CN106058351A - Environment-friendly recycling method for waste lead-acid storage battery - Google Patents
Environment-friendly recycling method for waste lead-acid storage battery Download PDFInfo
- Publication number
- CN106058351A CN106058351A CN201610562472.5A CN201610562472A CN106058351A CN 106058351 A CN106058351 A CN 106058351A CN 201610562472 A CN201610562472 A CN 201610562472A CN 106058351 A CN106058351 A CN 106058351A
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- CN
- China
- Prior art keywords
- lead
- acid
- storage battery
- acid storage
- old
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The invention relates to an environment-friendly recycling method for a waste lead-acid storage battery. The environment-friendly recycling method comprises the following steps: (1) punching a hole in the bottom of the waste lead-acid storage battery with a shell to discharge waste acid, collecting the waste acid by using a storage tank, delivering the waste acid in a sulphuric acid production workshop for producing sulphuric acid, performing primary crushing on the lead-acid storage battery by using a punching machine, further crushing the lead-acid storage battery by using an alligator-type crusher, and performing fine grinding by using a ball-grinding mill; (2) sorting the lead-acid storage battery which is treated in the step (1) by using a special tower-type weight sorter to obtain a light-weight material, an intermediate-weight material and a heavy-weight material; (3) calcining the light-weight material and the intermediate-weight material which are obtained in the step (2) for 3 to 6 hours at 500 to 600 DEG C; (4) mixing ultrafine lead powder obtained in the step (3) and industrial coarse lead powder. According to the environment-friendly recycling method, a lead-containing material is used for preparing active material slurry for negative plate coating paste for the lead-acid storage battery, so that the recovery utilization rate of the lead is remarkably improved, and the economic benefit is improved.
Description
Technical field
The present invention relates to scrap concrete technical field, it particularly relates to a kind of plumbic acid stores the environmental protection of old and useless battery again
Application way.
Background technology
Plumbic acid stores old and useless battery and is formed by positive/negative plate, dividing plate, housing, electrolyte and wiring pile are first-class, and waste and old lead stores
Containing lead and compound thereof in battery, possibly together with electrolyte solutions such as metal and acid such as hydrargyrum, cadmium, chromium and manganese, once enter people
Body, the insulting nervous system of meeting, hemopoietic function and kidney etc., the heavy metal that the lead-acid accumulator arbitrarily thrown is decomposed contains
Toxic waste liquid, can destroy ecological balance, be detrimental to health.China has produced 300,000 tons of lead-acid accumulators, usual lead every year
Acid stores old and useless battery and reclaims the lead mud produced, and main component is lead sulfate, lead oxide, Lead oxide brown and sulphuric acid, by thermal decomposition
May separate out monomer lead, but the decomposition temperature of lead sulfate is up to more than 900 degree, catabolite vulcanized lead is also required in higher temperatures
Replacing under degree, the method not only results in environmental pollution, and energy consumption is high, and the response rate of lead is relatively low, is about 80%.
Summary of the invention
It is an object of the invention to provide a kind of method storing old and useless battery recovery lead from plumbic acid, to solve prior art general
Plumbic acid stores that the energy consumption existed when old and useless battery reclaims lead is high, the response rate is low and causes environmental pollution and the deficiency that exists.
To achieve these goals, technical scheme is as follows.
A kind of plumbic acid stores the environmental protection reuse method of old and useless battery, comprises the following steps:
(1) plumbic acid of band shell is stored old and useless battery bear and discharge spent acid, this spent acid is collected with accumulator tank and sends into Sulphuric acid
Workshop Sulphuric acid, then carries out lead-acid accumulator punch press the most broken, then crushes further with alligator, then use
Ball mill fine grinding；
(2) the lead-acid accumulator special tower gravity classifier after step (1) being processed sorts, it is thus achieved that light material,
Middle pledge material and heavier feeds；
(3) light material obtained in step (2) and heavier feeds are calcined 3～6h under conditions of 500～600 DEG C, it is thus achieved that
Superfine lead powder；
(4) superfine lead powder that step (3) obtains is mixed with industrial crude Hydrocerussitum (Ceruse), add water and sulphuric acid, after being uniformly mixed,
Obtaining active substance slip, wherein, the mass ratio of superfine lead powder, industrial crude Hydrocerussitum (Ceruse), water and sulphuric acid is 1:3:6:3.
In described step (1), for the first time broken granularity is 200～300mm, the most broken after granularity be 60～
100mm, after fine grinding, granularity is 10～15mm.
Described light material is the mixture such as epoxy resin particle and plastics, and middle pledge material is lead and metal, weight
Pledge material is the mixture of lead, lead oxide, Lead oxide brown and lead sulfate.
This beneficial effect of the invention is: after the present invention is by carrying out lead-acid accumulator twice crushing, then carry out fine grinding,
The recycling of follow-up lead can be effectively facilitated, be used for leaded material preparing the negative plate cream being used for lead-acid accumulator
Active substance slip, significantly improve the recovery utilization rate of lead, improve economic benefit.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described, in order to be better understood from the present invention.
Embodiment 1
Plumbic acid in the present embodiment stores the environmental protection reuse method of old and useless battery, comprises the following steps:
(1) plumbic acid of band shell is stored old and useless battery bear and discharge spent acid, this spent acid is collected with accumulator tank and sends into Sulphuric acid
Workshop Sulphuric acid, then carries out lead-acid accumulator punch press the most broken, then crushes further with alligator, then use
Ball mill fine grinding；
(2) the lead-acid accumulator special tower gravity classifier after step (1) being processed sorts, it is thus achieved that light material,
Middle pledge material and heavier feeds；
(3) light material obtained in step (2) and heavier feeds are calcined 6h under conditions of 500 DEG C, it is thus achieved that superfine lead powder；
(4) superfine lead powder that step (3) obtains is mixed with industrial crude Hydrocerussitum (Ceruse), add water and sulphuric acid, after being uniformly mixed,
Obtaining active substance slip, wherein, the mass ratio of superfine lead powder, industrial crude Hydrocerussitum (Ceruse), water and sulphuric acid is 1:3:6:3.
In described step (1), the most broken granularity is 200mm, and the most broken rear granularity is 60mm, grain after fine grinding
Degree is 10mm.
Described light material is epoxy resin particle, and middle pledge material is lead and metal, and heavier feeds is lead, oxidation
The mixture of lead, Lead oxide brown and lead sulfate.
Embodiment 2
Plumbic acid in the present embodiment stores the environmental protection reuse method of old and useless battery, comprises the following steps:
(1) plumbic acid of band shell is stored old and useless battery bear and discharge spent acid, this spent acid is collected with accumulator tank and sends into Sulphuric acid
Workshop Sulphuric acid, then carries out lead-acid accumulator punch press the most broken, then crushes further with alligator, then use
Ball mill fine grinding；
(2) the lead-acid accumulator special tower gravity classifier after step (1) being processed sorts, it is thus achieved that light material,
Middle pledge material and heavier feeds；
(3) light material obtained in step (2) and heavier feeds are calcined 3h under conditions of 600 DEG C, it is thus achieved that superfine lead powder；
(4) superfine lead powder that step (3) obtains is mixed with industrial crude Hydrocerussitum (Ceruse), add water and sulphuric acid, after being uniformly mixed,
Obtaining active substance slip, wherein, the mass ratio of superfine lead powder, industrial crude Hydrocerussitum (Ceruse), water and sulphuric acid is 1:3:6:3.
In described step (1), the most broken granularity is 300mm, and the most broken rear granularity is 100mm, after fine grinding
Granularity is 15mm.
Described light material is the mixture such as epoxy resin particle and plastics, and middle pledge material is lead and metal, weight
Pledge material is the mixture of lead, lead oxide, Lead oxide brown and lead sulfate.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (3)
1. the environmental protection reuse method of a plumbic acid storage old and useless battery, it is characterised in that: comprise the following steps:
(1) plumbic acid of band shell is stored old and useless battery bear and discharge spent acid, this spent acid is collected with accumulator tank and sends into Sulphuric acid
Workshop Sulphuric acid, then carries out lead-acid accumulator punch press the most broken, then crushes further with alligator, then use
Ball mill fine grinding；
(2) the lead-acid accumulator special tower gravity classifier after step (1) being processed sorts, it is thus achieved that light material,
Middle pledge material and heavier feeds；
(3) light material obtained in step (2) and heavier feeds are calcined 3～6h under conditions of 500～600 DEG C, it is thus achieved that
Superfine lead powder；
(4) superfine lead powder that step (3) obtains is mixed with industrial crude Hydrocerussitum (Ceruse), add water and sulphuric acid, after being uniformly mixed,
Obtaining active substance slip, wherein, the mass ratio of superfine lead powder, industrial crude Hydrocerussitum (Ceruse), water and sulphuric acid is 1:3:6:3.
Plumbic acid the most according to claim 1 stores the environmental protection reuse method of old and useless battery, it is characterised in that: described step
(1) in, the most broken granularity is 200～300mm, and the most broken rear granularity is 60～100mm, and after fine grinding, granularity is 10
～15mm.
Plumbic acid the most according to claim 1 stores the environmental protection reuse method of old and useless battery, it is characterised in that: described lightweight thing
Material is for the mixture such as epoxy resin particle and plastics, and middle pledge material is lead and metal, heavier feeds be lead, lead oxide,
Lead oxide brown and the mixture of lead sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562472.5A CN106058351A (en) | 2016-07-18 | 2016-07-18 | Environment-friendly recycling method for waste lead-acid storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562472.5A CN106058351A (en) | 2016-07-18 | 2016-07-18 | Environment-friendly recycling method for waste lead-acid storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106058351A true CN106058351A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610562472.5A Pending CN106058351A (en) | 2016-07-18 | 2016-07-18 | Environment-friendly recycling method for waste lead-acid storage battery |
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| CN (1) | CN106058351A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544510A (en) * | 2016-12-07 | 2017-03-29 | 天津华庆百胜能源有限公司 | A kind of processing method of waste and old lead acid accumulator |
| CN111146521A (en) * | 2019-12-17 | 2020-05-12 | 界首市双特新材料科技有限公司 | Harmless regeneration method for waste lead-acid battery shell |
-
2016
- 2016-07-18 CN CN201610562472.5A patent/CN106058351A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544510A (en) * | 2016-12-07 | 2017-03-29 | 天津华庆百胜能源有限公司 | A kind of processing method of waste and old lead acid accumulator |
| CN111146521A (en) * | 2019-12-17 | 2020-05-12 | 界首市双特新材料科技有限公司 | Harmless regeneration method for waste lead-acid battery shell |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161026 |