CN106072761A - A kind of method reducing the peculiar N content of nitrosamines of Nicotiana tabacum L. in cigarette mainstream flue gas - Google Patents
A kind of method reducing the peculiar N content of nitrosamines of Nicotiana tabacum L. in cigarette mainstream flue gas Download PDFInfo
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- CN106072761A CN106072761A CN201610635660.6A CN201610635660A CN106072761A CN 106072761 A CN106072761 A CN 106072761A CN 201610635660 A CN201610635660 A CN 201610635660A CN 106072761 A CN106072761 A CN 106072761A
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- Prior art keywords
- cigarette
- butyl
- tert
- nicotiana tabacum
- methy
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/301—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
Abstract
The present invention provides a kind of method reducing the peculiar N nitrosamine of Nicotiana tabacum L. in cigarette mainstream flue gas, and the method includes the step adding 2,6 di-t-butyl 4 methylphenols in Medicated cigarette.The method can effectively reduce the content of the peculiar N nitrosamine of the Nicotiana tabacum L. in cigarette mainstream flue gas, and does not affect the organoleptic quality of Medicated cigarette.
Description
Technical field
The invention belongs to Medicated cigarette field, be specifically related to Nicotiana tabacum L. peculiar N-content of nitrosamines in a kind of reduction cigarette mainstream flue gas
Method.
Background technology
Nicotiana tabacum L. peculiar N-nitrosamine (TSNAs) is the class nitrosamine material that in Nicotiana tabacum L., N-content of nitrosamines is the abundantest, only
It is present in Nicotiana tabacum L., tobacco product and cigarette smoke.Studying the most deep TSNAs at present is N-nitrosonornicotine
(NNN), N-nitroso-group anabasine (NAB), N-nitrosoanatabine (NAT) and 4-(N-methyl-N-nitrosamine)-1-(3-
Pyridine radicals)-butanone (NNK), their chemical structural formula is as follows:
In cigarette smoke, the burst size of TSNAs is significant to correct evaluation bitting midges.International cancer
The toxicity assessment result of harmful components in Canadian government list is shown by disease research administration (IARC), NNK and NNN pure chemistry composition
For questionable person's body carcinogenic components.In order to reduce Nicotiana tabacum L. peculiar N-nitrosamine possible wound healthy to smoker and involuntary smoker
Evil, controls its content in Nicotiana tabacum L. and tobacco product, is highly important problem.
2,6-di-tert-butyl-4-methy phenols (No. CAS: 128-37-0), molecular formula is C15H24O, is called for short BHT.
Summary of the invention
It is an object of the present invention to provide a kind of tobacco shred.It is also another object of the present invention to provide a kind of cigarette filter rod,
Further object of the present invention is to provide a kind of Medicated cigarette, and further object of the present invention is to provide a kind of 2,6-di-t-butyl-4-methyl
The purposes of phenol, further object of the present invention is to provide a kind of Nicotiana tabacum L. in cigarette mainstream flue gas peculiar N-content of nitrosamines of reducing
Method.
Inventor finds, 2,6-di-tert-butyl-4-methy phenols add in Medicated cigarette, can reduce cigarette in cigarette mainstream flue gas
The content of the peculiar N-nitrosamine (TSNAs) of grass.
For realizing said one or multiple purpose, first aspect present invention provides first aspect present invention to provide 2,6-bis-uncle
Butyl-4-methylphenol purposes in Medicated cigarette.
In one embodiment, the purposes of any one of the present invention, described purposes is for reducing in cigarette mainstream flue gas
Nicotiana tabacum L. peculiar N-content of nitrosamines.
In one embodiment, the purposes of any one of the present invention, described purposes is by by 2,6-di-t-butyl-4-first
Base phenol adds realization in Medicated cigarette to;
Preferably, described purposes is that 6-di-tert-butyl-4-methy phenol adds realization in tobacco shred or Nicotiana tabacum L. to by by 2;
Preferably, described purposes is that 6-di-tert-butyl-4-methy phenol adds realization in cigarette filter rod to by by 2.
Second aspect present invention provides a kind of cigarette filter rod, wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described cigarette filter rod, the content of 2,6-di-tert-butyl-4-methy phenols is 15~25mg/ to prop up (preferably
18~20mg/ prop up).
In one embodiment, any one of the present invention cigarette filter rod, described cigarette filter rod for acetate fiber filter
Rod, head for polypropylene fiber filtering rod and paper filter stick.
In one embodiment, any one of the present invention cigarette filter rod, described cigarette filter rod is homogenizing filter stick, binary
Filter stick or ternary filter stick.
In one embodiment, any one of the present invention cigarette filter rod, wherein contain sorptive filler, described 2,6-
Di-tert-butyl-4-methy phenol is carried in described sorptive filler.
In one embodiment, any one of the present invention cigarette filter rod, described sorptive filler is silicon dioxide
Grain, kieselguhr or activated carbon.
Third aspect present invention provides a kind of tobacco shred or Nicotiana tabacum L., wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described tobacco shred or Nicotiana tabacum L., the content of 2,6-di-tert-butyl-4-methy phenols is 15~25mg/g (excellent
Select 18~20mg/g).
Fourth aspect present invention provides a kind of Medicated cigarette, wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described Medicated cigarette, the content of 2,6-di-tert-butyl-4-methy phenols is that 5-30mg/ props up Medicated cigarette, effective 6-
10mg/ props up Medicated cigarette;
Preferably, 2,6-di-tert-butyl-4-methy phenols are to add Medicated cigarette to the form of pressed powder or liquid solution
In;
Preferably, described Medicated cigarette contains the cigarette filter rod of any one of the present invention and/or the tobacco shred of any one of the present invention or cigarette
Leaf.
Fifth aspect present invention provides a kind of method reducing the peculiar N-nitrosamine of Nicotiana tabacum L. in cigarette mainstream flue gas, the method
Including: in Medicated cigarette, add 2,6 di tert butyl 4 methyl phenol.
In one embodiment, any one of the present invention reduce Nicotiana tabacum L. peculiar N-nitrosamine in cigarette mainstream flue gas
Method, the method includes following one or more:
A) adding 2 in filter stick, 6-di-tert-butyl-4-methy phenol, preferred addition manner is included in filter stick interpolation
The 2,6 di tert butyl 4 methyl phenol of powder;Or
In sorptive filler, applying 2, the alcoholic solution of 6-di-tert-butyl-4-methy phenol or aqueous solution, then dry, then
Sorptive filler is arranged in cigarette filter rod.
B) adding 2 in tobacco shred or Nicotiana tabacum L., 6-di-tert-butyl-4-methy phenol, preferred addition manner is included in tobacco shred
Or on Nicotiana tabacum L. apply 2, the alcoholic solution of 6-di-tert-butyl-4-methy phenol or aqueous solution, then dry.
In one embodiment, any one of the present invention reduce Nicotiana tabacum L. peculiar N-nitrosamine in cigarette mainstream flue gas
Method, adds 2 in filter stick, and the mode of 6-di-tert-butyl-4-methy phenol includes: prepare a cavity filter stick, and this cavity is filtered
The middle part of rod has cavity, and by powder 2,6-di-tert-butyl-4-methy phenol is directly added in the cavity of this cavity filter stick,
Filter stick is wrapped up again, it is thus achieved that containing 2, the cigarette filter rod of 6-di-tert-butyl-4-methy phenol by forming paper.
In one embodiment, any one of the present invention reduce Nicotiana tabacum L. peculiar N-nitrosamine in cigarette mainstream flue gas
Method, applies 2 on Nicotiana tabacum L. or tobacco shred, and the mode of 6-di-tert-butyl-4-methy phenol includes: by 2,6-di-t-butyl-4-first
Base phenol is dissolved in ethanol, it is thus achieved that 2,6-di-tert-butyl-4-methy phenol ethanol solution.This solution is applied on tobacco shred, then
Dry tobacco shred, it is thus achieved that containing 2, the tobacco shred of 6-di-tert-butyl-4-methy phenol.
In one embodiment, any one of the present invention purposes or the method for any one of the present invention, described Nicotiana tabacum L. is special
Having N-nitrosamine is one or more in NNN, NNK, NAT and NAB, preferably NNK.
In one embodiment, tobacco shred be cut tobacco, stem, tobacco thin filament or a combination thereof.
In one embodiment, binary or Three-element composite filter core can be CN204519347U, CN104013104A or
Composite filter disclosed in CN203762278U, or composite filter similarly.
In one embodiment, cavity filter stick refers to offer cavity (such as on filter stick base material (such as acetate fiber)
Cylindrical cavity).
Beneficial effects of the present invention
Some embodiments of the present invention have a following one or more advantage:
1) 2,6-di-tert-butyl-4-methy phenol puts on tobacco shred, Nicotiana tabacum L., cigarette filter rod or Medicated cigarette, it is possible to effectively reduce
The content of Nicotiana tabacum L. peculiar N-nitrosamine, the content of especially NNK in cigarette mainstream flue gas;
2) addition of 2,6-di-tert-butyl-4-methy phenol is few, little on Sensory Quality of Cigarette impact, beneficially Medicated cigarette
The follow-up improvement of flavor and taste;
3) addition manner of 2,6-di-tert-butyl-4-methy phenol is simple, can add in the production process of filter stick or tobacco shred
Entering, such as add in tobacco shred or Tobacco Leaf Curing, it is convenient to add;
4) by 2,6-di-tert-butyl-4-methy phenol loads on the carrier particles, and this carrier granular can add homogenizing to
In filter stick;Can also add in band cavity filter stick, it is thus achieved that in binary or Three-element composite filter core;
5) by 2,6-di-tert-butyl-4-methy phenol is configured to solution, can be applied directly on filter stick material, it is also possible to execute
It is added on tobacco shred or cigarette;
6) reduce the method for Nicotiana tabacum L. peculiar N-content of nitrosamines in cigarette mainstream flue gas and there is good practicality, can produce
Preferably economic benefit and social effect.
Detailed description of the invention
Below by embodiment, technical scheme is described in further detail.
Embodiment 1
The tobacco sample weighing 0.8g loads quartz glass tube, is separately added into 30mg 2,6-di-t-butyl-4-methyl simultaneously
Phenol (is called for short BHT), is placed in quick tubular type heating furnace, with N2Or air as reaction atmosphere, gas flow control is
2.1L/min, after ventilation 3min, is warming up to 800 DEG C with the heating rate of 20 DEG C/s, and at 800 DEG C, insulation stops 10min, uses sword
Bridge filter disc trapping granule phase substance.After being incubated, open after heating furnace continues ventilation cooling 5min and take off cambridge filter.Before and after trapping
The mass change of cambridge filter is i.e. pyrolyzed the tar content of generation.
After being pyrolyzed, cambridge filter is turned up and is placed in bottom boiling flask, launch, be subsequently added 0.01mol/L acetic acid
Ammonium salt solution (containing the internal standard) 50mL, stoppers bottleneck with rubber stopper, with the speed oscillation 30min of 180r/min, stands 5min;Through micropore
Filter membrane filter pressing, to chromatogram bottle, carries out LC-MS/MS analysis.Inner mark method ration is used to measure the concentration of NNK in extracting solution.Concrete number
According to see table 1.
As can be known from Table 1,2,6-di-tert-butyl-4-methy phenols have and preferably reduce the Main Tobacco Planting in cigarette smoke
The effect of the peculiar N-nitrosamine NNK of grass, compared with comparison Medicated cigarette, the reduction amplitude to NNK is 54.19%.
Table 1
NNK(ng/g) | Total reduction rate | |
Blank tobacco shred | 581.25 | -- |
Tobacco shred containing BHT | 266.25 | 54.19% |
Embodiment 2
(1) by 2,6-di-tert-butyl-4-methy phenol is dissolved in ethanol, ultrasonic 30min, it is thus achieved that concentration is the 2,6-of 2mg/mL
Di-tert-butyl-4-methy phenol ethanol solution.This solution is applied on tobacco shred, then dries tobacco shred, it is thus achieved that containing 2,6-bis-
The tobacco shred of tert-butyl-4-methyl-Phenol, in tobacco shred 2, the content of 6-di-tert-butyl-4-methy phenol is 20mg/g.
(2) by above-mentioned containing having 2, the tobacco shred of 6-di-tert-butyl-4-methy phenol is fabricated to Medicated cigarette, numbering A1, every volume
Cigarette A1 about 18mg Han 2,6 di tert butyl 4 methyl phenol.
Embodiment 3
(1) preparing a cavity filter stick, the middle part of this cavity filter stick has cavity, by powder 2,6-di-t-butyl-4-
Methylphenol is directly added in the cavity of this cavity filter stick, then wraps up filter stick by forming paper, it is thus achieved that containing 2, and 6-di-t-butyl-
The cigarette filter rod of 4-methylphenol, in this filter stick 2, the content of 6-di-tert-butyl-4-methy phenol is that 18mg/ props up;
(2) by above-mentioned containing 2, the cigarette filter rod of 6-di-tert-butyl-4-methy phenol is connected with cigarette makes Medicated cigarette, numbering
A2。
Comparative example
Without 2, the blank Medicated cigarette of 6-di-tert-butyl-4-methy phenol, numbering A0.
In addition to above-mentioned restriction, embodiment 2,3 and comparative example use essentially identical tobacco raw material and technique to prepare Medicated cigarette.
Analyze detection 1
According to the mensuration gas phase color of Nicotiana tabacum L. peculiar N-nitrosamine in GB/T 23228-2008 cigarette mainstream smoke total particulate matter
Spectrum-heat energy analysis combination method, analyzes Medicated cigarette A0~A2.
NNK (ng/ props up) | Reduction rate | |
A0 | 4.52 | |
A1 | 3.11 | 31.2% |
A2 | 3.37 | 25.4% |
In Medicated cigarette A1 and A2 main flume, the content of NNK is greatly reduced, this explanation 2, and 6-di-tert-butyl-4-methy phenol is used
In Medicated cigarette, such as, it is added on tobacco shred or in cigarette filter rod, it is possible to effectively reduce tobacco-specific nitrosamine in cigarette mainstream flue gas
Content, especially reduces the content of NNK.
Analyze detection 2-Sensory Quality of Cigarette to evaluate
According to the Sensory Quality of Cigarette evaluation criterion in GB GB 5606.4-2005, Medicated cigarette A0~A2 is smoked panel test, knot
Fruit is as shown in table 1.
Table 2
After specialty Medicated cigarette sensory evaluating smoking personnel smoke panel test, it is believed that Medicated cigarette A1~A2 and Medicated cigarette A0 is in overall mouthfeel and suction
Taste aspect is basically identical.This explanation 2,6-di-tert-butyl-4-methy phenol adds in Medicated cigarette, has substantially no effect on the sense organ of Medicated cigarette
Quality.
Finally should be noted that: above example is only in order to illustrate that technical scheme is not intended to limit;To the greatest extent
The present invention has been described in detail by pipe with reference to preferred embodiment, and those of ordinary skill in the field are it is understood that still
The detailed description of the invention of the present invention can be modified or portion of techniques feature is carried out equivalent;Without deviating from this
The spirit of bright technical scheme, it all should be contained in the middle of the technical scheme scope that the present invention is claimed.
Claims (13)
1.2,6-di-tert-butyl-4-methy phenol purposes in Medicated cigarette.
2. the purposes of claim 1, described purposes is for reducing the peculiar N-content of nitrosamines of Nicotiana tabacum L. in cigarette mainstream flue gas.
3. the purposes of claim 1, described purposes is that 6-di-tert-butyl-4-methy phenol adds in Medicated cigarette real by by 2
Existing;
Preferably, described purposes is that 6-di-tert-butyl-4-methy phenol adds realization in tobacco shred or Nicotiana tabacum L. to by by 2;
Preferably, described purposes is that 6-di-tert-butyl-4-methy phenol adds realization in cigarette filter rod to by by 2.
4. a cigarette filter rod, wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described cigarette filter rod, the content of 2,6-di-tert-butyl-4-methy phenols be 15~25mg/ prop up (preferably 18~
20mg/ props up).
5. the cigarette filter rod of claim 4, filtering for cellulose acetate filter rod, head for polypropylene fiber filtering rod and papery of described cigarette filter rod
Rod.
6. the cigarette filter rod of claim 4, described cigarette filter rod is homogenizing filter stick, binary filter stick or ternary filter stick.
7. the cigarette filter rod of claim 4, wherein contains sorptive filler, and described 2,6-di-tert-butyl-4-methy phenol loads
In described sorptive filler.
8. the cigarette filter rod of claim 7, described sorptive filler is silica dioxide granule, kieselguhr or activated carbon.
9. tobacco shred or a Nicotiana tabacum L., wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described tobacco shred or Nicotiana tabacum L., the content of 2,6-di-tert-butyl-4-methy phenols is 15~25mg/g (preferably 18
~20mg/g).
10. a Medicated cigarette, wherein contains 2,6-di-tert-butyl-4-methy phenol;
Preferably, in described Medicated cigarette, the content of 2,6-di-tert-butyl-4-methy phenols is that 5-30mg/ props up Medicated cigarette, effective 6-
10mg/ props up Medicated cigarette;
Preferably, 2,6-di-tert-butyl-4-methy phenols are to add in Medicated cigarette with the form of pressed powder or liquid solution;
Preferably, described Medicated cigarette contains the cigarette filter rod of any one of claim 6~9 and/or the tobacco shred of claim 10 or cigarette
Leaf.
11. 1 kinds of methods reducing the peculiar N-nitrosamine of Nicotiana tabacum L. in cigarette mainstream flue gas, the method includes: add 2 in Medicated cigarette,
6-di-tert-butyl-4-methy phenol.
The method of Nicotiana tabacum L. peculiar N-nitrosamine in the reduction cigarette mainstream flue gas of 12. claim 11, the method includes with next
Item or multinomial:
A) adding 2 in filter stick, 6-di-tert-butyl-4-methy phenol, preferred addition manner includes: add powder in filter stick
The 2,6 di tert butyl 4 methyl phenol of shape;
B) adding 2 in tobacco shred or Nicotiana tabacum L., 6-di-tert-butyl-4-methy phenol, preferred addition manner includes: at tobacco shred or cigarette
Alcoholic solution or the aqueous solution of 2,6 di tert butyl 4 methyl phenol is applied on leaf.
The purposes of 13. claim 2 or the method for claim 11, described Nicotiana tabacum L. peculiar N-nitrosamine be selected from NNN, NNK,
One or more in NAT and NAB, preferably NNK.
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Cited By (1)
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CN110313631A (en) * | 2018-03-30 | 2019-10-11 | 上海新型烟草制品研究院有限公司 | A method of for adsorbing tobacco-specific nitrosamine in buccal cigarette offal |
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