CN106049038A - Antibacterial finishing agent for apparel fabrics and finishing process thereof - Google Patents

Antibacterial finishing agent for apparel fabrics and finishing process thereof Download PDF

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Publication number
CN106049038A
CN106049038A CN201610369404.7A CN201610369404A CN106049038A CN 106049038 A CN106049038 A CN 106049038A CN 201610369404 A CN201610369404 A CN 201610369404A CN 106049038 A CN106049038 A CN 106049038A
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CN
China
Prior art keywords
clothing fabric
finishing agent
parts
antibacterial finishing
antibacterial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610369404.7A
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Chinese (zh)
Inventor
张红桥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hongqiao Taicang Garments Co Ltd
Original Assignee
Hongqiao Taicang Garments Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hongqiao Taicang Garments Co Ltd filed Critical Hongqiao Taicang Garments Co Ltd
Priority to CN201610369404.7A priority Critical patent/CN106049038A/en
Publication of CN106049038A publication Critical patent/CN106049038A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/425Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/463Compounds containing quaternary nitrogen atoms derived from monoamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides an antibacterial finishing agent for apparel fabrics and a finishing process thereof. The antibacterial finishing agent for the apparel fabrics is prepared from, by weight, 2-methyl-4-isothiazolin-3-ketone, N,N-normal-nickel dibutyl dithiocarbamate, chitosan, dodecyl dimethyl betaine, licorice extract, a dispersing agent and deionized water. The antibacterial finishing agent for the apparel fabrics is non-toxic and has a good antibacterial effect and an antistatic function, the apparel fabrics are finished by utilizing the antibacterial finishing agent, and the wrinkle resistance capability of the fabrics can be improved. In addition, the finishing process of the antibacterial finishing agent is simple in operation, and the cost is low.

Description

The antibacterial finishing agent of a kind of clothing fabric and finishing technique thereof
Technical field
The present invention relates to a kind of antibiotic finish technical field, particularly to the antibacterial finishing agent of a kind of clothing fabric and whole Science and engineering skill.
Background technology
The skin of various microorganism, only upper half of human body it is known that survive in the environment of human lives Upper every square metre just has 50~5000 microorganisms, and some of which is useful to human body, the most indispensable, but also Having many microorganisms to impair health, they can survive in people's fabric used in everyday, such as socks, clothing Trousers, cotton-wadded quilt, sheet, towel etc., in the environment of warm moist, these microorganisms with the perspiration of human secretory, oils and fats, scurf or The decomposed substance of fabric itself is bred rapidly as nutriment, forms a large amount of harmful antibacterial, and they can be catalyzed metabolite and divide Solve the volatile compounds frowzy such as various lower fatty acid and amine, add that the secretions of antibacterial itself and its dead bones of the body are rotten Rotten abnormal smells from the patient, discharges nauseating bad odor.
More seriously they also can produce abnormal stimulation to human body skin, induces various dermatosis, even can Enough propagate various disease such as sexually transmitted disease (STD), dermatosis etc., unhealthful.In addition, the existence of microorganism also results in fabric fibre Macromolecules degradation, makes fabric tendering, variable color, the phenomenon such as go mouldy occur, affects clothing and the outward appearance of ornament, color and luster;For one A little militarias, such as parachute, gun cover, tent etc., then entail dangers to safety, affect fighting capacity, and consequence is hardly imaginable.
Along with industrial develops the raising with living standards of the people rapidly, the health consciousness of people improves further, people Requirement to quality of life is more and more higher.Antibacterial fabric is increasingly liked by consumer, especially with life breath manner of breathing The clothing fabric closed, the formation of the ideas such as the safest, comfortable, healthy, cleaning, make antibacterial, the mildew-resistant of clothing fabric, deodorant The attention of people it is more exposed to Deng Final finishing processing.
But, for the antibacterial finishing agent of current clothing fabric, often there is a lot of deficiencies, function is the most single, very Difficult satisfied modern Man's Demands, its concrete defect is as follows:
1) a lot of clothing fabric antibacterial finishing agents that presently, there are, mostly have toxicity in various degree, teratogenecity, mutagens The opposite sex and carcinogenecity, although antibacterial finishing agent itself also has certain antibacterial action, but after treatment easily to fabric and Health produces certain side effect.
2) existing clothing fabric antibacterial finishing agent does not the most possess anlistatig function, after being arranged by antibacterial finishing agent Its thermostability of clothing fabric and the comfort level of dress mostly can not be satisfactory.
3) anti-fold ability, the clothing fabric after utilizing existing antibacterial finishing agent to arrange is past after people's washing is dried Past phenomenon fold easily occur, affects the attractive in appearance of people's dress.
4) current, a lot of antibacterial finishing agents, its durability and reusability are poor, the antibacterial finishing agent of clothing fabric Itself can not carry out repeated finishing technique;Secondly, the antibacterial effect of the clothing fabric after every time arranging is difficult to long Kubo Hold, easily lost efficacy.
5) existing antibacterial finishing process, often arranges step comparatively laborious, operates complex, relatively costly.
Summary of the invention
For solve above-mentioned existence problem, it is an object of the invention to provide a kind of clothing fabric antibacterial finishing agent and Finishing technique, the antibacterial finishing agent safety non-toxic of described clothing fabric and possess good antibacterial effect and anti-static function, profit With described antibacterial finishing agent, clothing fabric is arranged, the anti-fold ability of fabric can be made to strengthen;Meanwhile, described antibacterial whole The finishing technique of reason agent is simple to operate, with low cost.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
The antibacterial finishing agent of a kind of clothing fabric, the antibacterial finishing agent of described clothing fabric includes that following weight proportion is former Material: MIT: 15~30 parts, N, N-second, n-butyl dithiocarbamate nickel: 5~15 parts, shell gathers Sugar: 2~10 parts, dodecyldimethylammonium hydroxide inner salt: 3~9 parts, Radix Glycyrrhizae extract: 1~3 part, dispersant: 0.1~1 part, go from Sub-water: 40~60 parts.
Preferably, the antibacterial finishing agent of described clothing fabric includes following weight proportion raw material: 2-methyl-4-isothiazole Quinoline-3-ketone: 18~28 parts, N, N-second, n-butyl dithiocarbamate nickel: 6~13 parts, chitosan: 3~9 parts, dodecyl Dimethyl betaine: 3.5~8.6 parts, Radix Glycyrrhizae extract: 1.2~2.8 parts, dispersant: 0.18~0.95 part, deionized water: 43 ~56 parts.
Preferably, the antibacterial finishing agent of described clothing fabric includes following weight proportion raw material: 2-methyl-4-isothiazole Quinoline-3-ketone: 22 parts, N, N-second, n-butyl dithiocarbamate nickel: 9 parts, chitosan: 6.2 parts, dodecyl dimethyl Radix Betae Alkali: 5.85 parts, Radix Glycyrrhizae extract: 2 parts, dispersant: 0.56 part, deionized water: 48 parts.
Separately, during described Radix Glycyrrhizae extract is glycyrrhizic acid, glycyrrhizin, liquiritin, flavonoids of Glycyrrhiza and Quercetin Plant or multiple.
Separately having, described dispersant is fatty acid dispersant
Further, the present invention also provides for the antibacterial finishing process of a kind of clothing fabric, comprises the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 45~65 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 15~35min;
(3) it is rinsed with the cooling water of 0~5 DEG C after clothing fabric being taken out, and dries.
Preferably, the antibacterial finishing process of a kind of clothing fabric, comprise the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 50~60 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 20~30min;
(3) it is rinsed with the cooling water of 1~4 DEG C after clothing fabric being taken out, and dries.
Preferably, the antibacterial finishing process of a kind of clothing fabric, comprise the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 55 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 25min;
(3) it is rinsed with the cooling water of 2 DEG C after clothing fabric being taken out, and dries.
The beneficial effects of the present invention is:
1) antibacterial finishing agent of described clothing fabric can give the anti-microbial property that clothing fabric is good, it is possible to well protects Mask material is not by the degraded of the microbial bacterials such as mycete, and prevents the propagation of microorganism, reduces the cross-infection rate of public environment; Meanwhile, moreover it is possible to effectively prevent antibacterial from breeding on clothing fabric, growing, from source, health is ensured.
2) antibacterial finishing agent of the described clothing fabric toxic gas without volatile, arranges through described antibacterial finishing agent After clothing fabric will not remain noxious substance, to human body skin and other aspects all without producing injury.
3) clothing fabric after being arranged by described antibacterial finishing agent possesses good anti-fold ability, after arranging Clothing fabric, repeatedly washing, dries the phenomenon not havinging fold afterwards, is also not easy the situation occurring fading simultaneously, wears With the most bright in colour, beautiful and comfortable.
4) antibacterial finishing agent of described clothing fabric can give clothing fabric and has certain antistatic property, is through body On do not adsorb dust, compare and bear dirty.
5) antibacterial finishing agent of described clothing fabric has good durability and reusability, whole through antibacterial finishing agent Cloth after reason can keep long-term anti-microbial effectiveness, and the use that can repeat of described antibacterial finishing agent and do not affect The effects such as it is antibacterial.
6) finishing technique of the antibacterial finishing agent of the clothing fabric that the present invention provides, simple to operate, with low cost.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection Scope.
The antibacterial finishing agent that table 1 is clothing fabric a kind of described in embodiment of the present invention materials list by weight ratio.
The raw material (unit: part) by weight ratio of the antibacterial finishing agent of a kind of clothing fabric described in table 1 embodiment
The finishing technique of the antibacterial finishing agent of a kind of clothing fabric of the present invention:
Embodiment one
(1) antibacterial finishing agent of described clothing fabric is heated to 55 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 25min;
(3) it is rinsed with the cooling water of 2 DEG C after clothing fabric being taken out, and dries.
Embodiment two
(1) antibacterial finishing agent of described clothing fabric is heated to 45 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 35min;
(3) it is rinsed with the cooling water of 0 DEG C after clothing fabric being taken out, and dries.
Embodiment three
(1) antibacterial finishing agent of described clothing fabric is heated to 50 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 20min;
(3) it is rinsed with the cooling water of 5 DEG C after clothing fabric being taken out, and dries.
Embodiment four
(1) antibacterial finishing agent of described clothing fabric is heated to 60 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 15min;
(3) it is rinsed with the cooling water of 1 DEG C after clothing fabric being taken out, and dries.
Embodiment five
(1) antibacterial finishing agent of described clothing fabric is heated to 65 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 30min;
(3) it is rinsed with the cooling water of 4 DEG C after clothing fabric being taken out, and dries.
Embodiment six
(1) antibacterial finishing agent of described clothing fabric is heated to 55 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 35min;
(3) it is rinsed with the cooling water of 2 DEG C after clothing fabric being taken out, and dries.
Antibacterial finishing agent and the finishing technique thereof of a kind of clothing fabric of present invention offer, resisting of described clothing fabric are provided Bacterium finishing agent can give the anti-microbial property that clothing fabric is good, it is possible to well protection fabric is not by microbial bacterials such as mycetes Degraded, and prevent the propagation of microorganism, reduce the cross-infection rate of public environment;Meanwhile, moreover it is possible to effectively prevent antibacterial Clothing fabric is bred, grows, from source, ensure health.And, the antibacterial finishing agent of described clothing fabric does not contains The toxic gas of volatile, the clothing fabric after described antibacterial finishing agent arranges will not remain noxious substance, to human body skin Skin and other aspects are all without producing injury.
Further, the clothing fabric after being arranged by described antibacterial finishing agent possesses good anti-fold ability, through arranging After clothing fabric, repeatedly washing, dry the phenomenon not havinging fold afterwards, be also not easy the feelings occurring fading simultaneously Condition, wears the most bright in colour, beautiful and comfortable.Further, the antibacterial finishing agent of described clothing fabric can give dress ornament face Material has certain antistatic property, wears and does not adsorbs dust, compares and bear dirty.
Additionally, the antibacterial finishing agent of described clothing fabric has good durability and reusability, through antibiotic finish Cloth after agent arranges can keep long-term anti-microbial effectiveness, and the use that can repeat of described antibacterial finishing agent and not Affect its effect such as antibacterial.Certainly, the finishing technique of the antibacterial finishing agent of the clothing fabric that the present invention provides, simple to operate, become This is cheap.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention In profit claimed range.

Claims (8)

1. the antibacterial finishing agent of a clothing fabric, it is characterised in that: described clothing fabric antibacterial finishing agent includes following weight Proportioning raw material:
MIT: 15~30 parts, N, N-second, n-butyl dithiocarbamate nickel: 5~15 parts, shell gathers Sugar: 2~10 parts, dodecyldimethylammonium hydroxide inner salt: 3~9 parts, Radix Glycyrrhizae extract: 1~3 part, dispersant: 0.1~1 part, go from Sub-water: 40~60 parts.
The antibacterial finishing agent of a kind of clothing fabric the most according to claim 1, it is characterised in that: resisting of described clothing fabric Bacterium finishing agent includes following weight proportion raw material:
MIT: 18~28 parts, N, N-second, n-butyl dithiocarbamate nickel: 6~13 parts, shell gathers Sugar: 3~9 parts, dodecyldimethylammonium hydroxide inner salt: 3.5~8.6 parts, Radix Glycyrrhizae extract: 1.2~2.8 parts, dispersant: 0.18~ 0.95 part, deionized water: 43~56 parts.
The antibacterial finishing agent of a kind of clothing fabric the most according to claim 1, it is characterised in that: resisting of described clothing fabric Bacterium finishing agent includes following weight proportion raw material:
MIT: 22 parts, N, N-second, n-butyl dithiocarbamate nickel: 9 parts, chitosan: 6.2 Part, dodecyldimethylammonium hydroxide inner salt: 5.85 parts, Radix Glycyrrhizae extract: 2 parts, dispersant: 0.56 part, deionized water: 48 parts.
4. according to the antibacterial finishing agent of a kind of clothing fabric described in claim 1 or 2 or 3, it is characterised in that: described Radix Glycyrrhizae carries Taking thing is one or more in glycyrrhizic acid, glycyrrhizin, liquiritin, flavonoids of Glycyrrhiza and Quercetin.
5. according to the antibacterial finishing agent of a kind of clothing fabric described in claim 1 or 2 or 3, it is characterised in that: described dispersant For fatty acid dispersant.
6. the antibacterial finishing process of a clothing fabric, it is characterised in that: comprise the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 45~65 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 15~35 min;
(3) it is rinsed with the cooling water of 0~5 DEG C after clothing fabric being taken out, and dries.
The antibacterial finishing process of a kind of clothing fabric the most according to claim 6, it is characterised in that: comprise the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 50~60 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 20~30 min;
(3) it is rinsed with the cooling water of 1~4 DEG C after clothing fabric being taken out, and dries.
The antibacterial finishing process of a kind of clothing fabric the most according to claim 6, it is characterised in that: comprise the steps:
(1) antibacterial finishing agent of described clothing fabric is heated to 55 DEG C;
(2) being immersed in antibacterial finishing agent by clothing fabric and arrange, finishing time is: 25 min;
(3) it is rinsed with the cooling water of 2 DEG C after clothing fabric being taken out, and dries.
CN201610369404.7A 2016-05-30 2016-05-30 Antibacterial finishing agent for apparel fabrics and finishing process thereof Pending CN106049038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN106049038A true CN106049038A (en) 2016-10-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107447501A (en) * 2017-07-26 2017-12-08 南通唐盛纺织有限公司 Antibacterial green finishing technique for fabric

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103668954A (en) * 2012-09-21 2014-03-26 上海韬鸿化工科技有限公司 Antibacterial finishing agent, antibacterial finishing method of fabrics, and antibacterial fabrics
CN104790218A (en) * 2015-05-14 2015-07-22 宣海成 Durable fabric mold-proof and antistatic finishing agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103668954A (en) * 2012-09-21 2014-03-26 上海韬鸿化工科技有限公司 Antibacterial finishing agent, antibacterial finishing method of fabrics, and antibacterial fabrics
CN104790218A (en) * 2015-05-14 2015-07-22 宣海成 Durable fabric mold-proof and antistatic finishing agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107447501A (en) * 2017-07-26 2017-12-08 南通唐盛纺织有限公司 Antibacterial green finishing technique for fabric

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