CN106065483A - A kind of electrolysis propylene fine making adiponitrile electrolytic cell - Google Patents

A kind of electrolysis propylene fine making adiponitrile electrolytic cell Download PDF

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Publication number
CN106065483A
CN106065483A CN201610595917.XA CN201610595917A CN106065483A CN 106065483 A CN106065483 A CN 106065483A CN 201610595917 A CN201610595917 A CN 201610595917A CN 106065483 A CN106065483 A CN 106065483A
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CN
China
Prior art keywords
electrolytic cell
cell housing
anode
cathode
electrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610595917.XA
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Chinese (zh)
Inventor
潘洪明
唐正飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Maple Titanium Material Equipment Manufacturing Co Ltd
Original Assignee
Suzhou Maple Titanium Material Equipment Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Maple Titanium Material Equipment Manufacturing Co Ltd filed Critical Suzhou Maple Titanium Material Equipment Manufacturing Co Ltd
Priority to CN201610595917.XA priority Critical patent/CN106065483A/en
Publication of CN106065483A publication Critical patent/CN106065483A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/20Processes
    • C25B3/29Coupling reactions
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses a kind of electrolysis propylene fine making adiponitrile electrolytic cell, including electrolytic cell housing and support;Described electrolytic cell housing is rack-mount;It is provided with anode assemblies and cathode assembly in described electrolytic bath shell body;Described anode assemblies and cathode assembly are all by connecting copper bar power transmission;It is provided with inlet bottom described electrolytic cell housing;Described electrolytic cell housing outer end is provided with ear mount;It is provided with cylinder seal washer between described electrolytic cell housing and ear mount;The present invention uses the setting of anode assemblies and cathode assembly, improve anode assemblies and cathode assembly service life, improve electrolytic efficiency, cylinder seal washer is set between electrolytic cell housing and ear mount, reduces cathode anode spacing, improve electrolytic efficiency, solve electrolyte distribution and the irregular problem causing anode and cathode to be corroded of flow velocity, reduce energy consumption, solve to pollute, improve yield.

Description

A kind of electrolysis propylene fine making adiponitrile electrolytic cell
Technical field
The present invention relates to a kind of electrolysis propylene fine making adiponitrile electrolytic cell, belong to chemical process accessory technical field.
Background technology
Diaphragm process produces adiponitrile and uses the bipolar type press filter type electrolyzer strongly circulating with electrolyte, this The battery lead plate that the critical piece of electrolytic cell is made up of the plastics of organic solvent-resistant, is respectively mounted the moon in the lateral notches of battery lead plate Pole and anode, two electrode metal pins are connected, and have ditch in electrode plate body, are used for leading into or derive solution to anode and negative electrode Room, ditch has hole, and solution is evenly distributed on electrode chamber along hole, and each battery lead plate is clipped between two diaphragm frames, Hou Zheye Being made of plastic, the middle part of diaphragm frame press-fits barrier film, and panel is installed at electrolytic cell two ends, and is respectively arranged with an electrode;Diaphragm electrolysis Method, the barrier film of electrolytic cell now more uses cation-exchange membrane, and negative electrode requires to use the material with higher hydrogen overpotential, as Lead, cadmium and graphite etc., anode uses the metal containing 1%~2% silver medal in diaphragm electrolytic cell;Above-mentioned diaphragm process exists such as Lower problem: diaphragm process electrolytic cell cathode and anode is low for service life;Barrier film is low for service life;Detachable maintaining frequency is high;Electrolytic cell Electrolytic efficiency is low, produces industrialization continuity and brings puzzlement;Energy consumption is high, and yield is low, pollutes big, later maintenance expense and production Cost is high.
Content of the invention
For the technical problem of above-mentioned existence, it is an object of the invention to: propose one length in service life, electrolytic efficiency height Electrolysis propylene fine making adiponitrile electrolytic cell.
The technical solution of the present invention is achieved in that a kind of electrolysis propylene fine making adiponitrile electrolytic cell, including Electrolytic cell housing and support;Described electrolytic cell housing is rack-mount;It is provided with anode assemblies and the moon in described electrolytic bath shell body Pole assembly;Described anode assemblies and cathode assembly are all by connecting copper bar power transmission;It is provided with inlet bottom described electrolytic cell housing; Described electrolytic cell housing outer end is provided with ear mount;It is provided with cylinder seal washer between described electrolytic cell housing and ear mount.
Preferably, described anode assemblies includes anode end plate and anode strip;Described anode end plate and anode strip are connected with each other.
Preferably, described cathode assembly includes cathode end plate and cathode sheets;Described cathode end plate and cathode sheets are connected with each other.
Preferably, described ear mount is provided with four, is symmetricly set on electrolytic cell housing both sides.
Due to the utilization of technique scheme, the present invention compared with prior art has the advantage that
A kind of electrolysis propylene fine making adiponitrile electrolytic cell of the present invention, uses the setting of anode assemblies and cathode assembly, improves Anode assemblies and cathode assembly service life, improve electrolytic efficiency, cylinder is set between electrolytic cell housing and ear mount and seals Packing ring, reduces cathode anode spacing, improves electrolytic efficiency, solves electrolyte distribution and flow velocity is irregular causes what anode and cathode corroded to ask Topic, reduces energy consumption, solves to pollute, improves yield.
Brief description
Below in conjunction with the accompanying drawings technical solution of the present invention is described further:
A kind of structural representation being electrolysed propylene fine making adiponitrile electrolytic cell that accompanying drawing 1 is the present invention;
Wherein: the 1st, electrolytic cell housing;2nd, support;3rd, anode assemblies;4th, cathode assembly;5th, copper bar is connected;6th, inlet;7th, ear Seat;8th, cylinder seal washer.
Detailed description of the invention
The present invention is described below in conjunction with the accompanying drawings.
As shown in Figure 1 for a kind of electrolysis propylene of the present invention fine making adiponitrile electrolytic cell, including electrolytic bath shell Body 1 and support 2;Described electrolytic cell housing 1 is arranged on support 2;It is provided with anode assemblies 3 and negative electrode in described electrolytic cell housing 1 Assembly 4;Described anode assemblies 3 and cathode assembly 4 are all by connecting copper bar 5 power transmission;It is provided with feed liquor bottom described electrolytic cell housing 1 Mouth 6;Described electrolytic cell housing 1 outer end is provided with ear mount 7;It is provided with cylinder seal washer 8 between described electrolytic cell housing 1 and ear mount 7; Described anode assemblies 3 includes anode end plate and anode strip;Described anode end plate and anode strip are connected with each other;Described cathode assembly 4 Including cathode end plate and cathode sheets;Described cathode end plate and cathode sheets are connected with each other;Described ear mount 7 is provided with four, is symmetrical arranged In electrolytic cell housing 1 both sides.
Setting of a kind of electrolysis propylene fine making adiponitrile electrolytic cell of the present invention, employing anode assemblies 3 and cathode assembly 4 Put, improve anode assemblies 3 and cathode assembly 4 service life, improve electrolytic efficiency, set between electrolytic cell housing 1 and ear mount 7 Putting cylinder seal washer 8, reducing cathode anode spacing, improve electrolytic efficiency, solution electrolyte is distributed and flow velocity is irregular causes the moon The problem of anodic attack, reduces energy consumption, solves to pollute, improves yield.
Above-described embodiment is only that the technology that the present invention be described is conceived and feature, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and is carried out, and can not limit the scope of the invention with this, all according to the present invention The equivalence that Spirit Essence is made changes or modifies, and all should cover within the scope of the present invention.

Claims (4)

1. an electrolysis propylene fine making adiponitrile electrolytic cell, it is characterised in that: include electrolytic cell housing and support;Described electrolysis Slot shell is rack-mount;It is provided with anode assemblies and cathode assembly in described electrolytic bath shell body;Described anode assemblies and negative electrode Assembly is all by connecting copper bar power transmission;It is provided with inlet bottom described electrolytic cell housing;Described electrolytic cell housing outer end is provided with ear Seat;It is provided with cylinder seal washer between described electrolytic cell housing and ear mount.
2. a kind of electrolysis propylene as claimed in claim 1 fine making adiponitrile electrolytic cell, it is characterised in that: described anode assemblies Including anode end plate and anode strip;Described anode end plate and anode strip are connected with each other.
3. a kind of electrolysis propylene as claimed in claim 1 fine making adiponitrile electrolytic cell, it is characterised in that: described cathode assembly Including cathode end plate and cathode sheets;Described cathode end plate and cathode sheets are connected with each other.
4. a kind of electrolysis propylene as claimed in claim 1 fine making adiponitrile electrolytic cell, it is characterised in that: described ear mount is provided with It four, is symmetricly set on electrolytic cell housing both sides.
CN201610595917.XA 2016-07-27 2016-07-27 A kind of electrolysis propylene fine making adiponitrile electrolytic cell Pending CN106065483A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610595917.XA CN106065483A (en) 2016-07-27 2016-07-27 A kind of electrolysis propylene fine making adiponitrile electrolytic cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610595917.XA CN106065483A (en) 2016-07-27 2016-07-27 A kind of electrolysis propylene fine making adiponitrile electrolytic cell

Publications (1)

Publication Number Publication Date
CN106065483A true CN106065483A (en) 2016-11-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610595917.XA Pending CN106065483A (en) 2016-07-27 2016-07-27 A kind of electrolysis propylene fine making adiponitrile electrolytic cell

Country Status (1)

Country Link
CN (1) CN106065483A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4136004A (en) * 1975-07-15 1979-01-23 Kamarian Georgy M Solid electrode electrolyzer for electrolysis of aqueous solutions
US4402810A (en) * 1980-05-15 1983-09-06 Imperial Chemical Industries Limited Bipolarly connected electrolytic cells of the filter press type
CN201128761Y (en) * 2007-11-26 2008-10-08 苏州卓群钛镍设备有限公司 Chlorates electrolytic tank
CN201390789Y (en) * 2009-04-29 2010-01-27 苏州卓群钛镍设备有限公司 Composite round chlorate electrolyzer unit device
CN201390790Y (en) * 2009-04-29 2010-01-27 苏州卓群钛镍设备有限公司 Cathode-anode combination of composite round chlorate electrolyzer unit
CN205934038U (en) * 2016-07-27 2017-02-08 苏州市枫港钛材料设备制造有限公司 Fine preparation adiponitrile electrolysis trough of electrolysis propylene

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4136004A (en) * 1975-07-15 1979-01-23 Kamarian Georgy M Solid electrode electrolyzer for electrolysis of aqueous solutions
US4402810A (en) * 1980-05-15 1983-09-06 Imperial Chemical Industries Limited Bipolarly connected electrolytic cells of the filter press type
CN201128761Y (en) * 2007-11-26 2008-10-08 苏州卓群钛镍设备有限公司 Chlorates electrolytic tank
CN201390789Y (en) * 2009-04-29 2010-01-27 苏州卓群钛镍设备有限公司 Composite round chlorate electrolyzer unit device
CN201390790Y (en) * 2009-04-29 2010-01-27 苏州卓群钛镍设备有限公司 Cathode-anode combination of composite round chlorate electrolyzer unit
CN205934038U (en) * 2016-07-27 2017-02-08 苏州市枫港钛材料设备制造有限公司 Fine preparation adiponitrile electrolysis trough of electrolysis propylene

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Application publication date: 20161102