CN106045478A - 防静电喷墨抛光砖及其制备方法 - Google Patents

防静电喷墨抛光砖及其制备方法 Download PDF

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CN106045478A
CN106045478A CN201610378523.9A CN201610378523A CN106045478A CN 106045478 A CN106045478 A CN 106045478A CN 201610378523 A CN201610378523 A CN 201610378523A CN 106045478 A CN106045478 A CN 106045478A
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antistatic
glaze
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polished bricks
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张召
李化珂
张维炬
张烃
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Zibo Chengchang Building Ceramic Co Ltd
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Abstract

本发明属于建筑材料技术领域，具体涉及一种防静电喷墨抛光砖及其制备方法。防静电喷墨抛光砖由坯料和防静电釉料制成，坯料组成：高岭土、蒙脱石、钾长石、钠长石、滑石、叶蜡石、氧化锡、氧化锑；防静电釉料组成：氧化锡、氧化锑、氧化锌、甲基纤维素。本发明各层面均匀分布防静电釉料，釉料嵌入坯体内部，导电效果持久有效，避免了同类产品以涂料方式外涂而导致的防静电有效期短，磨损后失效的弊端。

Description

防静电喷墨抛光砖及其制备方法
技术领域
本发明属于建筑材料技术领域，具体涉及一种防静电喷墨抛光砖及其制备方法。
背景技术
在精密仪器、电子产品生产存储、计算机机房等设计领域静电的防治是必须考虑的因素，目前防静电地砖或装饰材料一般为防静电活动地板或防静电釉面砖等等防静电材料，这些材料使用过程中会存在易老化的问题，持久性不好，养护困难。
发明内容
本发明的目的是提供一种防静电喷墨抛光砖，具有良好的使用可靠性和稳定性，而且装饰效果好、防静电功能强；本发明同时提供了防静电喷墨抛光砖的制备方法，科学合理、简单易行。
本发明所述的防静电喷墨抛光砖，由坯料和防静电釉料制成：
坯料重量百分组成如下：
防静电釉料重量百分组成如下：
所述的坯料和防静电釉料的重量比为200：0.5-1.5。
本发明所述的防静电喷墨抛光砖的制备方法，步骤如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后，采用多管自由布料系统按锥形立体方式布料；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆研细搅拌备用；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；
(4)砖坯干燥，烧成，抛光，分选，包装入库。
步骤(1)中所述的泥浆除铁过筛后直接着色。
步骤(2)中所述的釉浆的比重为1.8-2.5g/ml。
步骤(2)中所述的釉浆研细搅拌后添加颜料。
步骤(3)中所述的压制成型压力大于等于260bar，压制成型次数为3.5-5.5次/分。
步骤(4)中所述的干燥时间为35-120min，干燥温度为160-300℃。
步骤(4)中所述的烧成周期为35-55min，烧成温度为1145-1175℃。
本发明所述的防静电喷墨抛光砖的制备方法，具体步骤如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后可以不着色也可以直接着色，直接着色后形成各种色调及深浅不一的带色粉料十到十二三种，以料车采用多管自由布料系统按锥形立体方式布料，形成各种花纹图案；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆研细搅拌备用，为确保艺术效果也可以在釉浆研细搅拌后适当添加颜料；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；
(4)砖坯干燥，烧成，抛光，分选，包装入库。
本发明制备的产品为全瓷防静电喷墨抛光砖，吸水率：0.05％以内，不会因为空气湿度的变化而影响其防静电效果和使用寿命，本产品采用微粉砖生产工艺，花色艳丽装饰效果好，易于厂房、机房、办公、家居使用，在家居使用中可有效的减少小孩、老年人因静电诱发的各种危险因素的伤害。
本发明以喷墨抛光砖为载体，将坯料原料混料入磨研磨，经制粉通过多管自由布料系统成型，在布料时将防静电半导体材料氧化锡、氧化锑、氧化锌及甲基纤维素合成的防静电釉喷淋到坯料各断面，形成网格状半导体层，经压制煅烧，抛光分选成产品，砖坯经抛削后成网状，网状防静电釉层露于表面，具备了很强的防静电功能。
砖坯经煅烧冷却后抛光，抛光后防静电釉呈网格状裸露于砖表面，周围被熔体固定，永久不损伤，既有装饰的效果又起到防静电的功能。
本发明的防静电喷墨微粉砖的防静电功能来自于防静电釉料，决定防静电效果的是防静电釉料的组成和使用量。
本发明与现有技术相比，具有如下有益效果：
(1)本发明以喷墨抛光砖工艺为基础，采用料车多管自由布料系统，同时采用锥形立体布料，然后用料车喷枪喷淋防静电釉料这种新式方式布料经过抛光后，各层面均匀分布防静电釉料，釉料嵌入坯体内部，导电效果持久有效，避免了同类产品以涂料方式外涂而导致的防静电有效期短，磨损后失效的弊端。
(2)本发明布料后装饰效果更强，将防静电釉自身作为一种原料，使其花色层次更加丰富。
(3)本发明生产的防静电喷墨微粉砖：
抗折强度大于37Mpa
吸水率小于0.05％
莫氏硬度大于7
点对点电阻：3-8x 10'8欧姆。
具体实施方式
以下结合实施例对本发明做进一步描述。
实施例1
原料组成如下：
坯料重量百分组成如下：
防静电釉料重量百分组成如下：
坯料和防静电釉料的重量比为200:1。
制备方法如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后，采用多管自由布料系统按锥形立体方式布料；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆的比重为2.0g/ml，釉浆研细搅拌备用；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；压制成型压力270bar，压制成型次数为5次/分；
(4)砖坯干燥，烧成，抛光，分选，包装入库；干燥时间为120min，干燥温度为300℃，烧成周期为50min，烧成温度为1160℃。
产品指标：
抗折强度：38MPa，吸水率：0.02％，光泽度：92度，点对点电阻：3.65x10'8欧姆。
实施例2
原料组成如下：
坯料重量百分组成如下：
防静电釉料重量百分组成如下：
坯料和防静电釉料的重量比为200:0.5。
制备方法如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后直接着色，形成带色粉料，采用多管自由布料系统按锥形立体方式布料；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆的比重为2.5g/ml，釉浆研细搅拌后适当添加颜料备用；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；压制成型压力285bar，压制成型次数为5次/分；
(4)砖坯干燥，烧成，抛光，分选，包装入库；干燥时间为90min，干燥温度为210℃，烧成周期为50min，烧成温度为1170℃。
产品指标：
抗折强度：40MPa，吸水率：0.02％，光泽度：92度，点对点电阻：6.52x10'8欧姆。
实施例3
原料组成如下：
坯料重量百分组成如下：
防静电釉料重量百分组成如下：
坯料和防静电釉料的重量比为200:1.5。
制备方法如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后，采用多管自由布料系统按锥形立体方式布料；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆的比重为1.8g/ml，釉浆研细搅拌备用；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；压制成型压力260bar，压制成型次数为4次/分；
(4)砖坯干燥，烧成，抛光，分选，包装入库；干燥时间为35min，干燥温度为160℃，烧成周期为35min，烧成温度为1156℃。
产品指标：
抗折强度：40MPa，吸水率：0.02％，光泽度：92度，点对点电阻：4.68x10'8欧姆。

Claims (9)

1.一种防静电喷墨抛光砖，其特征在于由坯料和防静电釉料制成：
坯料重量百分组成如下：
防静电釉料重量百分组成如下：
2.根据权利要求1所述的防静电喷墨抛光砖，其特征在于所述的坯料和防静电釉料的重量比为200：0.5-1.5。
3.一种权利要求1或2所述的防静电喷墨抛光砖的制备方法，其特征在于步骤如下：
(1)坯料原料经混料球磨成泥浆，泥浆除铁过筛后，采用多管自由布料系统按锥形立体方式布料；
(2)防静电釉料原料混料球磨，得到釉浆，釉浆研细搅拌备用；
(3)坯料布料完成后，用机械手分割坯料形成网状，向网状缺口内喷淋釉浆，压制成型，得到砖坯；
(4)砖坯干燥，烧成，抛光，分选，包装入库。
4.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(1)中所述的泥浆除铁过筛后直接着色。
5.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(2)中所述的釉浆的比重为1.8-2.5g/ml。
6.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(2)中所述的釉浆研细搅拌后添加颜料。
7.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(3)中所述的压制成型压力大于等于260bar，压制成型次数为3.5-5.5次/分。
8.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(4)中所述的干燥时间为35-120min，干燥温度为160-300℃。
9.根据权利要求3所述的防静电喷墨抛光砖的制备方法，其特征在于步骤(4)中所述的烧成周期为35-55min，烧成温度为1145-1175℃。
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1390712A (zh) * 2001-06-08 2003-01-15 南海市樵东陶瓷有限公司 云影石抛光砖及其制作方法
CN1746129A (zh) * 2004-09-08 2006-03-15 广东蒙娜丽莎陶瓷有限公司 复合半透明微粉抛光砖及其生产方法
CN1900012A (zh) * 2005-09-27 2007-01-24 广东博华陶瓷有限公司 一种仿石抛光砖及其生产方法
CN101475364A (zh) * 2009-02-02 2009-07-08 山东瓦伦蒂诺陶瓷有限公司 防静电陶瓷砖用防静电粉
CN102030519A (zh) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 一种防静电陶瓷砖及生产方法
CN102219525A (zh) * 2011-05-10 2011-10-19 广东东鹏陶瓷股份有限公司 一种防静电瓷砖及其制备方法
CN102765930A (zh) * 2012-07-03 2012-11-07 福建省南安市荣达建材有限公司 一种抗菌瓷砖的制造方法
CN103159467A (zh) * 2011-12-09 2013-06-19 辽宁金地阳陶瓷有限公司 具有峡谷纹理的仿古砖及其生产工艺

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1390712A (zh) * 2001-06-08 2003-01-15 南海市樵东陶瓷有限公司 云影石抛光砖及其制作方法
CN1746129A (zh) * 2004-09-08 2006-03-15 广东蒙娜丽莎陶瓷有限公司 复合半透明微粉抛光砖及其生产方法
CN1900012A (zh) * 2005-09-27 2007-01-24 广东博华陶瓷有限公司 一种仿石抛光砖及其生产方法
CN101475364A (zh) * 2009-02-02 2009-07-08 山东瓦伦蒂诺陶瓷有限公司 防静电陶瓷砖用防静电粉
CN102030519A (zh) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 一种防静电陶瓷砖及生产方法
CN102219525A (zh) * 2011-05-10 2011-10-19 广东东鹏陶瓷股份有限公司 一种防静电瓷砖及其制备方法
CN103159467A (zh) * 2011-12-09 2013-06-19 辽宁金地阳陶瓷有限公司 具有峡谷纹理的仿古砖及其生产工艺
CN102765930A (zh) * 2012-07-03 2012-11-07 福建省南安市荣达建材有限公司 一种抗菌瓷砖的制造方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
俞康泰: "《陶瓷添加剂应用技术》", 31 May 2006, 化学工业出版社 *
况金华等: "《陶瓷生产工艺技术》", 31 December 2013, 武汉理工大学 *
张云洪等: "《生产质量控制》", 31 August 2002, 武汉理工大学 *
裴秀娟等: "《陶瓷墙地砖工厂技术员手册》", 30 June 2004, 化学工业出版社 *

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