CN106046669A - Red mud phenolic foam thermal-insulation material and preparation method thereof - Google Patents
Red mud phenolic foam thermal-insulation material and preparation method thereof Download PDFInfo
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- CN106046669A CN106046669A CN201610624886.6A CN201610624886A CN106046669A CN 106046669 A CN106046669 A CN 106046669A CN 201610624886 A CN201610624886 A CN 201610624886A CN 106046669 A CN106046669 A CN 106046669A
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- red mud
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
Abstract
The invention provides a red mud phenolic foam thermal-insulation material and a preparation method thereof. The red mud phenolic foam thermal-insulation material is prepared from the following raw materials in parts by weight: 50-60 parts of phenolic resin, 10-15 parts of polyurethane, 15-22 parts of red mud, 2-4 parts of coupling agent, 3-6 parts of surface activating agent, 5-10 parts of foaming agent, 10-15 parts of curing agent, and 3-6 parts of toughening agent, wherein the toughening agent is a mixture prepared from nano silicon dioxide and graphite oxide in an alcohol acid salt solution. The preparation method comprises the following steps: (1), uniformly mixing the phenolic resin, the polyurethane, the curing agent, and the toughening agent at 40-60 DEG C, thereby obtaining a mixture A; and (2), uniformly mixing and stirring the mixture A, the red mud, the coupling agent, the surface activating agent and the foaming agent, quickly pouring the mixture into a pre-heated mold to foam, and curing, thereby obtaining the red mud phenolic foam thermal-insulation material. The red mud phenolic foam thermal-insulation material not only has high strength, but also has low heat conduction coefficient.
Description
Technical field
The invention belongs to building exterior wall material technical field, be specifically related to a kind of red mud phenolic aldehyde foam thermal insulation material and system thereof
Preparation Method.
Background technology
Phenolic-aldehyde heat-insulation board and hard polyurethane foam belong to organic thermosetting thermal insulation material, building energy saving rate the most in recent years together
Gradually step up, application insulation material technical performance more and more higher, market demand is increasing.At Application in Building insulation material
In application, not only require that physical technique performance is high and it is necessary to reach fire protecting performance.The foam of phenolic resin production and polyurethane
Relatively good insulation material is belonged to though hard bubbling, but excellent, shortcoming that two class insulation materials are had nothing in common with each other, not there is fine complex art
Performance.The hard polyurethane foam of polyurethane resin synthesis, has the spy such as lightweight, high-strength, heat conductivity is low, good toughness and easy construction
Point, but fire protecting performance only up to reach B1 level fire protecting performance, oxygen index (OI) only up to reach 30%.
The phenolic-aldehyde heat-insulation board that phenolic resin produces, possesses the main principal advantages of Polyurethane Thermal Insulation Building Materials, but fire line
Can highlight than hard polyurethane foam, fire-resistant combustion penetrates, cigarette high temperature resistant, low, and oxygen index (OI) is up to 50%, but phenolic-aldehyde heat-insulation board and polyurethane
Hard bubbling and compare, the shortcoming of phenolic-aldehyde heat-insulation board maximum is that fragility is big, acid big.Owing to the fragility of phenolic-aldehyde heat-insulation board is big, phenolic aldehyde heat preserving
There is the problems such as dry linting, elasticity is low, compressive strength is low, and heat conductivity is the most up to standard in plate, intrinsic excellent fire protecting performance does not has in use
Can be utilized very well, therefore, affect the extension of this products application technology, bring a lot of inconvenience to transport, construction simultaneously.Especially
Pull strength is low, is difficult to meet relevant criterion requirement.Owing to acidity is big so that phenolic-aldehyde heat-insulation board connects with metal, cement-based material
Touch and have certain corrosivity.
Summary of the invention
In order to solve the problem that the heat conductivity of above phenolic foam board is higher, toughness is bad, the present invention proposes a kind of red
Mud phenolic aldehyde foam thermal insulation material, this insulation material not only intensity is high, and heat conductivity is low.
The technical scheme is that and be achieved in that:
A kind of red mud phenolic aldehyde foam thermal insulation material, calculates, by weight including following raw material:
Phenolic resin 50~60 parts, polyurethane 10~15 parts, red mud 15~22 parts, coupling agent 2~4 parts, surfactant 3
~6 parts, foaming agent 5~10 parts, firming agent 10~15 parts and toughener 3~6 parts, described toughener is nano silicon and oxygen
The mixture that graphite is formed in alcohol acid salt solution.
Further, described alcohol hydrochlorate is lactate, malate, tartrate or citrate;Be preferably sodium lactate,
Natrium malicum, sodium tartrate or sodium citrate.
Further, the concentration of described alcohol acid salt solution is 2~6wt%.
Further, described surfactant is Tween 80.
Further, described foaming agent is Pentamethylene. or pentane.
Further, described firming agent is phosphoric acid and the mixed acid of p-methyl benzenesulfonic acid or hydrochloric acid.
Further, described coupling agent is Silane coupling agent KH550 or silane coupler KH560.
It is a further object to provide the preparation method of a kind of red mud phenolic aldehyde foam thermal insulation material, including following step
Rapid:
1) phenolic resin, polyurethane, firming agent and toughener are carried out under the conditions of 40~60 DEG C mix homogeneously, obtain
Mixture A;
2) by mixture A, red mud, coupling agent, surfactant and foaming agent mixing and stirring, it is quickly poured into preheating
Mould in foam, solidify.
Further, described step 2) the preheating temperature of preheated mold is 30~50 DEG C.
The method have the benefit that
1, its toughener of red mud phenolic aldehyde foam thermal insulation material of the present invention is nano silicon with graphite oxide at alkyd
The mixture formed in saline solution, toughening effect is notable, and has the most fire-retardant and heat resistance.40~60 DEG C of conditions
Under, phenolic resin, firming agent and toughener mix, beneficially the toughening modifying of phenolic resin.Owing to polyurethane is tough and tensile,
Soft and adhesion epistasis energy, participates in phenolic foam board Aided Modification so that phenolic foam board toughness improves, and is difficult to dry linting,
Elastic enhancing.Add red mud and can improve the performance of insulation material acid rain resistant.In red mud, existing silicate has again ferrum oxide, oxidation
The metal-oxides such as calcium, make the thermostability of phenolic foam, anti-flame performance improve.By the effect of coupling agent, red mud without
Machine filler is uniformly dispersed in phenolic resin, and hole is fine and smooth, dimensionally stable, and its resistance to compression, tension combination property improve, and save into
This.
2, the heat conductivity of the red mud phenolic aldehyde foam thermal insulation material of the present invention is 0.016~0.022W/m K, compressive strength
Being 0.184~0.191MPa, being perpendicular to plate face intensity is 0.123~0.126MPa.
Detailed description of the invention
Embodiment 1
A kind of red mud phenolic aldehyde foam thermal insulation material, calculates, by weight including following raw material:
55 parts of phenolic resin, polyurethane 12 parts, 5 parts, 3 parts Silane coupling agent KH550s of red mud, 4 parts of Tween 80s, Pentamethylene. 7
12 parts of the mixed acid of part, phosphoric acid and p-methyl benzenesulfonic acid and toughener 4 parts, toughener is that nano silicon exists with graphite oxide
The mixture formed in 4wt% sodium citrate solution.
Preparation method, comprises the following steps:
1) mixed acid and the toughener of phenolic resin, polyurethane, phosphoric acid and p-methyl benzenesulfonic acid are entered under the conditions of 50 DEG C
Row mix homogeneously, obtains mixture A;
2) by mixture A, Tween 80, red mud, Silane coupling agent KH550 and Pentamethylene. mixing and stirring, quickly fall
Enter in the mould of 40 DEG C of preheatings and foam, solidify.
Embodiment 2
A kind of red mud phenolic aldehyde foam thermal insulation material, calculates, by weight including following raw material:
50 parts of phenolic resin, polyurethane 10 parts, 4 parts, 2 parts silane coupler KH560 of red mud, 3 parts of Tween 80s, pentanes 5
Part, hydrochloric acid 11 parts and toughener 3 parts, toughener is nano silicon and graphite oxide shape in 2wt% sodium tartrate solution
The mixture become.
Preparation method, comprises the following steps:
1) phenolic resin, hydrochloric acid, polyurethane and toughener are carried out under the conditions of 40 DEG C mix homogeneously, obtain mixture
A;
2) by mixture A, Tween 80, red mud, silane coupler KH560 and pentane mixing and stirring, quickly fall
Enter in the mould of 30 DEG C of preheatings and foam, solidify.
Embodiment 3
A kind of red mud phenolic aldehyde foam thermal insulation material, calculates, by weight including following raw material:
58 parts of phenolic resin, polyurethane 13 parts, 6 parts, 4 parts silane coupler KH560 of red mud, 5 parts of Tween 80s, pentanes 8
10 parts of mixed acid (phosphoric acid is 3:1 with the mass ratio of P-TOLUENE SULFO ACID 99) and the toughener 5 parts of part, phosphoric acid and p-methyl benzenesulfonic acid, toughness reinforcing
Agent is the mixture that nano silicon is formed in 5wt% sodium lactate solution with graphite oxide.
Preparation method, comprises the following steps:
1) mixed acid and the toughener of phenolic resin, polyurethane, phosphoric acid and p-methyl benzenesulfonic acid are entered under the conditions of 55 DEG C
Row mix homogeneously, obtains mixture A;
2) by mixture A, Tween 80, red mud, silane coupler KH560 and pentane mixing and stirring, quickly fall
Enter in the mould of 45 DEG C of preheatings and foam, solidify.
Embodiment 4
A kind of red mud phenolic aldehyde foam thermal insulation material, calculates, by weight including following raw material:
60 parts of phenolic resin, polyurethane 15 parts, 4 parts, 4 parts Silane coupling agent KH550s of red mud, 6 parts of Tween 80s, Pentamethylene. 10
Part, hydrochloric acid 15 parts and toughener 6 parts, toughener is nano silicon and graphite oxide shape in 6wt% natrium malicum solution
The mixture become.
Preparation method, comprises the following steps:
1) phenolic resin, polyurethane, hydrochloric acid and toughener are carried out under the conditions of 60 DEG C mix homogeneously, obtain mixture
A;
2) by mixture A, Tween 80, red mud, Silane coupling agent KH550 and Pentamethylene. mixing and stirring, quickly fall
Enter in the mould of 50 DEG C of preheatings and foam, solidify.
Embodiment 5
Warming plate embodiment 1-4 prepared carries out performance detection, the results are shown in Table 1.
Table 1 embodiment 1-4 warming plate performance test results
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (9)
1. a red mud phenolic aldehyde foam thermal insulation material, it is characterised in that calculate by weight, including following raw material:
Phenolic resin 50~60 parts, polyurethane 10~15 parts, red mud 15~22 parts, coupling agent 2~4 parts, surfactant 3~6
Part, foaming agent 5~10 parts, firming agent 10~15 parts and toughener 3~6 parts, described toughener is nano silicon and oxidation
The mixture that graphite is formed in alcohol acid salt solution.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1, it is characterised in that described alcohol hydrochlorate be lactate,
Malate, tartrate or citrate.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1 and 2, it is characterised in that described alcohol acid salt solution
Concentration is 2~6wt%.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1 and 2, it is characterised in that described surfactant is
Tween 80.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1 and 2, it is characterised in that described foaming agent is ring penta
Alkane or pentane.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1 and 2, it is characterised in that described firming agent is phosphoric acid
Mixed acid or hydrochloric acid with p-methyl benzenesulfonic acid.
Red mud phenolic aldehyde foam thermal insulation material the most according to claim 1 and 2, it is characterised in that described coupling agent is silane
Coupling agent KH550 or silane coupler KH560.
8. the preparation method of a red mud phenolic aldehyde foam thermal insulation material as claimed in claim 1, it is characterised in that include following
Step:
1) phenolic resin, polyurethane, firming agent and toughener are carried out under the conditions of 40~60 DEG C mix homogeneously, mixed
Thing A;
2) by mixture A, red mud, coupling agent, surfactant and foaming agent mixing and stirring, it is quickly poured into the mould of preheating
Tool foams, solidifies.
The preparation method of red mud phenolic aldehyde foam thermal insulation material the most according to claim 8, it is characterised in that described step 2)
The preheating temperature of preheated mold is 30~50 DEG C.
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CN103881292A (en) * | 2014-03-13 | 2014-06-25 | 石河子大学 | Novel external-wall insulation composite material and preparation method thereof |
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