CN106075796A - A kind of synthetic material runway cover harmful substance minimizing technology - Google Patents

A kind of synthetic material runway cover harmful substance minimizing technology Download PDF

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Publication number
CN106075796A
CN106075796A CN201610436024.0A CN201610436024A CN106075796A CN 106075796 A CN106075796 A CN 106075796A CN 201610436024 A CN201610436024 A CN 201610436024A CN 106075796 A CN106075796 A CN 106075796A
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synthetic material
runway cover
harmful substance
material runway
minimizing technology
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姚玉龙
陈佳
胡朝霞
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Chengdu Totem Environmental Protection Technology Co Ltd
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Chengdu Totem Environmental Protection Technology Co Ltd
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    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/10Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation
    • A62D3/17Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation to electromagnetic radiation, e.g. emitted by a laser
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    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
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    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
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Abstract

The present invention relates to synthetic material runway cover harmful substance minimizing technology.The method includes using hydrogen peroxide to spray synthetic material runway cover 24 times, then uses photocatalyst product to spray synthetic material runway cover 24 times, the synthetic material runway cover after being processed.The present invention first initiative hydrogen peroxide and photocatalyst are applied to synthetic material runway cover harmful substance remove a good appetite suddenly appearing in a serious disease, photocatalyst product is mainly used in removing various organic pollution and bacterial virus, hydrogen peroxide is mainly used in the heavy metal in oxidation removal synthetic material runway cover and antibacterial, virus, and rapid decomposing organic matter, organic pollution in synthetic material runway cover, heavy metal and antibacterial, virus are removed by the method for the present invention effectively in the lump, and method is simple, green non-pollution, has huge application prospect.

Description

A kind of synthetic material runway cover harmful substance minimizing technology
Technical field
Present invention relates particularly to a kind of synthetic material runway cover harmful substance minimizing technology.
Background technology
Photocatalyst is a kind of nano level metal oxide materials, and it is coated substrate surface, forms thin film after drying, Under the irradiation of light, active oxygen species (O can be generated2 -、·O-、·OH、H2O2And HO2Deng), there is the strongest photoredox Function, the various organic compound of oxidable decomposition and part inorganic matter, can destroy cell membrane and the albumen of solidification virus of antibacterial Matter, thus there is extremely strong sterilization, deodorization, anti-fouling and self-cleaning and the function of purification air.
In recent years, often have news to expose: Duo Di school plastic cement race track harmful substance exceeds standard, cause student occur epistaxis, Dizzy, cough, play the body abnormality symptoms such as erythema, these " poison runways " seriously compromise the healthy of adolescent student;With Time, plastic cement race track is the most often widely used in each athletic training and competition area, the convenience-for-people activity centre of each grass-roots community, " poison runway " The most become yoke Chinese sports cause healthy flourish and affect the stealthy killer of national health quality lifting.Although various places All departments all take many measures, including rooting out poison runway, lay the methods such as meadow, although these methods can play certain Effect, but cost is high, and cost is big, long in time limit, implements the biggest difficulty, and therefore, needing one at present badly can be effective The method removing plastic cement race track harmful substance.
Summary of the invention
It is directed to the above-mentioned problems in the prior art, the invention provides a kind of synthetic material runway cover nuisance Matter minimizing technology, efficiently solves plastic cement race track harmful substance in prior art and exceeds standard the problem of serious harm national health.
To achieve these goals, the technical solution used in the present invention is:
A kind of synthetic material runway cover harmful substance minimizing technology is provided, including:
(1), in the environment below 35 DEG C, on every square metre of synthetic material runway cover, hydrogen peroxide 300-is sprayed 1000ml, sprays 2-4 time, and each response time is 3-7 days;
(2) in the environment of less than 40 DEG C, on every square metre of synthetic material runway cover, photocatalyst 20-is sprayed 200ml, sprays 2-4 time, and each response time is 3-7 days, the synthetic material runway cover after being processed.
Preferably, also include:
(3) on the synthetic material runway cover that step (two) process obtains, hydrogen peroxide, every square metre of synthesis are sprayed again On material runway cover, the fountain height of hydrogen peroxide is 300-1000ml, sprays 2-4 time, and each response time is 3-7 days.
Preferably, in the environment of 35 DEG C, on every square metre of synthetic material runway cover, spray hydrogen peroxide 400ml, Spraying 2 times, each response time is 5 days;
In the environment of 35 DEG C, on every square metre of synthetic material runway cover, spray photocatalyst 100ml, spray 2 times, Response time is 7 days every time, the synthetic material runway cover after being processed.
Preferably, the mass fraction of described hydrogen peroxide is 15-50%.
Described photocatalyst is made up of the component of following weight portion:
Nano-metal-oxide 0.3-2 part, solion 0.1-3 part and soft water 95-98 part;Wherein, nano metal oxide The particle diameter of thing is 3-30nm.
Preferably, described photocatalyst also includes rare earth element 1-3 part.
Preferably, at least one during described rare earth element is lanthanum, cerium, erbium, neodymium and yttrium.
Preferably, during described nano-metal-oxide is nano titanium oxide, nanometer tungsten oxide and nano zine oxide extremely Few one;The particle diameter of described nano-metal-oxide is 3-20nm;
Described solion is at least in silver ion solution, copper ion solution, ferric ion solutions and zinc ion solution Kind.
Preferably, described nano-metal-oxide is nano titanium oxide, and the particle diameter of nano titanium oxide is 3-15nm;Institute Stating solion is silver ion solution.
Preferably, the preparation method of described photocatalyst is:
Nano-metal-oxide, solion and soft water is weighed according to formula proportion, stirring, make the mixing of above-mentioned material all Even, prepare the photocatalyst with high efficiency photocatalysis removal synthetic material runway cover harmful substance.
The invention have the benefit that
1) photocatalyst product is applied to the removal of synthetic material runway cover harmful substance by the present invention the most in a creative way In, this photocatalyst product is mainly used in the various organic pollutions in long-acting local behavior material runway cover and antibacterial, virus, Method is simple, and the time is short, complete decomposition, and removal effect is good, with low cost, non-secondary pollution, is a kind of highly useful and is suitable to The method being widely popularized, beneficially industrialized production.
2) application of the hydrogen peroxide is removed a good appetite suddenly appearing in a serious disease at synthetic material runway cover harmful substance by the present invention the most in a creative way, This hydrogen peroxide is mainly used in the heavy metal in oxidation removal synthetic material runway cover and antibacterial, virus, and decomposes rapidly Organic substance, method is simple, and the time is short, and removal effect is good, with low cost, and will not bring new poisonous and harmful substance, is one Plant highly useful and be suitable to the method being widely popularized.
3) present invention is initiative first is applied to synthetic material runway cover harmful substance by hydrogen peroxide and photocatalyst Going a good appetite suddenly appearing in a serious disease, photocatalyst product to be mainly used in removal organic polluter and bacterial virus, hydrogen peroxide is mainly used in removing heavy metals And bacterial virus, the method for the present invention is effectively by the organic pollution in synthetic material runway cover, heavy metal and bacterial disease Poison is removed in the lump, and, method is simple, and green non-pollution has huge application prospect.
4) photocatalyst product employed in the poisonous and harmful substance removal process of the present invention is the group using certain content Divide and be prepared from, this product does not has the addition of any emulsifying agent, dispersant and suspending agent, in use, nano metal Oxide is spherical being dispersed in suspension within equably in water, and specific surface area increases, and considerably increases the contact area with harmful substance, Activity increases, and will not produce any precipitation, it is possible to effectively remove the organic pollution in synthetic material runway cover and Also will not destroy the effective ingredient in runway cover while bacterial virus, be that one is specifically designed in synthetic material runway cover The product that harmful substance and bacterial virus are removed, has huge using value.
5) photocatalyst product of the present invention is by adding solion and the rare earth element of certain content in formula, should be from The utilization of sub-doping techniques and rare-earth modification technology can improve catalyst and absorb the ability of longer-wave photons energy so that wave-length coverage Expanding, ultraviolet light becomes visible ray, is greatly enhanced the intensity of light, thus increases the catalysis activity of photocatalyst, more effectively removes Poisonous and harmful substance in synthetic material runway cover.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with the specific embodiment of the invention pair Technical solution of the present invention is clearly and completely described.
Embodiment 1
As a example by the plastic cement race track of high and new technology industrial development zone, Chengdu experimental primary school sports ground, use the method for the present invention to this plastic cement race track The detailed process that surface layer carries out processing is:
When 35 DEG C, spraying 400ml mass fraction on every square metre of plastic cement race track surface layer is 15% hydrogenperoxide steam generator, After reacting 5 days, spray hydrogenperoxide steam generator according still further to same method, then react 5 days, to remove the weight in plastic cement race track surface layer Metal;
Then, then spraying photocatalyst product on the plastic cement race track surface layer that above-mentioned steps processed, every square metre of plastic cement runs Spray 100ml photocatalyst product on road surface layer, after reacting 5 days, spray photocatalyst product according still further to identical method, then react 5 My god, to remove the benzene,toluene,xylene in plastic cement race track surface layer and toluene di-isocyanate(TDI) and 3,3'-bis-chloro-4,4'-bis- The organic pollutions such as aminodiphenylmethane (MOCA), the plastic cement race track surface layer after being processed.
After above-mentioned photocatalyst product is sprayed on plastic cement race track surface layer, photocatalyst, under the irradiation of light, produces oxidation Very competent free hydroxy and active oxygen, the benzene,toluene,xylene in plastic cement race track, toluene di-isocyanate(TDI) and 3,3'-bis-chloro-4, the organic pollution such as 4'-diaminodiphenyl-methane (MOCA) resolves into free of contamination water and carbon dioxide, Can also effectively remove the bacterium colony in plastic cement race track surface layer, degerming rate reaches more than 99%, thus " poison runway " is become simultaneously Indices is become to meet and be far superior to the qualified runway of national standard.
Wherein, the photocatalyst employed in this method is by nano titanium oxide 0.3 part, silver ion solution 3 parts and soft water 96.7 part forms;Wherein, the particle diameter of nano titanium oxide is 5nm.
The preparation method of above-mentioned photocatalyst product is:
Nano titanium oxide, silver ion solution and soft water is weighed according to formula proportion, stirring, make the mixing of above-mentioned material all Even, prepare the photocatalyst product with high efficiency photocatalysis removal synthetic material runway cover harmful substance function.
Embodiment 2
As a example by the plastic cement race track of green boat Lagerstroemia indica L. kindergarten, use the present invention method to this plastic cement race track surface layer at The detailed process of reason is:
When 30 DEG C, spraying 1000ml mass fraction on every square metre of plastic cement race track surface layer is that 35% hydrogen peroxide is molten Liquid, after reacting 7 days, sprays hydrogenperoxide steam generator 2 times according still further to same method, and every secondary response 7 days, to remove plastic cement race track face Heavy metal in Ceng;
Then, then spraying photocatalyst product on the plastic cement race track surface layer that above-mentioned steps processed, every square metre of plastic cement runs Spray 200ml photocatalyst product on road surface layer, after reacting 7 days, spray photocatalyst product 3 times according still further to identical method, every time React 7 days, to remove benzene,toluene,xylene, toluene di-isocyanate(TDI) and 3 in plastic cement race track surface layer, 3'-bis-chloro-4, The organic pollutions such as 4'-diaminodiphenyl-methane (MOCA), the plastic cement race track surface layer after being processed.
After above-mentioned photocatalyst product is sprayed on plastic cement race track surface layer, photocatalyst, under the irradiation of light, produces oxidation Very competent free hydroxy and active oxygen, the benzene,toluene,xylene in plastic cement race track surface layer, toluene di-isocyanate(TDI) And the organic pollution such as 3,3'-bis-chloro-4,4'-diaminodiphenyl-methane (MOCA) resolves into free of contamination water and titanium dioxide Carbon, can also remove the bacterium colony in plastic cement race track surface layer simultaneously effectively, and degerming rate reaches more than 99%, thus by " poison runway " Become the qualified runway that indices meets and is far superior to national standard.
Wherein, the photocatalyst product employed in this method is molten by nano zine oxide 2 parts, silver ion solution 2 parts, copper ion Liquid 1 part and soft water 95 parts composition;Wherein, the particle diameter of nano zine oxide is 8nm.
The preparation method of above-mentioned photocatalyst product is:
Nano zine oxide, silver ion solution, copper ion solution and soft water is weighed according to formula proportion, stirring, make above-mentioned thing Material mix homogeneously, prepares the photocatalyst product with high efficiency photocatalysis removal synthetic material runway cover harmful substance function.
Embodiment 3
Synthetic material runway cover harmful substance minimizing technology, including:
When 35 DEG C, spraying 500ml mass fraction on every square metre of plastic cement race track surface layer is 50% hydrogenperoxide steam generator, After reacting 3 days, spraying hydrogenperoxide steam generator 3 times according still further to same method, every secondary response 3 days, to remove plastic cement race track surface layer In heavy metal;
Then, then spraying photocatalyst product on the plastic cement race track surface layer that above-mentioned steps processed, every square metre of plastic cement runs Spray 150ml photocatalyst product on road surface layer, after reacting 3 days, spray photocatalyst product 3 times according still further to identical method, every time React 5 days, to remove benzene,toluene,xylene, toluene di-isocyanate(TDI) and 3 in plastic cement race track surface layer, 3'-bis-chloro-4, The organic pollutions such as 4'-diaminodiphenyl-methane (MOCA);
Spraying mass fraction again on the above-mentioned plastic cement race track surface layer processed is 30% hydrogen peroxide product, every square metre On plastic cement race track surface layer, the fountain height of hydrogen peroxide is 300ml, sprays 2 times, and each response time is 3 days, after being processed Plastic cement race track surface layer.
Original plastic cement race track under the process of above-mentioned hydrogen peroxide and photocatalyst, biodegradation of benzene therein, toluene, Dimethylbenzene, toluene di-isocyanate(TDI) and the thing such as 3,3'-bis-chloro-4,4'-diaminodiphenyl-methane (MOCA) and heavy metal Matter major part is removed, can also effectively remove the bacterium colony in plastic cement race track surface layer simultaneously, and degerming rate reaches more than 99%, Thus " poison runway " is become the qualified runway that indices meets and is far superior to national standard.
Wherein, the photocatalyst product employed in this method is by nanometer tungsten oxide 1 part, copper ion solution 2 parts, rare earth element Lanthanum 2 parts and soft water 95 parts composition;Wherein, the particle diameter of nanometer tungsten oxide is 30nm.
The preparation method of above-mentioned photocatalyst product is:
Nanometer tungsten oxide, copper ion solution, rare-earth elements of lanthanum and soft water is weighed according to formula proportion, stirring, make above-mentioned thing Material mix homogeneously, prepares the photocatalyst product with high efficiency photocatalysis removal synthetic material runway cover harmful substance function.
Embodiment 4
Synthetic material runway cover harmful substance minimizing technology, including:
When 30 DEG C, spraying 500ml mass fraction on every square metre of plastic cement race track surface layer is 30% hydrogenperoxide steam generator, After reacting 6 days, spray hydrogenperoxide steam generator according still further to same method, react 6 days, to remove the huge sum of money in plastic cement race track surface layer Belong to;
Then, then spraying photocatalyst product on the plastic cement race track surface layer that above-mentioned steps processed, every square metre of plastic cement runs Spray 20ml photocatalyst product on road surface layer, after reacting 3 days, spray photocatalyst product 2 times according still further to identical method, the most instead Answer 7 days, to remove benzene,toluene,xylene, toluene di-isocyanate(TDI) and 3 in plastic cement race track surface layer, 3'-bis-chloro-4,4'- The organic pollutions such as diaminodiphenyl-methane (MOCA);
Original plastic cement race track under the process of above-mentioned hydrogen peroxide and photocatalyst, biodegradation of benzene therein, toluene, Dimethylbenzene, toluene di-isocyanate(TDI) and the thing such as 3,3'-bis-chloro-4,4'-diaminodiphenyl-methane (MOCA) and heavy metal Matter major part is removed, can also effectively remove the bacterium colony in plastic cement race track surface layer simultaneously, and degerming rate reaches more than 99%, Thus " poison runway " is become the qualified runway that indices meets and is far superior to national standard.
Wherein, the photocatalyst product employed in this method is by nano titanium oxide 0.8 part, nano zine oxide 0.5 part, silver Solion 0.1 part, rare-earth element cerium 3 parts and soft water 95.6 parts composition;Wherein, the particle diameter of nano titanium oxide is 15nm, receives The particle diameter of rice zinc oxide is 3nm.
The preparation method of above-mentioned photocatalyst product is:
Nano titanium oxide, nano zine oxide, silver ion solution, rare-earth element cerium and soft water is weighed according to formula proportion, Stirring, makes above-mentioned material mix homogeneously, prepares and has high efficiency photocatalysis removal synthetic material runway cover harmful substance function Photocatalyst product.
Embodiment 5
Synthetic material runway cover harmful substance minimizing technology, including:
When 40 DEG C, spraying 800ml mass fraction on every square metre of plastic cement race track surface layer is 35% hydrogenperoxide steam generator, After reacting 4 days, spray hydrogenperoxide steam generator according still further to same method, react 4 days, to remove the huge sum of money in plastic cement race track surface layer Belong to;
Then, then spraying photocatalyst product on the plastic cement race track surface layer that above-mentioned steps processed, every square metre of plastic cement runs Spray 60ml photocatalyst product on road surface layer, after reacting 6 days, spray photocatalyst product according still further to identical method, react 5 days, To remove benzene,toluene,xylene, toluene di-isocyanate(TDI) and the 3,3'-bis-chloro-4,4'-diaminourea in plastic cement race track surface layer The organic pollutions such as diphenyl methane (MOCA);
Original plastic cement race track under the process of above-mentioned hydrogen peroxide and photocatalyst, biodegradation of benzene therein, toluene, Dimethylbenzene, toluene di-isocyanate(TDI) and the thing such as 3,3'-bis-chloro-4,4'-diaminodiphenyl-methane (MOCA) and heavy metal Matter major part is removed, can also effectively remove the bacterium colony in plastic cement race track surface layer simultaneously, and degerming rate reaches more than 99%, Thus " poison runway " is become the qualified runway that indices meets and is far superior to national standard.
Wherein, the photocatalyst product employed in this method is by nano titanium oxide 1.5 parts, ferric ion solutions 0.5 part, dilute Earth elements yttrium 1 part and soft water 97 parts composition;Wherein, the particle diameter of nano titanium oxide is 10nm.
The preparation method of above-mentioned photocatalyst product is:
Nano titanium oxide, ferric ion solutions, rare earth element yttrium and soft water is weighed according to formula proportion, stirring, make above-mentioned Material mix homogeneously, prepares the photocatalyst product with high efficiency photocatalysis removal synthetic material runway cover harmful substance function.
Test example
Take the synthetic material runway cover (labelling respectively using embodiment 1, the method for embodiment 2 to obtain after processing For 1# and 2#), and deliver to Shenzhen Academy of Metrology & Quality Inspection, according to GB/T14833-2011 " synthetic material runway cover " The harmful substance index of runway cover detects by standard method, and with do not carry out the plastic cement race track surface layer of post-processing technology Harmful substance performance indications contrast, result such as table 1 below:
Table 1 synthetic material runway cover harmful substance performance indications detect
Do not detect: content is less than method detection limit;
From above experimental data it can be seen that be provided without the plastic cement race track that the inventive method processed organic pollution and Content of beary metal is the highest exceeds standard 20 times, very harmful, and use the method for the present invention to synthetic material runway cover at After reason, poisonous and harmful substance content is substantially reduced, substantially all in not detecting state, well below national standard and degerming Rate reaches more than 99%, meets the use requirement of synthetic material runway cover, and safety is greatly enhanced.

Claims (10)

1. a synthetic material runway cover harmful substance minimizing technology, is characterized in that, including:
(1), in the environment below 35 DEG C, on every square metre of synthetic material runway cover, hydrogen peroxide 300-is sprayed 1000ml, sprays 2-4 time, and each response time is 3-7 days;
(2) in the environment of less than 40 DEG C, on every square metre of synthetic material runway cover, photocatalyst 20-200ml is sprayed, Spraying 2-4 time, each response time is 3-7 days, the synthetic material runway cover after being processed.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 1, is characterized in that, also include:
(3) on the synthetic material runway cover that step (two) process obtains, hydrogen peroxide, every square metre of synthetic material are sprayed again On runway cover, the fountain height of hydrogen peroxide is 300-1000ml, sprays 2-4 time, and each response time is 3-7 days.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 1, is characterized in that, including:
In the environment of 35 DEG C, on every square metre of synthetic material runway cover, spray hydrogen peroxide 400ml, spray 2 times, every time Response time is 5 days;
In the environment of 35 DEG C, on every square metre of synthetic material runway cover, spray photocatalyst 100ml, spray 2 times, every time Response time is 7 days, the synthetic material runway cover after being processed.
4., according to the synthetic material runway cover harmful substance minimizing technology described in claim 1 or 2 or 3, it is characterized in that, described The mass fraction of hydrogen peroxide is 15-50%.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 1 and 2, is characterized in that, described light Catalyst is made up of the component of following weight portion:
Nano-metal-oxide 0.3-2 part, solion 0.1-3 part and soft water 95-98 part;Wherein, nano-metal-oxide Particle diameter is 3-30nm.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 5, is characterized in that:
Described photocatalyst also includes rare earth element 1-3 part.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 6, is characterized in that,
Described rare earth element is at least one in lanthanum, cerium, erbium, neodymium and yttrium.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 5, is characterized in that:
Described nano-metal-oxide is at least one in nano titanium oxide, nanometer tungsten oxide and nano zine oxide;Described The particle diameter of nano-metal-oxide is 3-20nm;
Described solion is at least one in silver ion solution, copper ion solution, ferric ion solutions and zinc ion solution.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 8, is characterized in that: described nanometer gold Genus oxide is nano titanium oxide, and the particle diameter of nano titanium oxide is 3-15nm;
Described solion is silver ion solution.
Synthetic material runway cover harmful substance minimizing technology the most according to claim 5, is characterized in that, described light touches The preparation method of matchmaker is:
Nano-metal-oxide, solion and soft water is weighed according to formula proportion, stirring, make above-mentioned material mix homogeneously, system Must have high efficiency photocatalysis and remove the photocatalyst of synthetic material runway cover harmful substance.
CN201610436024.0A 2016-06-16 2016-06-16 A kind of synthetic material runway cover harmful substance minimizing technology Pending CN106075796A (en)

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