CN106046694A - Basalt fiber composite-material photovoltaic support profile and photovoltaic panel support manufactured by use of profile - Google Patents

Basalt fiber composite-material photovoltaic support profile and photovoltaic panel support manufactured by use of profile Download PDF

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Publication number
CN106046694A
CN106046694A CN201610643571.6A CN201610643571A CN106046694A CN 106046694 A CN106046694 A CN 106046694A CN 201610643571 A CN201610643571 A CN 201610643571A CN 106046694 A CN106046694 A CN 106046694A
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CN
China
Prior art keywords
column
girder
basalt fiber
hound
fiber composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610643571.6A
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Chinese (zh)
Inventor
姜厚文
杨树平
张伟
潘丽春
戴存武
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanxi Jin Jin Basalt Development Co Ltd
Original Assignee
Shanxi Jin Jin Basalt Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanxi Jin Jin Basalt Development Co Ltd filed Critical Shanxi Jin Jin Basalt Development Co Ltd
Priority to CN201610643571.6A priority Critical patent/CN106046694A/en
Publication of CN106046694A publication Critical patent/CN106046694A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10Epoxy resins modified by unsaturated compounds
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to the field of composite materials, especially to a basalt fiber composite-material photovoltaic support profile. The basalt fiber composite-material photovoltaic support profile is a fiber material which is prepared by the following steps: processing basalt fiber roving with a surface treating agent, impregnating with matrix resin and solidifying. The basalt fiber roving is prepared by steps of drawing by a drawing machine and impregnating. Materials for preparing the basalt fiber roving contain the following ingredients (by weight): 51-54% of SO2, 15-17% of Al2O3, 8-9% of CaO, 9-11% of Fe2O3.FeO, 6-7% of MgO, 3-4% of Na2O and 1-2.5% of other alkali metal. According to the invention, service life of the support can be effectively prolonged, and the support is easy for batch production and has a simple structure.

Description

A kind of basalt fiber composite material photovoltaic bracket section bar and the photovoltaic panel made of it Support
Technical field
The present invention relates to field of compound material, particularly relate to a kind of basalt fiber composite material photovoltaic bracket section bar and use Its photovoltaic panel support made.
Background technology
The research and development of basalt continuous fiber material and production, not only make basaltic value sharp increase, economic and social benefits show Write and because of performance characteristics such as the heatproof of its excellence, wear-resisting, acid and alkali-resistance, enhancing are good with adsorption filtration.Multiple industry neck can be met Many application demands in territory.The market demand potential is huge, and development prospect is good, and industry eruptive growth is coming.Can Having a bright future infinitely to say, road bumpiness is bumpy.
Basalt ore is the lustration raw material of a kind of natural environment-friendly type, produces and discharges without " three wastes ".By basalt fibre The composite manufactured has natural high intensity and to the stability of Korrosionsmedium effect, ruggedness, electrical insulating property.Along with Continuous research and development to basalt fiber composite material, it will reduce cost, improve and stabilised quality, expand rapidly yield, expand Application, it will with bigger breadth and depth, is increasingly applied to all trades and professions.Owing to Basalt fiber products has There are high specific strength, high ratio modulus, high temperature resistant, low temperature resistant, corrosion-resistant, endurance, creep resistant, heat transfer non-conductive, non-and thermal expansion Coefficient little with adsorption filtration a series of excellent properties such as good, also there is some glass fibre, aramid fiber and carbon fiber and do not have Standby characteristic, he can not only be used for structural material bearing load, can play a role as functional material again, determines it as function Property material has the irreplaceable market demand in special industry field.
In state-owned wide market, have a demand widely, development basalt fiber material industry has broad prospects.With The development of other tec fibers is compared, and the development of China's basalt continuous fiber is hopeful most " the latecomers surpass the old-timers " eventually Become the maximum production in the whole world and application big country.
At present, photovoltaic bracket product strength is low, heatproof weak effect, is unsatisfactory for the demand of modern client.
Summary of the invention
It is an object of the invention to provide a kind of basalt fiber composite material photovoltaic bracket section bar and the light made of it Volt board mount, after selecting basalt fibre surface treated successively and the infusing matrix resin of specific component content, can not only obtain Obtain the fibrous material that decay resistance is more excellent compared with prior art, moreover it is possible to the cost performance that raising fibrous material makes, meanwhile, can To be effectively improved the service life of support, easily produce in batches, simple in construction.
For solving above-mentioned technical problem, the technical scheme is that
Described basalt fiber composite material photovoltaic bracket section bar is by basalt fibre roving surface treated agent After reason, then the fibrous material being impregnated by matrix resin and solidifying, described basalt fibre roving is by wire drawing machine Drawing, process through infiltration and form, count by weight ratio, the material making described basalt fibre roving includes following one-tenth Point:
SO2: 51~54%;
Al2O3: 15~17%;
CaO:8~9%;
Fe2O3FeO:9~11%;
MgO:6~7%;
Na2O:3~4%;
Otheralkali metal: 1~2.5%;
Described ultraviolet screening agent is the one in zinc oxide, benzophenone;
Described surface conditioning agent is made up of according to weight part ratio 1:3:2:3 coupling agent, film former, lubricant, ultraviolet screening agent.
Preferably, described coupling agent is KH550 or KH560.
Preferably, described film former is the one in epoxy polyurethane, polyester-polyurethane.
Preferably, the one during described lubricant is cetyl trimethyl quaternary ammonium bromides, polyacrylamide.
Preferably, described matrix resin is vinyl ester resins.
Preferably, described otheralkali metal includes K2O、TiO2In at least one.
A kind of basalt fiber composite material photovoltaic bracket section bar make photovoltaic panel support, including purlin, girder, first Column, the second column, the first hound and the second hound, at least two purlins be arranged in parallel, and on purlin, interval is fixed with many Root girder, described many girders are all vertically arranged with purlin, and each girder all strides across all purlins, under every described girder Side by the first column, the second upright supports, described first column and the second column the most vertically stand on ground, the first column and The top of the second column is all fixing with corresponding girder to be connected, and the length of described first column is more than the length of the second column, The rectangular frame that all purlins and girder are constituted is inclined;
Being respectively and fixedly provided with the first hound between described each first column and corresponding girder, one end of the first hound is fixed On girder, the other end is fixed on the first column, is provided with between described each second column and corresponding girder Two hounds, one end of the second hound is fixed on girder, and the other end is fixed on the second column.
Between described girder and the first column, the second column, the first hound, the second hound, the first column and first Between hound, it is between the second column and the second hound and is welded and fixed, or be to connect by backplate and bolt are fixing.
The present invention compared with the existing technology has the beneficial effect that
(1) the basalt fiber composite material photovoltaic bracket section bar that the present invention relates to is by the basalt fibre of specific component content Prepare after surface treated and infusing matrix resin successively, the good chemical stability that has based on basalt fibre, heat Stability, corrosion resistance and mechanical strength, can be widely applied to industry industrial, peculiar to vessel, petroleum industry and aircraft industry etc. Field.
(2) present invention is reasonable in design, in actual mechanical process, silane coupler inorganic agent can be used to process as surface Agent, processes for the surface of basalt fibre, thus reaches the purpose improving matrix resin with basalt fibre composite performance, makes With respond well.
(3) matrix resin that the present invention relates to is vinyl ester resins, such as: urethane-modified alicyclic vinyl tree Fat, bisphenol-A modified epoxy vinyl fat resin etc., tests prove that, at the basalt fibre using vinyl ester resins dipping When material carries out density measurement, test result surface, its anti-flammability, degree of drawing and bending property test are better.
(4) utilizing the photovoltaic bracket product that the present invention makes, can be effectively improved the service life of support, easily batch is raw Produce, simple in construction.
Accompanying drawing explanation
For the technical scheme being illustrated more clearly that in the embodiment of the present invention, below by use required in embodiment Accompanying drawing is briefly described, it should be apparent that, the accompanying drawing in describing below is only some embodiments of the present invention, for ability From the point of view of the those of ordinary skill of territory, on the premise of not paying creative work, it is also possible to obtain the attached of other according to these accompanying drawings Figure.
Fig. 1 is the structural representation of basalt fiber composite material photovoltaic bracket product forms.
Fig. 2 is the partial enlarged drawing of A.
Fig. 3 is the side view of basalt fiber composite material photovoltaic bracket product forms.
In figure: 1 is girder, 2 is purlin, and 3 is the first hound, and 4 is the first hound, and 5 is the first column, and 6 is second Column, 7 is backplate, and 8 is bolt.
Detailed description of the invention
The invention discloses a kind of basalt fiber composite material photovoltaic bracket section bar and the photovoltaic panel support made of it, Those skilled in the art can use for reference present disclosure, is suitably modified technological parameter and realizes.Special needs to be pointed out is, all similar Replacement and change apparent to those skilled in the art, they are considered as being included in the present invention.The present invention Described product is described by preferred embodiment, related personnel substantially can without departing from present invention, spirit and In the range of compositions as herein described and application be modified or suitably change and combine, realize and apply skill of the present invention Art.
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
The present invention proposes a kind of basalt fiber composite material photovoltaic bracket section bar and the photovoltaic panel support made of it, and this is profound Military rock fibrous composite be processed by basalt fibre roving surface treated agent after, then impregnated by matrix resin and consolidate The fibrous material changed.
The following is and technical solution of the present invention is further described:
In the present invention, described basalt fibre roving is to be drawn by wire drawing machine, processes through infiltration and forms, joins by weight Than meter, described basalt fibre roving includes following component:
SO2: 51%;
Al2O3: 17%;
CaO:9%;
Fe2O3FeO:10%;
MgO: 67%;
Na2O:4%;
Otheralkali metal: 2%.
Surface conditioning agent of the present invention is coupling agent, film former, lubricant, ultraviolet screening agent, described coupling agent For KH550, process for the surface of basalt fibre, thus reach the mesh improving matrix resin with basalt fibre composite performance , using effect is good;Described film former is epoxy polyurethane;Described lubricant is cetyl trimethyl quaternary ammonium bromination Thing;Described ultraviolet screening agent is zinc oxide, can be effectively improved the ultraviolet resistance of product;Described matrix resin is second Thiazolinyl fat resin;As: urethane-modified vinyl ester resins, tests prove that, using vinyl ester resins dipping Basalt fiber material carries out density measurement, test result surface, and its anti-flammability, degree of drawing and bending property test effect are more Good.
Embodiment 2
In the present invention, described basalt fibre roving is to be drawn by wire drawing machine, processes through infiltration and forms, by weight Proportioning meter, described basalt fibre roving includes following component:
SO2: 54%;
Al2O3: 15%;
CaO:9%;
Fe2O3FeO:11%;
MgO:7%;
Na2O:3%;
Otheralkali metal: 1%.
This experiment silane coupler used is KH560, and film former is polyester-polyurethane;Lubricant is polyacrylamide, anti- Ultraviolet agent is benzophenone, and matrix resin is bisphenol-A modified epoxy vinyl fat resin.
Embodiment 1 obtains mechanical property and the uvioresistant performance of photovoltaic bracket section bar, such as following table.
Table 1 mechanical property
Table 2 uvioresistant performance
Embodiment 3
Photovoltaic bracket embodiment 1 made, makes the product shown in Fig. 1.
The photovoltaic panel support that a kind of basalt fiber composite material photovoltaic bracket section bar makes, including purlin 2, girder 1, the One column the 5, second column the 6, first hound 3 and the second hound 4, at least two purlins 2 be arranged in parallel, and purlin 2 is spaced Being fixed with many girders 1, described many girders 1 are all vertically arranged with purlin 2, and each girder 1 all strides across all purlins 2, Being supported by first column the 5, second column 6 below every described girder 1, described first column 5 and the second column 6 the most vertically stand On ground, the top of the first column 5 and the second column 6 is all fixed with corresponding girder 1 and is connected, described first column 5 Length is more than the length of the second column 6 so that the rectangular frame that all purlins 2 and girder 1 are constituted is inclined;
The first hound 3, one end of the first hound 3 it is respectively and fixedly provided with between described each first column 5 and corresponding girder 1 Being fixed on girder 1, the other end is fixed on the first column 5, between described each second column 6 and corresponding girder 1 all Being provided with the second hound 4, one end of the second hound 4 is fixed on girder 1, and the other end is fixed on the second column 6;Described Between girder 1 and first column the 5, second column the 6, first hound the 3, second hound 4, the first column 5 and the first hound 3 Between, it is between the second column 6 and the second hound 4 and is welded and fixed, or be by backplate 7 and the fixing connection of bolt 8.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (8)

1. a basalt fiber composite material photovoltaic bracket section bar, it is characterised in that described basalt fiber composite material Photovoltaic bracket section bar be by basalt fibre roving surface treated agent process after, then impregnated by matrix resin and solidify and The fibrous material become, described basalt fibre roving is to be drawn by wire drawing machine, processes through infiltration and forms, joins by weight Than meter, make the material of described basalt fibre roving and include following component:
SO2: 51~54%;
Al2O3: 15~17%;
CaO:8~9%;
Fe2O3FeO:9~11%;
MgO:6~7%;
Na2O:3~4%;
Otheralkali metal: 1~2.5%;
Described ultraviolet screening agent is the one in zinc oxide, benzophenone;
Described surface conditioning agent is made up of according to weight part ratio 1:3:2:3 coupling agent, film former, lubricant, ultraviolet screening agent.
A kind of basalt fiber composite material photovoltaic bracket section bar the most according to claim 1, it is characterised in that described idol Connection agent is KH550 or KH560.
A kind of basalt fiber composite material photovoltaic bracket section bar the most according to claim 1, it is characterised in that described one-tenth Membrane is the one in epoxy polyurethane, polyester-polyurethane.
A kind of basalt fiber composite material photovoltaic bracket section bar the most according to claim 1, it is characterised in that described profit Lubrication prescription is the one in cetyl trimethyl quaternary ammonium bromides, polyacrylamide.
5. according to a kind of basalt fiber composite material photovoltaic bracket section bar described in claim 1, it is characterised in that: described Matrix resin is vinyl ester resins.
6. according to a kind of basalt fiber composite material photovoltaic bracket section bar described in claim 1, it is characterised in that: described Otheralkali metal includes K2O、TiO2In at least one.
7. the photovoltaic panel support made of a kind of basalt fiber composite material photovoltaic bracket section bar as claimed in claim 1, It is characterized in that: include that purlin (2), girder (1), the first column (5), the second column (6), the first hound (3) and second are oblique Strut (4), at least two purlins (2) be arranged in parallel, and the upper interval of purlin (2) is fixed with many girders (1), described many girders (1) being all vertically arranged with purlin (2), and each girder (1) all strides across all purlins (2), every described girder (1) lower section is all Being supported by the first column (5), the second column (6), described first column (5) and the second column (6) the most vertically stand on ground, the The top of one column (5) and the second column (6) is all fixing with corresponding girder (1) to be connected, the length of described first column (5) Length more than the second column (6) so that the rectangular frame that all purlins (2) and girder (1) are constituted is inclined;
It is respectively and fixedly provided with the first hound (3), the first hound between described each first column (5) and corresponding girder (1) (3) one end is fixed on girder (1), and the other end is fixed on the first column (5), and described each second column (6) is with relative Being provided with the second hound (4) between the girder (1) answered, one end of the second hound (4) is fixed on girder (1), another End is fixed on the second column (6).
Photovoltaic panel support the most according to claim 7, it is characterised in that: described girder (1) and the first column (5), second Between column (6), the first hound (3), the second hound (4), between the first column (5) and the first hound (3), second stands It is between post (6) and the second hound (4) and is welded and fixed, or be to connect by backplate (7) and bolt (8) are fixing.
CN201610643571.6A 2016-08-08 2016-08-08 Basalt fiber composite-material photovoltaic support profile and photovoltaic panel support manufactured by use of profile Pending CN106046694A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107640913A (en) * 2017-08-22 2018-01-30 江苏大学 A kind of preparation method and applications of Basalt fiber surface modification coating
WO2018214680A1 (en) * 2017-05-24 2018-11-29 洛阳尖端技术研究院 Basalt fiber composite material and preparation method therefor
RU2685646C1 (en) * 2018-02-19 2019-04-22 Общество с ограниченной ответственностью Научно - производственная фирма "АДЕС" Composite material and method for production thereof
CN109824273A (en) * 2019-01-25 2019-05-31 湖北汇尔杰玄武岩纤维有限公司 Basalt rope and its production method
CN115913079A (en) * 2023-01-10 2023-04-04 北京连续玄武岩纤维科技有限公司 Photovoltaic panel support

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018214680A1 (en) * 2017-05-24 2018-11-29 洛阳尖端技术研究院 Basalt fiber composite material and preparation method therefor
CN108929519A (en) * 2017-05-24 2018-12-04 洛阳尖端技术研究院 A kind of basalt fiber composite material and preparation method thereof
CN107640913A (en) * 2017-08-22 2018-01-30 江苏大学 A kind of preparation method and applications of Basalt fiber surface modification coating
CN107640913B (en) * 2017-08-22 2019-10-01 江苏大学 A kind of preparation method and applications of Basalt fiber surface modification coating
RU2685646C1 (en) * 2018-02-19 2019-04-22 Общество с ограниченной ответственностью Научно - производственная фирма "АДЕС" Composite material and method for production thereof
CN109824273A (en) * 2019-01-25 2019-05-31 湖北汇尔杰玄武岩纤维有限公司 Basalt rope and its production method
CN115913079A (en) * 2023-01-10 2023-04-04 北京连续玄武岩纤维科技有限公司 Photovoltaic panel support
CN115913079B (en) * 2023-01-10 2023-09-26 北京连续玄武岩纤维科技有限公司 Photovoltaic panel support

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