CN106048682A - Production technology of corrosion-resistant bolt for automobile transmission system - Google Patents

Production technology of corrosion-resistant bolt for automobile transmission system Download PDF

Info

Publication number
CN106048682A
CN106048682A CN201610640779.2A CN201610640779A CN106048682A CN 106048682 A CN106048682 A CN 106048682A CN 201610640779 A CN201610640779 A CN 201610640779A CN 106048682 A CN106048682 A CN 106048682A
Authority
CN
China
Prior art keywords
bolt
concentration
corrosion
production technology
electrolyzer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610640779.2A
Other languages
Chinese (zh)
Inventor
包正芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu City Constance Force Securing Member Co Ltd
Original Assignee
Changshu City Constance Force Securing Member Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu City Constance Force Securing Member Co Ltd filed Critical Changshu City Constance Force Securing Member Co Ltd
Priority to CN201610640779.2A priority Critical patent/CN106048682A/en
Publication of CN106048682A publication Critical patent/CN106048682A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/003Threaded pieces, e.g. bolts or nuts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/40Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions
    • C23C8/42Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions only one element being applied
    • C23C8/44Carburising
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys
    • C25D3/565Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention discloses a production technology of a corrosion-resistant bolt for an automobile transmission system. The production technology orderly comprises pretreatment, electroplating and carburizing treatment. The electroplating process comprises putting a bolt in a cathode in an electrolytic tank and putting a zinc-nickel alloy in an anode in the electrolytic tank. The carburizing treatment process comprises thermal insulation in a salt bath furnace at a temperature of 400-480 DEG C for 4.8-5.4h. Transfer time between the electroplating process and the carburizing treatment process is less than or equal to 30s. The technology greatly improves bolt corrosion resistance, reduces bolt heating frequency in production, improves bolt surface electroplated layer firmness and greatly improves a service life.

Description

A kind of car transmissions production technology of corrosion-resistant bolt
Technical field
The present invention relates to a kind of production technology, particularly to a kind of car transmissions production work of corrosion-resistant bolt Skill.
Background technology
Along with the development of science and technology, bolt needs as fastenings indispensable in present all trades and professions, its market The amount of asking grows with each passing day, and automobile industry is exactly that one of them typically represents, and is both needed to use substantial amounts of spiral shell in each assembly of automobile It is fixed by bolt, such as: electromotor, wheel, vehicle frame, drive system, shock mitigation system etc., and car transmissions are due to inside There is a large amount of hydraulic oil, therefore result in the bolt employed in car transmissions and be easily corroded, it is more difficult to meet the most raw Requirement needed for product.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of car transmissions production technology with corrosion-resistant bolt, The decay resistance of bolt can not only be greatly improved, but also the heating times to bolt can be reduced in process of production, The electrodeposited coating making bolt surface is more firm, and service life is greatly improved.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of car transmissions to use The production technology of corrosion-resistant bolt, specifically includes following steps:
(1), pre-treatment: bolt is put into pickling tube and removes surface oxide layer and dry;
(2), plating: the negative electrode in electrolyzer put into by the bolt after above-mentioned pickling being completed, and is put in electrolyzer by admiro Anode, be filled with electrolyte in described electrolyzer, described electrolyte by concentration be the sodium silicate of 7-9g/L, concentration be 10- The sodium hydroxide of 30g/L and the sodium tetraborate that concentration is 12-18g/L mix;
(3), Carburization Treatment: will plating after product be transferred quickly in the salt bath furnace of 400-480 DEG C insulation 4.8-5.4 hour, Transfer time is less than 30 seconds, is filled with saline solution in described salt bath furnace, and described saline solution is by the potassium chloride that concentration is 7-11g/L, dense Degree is the sodium sulfate of 17-21g/L, and concentration is 8-12g/L potassium nitrate and the sodium chloride that concentration is 15-21g/L mixes.
In a preferred embodiment of the present invention, described nickel zinc alloy is formed by metallic zinc and the fusion of metallic nickel high temperature, presses Calculating according to mass percent, the content of described metallic zinc accounts for 78-82%, and the content of described nickel accounts for 18-22%.
In a preferred embodiment of the present invention, the water quality in described electrolyte uses deionized water.
The invention has the beneficial effects as follows: the production technology of the corrosion-resistant bolt of a kind of car transmissions of the present invention can not only The decay resistance of bolt is enough greatly improved, but also the heating times to bolt can be reduced in process of production so that spiral shell The electrodeposited coating on bolt surface is more firm, and service life is greatly improved.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
A kind of car transmissions production technology of corrosion-resistant bolt, specifically includes following steps:
(1), pre-treatment: bolt is put into pickling tube and removes surface oxide layer and dry;
(2), plating: the negative electrode in electrolyzer put into by the bolt after above-mentioned pickling being completed, and is put in electrolyzer by admiro Anode, be filled with electrolyte in described electrolyzer, described electrolyte by concentration be the sodium silicate of 7g/L, concentration be 30g/L's Sodium hydroxide and the sodium tetraborate that concentration is 12g/L mix, described nickel zinc alloy is by metallic zinc and metallic nickel high-temperature molten Conjunction forms, and calculates according to mass percent, and the content of described metallic zinc accounts for 78%, and the content of described nickel accounts for 22%;
(3), Carburization Treatment: the product after plating is transferred quickly in the salt bath furnace of 400 DEG C insulation 5.4 hours, transfer time Less than 30 seconds, described salt bath furnace is filled with saline solution, described saline solution by concentration be the potassium chloride of 7g/L, concentration be 17g/L's Sodium sulfate, concentration is 12g/L potassium nitrate and the sodium chloride that concentration is 21g/L mixes.
Embodiment 2:
A kind of car transmissions production technology of corrosion-resistant bolt, specifically includes following steps:
(1), pre-treatment: bolt is put into pickling tube and removes surface oxide layer and dry;
(2), plating: the negative electrode in electrolyzer put into by the bolt after above-mentioned pickling being completed, and is put in electrolyzer by admiro Anode, be filled with electrolyte in described electrolyzer, described electrolyte by concentration be the sodium silicate of 9g/L, concentration be 10g/L's Sodium hydroxide and the sodium tetraborate that concentration is 18g/L mix, described nickel zinc alloy is by metallic zinc and metallic nickel high-temperature molten Conjunction forms, and calculates according to mass percent, and the content of described metallic zinc accounts for 82%, and the content of described nickel accounts for 18%;
(3), Carburization Treatment: the product after plating is transferred quickly in the salt bath furnace of 480 DEG C insulation 4.8 hours, transfer time Less than 30 seconds, described salt bath furnace is filled with saline solution, described saline solution by concentration be the potassium chloride of 11g/L, concentration be 21g/L's Sodium sulfate, concentration is 8g/L potassium nitrate and the sodium chloride that concentration is 15g/L mixes.
Embodiment 3:
A kind of car transmissions production technology of corrosion-resistant bolt, specifically includes following steps:
(1), pre-treatment: bolt is put into pickling tube and removes surface oxide layer and dry;
(2), plating: the negative electrode in electrolyzer put into by the bolt after above-mentioned pickling being completed, and is put in electrolyzer by admiro Anode, be filled with electrolyte in described electrolyzer, described electrolyte by concentration be the sodium silicate of 8g/L, concentration be 20g/L's Sodium hydroxide and the sodium tetraborate that concentration is 15g/L mix, described nickel zinc alloy is by metallic zinc and metallic nickel high-temperature molten Conjunction forms, and calculates according to mass percent, and the content of described metallic zinc accounts for 80%, and the content of described nickel accounts for 20%;
(3), Carburization Treatment: the product after plating is transferred quickly in the salt bath furnace of 450 DEG C insulation 5.1 hours, transfer time Less than 30 seconds, described salt bath furnace is filled with saline solution, described saline solution by concentration be the potassium chloride of 9g/L, concentration be 19g/L's Sodium sulfate, concentration is 12g/L potassium nitrate and the sodium chloride that concentration is 21g/L mixes.
Being different from prior art, a kind of car transmissions of present invention production technology of corrosion-resistant bolt is passed through at bolt One layer of nickel zinc alloy of electroplating surface, carries out Carburization Treatment in being transferred quickly to salt bath furnace subsequently, bolt can not only be greatly improved Decay resistance, but also the heating times to bolt can be reduced in process of production so that the electrodeposited coating on bolt surface More firm, service life is greatly improved.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (3)

1. the car transmissions production technology of corrosion-resistant bolt, it is characterised in that specifically include following steps:
(1), pre-treatment: bolt is put into pickling tube and removes surface oxide layer and dry;
(2), plating: the negative electrode in electrolyzer put into by the bolt after above-mentioned pickling being completed, and is put in electrolyzer by admiro Anode, be filled with electrolyte in described electrolyzer, described electrolyte by concentration be the sodium silicate of 7-9g/L, concentration be 10- The sodium hydroxide of 30g/L and the sodium tetraborate that concentration is 12-18g/L mix;
(3), Carburization Treatment: will plating after product be transferred quickly in the salt bath furnace of 400-480 DEG C insulation 4.8-5.4 hour, Transfer time is less than 30 seconds, is filled with saline solution in described salt bath furnace, and described saline solution is by the potassium chloride that concentration is 7-11g/L, dense Degree is the sodium sulfate of 17-21g/L, and concentration is 8-12g/L potassium nitrate and the sodium chloride that concentration is 15-21g/L mixes.
The car transmissions the most according to claim 1 production technology of corrosion-resistant bolt, it is characterised in that described nickel Kirsite is formed by metallic zinc and the fusion of metallic nickel high temperature, calculates according to mass percent, and the content of described metallic zinc accounts for 78- 82%, the content of described nickel accounts for 18-22%.
The car transmissions the most according to claim 1 production technology of corrosion-resistant bolt, it is characterised in that described electricity Solve the water quality in liquid and use deionized water.
CN201610640779.2A 2016-08-08 2016-08-08 Production technology of corrosion-resistant bolt for automobile transmission system Pending CN106048682A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610640779.2A CN106048682A (en) 2016-08-08 2016-08-08 Production technology of corrosion-resistant bolt for automobile transmission system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610640779.2A CN106048682A (en) 2016-08-08 2016-08-08 Production technology of corrosion-resistant bolt for automobile transmission system

Publications (1)

Publication Number Publication Date
CN106048682A true CN106048682A (en) 2016-10-26

Family

ID=57480132

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610640779.2A Pending CN106048682A (en) 2016-08-08 2016-08-08 Production technology of corrosion-resistant bolt for automobile transmission system

Country Status (1)

Country Link
CN (1) CN106048682A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107604406A (en) * 2017-10-25 2018-01-19 苏州华丰不锈钢紧固件有限公司 A kind of electroplating technology of high rigidity bolt
CN107955957A (en) * 2017-11-29 2018-04-24 芜湖强振汽车紧固件有限公司 Fastening bolt surface smooth treatment technique
CN111749376A (en) * 2020-03-31 2020-10-09 江苏长达特钢制品有限公司 Production process capable of avoiding falling off connecting claw

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388160A (en) * 1980-02-20 1983-06-14 Rynne George B Zinc-nickel alloy electroplating process
CN103398067A (en) * 2013-07-17 2013-11-20 春雨(东莞)五金制品有限公司 Bolt manufacturing process
CN103643018A (en) * 2013-11-26 2014-03-19 常熟市福熙机械零部件制造有限公司 Thermal processing technology for bolts
CN103757181A (en) * 2013-11-26 2014-04-30 常熟市福熙机械零部件制造有限公司 High-strength nut heat treatment technology
CN104480477A (en) * 2014-11-20 2015-04-01 海盐汇联通用配件有限公司 Production process of corrosion-resistant high-strength hexagon bolts
CN104625617A (en) * 2014-12-13 2015-05-20 海盐双赢管件制造有限公司 High-strength bolt production process
CN105063530A (en) * 2015-08-07 2015-11-18 昆山—邦泰汽车零部件制造有限公司 Method for manufacturing high-hardness automobile hardware
CN105779738A (en) * 2014-12-13 2016-07-20 青岛勤德索具有限公司 Heat treatment technology of bolt

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388160A (en) * 1980-02-20 1983-06-14 Rynne George B Zinc-nickel alloy electroplating process
CN103398067A (en) * 2013-07-17 2013-11-20 春雨(东莞)五金制品有限公司 Bolt manufacturing process
CN103643018A (en) * 2013-11-26 2014-03-19 常熟市福熙机械零部件制造有限公司 Thermal processing technology for bolts
CN103757181A (en) * 2013-11-26 2014-04-30 常熟市福熙机械零部件制造有限公司 High-strength nut heat treatment technology
CN104480477A (en) * 2014-11-20 2015-04-01 海盐汇联通用配件有限公司 Production process of corrosion-resistant high-strength hexagon bolts
CN104625617A (en) * 2014-12-13 2015-05-20 海盐双赢管件制造有限公司 High-strength bolt production process
CN105779738A (en) * 2014-12-13 2016-07-20 青岛勤德索具有限公司 Heat treatment technology of bolt
CN105063530A (en) * 2015-08-07 2015-11-18 昆山—邦泰汽车零部件制造有限公司 Method for manufacturing high-hardness automobile hardware

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107604406A (en) * 2017-10-25 2018-01-19 苏州华丰不锈钢紧固件有限公司 A kind of electroplating technology of high rigidity bolt
CN107955957A (en) * 2017-11-29 2018-04-24 芜湖强振汽车紧固件有限公司 Fastening bolt surface smooth treatment technique
CN111749376A (en) * 2020-03-31 2020-10-09 江苏长达特钢制品有限公司 Production process capable of avoiding falling off connecting claw

Similar Documents

Publication Publication Date Title
US9416460B2 (en) Steel sheet for containers
US20130216714A1 (en) Manufacturing method for steel sheets for containers
CN103014787B (en) A kind of copper electroplating liquid and electroplating technology thereof
CN106048682A (en) Production technology of corrosion-resistant bolt for automobile transmission system
CN109208049A (en) A kind of uniform stainless steel continuous plating process of tint
BR112016018584A2 (en) trivalent chrome continuous bath process
CN104532316B (en) Anti-nitridation process for copper-tin composite plating
CN104120462B (en) Steel cord is without the cuprous brass plating of cyanogen and the passivating method of brass coating
CN107805830A (en) Flash iron plating solution and flash method
CN101255581B (en) Alkaline chloride galvanizing agent and preparation method thereof
JP6098763B2 (en) Sn-plated steel sheet, chemical conversion-treated steel sheet, and production methods thereof
CN103774126A (en) Method for increasing thickness of chemical nickel-phosphorus plating alloy layer through electrical pulse
CN106567113A (en) Nickel pre-plating process suitable for battery shell steel
CN102206840B (en) Alkaline chloride copper-plating treatment agent and preparation method thereof
KR101318588B1 (en) Process for producing tin-plated steel plate, and tin-plated steel plate
JP5994960B1 (en) Steel plate for container and method for producing steel plate for container
CN104419954A (en) Method for electroplating zinc-nickel alloy by use of acidic plating solution
CN102560495A (en) Coating stripping technology method for tin-nickel alloy coating
CN104419953A (en) Process for electroplating zinc-nickel alloy to surface of iron matrix
US20190169762A1 (en) Method for producing electrode
US3039943A (en) Methods for the electrodeposition of metals
JP6897875B2 (en) Manufacturing method of surface-treated steel sheet and surface-treated steel sheet
CN101914791B (en) Method for electroplating corrosion resistant aluminum-manganese alloy layer
CN108130572A (en) A kind of aluminium alloy pre-nickel plating solution
CN107460506A (en) A kind of electroplate liquid of nickel

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20161026

WD01 Invention patent application deemed withdrawn after publication