CN106065179A - Polyaniline carbon fibre composite and preparation method thereof - Google Patents

Polyaniline carbon fibre composite and preparation method thereof Download PDF

Info

Publication number
CN106065179A
CN106065179A CN201610390137.1A CN201610390137A CN106065179A CN 106065179 A CN106065179 A CN 106065179A CN 201610390137 A CN201610390137 A CN 201610390137A CN 106065179 A CN106065179 A CN 106065179A
Authority
CN
China
Prior art keywords
parts
polyaniline
carbon fibre
fibre composite
hexamethylenamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610390137.1A
Other languages
Chinese (zh)
Inventor
蔡小连
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Kuikeli Electronic Technology Co Ltd
Original Assignee
Suzhou Kuikeli Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Kuikeli Electronic Technology Co Ltd filed Critical Suzhou Kuikeli Electronic Technology Co Ltd
Priority to CN201610390137.1A priority Critical patent/CN106065179A/en
Publication of CN106065179A publication Critical patent/CN106065179A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention provides polyaniline carbon fibre composite, including following component: polyaniline, carbon fiber, cerous nitrate, zinc oxide, cinnamic acid, silicone powder, EPR, dimethicone, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, VTES, phthalic acid ester part, ethylene vinyl acetate copolymer, EVA, N, N dimethylformamide.Present invention also offers the preparation method of described polyaniline carbon fibre composite.Polyaniline carbon fibre composite prepared by the present embodiment has good electric conductivity, hot strength and elongation at break values are high simultaneously, and high comprehensive performance additionally has good heat conduction and antistatic behaviour, the respective advantage of material, wide market are given full play to.

Description

Polyaniline-carbon fibre composite and preparation method thereof
Technical field
The present invention relates to field of compound material, be specifically related to polyaniline-carbon fibre composite and preparation method thereof.
Background technology
Containing phenyl ring alternately and nitrogen-atoms on the main chain of polyaniline, it it is a kind of special conducting polymer.Polyaniline by Simple in synthesis, cheap, high temperature resistant, good in oxidation resistance, electrical conductivity is high and the advantage such as electrochromism, at secondary cell, anti- Electrostatic and absorbing material, anticorrosive, ultracapacitor, selectivity are through film, sensor, molecular wire and molecular device etc. Aspect has certain application.But, in order to preferably apply, the aspect such as the antistatic behaviour of polyaniline material, conduction, heat conductivity It need to improve further.
Carbon fiber is phosphorus content high strength and modulus fiber more than 90%, by decomposition temperature less than melt temperature Fiber polymer, is made by more than thousand degree solid phase pyrolysis.Its kind includes polyacrylonitrile-based carbon fibre (PAN base carbon Fine), asphalt base carbon fiber, viscose-based carbon fiber.It is big that carbon fiber has high intensity, light weight, endurance, function admirable, modulus With advantage, the applied range such as thermal coefficient of expansion is low.But, the carbon planes of molecules in fiber be along fiber axis be orientated, surface in Between chemical inertness, and thermoplastic resin matrix, affinity is poor, it is difficult to form chemical bond connection and interface exists incompatible Component, interface binding intensity is low, and compound tense easily forms hole and defect on interface, and reinforcement and matrix resin are difficult to be formed There is effective adhesive, affect the performance of composite material combination property.
Summary of the invention
It is an object of the invention to provide polyaniline-carbon fibre composite and preparation method thereof.
In order to realize the purpose of the present invention, the present invention provides polyaniline-carbon fibre composite, including following parts by weight Component: polyaniline 45-66 part, carbon fiber 13-19 part, cerous nitrate 5-9 part, zinc oxide 3-6 part, cinnamic acid 5-10 part, silicon Ketone powder 3-7 part, EPR 2-5 part, dimethicone 2-8 part, erucyl amide 3-7 part, sodium metaantimonate 2-5 part, Tissuemat E 2-6 Part, hexamethylenamine 4-7 part, VTES 3-9 part, phthalic acid ester 2-7 part, ethylene-vinyl acetate are common Polymers 1-4 part, EVA 1-3 part, N,N-dimethylformamide 65-120 part.
Preferably, described carbon fiber is PAN base carbon fibre.
Preferably, including the component of following parts by weight: polyaniline 49 parts, 17 parts of carbon fiber, cerous nitrate 6 parts, oxidation 5 parts of zinc, cinnamic acid 8 parts, silicone powder 6 parts, EPR 4 parts, dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 3 parts, poly-second 4 parts of alkene wax, hexamethylenamine 6 parts, VTES 6 parts, phthalic acid ester 3 parts, ethylene-vinyl acetate copolymerization Thing 3 parts, EVA 2 parts, N,N-dimethylformamide 98 parts.
Preferably, include the component of following parts by weight described in: polyaniline 63 parts, 16 parts of carbon fiber, cerous nitrate 7 parts, Zinc oxide 5 parts, cinnamic acid 8 parts, silicone powder 4 parts, EPR 3 parts, dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 4 parts, Tissuemat E 4 parts, hexamethylenamine 5 parts, VTES 7 parts, phthalic acid ester 4 parts, ethylene-vinyl acetate Copolymer 2 parts, EVA 1.8 parts, N,N-dimethylformamide 105 parts.
The present invention also provides for the preparation method of above-mentioned polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 45-66 part, carbon fiber 13-19 part, cerous nitrate 5-9 part, oxidation Zinc 3-6 part, cinnamic acid 5-10 part, silicone powder 3-7 part, EPR 2-5 part, dimethicone 2-8 part, erucyl amide 3-7 part, inclined antimony Acid sodium, Tissuemat E 2-6 part, hexamethylenamine 4-7 part, VTES 3-9 part, phthalic acid ester 2-7 part, second Alkene-vinyl acetate co-polymer 1-4 part, EVA 1-3 part, N,N-dimethylformamide 65-120 part；
Step 2): polyaniline is entered in DMF, stir 50-90 minute at 75-100 DEG C, obtain polyaniline Solution；
Step 3): through carbon fiber and VTES, phthalic acid ester, ethylene-vinyl acetate copolymer, EVA adds in mixer, mixed at high speed 30min at 85 DEG C；Be subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, control temperature and be 70-90 DEG C, and rotating speed is 250-500rpm, stirs Mix 50-120 minute, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controls temperature and is 40-60 DEG C, and rotating speed is 300-600rpm, stirs 15-60 minute, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
Preferably, described step 2) at 80 DEG C stir 65 minutes.
Preferably, controlling temperature in described step 3) is 82 DEG C, and rotating speed is 450rpm, stirs 110 minutes.
Preferably, controlling temperature in step 4) is 45 DEG C, and rotating speed is 320rpm, stirs 20 minutes.
The invention have the benefit that
Polyaniline-carbon fibre composite prepared by the present embodiment is by introducing carbon fiber, and prepared composite has good Good electric conductivity, hot strength and elongation at break values are high simultaneously, high comprehensive performance, additionally have good heat conduction and resist Static behaviour, has given full play to the respective advantage of material, wide market.
Detailed description of the invention
Below by way of the description of detailed description of the invention, the invention will be further described, but this is not the limit to the present invention System, those skilled in the art are according to the basic thought of the present invention, and various modifications may be made or improves, but without departing from The basic thought of the present invention, the most within the scope of the present invention.
Embodiment 1
The preparation method of polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 45 parts, PAN base carbon fibre 13 parts, cerous nitrate 5 parts, zinc oxide 3 Part, cinnamic acid 5 parts, silicone powder 3 parts, EPR 2 parts, dimethicone 2 parts, erucyl amide 3 parts, sodium metaantimonate 2 parts, Tissuemat E 2 parts, hexamethylenamine 4 parts, VTES 3 parts, phthalic acid ester 2 parts, ethylene-vinyl acetate copolymer 1 Part, EVA 1 part, N,N-dimethylformamide 65 parts；
Step 2): polyaniline is entered in DMF, stir 50 minutes at 75 DEG C, obtain polyaniline solutions；
Step 3): through PAN base carbon fibre and VTES, phthalic acid ester, ethylene-vinyl acetate copolymerization Thing, EVA add in mixer, mixed at high speed 30min at 85 DEG C；It is subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone Powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, controlling temperature is 70 DEG C, and rotating speed is 250rpm, stirs 50 Minute, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controlling temperature is 40 DEG C, and rotating speed is 300rpm, stirs 15-60 minute, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The performance test results of polyaniline-carbon fibre composite prepared by the present embodiment is: sheet resistance by 3.84 × 106Ohm, hot strength is 48MPa, and elongation at break is 116%.
Embodiment 2
The preparation method of polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 55 parts, PAN base carbon fibre 16 parts, cerous nitrate 7 parts, zinc oxide 4.5 parts, cinnamic acid 7 parts, silicone powder 5 parts, EPR 3.5 parts, dimethicone 5 parts, erucyl amide 5 parts, sodium metaantimonate 3.5 parts, Tissuemat E 4 parts, hexamethylenamine 5 parts, VTES 6 parts, phthalic acid ester 4 parts, ethylene-vinyl acetate Copolymer 2 parts, EVA 2 parts, N,N-dimethylformamide 92 parts；
Step 2): polyaniline is entered in DMF, stir 70 minutes at 87 DEG C, obtain polyaniline solutions；
Step 3): through PAN base carbon fibre and VTES, phthalic acid ester, ethylene-vinyl acetate copolymerization Thing, EVA add in mixer, mixed at high speed 30min at 85 DEG C；It is subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone Powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, controlling temperature is 80 DEG C, and rotating speed is 375rpm, stirs 85 Minute, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controlling temperature is 50 DEG C, and rotating speed is 450rpm, stirs 15-60 minute, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The performance test results of polyaniline-carbon fibre composite prepared by the present embodiment is: sheet resistance by 3.23 × 106Ohm, hot strength is 52MPa, and elongation at break is 125%.
Embodiment 3
The preparation method of polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 66 parts, PAN base carbon fibre 19 parts, cerous nitrate 9 parts, zinc oxide 6 Part, cinnamic acid 10 parts, silicone powder 7 parts, EPR 5 parts, dimethicone 8 parts, erucyl amide 7 parts, sodium metaantimonate 5 parts, polyethylene 6 parts of wax, hexamethylenamine 7 parts, VTES 9 parts, phthalic acid ester 7 parts, ethylene-vinyl acetate copolymer 4 parts, EVA 3 parts, N,N-dimethylformamide 120 parts；
Step 2): polyaniline is entered in DMF, stir 90 minutes at 100 DEG C, obtain polyaniline solutions；
Step 3): through PAN base carbon fibre and VTES, phthalic acid ester, ethylene-vinyl acetate copolymerization Thing, EVA add in mixer, mixed at high speed 30min at 85 DEG C；It is subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone Powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, controlling temperature is 90 DEG C, and rotating speed is 500rpm, stirring 120 minutes, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controlling temperature is 60 DEG C, and rotating speed is 600rpm, stirs 60 minutes, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The performance test results of polyaniline-carbon fibre composite prepared by the present embodiment is: sheet resistance by 3.87 × 106Ohm, hot strength is 43MPa, and elongation at break is 104%.
Embodiment 4
The preparation method of polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 49 parts, 17 parts of carbon fiber, cerous nitrate 6 parts, zinc oxide 5 parts, meat Cinnamic acid 8 parts, silicone powder 6 parts, EPR 4 parts, dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 3 parts, Tissuemat E 4 parts, Hexamethylenamine 6 parts, VTES 6 parts, phthalic acid ester 3 parts, ethylene-vinyl acetate copolymer 3 parts, EVA 2 parts, N,N-dimethylformamide 98 parts；
Step 2): polyaniline is entered in DMF, stir 65 minutes at 80 DEG C, obtain polyaniline solutions；
Step 3): through PAN base carbon fibre and VTES, phthalic acid ester, ethylene-vinyl acetate copolymerization Thing, EVA add in mixer, mixed at high speed 30min at 85 DEG C；It is subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone Powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, controlling temperature is 82 DEG C, and rotating speed is 450rpm, stirring 110 minutes, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controlling temperature is 45 DEG C, and rotating speed is 320rpm, stirs 20 minutes, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The performance test results of polyaniline-carbon fibre composite prepared by the present embodiment is: sheet resistance by 1.66 × 106Ohm, hot strength is 56MPa, and elongation at break is 131%.
Embodiment 5
The preparation method of polyaniline-carbon fibre composite, including following preparation process:
Step 1): each component of weighing by weight: polyaniline 63 parts, 16 parts of carbon fiber, cerous nitrate 7 parts, zinc oxide 5 parts, meat Cinnamic acid 8 parts, silicone powder 4 parts, EPR 3 parts, dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 4 parts, Tissuemat E 4 parts, Hexamethylenamine 5 parts, VTES 7 parts, phthalic acid ester 4 parts, ethylene-vinyl acetate copolymer 2 parts, EVA 1.8 parts, N,N-dimethylformamide 105 parts；
Step 2): polyaniline is entered in DMF, stir 65 minutes at 80 DEG C, obtain polyaniline solutions；
Step 3): through PAN base carbon fibre and VTES, phthalic acid ester, ethylene-vinyl acetate copolymerization Thing, EVA add in mixer, mixed at high speed 30min at 85 DEG C；It is subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone Powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, controlling temperature is 82 DEG C, and rotating speed is 450rpm, stirring 110 minutes, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controlling temperature is 45 DEG C, and rotating speed is 320rpm, stirs 20 minutes, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The performance test results of polyaniline-carbon fibre composite prepared by the present embodiment is: sheet resistance by 1.58 × 106Ohm, hot strength is 54MPa, and elongation at break is 128%.

Claims (8)

1. polyaniline-carbon fibre composite, it is characterised in that include the component of following parts by weight: polyaniline 45-66 part, Carbon fiber 13-19 part, cerous nitrate 5-9 part, zinc oxide 3-6 part, cinnamic acid 5-10 part, silicone powder 3-7 part, EPR 2-5 part, two Methyl-silicone oil 2-8 part, erucyl amide 3-7 part, sodium metaantimonate 2-5 part, Tissuemat E 2-6 part, hexamethylenamine 4-7 part, vinyl Triethoxysilane 3-9 part, phthalic acid ester 2-7 part, ethylene-vinyl acetate copolymer 1-4 part, EVA 1-3 part, N, N- Dimethylformamide 65-120 part.
Polyaniline-carbon fibre composite the most according to claim 1, it is characterised in that described carbon fiber is PAN base carbon Fiber.
Polyaniline-carbon fibre composite the most according to claim 1, it is characterised in that include following parts by weight Component: polyaniline 49 parts, 17 parts of carbon fiber, cerous nitrate 6 parts, zinc oxide 5 parts, cinnamic acid 8 parts, silicone powder 6 parts, EPR 4 parts, Dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 3 parts, Tissuemat E 4 parts, hexamethylenamine 6 parts, vinyl triethoxyl 6 parts of silane, phthalic acid ester 3 parts, ethylene-vinyl acetate copolymer 3 parts, EVA 2 parts, N,N-dimethylformamide 98 Part.
Polyaniline-carbon fibre composite the most according to claim 1, it is characterised in that include following parts by weight Component: polyaniline 63 parts, 16 parts of carbon fiber, cerous nitrate 7 parts, zinc oxide 5 parts, cinnamic acid 8 parts, silicone powder 4 parts, EPR 3 parts, Dimethicone 6 parts, erucyl amide 4 parts, sodium metaantimonate 4 parts, Tissuemat E 4 parts, hexamethylenamine 5 parts, vinyl triethoxyl 7 parts of silane, phthalic acid ester 4 parts, ethylene-vinyl acetate copolymer 2 parts, EVA 1.8 parts, N,N-dimethylformamide 105 parts.
5. the preparation method of polyaniline-carbon fibre composite, it is characterised in that include following preparation process:
Step 1): each component of weighing by weight: polyaniline 45-66 part, carbon fiber 13-19 part, cerous nitrate 5-9 part, oxidation Zinc 3-6 part, cinnamic acid 5-10 part, silicone powder 3-7 part, EPR 2-5 part, dimethicone 2-8 part, erucyl amide 3-7 part, inclined antimony Acid sodium, Tissuemat E 2-6 part, hexamethylenamine 4-7 part, VTES 3-9 part, phthalic acid ester 2-7 part, second Alkene-vinyl acetate co-polymer 1-4 part, EVA 1-3 part, N,N-dimethylformamide 65-120 part；
Step 2): polyaniline is entered in DMF, stir 50-90 minute at 75-100 DEG C, obtain polyaniline Solution；
Step 3): through carbon fiber and VTES, phthalic acid ester, ethylene-vinyl acetate copolymer, EVA adds in mixer, mixed at high speed 30min at 85 DEG C；Be subsequently adding cerous nitrate, zinc oxide, cinnamic acid, silicone powder, EPR, erucyl amide, sodium metaantimonate, Tissuemat E, hexamethylenamine, control temperature and be 70-90 DEG C, and rotating speed is 250-500rpm, stirs Mix 50-120 minute, discharging；
Step 4): the material in step 3) is joined step 2) in polyaniline solutions in stir；It is subsequently adding Remaining components, controls temperature and is 40-60 DEG C, and rotating speed is 300-600rpm, stirs 15-60 minute, obtains compound；
The compound that step 4) is obtained by step 5) enters to melt extrude pelletize in double screw extruder, controls extruder barrel temperature Degree is for 150-190 DEG C, and screw speed is 70rpm, obtains polyaniline-carbon fibre composite.
The preparation method of polyaniline-carbon fibre composite the most according to claim 5, it is characterised in that step 2) in Stir 65 minutes at 80 DEG C.
The preparation method of polyaniline-carbon fibre composite the most according to claim 5, it is characterised in that in step 3) Controlling temperature is 82 DEG C, and rotating speed is 450rpm, stirs 110 minutes.
The preparation method of polyaniline-carbon fibre composite the most according to claim 5, it is characterised in that in step 4) Controlling temperature is 45 DEG C, and rotating speed is 320rpm, stirs 20 minutes.
CN201610390137.1A 2016-06-06 2016-06-06 Polyaniline carbon fibre composite and preparation method thereof Pending CN106065179A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610390137.1A CN106065179A (en) 2016-06-06 2016-06-06 Polyaniline carbon fibre composite and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610390137.1A CN106065179A (en) 2016-06-06 2016-06-06 Polyaniline carbon fibre composite and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106065179A true CN106065179A (en) 2016-11-02

Family

ID=57420272

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610390137.1A Pending CN106065179A (en) 2016-06-06 2016-06-06 Polyaniline carbon fibre composite and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106065179A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659455A (en) * 2018-05-31 2018-10-16 芜湖卓越线束系统有限公司 A kind of new-energy automobile electromagnetism interference wire harness sheath material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031037A (en) * 2012-12-19 2013-04-10 中国科学院长春应用化学研究所 Polyaniline/carbon conducting composite material with low resistance temperature coefficient, as well as preparation method and application thereof
CN105315474A (en) * 2014-06-13 2016-02-10 黑龙江鑫达企业集团有限公司 Preparation method of enhancing PEEK by treating carbon fibers with special coupling agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031037A (en) * 2012-12-19 2013-04-10 中国科学院长春应用化学研究所 Polyaniline/carbon conducting composite material with low resistance temperature coefficient, as well as preparation method and application thereof
CN105315474A (en) * 2014-06-13 2016-02-10 黑龙江鑫达企业集团有限公司 Preparation method of enhancing PEEK by treating carbon fibers with special coupling agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659455A (en) * 2018-05-31 2018-10-16 芜湖卓越线束系统有限公司 A kind of new-energy automobile electromagnetism interference wire harness sheath material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102863686B (en) Semiconductive low-smoke zero-halogen flame-retardant polyolefin sheath material and preparation method thereof
Wen et al. Vulcanization characteristics of asphalt/SBS blends in the presence of sulfur
CN105949697B (en) A kind of high temperature resistant acrylic rubber and preparation method thereof
CN1970612A (en) Preparation method of electrically conductive composite material with positive temperature coefficient effect
Tang et al. Nanostructured thermoplastic vulcanizates by selectively cross-linking a thermoplastic blend with similar chemical structures
CN101928452B (en) Poly(arylene ether nitrile) and aluminum oxide composite insulating heat-conduction material and preparation method thereof
CN105131611A (en) High-strength halogen-free fire resisting cable insulating plastic and preparation method thereof
CN105778295A (en) Preparation method of polypropylene cable material and polypropylene cable material
Khan et al. Enhancement of mechanical and electrical properties for in-situ compatibilization of immiscible polypropylene/polystyrene blends
CN105086378A (en) Liquid crystal polymer in-situ composite material and preparation method therefor
CN106065179A (en) Polyaniline carbon fibre composite and preparation method thereof
CN107345033B (en) Polyvinyl chloride cable composite material and its manufacturing method, cable
CN104072954A (en) Poly-2,5-furandicarboxylic acid glycol ester composite material and preparation method thereof
KR102003686B1 (en) Modified asphalt containing vegetable oil and method for manufacturing the same
Zhou et al. A bio‐based compatibilizer for improved interfacial compatibility in thermally conductive and electrically insulating graphite/high density poly (ethylene) composites
Mir et al. Development of polypyrrole/epoxy composites as isotropically conductive adhesives
CN104262965A (en) PPS (polyphenylene sulfide) composite material and preparation method thereof
US20050035334A1 (en) PTC compositions based on PVDF and their applications for self-regulated heating systems
CN114410109B (en) Extruded and low-temperature-bending-resistant aliphatic long-carbon-chain nylon composite material and preparation method thereof
CN104262924B (en) There is the flame resistant aromatic polycarbonate compositions of low precipitate and good appearance
CN113444319B (en) Antistatic polypropylene composite material and preparation method thereof
CN105694469A (en) Insulating heat-conducting composition, insulating heat-conducting material, insulating heat-conducting sheet, preparing method of the insulating heat-conducting sheet and positive temperature coefficient thermistors heater
CN105647088A (en) Thermally conductive plastics and preparation method thereof
CN102604558B (en) Heat-resistant laminated-positioning electronic adhesive tape for solar cell and preparation method thereof
CN109721841B (en) Long-acting antistatic PP material and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161102