CN106076428B - It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil - Google Patents
It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil Download PDFInfo
- Publication number
- CN106076428B CN106076428B CN201610431669.5A CN201610431669A CN106076428B CN 106076428 B CN106076428 B CN 106076428B CN 201610431669 A CN201610431669 A CN 201610431669A CN 106076428 B CN106076428 B CN 106076428B
- Authority
- CN
- China
- Prior art keywords
- recessed soil
- catalyst
- soil matrix
- matrix catalyst
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 43
- 239000002689 soil Substances 0.000 title claims abstract description 36
- 239000011159 matrix material Substances 0.000 title claims abstract description 19
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 17
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002608 ionic liquid Substances 0.000 claims abstract description 16
- 229960000892 attapulgite Drugs 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 10
- 150000004040 pyrrolidinones Chemical class 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 20
- 230000020477 pH reduction Effects 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000000465 moulding Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 150000007522 mineralic acids Chemical class 0.000 claims description 5
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 16
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 238000010790 dilution Methods 0.000 description 10
- 239000012895 dilution Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 9
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 9
- 229910052794 bromium Inorganic materials 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000005070 sampling Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229910003158 γ-Al2O3 Inorganic materials 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910001648 diaspore Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JDQDSEVNMTYMOC-UHFFFAOYSA-N 3-methylbenzenesulfonic acid Chemical compound CC1=CC=CC(S(O)(=O)=O)=C1 JDQDSEVNMTYMOC-UHFFFAOYSA-N 0.000 description 1
- CHEADILRIOMTBE-UHFFFAOYSA-N 4-methylbenzenesulfonic acid;pyrrolidin-2-one Chemical class O=C1CCCN1.CC1=CC=C(S(O)(=O)=O)C=C1 CHEADILRIOMTBE-UHFFFAOYSA-N 0.000 description 1
- -1 N- isopropylpyrrolidine ketone Chemical class 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0292—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature immobilised on a substrate
- B01J31/0294—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature immobilised on a substrate by polar or ionic interaction with the substrate, e.g. glass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
Abstract
It is the invention belongs to reform the purification process field of oil product, in particular to a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil.The present invention provides a kind of using mineral acid acidified attapulgite as raw material, and it is organically-modified to load the progress of pyrrolidinone compounds ionic liquid, prepare the preparation method for removing the acidic catalyst of trace amounts of olefin in reformed oil, the catalyst is not under conditions of changing existing carclazyte method deolefination device, substitute existing clay catalyst, remove the trace amounts of olefin of reformed oil, the preparation process of catalyst is simple, and it is at low cost, catalyst life is long (10 months), and deolefination temperature is low (140~180 DEG C).
Description
Technical field
It is the invention belongs to reform the purification process field of oil product, in particular to a kind of micro in reformed oil for removing
The preparation method and application of the recessed soil matrix catalyst of alkene.
Background technique
Contain a certain amount of olefin impurity, these olefin impurity properties in reformed oil (intermediate products of aromatics production)
It is very active, it is easy to which that polymerization, which forms colloid, influences the quality of aromatic hydrocarbon product, can be right olefin(e) centent considerably less (ppm grades)
Subsequent reactions process generates very detrimental effect.In order to obtain qualified industrial chemicals and guarantee subsequent technique it is smooth into
Row, it is necessary to by olefin removal a small amount of in reformed oil, to improve the economic benefit of aromatic hydrocarbons processing technology.
Summary of the invention
The present invention is directed to short using the removing of catalyst in the prior art alkene temperature higher (180~210 DEG C), service life
The technical issues of (2~3 months), provides a kind of preparation process of the acidification Attapulgite Catalyst of supported ion liquid, and its
Method for trace amounts of olefin in catalytic eliminating reformed oil, it is ensured that aromatic hydrocarbons in subtractive process in reformed oil not by
Loss, and reduce deolefination temperature, extend catalyst life.
Preparation method of the present invention are as follows: using inorganic acid to attapulgite carry out acidification, then filter drying,
Graininess is made after molding, roasting and is acidified recessed soil；Then the recessed soil of resulting graininess acidification is added in ionic liquid again and is carried out
It is loaded modified, recessed soil matrix catalyst is obtained after drying,
Wherein, inorganic acid is sulfuric acid or hydrochloric acid, and inorganic acid concentration is 0.5mol/L~2mol/L,
Ionic liquid is pyrrolidinone compounds ionic liquid, and specially pyrrolidones reacts gained with sulfuric acid or p-methyl benzenesulfonic acid
Pyrrolidinone compounds ionic liquid,
Wherein, pyrrolidones is the one or more of mixtures having following structure,
Wherein, R is saturations or undersaturated straight chain or the alkyl with branch, the carbon atom number of the alkyl 1~20 it
Between；
It is 50 DEG C~90 DEG C that graininess, which is acidified, and carries out loaded modified temperature in recessed soil addition ionic liquid, loaded modified
Time be 0.5~2h, it is loaded modified after drying temperature be 100 DEG C~160 DEG C, 3.0~5.0h of drying time,
Ingredient proportion is controlled, the content 1%~15% (wt) of resulting recessed soil matrix catalyst intermediate ion liquid, particle are made
The recessed native content of shape acidification is 85%~99% (wt).
The present invention also provides a kind of recessed soil matrix catalyst using above method preparation is micro- in removing reformed oil
Measure the application of alkene, concrete application are as follows: recessed soil matrix catalyst is put into tubular continuous reactor, reformed oil is passed through, into
Row tubular type successive reaction, tubular continuous reactor exported product are the reformed oil for removing alkene,
Wherein, the pressure of tubular type successive reaction be 0.5MPa~3MPa, air speed 0.5h-1~5h-1, reaction temperature 130
DEG C~180 DEG C.
The beneficial effects of the present invention are: first by ionic liquid loaded on acidified attapulgite, then will
The loaded catalyst arrived is used for the processing of reformed oil, and loaded catalyst has a small amount of alkene in reformed oil
Very strong removing selectivity, therefore not will lead to the reduction of the effective component aromatic hydrocarbons of reformed oil in treatment process.
Specific embodiment
Embodiment 1
It weighs 10 grams of attapulgites to be added in the beaker equipped with the dilution heat of sulfuric acid that 40ml concentration is 0.5mol/L, be heated to
90 DEG C, stir 1.5h, after stopping acidification, filtration washing to neutrality；Forming agent is added after drying, and (forming agent is γ-Al2O3With it is quasi-
Boehmite is prepared by mixing into according to the weight ratio of 1:1；The mass ratio of forming agent dosage and attapulgite is 20:80) molding,
110 DEG C of drying 12h, 550 DEG C of roasting 8h obtain particle and are acidified recessed soil.Take the N-Methyl pyrrolidone and p-methyl benzenesulfonic acid of 1 mass parts
Manufactured ionic liquid, after dilution plus the aforementioned particles of 99 mass parts are acidified recessed soil, are heated to 70 DEG C of stirring 3h, filter, 150 DEG C
Drying 4hr obtains catalyst.
The catalyst 5g prepared in the present embodiment is fitted into fixed bed continuous tubular reactor, reformed oil (raw material
Bromine index is 1877mgBr/100g oil, raw material 47.02wt% containing aromatic hydrocarbons (referring to benzene,toluene,xylene total amount)) it is squeezed into instead with pump
It answers in device, holding pressure is 1.3MPa, controls 180 DEG C of temperature, air speed (weight space velocity) 0.5h-1, reactor outlet sampling analysis
Bromine index is 96mgBr/100g oil, product 46.98wt% containing aromatic hydrocarbons.
Embodiment 2
It weighs 10 grams of attapulgites to be added in the beaker equipped with the dilution heat of sulfuric acid that 40ml concentration is 1mol/L, is heated to 80
DEG C, stir 1.5h, after stopping acidification, filtration washing to neutrality；Forming agent is added after drying, and (forming agent is γ-Al2O3With intend it is thin
Diaspore is prepared by mixing into according to the weight ratio of 1:1；The mass ratio of forming agent dosage and attapulgite is 20:80) molding, 110
DEG C drying 12h, 550 DEG C of roasting 8h, obtain the recessed soil of particle acidification.Take the N- isopropylpyrrolidine ketone and p-methyl benzenesulfonic acid of 10 mass parts
Manufactured ionic liquid, after dilution plus the aforementioned particles of 90 mass parts are acidified recessed soil, are heated to 70 DEG C of stirring 3h, filter, 130 DEG C
Drying 3hr obtains catalyst.
The catalyst 5g prepared in the present embodiment is fitted into fixed bed continuous tubular reactor, reformed oil (ingredient
With embodiment 1) it is squeezed into reactor with pump, holding pressure is 1.1MPa, controls 150 DEG C of temperature, air speed 1h-1, reactor outlet
Sampling analysis bromine index is 56mgBr/100g oil, product 46.92wt% containing aromatic hydrocarbons.
Embodiment 3
It weighs 10 grams of attapulgites to be added in the beaker equipped with the dilution heat of sulfuric acid that 40ml concentration is 2mol/L, is heated to 70
DEG C, stir 2h, after stopping acidification, filtration washing to neutrality；Forming agent is added after drying, and (forming agent is γ-Al2O3With intend thin water
Aluminium stone is prepared by mixing into according to the weight ratio of 1:1；The mass ratio of forming agent dosage and attapulgite is 20:80) molding, 110 DEG C
12h, 550 DEG C of roasting 8h are dried, particle is obtained and is acidified recessed soil.The N-Methyl pyrrolidone of 15 mass parts is taken to be made with p-methyl benzenesulfonic acid
Ionic liquid, after dilution plus the aforementioned particles of 85 mass parts are acidified recessed soil, are heated to 70 DEG C of stirring 3h, filter, and 150 DEG C dry
3hr obtains catalyst.
The catalyst 5g prepared in the present embodiment is fitted into fixed bed continuous tubular reactor, reformed oil (ingredient
With embodiment 1) it is squeezed into reactor with pump, holding pressure is 1.4MPa, controls 140 DEG C of temperature, air speed 1h-1, reactor outlet
Sampling analysis bromine index is 45mgBr/100g oil, product 46.92wt% containing aromatic hydrocarbons.
Embodiment 4
It weighs 10 grams of attapulgites to be added in the beaker equipped with the dilution heat of sulfuric acid that 40ml concentration is 2mol/L, is heated to 80
DEG C, stir 1h, after stopping acidification, filtration washing to neutrality；Forming agent is added after drying, and (forming agent is γ-Al2O3With intend thin water
Aluminium stone is prepared by mixing into according to the weight ratio of 1:1；The mass ratio of forming agent dosage and attapulgite is 20:80) molding, 110 DEG C
12h, 550 DEG C of roasting 8h are dried, particle is obtained and is acidified recessed soil.Take 15 mass parts N- Lauryl pyrolidone and sulfuric acid made of from
Sub- liquid, after dilution plus the aforementioned particles of 85 mass parts are acidified recessed soil, are heated to 70 DEG C of stirring 3h, filter, 140 DEG C of drying 4hr
Obtain catalyst.
The catalyst 5g prepared in the present embodiment is fitted into fixed bed continuous tubular reactor, reformed oil (ingredient
With embodiment 1) it is squeezed into reactor with pump, holding pressure is 1MPa, controls 180 DEG C of temperature, air speed 5h-1, reactor outlet takes
It is 95mgBr/100g oil, product 46.95wt% containing aromatic hydrocarbons that sample, which analyzes bromine index,.
Embodiment 5
It weighs 10 grams of attapulgites to be added in the beaker equipped with the dilution heat of sulfuric acid that 40ml concentration is 0.5mol/L, be heated to
90 DEG C, stir 2h, after stopping acidification, filtration washing to neutrality；Forming agent is added after drying, and (forming agent is γ-Al2O3With intend it is thin
Diaspore is prepared by mixing into according to the weight ratio of 1:1；The mass ratio of forming agent dosage and attapulgite is 20:80) molding, 110
DEG C drying 12h, 550 DEG C of roasting 8h, obtain the recessed soil of particle acidification.Take 10 mass parts polyvinylpyrrolidone and sulfuric acid made of from
Sub- liquid, after dilution plus the aforementioned particles of 90 mass parts are acidified recessed soil, are heated to 70 DEG C of stirring 3h, filter, 140 DEG C of drying 4hr
Obtain catalyst.
The catalyst 5g prepared in the present embodiment is fitted into fixed bed continuous tubular reactor, reformed oil (ingredient
With embodiment 1) it is squeezed into reactor with pump, holding pressure is 1.5MPa, controls 140 DEG C of temperature, air speed 4h-1, reactor outlet
Sampling analysis bromine index is 78mgBr/100g oil, product 46.94wt% containing aromatic hydrocarbons.
Embodiment 6- life test
Catalyst 5g prepared by embodiment 3 is fitted into successive reaction (this partially catalyzed in fixed bed continuous tubular reactor
Agent is always in the reactor), reformed oil (ingredient is with embodiment 1) is squeezed into reactor with pump, and holdings pressure is 1.4MPa,
Air speed 1h-1In the case where constant, 140 DEG C of initial reaction temperature are controlled, if the bromine index of sample tap product is more than or equal to
100mgBr/100g oil, then improve 10 DEG C of temperature, is promoted until 180 DEG C until reaction temperature, service life investigation terminates.Implement
The service life of 3 catalyst of example is 300 days (10 months) or more, as a result be see the table below:
| Time/day | Reaction temperature/DEG C | Bromine index/mgBr/100g oil |
| 1 | 140 | 45 |
| 75 | 140 | 93 |
| 76 | 150 | 29 |
| 140 | 150 | 103 |
| 141 | 160 | 48 |
| 208 | 160 | 99 |
| 209 | 170 | 44 |
| 259 | 170 | 101 |
| 260 | 180 | 52 |
| 305 | 180 | 101 |
Amount in this experimental product containing aromatic hydrocarbons is between 46.90wt%~47.00%, almost without loss.
Comparative example 1
Loaded catalyst in embodiment 3 is replaced all with into the ionic liquid effective component in the catalyst, remaining
It operates constant:
By ionic liquid 5g made of N-Methyl pyrrolidone in embodiment 3 and p-methyl benzenesulfonic acid, reforms and generate with 100g
Oily (ingredient is with embodiment 1) is uniformly mixed, and is squeezed into tubular reactor (i.e. a blank pipe) with pump, and holding pressure is 1.4MPa,
Control 140 DEG C of temperature, air speed (volume space velocity) 2h-1, reactor outlet sampling analysis bromine index is 253mgBr/100g oil, product
38.14wt% containing aromatic hydrocarbons.
Claims (6)
1. a kind of application of recessed soil matrix catalyst, it is characterised in that: the recessed soil matrix catalyst is for removing in reformed oil
Trace amounts of olefin, method particularly includes: recessed soil matrix catalyst is put into tubular continuous reactor, reformed oil is passed through, carries out pipe
Formula successive reaction, tubular continuous reactor exported product are the reformed oil for removing alkene；
The preparation method of the recessed soil matrix catalyst is, carries out acidification to attapulgite using inorganic acid, then filter drying,
Graininess is made after molding, roasting and is acidified recessed soil；Then the recessed soil of resulting graininess acidification is added in ionic liquid again and is carried out
It is loaded modified, recessed soil matrix catalyst is obtained after drying；
The ionic liquid is pyrrolidinone compounds ionic liquid, and specially alpha-pyrrolidone is reacted with sulfuric acid or p-methyl benzenesulfonic acid
Resulting pyrrolidinone compounds ionic liquid；
The mass content of the recessed soil matrix catalyst intermediate ion liquid of the preparation is 1%~15%, and graininess is acidified the matter of recessed soil
Measuring content is 85%~99%.
2. the application of recessed soil matrix catalyst as described in claim 1, it is characterised in that: the inorganic acid is sulfuric acid or salt
Acid, concentration are 0.5mol/L~2mol/L.
3. the application of recessed soil matrix catalyst as described in claim 1, it is characterised in that: the pyrrolidones be have it is following
One or more of mixtures of structure,
Wherein, R is saturations or undersaturated straight chain or the alkyl with branch, and the carbon atom number of the alkyl is 1~20
Between.
4. the application of recessed soil matrix catalyst as described in claim 1, it is characterised in that: graininess is acidified recessed soil, ion is added
It is 50 DEG C~90 DEG C that loaded modified temperature is carried out in liquid, and the loaded modified time is 0.5~2h.
5. the application of recessed soil matrix catalyst as described in claim 1, it is characterised in that: the drying temperature after loaded modified is
100 DEG C~160 DEG C, 3.0~5.0h of drying time.
6. the application of recessed soil matrix catalyst as described in claim 1, it is characterised in that: the pressure of the tubular type successive reaction is
0.5MPa~3MPa, air speed 0.5h-1~5h-1, reaction temperature be 130 DEG C~180 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610431669.5A CN106076428B (en) | 2016-06-16 | 2016-06-16 | It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610431669.5A CN106076428B (en) | 2016-06-16 | 2016-06-16 | It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106076428A CN106076428A (en) | 2016-11-09 |
| CN106076428B true CN106076428B (en) | 2018-12-28 |
Family
ID=57236679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610431669.5A Active CN106076428B (en) | 2016-06-16 | 2016-06-16 | It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106076428B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001025149A2 (en) * | 1999-10-07 | 2001-04-12 | The Dow Chemical Company | Silica gel composition and method for making |
| US20050148743A1 (en) * | 2004-01-07 | 2005-07-07 | Casty Gary L. | Supported activator |
| CN104888691A (en) * | 2015-05-29 | 2015-09-09 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Preparation method of antibacterial attapulgite zearalenone adsorbent |
-
2016
- 2016-06-16 CN CN201610431669.5A patent/CN106076428B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001025149A2 (en) * | 1999-10-07 | 2001-04-12 | The Dow Chemical Company | Silica gel composition and method for making |
| US20050148743A1 (en) * | 2004-01-07 | 2005-07-07 | Casty Gary L. | Supported activator |
| CN104888691A (en) * | 2015-05-29 | 2015-09-09 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Preparation method of antibacterial attapulgite zearalenone adsorbent |
Non-Patent Citations (1)
| Title |
|---|
| Using b-cyclodextrin/attapulgite-immobilized ionic liquid as sorbent in dispersive solid-phase microextraction to detect the benzoylurea insecticide contents of honey and tea beverages;Miyi Yang等;《Food Chemistry》;20151127;第197卷;第1064–1072页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106076428A (en) | 2016-11-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE19528220C1 (en) | Process for regenerating a catalyst and process for producing an epoxide in the presence of the catalyst | |
| CN103771353B (en) | A kind of renovation process of waste sulfuric acid from alkylation | |
| CN103626135B (en) | The method and apparatus of sulphur trioxide and sulfur cream sulfur dioxide liquid | |
| CN103665380A (en) | Preparation method for low hydrogen-containing silicon oil | |
| CN106732636A (en) | A kind of sulphided state poor oil suspension bed hydrogenation catalyst and its preparation method and application | |
| CN102935379A (en) | Preparation method of MCM-22 molecular sieve catalyst | |
| CN104874196B (en) | A kind of method processing sodium and ammonium acetate salt-diazonium Organic substance-methanol-water mixed solution | |
| CN107032308A (en) | A kind of waste sulfuric acid from alkylation resource recycle method | |
| CN103537252B (en) | Essence removes adsorbent of benzene medium sulphide content and its preparation method and application | |
| CN104588074B (en) | A kind of preparation method of catalytic hydro-dearomatization catalyst | |
| CN106076428B (en) | It is a kind of for removing the preparation method and application of the recessed soil matrix catalyst of trace amounts of olefin in reformed oil | |
| CN108147373A (en) | A kind of method that flue gas during smelting prepares sulfuric acid | |
| CN103172600A (en) | Preparation method of furfuraldehyde | |
| CN103861644B (en) | A kind of modified clay Catalysts and its preparation method for deolefination | |
| CN1915517B (en) | Catalyst in use for producing cyclohexene | |
| CN107876070B (en) | Acid mesoporous zirconium phosphate column-supported active clay olefin-removing catalyst | |
| CN208632327U (en) | A kind of advanced oxidation processes treatment process device of the waste water containing sodium phenolate | |
| CN106076308A (en) | A kind of method for preparing catalyst removing trace amounts of alkenes in reformate and application | |
| CN106345499B (en) | It is a kind of load P elements Attapulgite Catalyst preparation method and its reformed oil removing trace amounts of olefin in application | |
| CN104844418B (en) | The method of 2,6-DCT prepared by a kind of carried molecular sieve catalytic chlorination 2-toluene(mono)chloride | |
| CN104860815B (en) | Utilize the method that solid acid catalyst and peel prepare levulic acid | |
| CN105582976B (en) | A kind of hydrocracking catalyst composition and preparation method thereof | |
| CN111068642A (en) | Catalyst for removing mercaptan in natural gas and preparation method thereof | |
| CN107694321A (en) | A kind of normal temperature support type manganese hydrogen sulfide essence scavenger, its preparation method and application | |
| CN205253118U (en) | Take off liquid reation kettle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240130 Address after: Room 303-21579, No. 304, South Community A, Binhe Street, Pinggu District, Beijing, 101200 Patentee after: BEIJING ZHITOUJIA INTELLECTUAL PROPERTY OPERATION CO.,LTD. Country or region after: China Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee before: CHANGZHOU University Country or region before: China |
|
| TR01 | Transfer of patent right |