100g pour into same can be close In the container of envelope, equal 60min is shaken in mixing, obtains aqueous solution of chlorine dioxide；
B, take the straw wood shavings particle 100g of the abnormal smells from the patient that substantially goes mouldy standby sterilizing in a transparent sealable container of tubulose and kill Poison.Take above-mentioned ClO 2 solution 10g in hand-held siphon jet nozzle nebulizer storing fill in, build lid；
C, startup compressed air sprayer unit.In above-mentioned standby sterilization wood shavings particle, atomization applying chlorine dioxide is water-soluble Liquid；
D, observe find: the chlorine dioxide yellow green water smoke of gasification in transparent pipe color from depth to shallow, virus killing subject to sterilization Wood shavings particle color is the vividest；
E, after 15s-30s take out wood shavings particle, original go mouldy abnormal smells from the patient disappear, its wood shavings smell light grass smell and then go out Bacterium virus killing is fully；If there being the penetrating odor being similar to more by force chlorine, then explanation Chlorine excess, can reduce it and apply Amount；If its wood shavings particle still has the abnormal smells from the patient that goes mouldy, then chlorine dioxide applied amount is inadequate, need to strengthen the applied amount of chlorine dioxide.
Embodiment 2
A, take the sodium chlorite aqueous solution 180g that mass percent concentration is identical, aqueous citric acid solution 100g, pour into same can be close In the container of envelope, equal 60min is shaken in mixing, obtains aqueous solution of chlorine dioxide standby；
B, take substantially sewage 100g at blackout and wood shavings stacking frowzy, be put in sterilization deodorization in a glass beaker Taste；
C, take above-mentioned aqueous solution of chlorine dioxide about 3g with glue head straw, drip in above-mentioned sewage, and constantly shake；
D it has been observed that in said process the black of sewage gradually become shallower as to becoming clarification completely, the stink of solution is with the change of black Shallow and gradually weaken to being wholly absent.
Above-mentioned two embodiments detect in biochemical laboratory after sterilization: escherichia coli, staphylococcus aureus, withered Grass bacillus cereus, Resina garciniae ease coccus, bacillus pyocyaneus, dysentery bacterium, Salmonella and shigella and poliovirus I Type, Coxsackie B virus, Chinese mugwort can virus II, adenovirus I type, monomer Simplex Virus Type I and mumps virus, B-type hepatitis The antibacterial such as poison, influenza virus I, II, type III and virus are all loss inactivation.

Claims (4)

1. an ecological stalk-shaving board sterilization technique based on chlorine dioxide, it is characterised in that comprise the following steps: (1), by chlorite crystal or chlorate crystal water dissolution, it is configured to chlorite solution or chlorine that concentration is 35%～55% Acid salt solution；By Citric acid crystal water dissolution, it is configured to the citric acid solution that concentration is 35%～55%；
(2), by chlorite solution or solution of chlorate, with citric acid solution according to 9～10:5 mass ratio at hermetic container In mix, and it is shaken until reacting and terminating, i.e. prepares aqueous solution of chlorine dioxide；
(3), aqueous solution of chlorine dioxide is transferred in the tank of resistance to chemical attack, then uses compressed gas by titanium dioxide Chlorine water solution applies, in straw blank workshop section, the wood shavings particle after chopping to be carried out sterilization in air-stream spraying mode.
Ecological stalk-shaving board sterilization technique based on chlorine dioxide the most according to claim 1, it is characterised in that: Chlorite described in step (1) is sodium chlorite or potassium chlorite, and described chlorate is sodium chlorate or potassium chlorate.
Ecological stalk-shaving board sterilization technique based on chlorine dioxide the most according to claim 1, it is characterised in that: Tank described in step (3) is Teflon coating container or glass steel container.
Ecological stalk-shaving board sterilization technique based on chlorine dioxide the most according to claim 1, it is characterised in that: Compressed gas described in step (3) is compressed air, carbon dioxide or nitrogen.
CN201610469375.1A 2016-06-25 2016-06-25 A kind of ecological stalk-shaving board sterilization technique based on chlorine dioxide Active CN106079013B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113172722A (en) * 2021-03-30 2021-07-27 索菲亚家居股份有限公司 Formaldehyde-free addition shaving board and preparation method and application thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6067107A (en) * 1983-09-24 1985-04-17 Sanyo Kokusaku Pulp Co Ltd Manufacture of particle board
JPH0671621A (en) * 1992-08-28 1994-03-15 Eidai Co Ltd Production of wood board superior in water resistance, weatherability, and the like
CN1943359A (en) * 2006-10-13 2007-04-11 山西中威水处理技术有限公司 Method for preparing sterilizing and alga killing agent
CN101143225A (en) * 2007-10-17 2008-03-19 艾雪莉 Air purifying agent and its preparing process
CN101195232A (en) * 2007-12-28 2008-06-11 深圳市神竹科技有限公司 Rice-wheat haulm plywood and process technique thereof
CN101269507A (en) * 2008-05-15 2008-09-24 东营正和木业有限公司 Manufacturing technique for mildew resistant middle, high-density pressed-fibre board
CN101384507A (en) * 2006-02-17 2009-03-11 大幸药品株式会社 Chlorine dioxide generating composition
CN202379730U (en) * 2011-12-29 2012-08-15 西安兴德环保科技有限公司 Novel high-purity chlorine dioxide generator
CN103711016A (en) * 2012-09-28 2014-04-09 顾安东 Pretreatment and storage method for artificial straw board raw materials

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6067107A (en) * 1983-09-24 1985-04-17 Sanyo Kokusaku Pulp Co Ltd Manufacture of particle board
JPH0671621A (en) * 1992-08-28 1994-03-15 Eidai Co Ltd Production of wood board superior in water resistance, weatherability, and the like
CN101384507A (en) * 2006-02-17 2009-03-11 大幸药品株式会社 Chlorine dioxide generating composition
CN1943359A (en) * 2006-10-13 2007-04-11 山西中威水处理技术有限公司 Method for preparing sterilizing and alga killing agent
CN101143225A (en) * 2007-10-17 2008-03-19 艾雪莉 Air purifying agent and its preparing process
CN101195232A (en) * 2007-12-28 2008-06-11 深圳市神竹科技有限公司 Rice-wheat haulm plywood and process technique thereof
CN101269507A (en) * 2008-05-15 2008-09-24 东营正和木业有限公司 Manufacturing technique for mildew resistant middle, high-density pressed-fibre board
CN202379730U (en) * 2011-12-29 2012-08-15 西安兴德环保科技有限公司 Novel high-purity chlorine dioxide generator
CN103711016A (en) * 2012-09-28 2014-04-09 顾安东 Pretreatment and storage method for artificial straw board raw materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113172722A (en) * 2021-03-30 2021-07-27 索菲亚家居股份有限公司 Formaldehyde-free addition shaving board and preparation method and application thereof

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Address before: 434303 Hubei, Jingzhou, Gongan County, Qinghai Industrial Park, east of Xingye Road, south of Minsheng Road.

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