CN106045249A - Novel recycling sludge treatment system and treatment method - Google Patents

Novel recycling sludge treatment system and treatment method Download PDF

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Publication number
CN106045249A
CN106045249A CN201610559694.1A CN201610559694A CN106045249A CN 106045249 A CN106045249 A CN 106045249A CN 201610559694 A CN201610559694 A CN 201610559694A CN 106045249 A CN106045249 A CN 106045249A
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China
Prior art keywords
sludge
inorganic salt
precipitation
reservoir
mud
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CN201610559694.1A
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Inventor
王学科
穆童
马竞男
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New Ingegneria Ambientale Srl In Tianjin One
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New Ingegneria Ambientale Srl In Tianjin One
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Priority to CN201610559694.1A priority Critical patent/CN106045249A/en
Publication of CN106045249A publication Critical patent/CN106045249A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention provides a novel recycling sludge treatment system and belongs to the technical field of sludge treatment. A sludge pretreatment unit comprises a sludge storage bunker, an adjustment device and an inorganic salt dissolving device which are sequentially connected, a separation unit comprises an inorganic salt extraction device and a desanding device, an organic matter treatment unit comprises an organic matter sludge solution storage tank, a dehydration device, a drying device and an incinerator which are sequentially connected, an inorganic matter treatment unit comprises an inorganic matter solution storage tank, a primary sedimentation device and a primary sedimentation filtering device which are sequentially connected, the primary sedimentation device is connected with a secondary sedimentation device, the secondary sedimentation device is connected with a secondary sedimentation filtering device, and a sewage treatment unit comprises a sewage storage tank and a sewage treatment system. Inorganic matters and organic matters in the sludge are effectively separated and respectively utilized, the harmless treatment of the sludge is implemented while sludge recycle and reduction is achieved, the purpose of cleaner production is achieved, and economic, social and environmental benefits are remarkable.

Description

A kind of Novel reclamation sludge treating system and processing method
Technical field
The present invention relates to technical field of sludge treatment, specifically a kind of Novel reclamation sludge treating system and process side Method.
Background technology
Along with the raising of sewage disposal discharge standard in recent years, traditional Sewage Plant biochemical processing process cannot meet The emission request of total phosphorus, simultaneously takes account of cost factor, the method that most water factories use chemical dephosphorization, adds in processing technique A large amount of iron salt or aluminum salt flocculant, make to be mixed in water factory's activated sludge substantial amounts of inorganic metal salt, and then make in mixing sludge Organic composition reduce, ultimately result in the middle of the mud of Sewage Plant, inorganic salts accounts for the 35% of dewatered sludge component even More, dispose to the subsequent treatment of mud and bring problems.Such as, in mud, the reduction of organic principle result in anaerobic digestion With the reduction of aerobic compost treatment effeciency, in mud, the more reduction causing mud dry base heat value of inorganic constituents also makes mud Anhydration and incineration cost is significantly increased etc..It addition, for water purification plants, because needing the suspension in removal water in processing technique Thing, can put into a large amount of flocculant equally, causes in waterworks sludge containing a large amount of inorganic metal salts, follow-up is difficult to efficient resource Change.
Heavy metal in mud can pass through immobilization or stabilisation, makes by changing the chemical form of Heavy Metals in Sludge Its never stable form to stable form, reduce the activity of heavy metal, reach sewage sludge harmlessness.But this kind of method can only play Mitigation, it is impossible to be inherently eliminated the heavy metal pollution to soil, along with change and the passage of time of environmental condition, weight Metal still can enter environment.Only the harmful substance in mud is removed, could the relieved fertilizer that mud is made It is applied in gardens or farmland.Further, the heavy metal in mud, inorganic salt etc. are unfavorable for the element extraction of compost out, logical Cross simple process to be used, be only the real recycling achieving mud.
Summary of the invention
In view of this, it is desirable to provide a kind of innoxious, minimizing, resource, it is possible to efficiently separate in mud Inorganic salt, improves inorganic salt and organic utilization rate, it is achieved the Novel reclamation Treatment of Sludge system of the recycling of mud System and processing method.
For reaching above-mentioned purpose, the technical scheme is that and be achieved in that: a kind of Novel reclamation Treatment of Sludge system System, including sludge pretreatment unit, separative element, Organic substance disposal unit, inorganic matter disposal unit and sewage disposal unit,
Described sludge pretreatment unit includes warehouse of sludge, adjusting means and the inorganic salt dissolver being sequentially connected with, institute State connection inorganic salt lytic agent storage tank on inorganic salt dissolver;
Described separative element includes that inorganic salt extraction element and desanding device, described inorganic salt extraction element are at least one Individual, and be sequentially connected, described inorganic salt extraction element is connected with inorganic salt dissolver;
Described Organic substance disposal unit includes organic matter sludge solution reservoir, described Organic Sludge solution reservoir and desanding Device is connected;
Described inorganic matter disposal unit includes inanimate matter solution reservoir, primary sedimentation device and the primary sedimentation being sequentially connected with Defecator, described inanimate matter solution reservoir is connected with inorganic salt extraction element, and described primary sedimentation device fills with secondary precipitation Putting connected, described secondary precipitation device is connected with secondary precipitation defecator, and by that analogy, N-1 time settler precipitates with n times Device is connected, and described n times settler is connected with n times precipitation defecator, (N >=2);
Described sewage disposal unit includes that effluent holding reservoir and sewage disposal system, described effluent holding reservoir and inorganic matter are disposed single Unit is connected, and described sewage disposal system is connected with adjusting means and inorganic salt extraction element respectively.
Further, described Organic substance disposal unit also includes: dehydration device, and described dehydration device is dirty with organic matter respectively Mud solution reservoir is connected with effluent holding reservoir.
Further, described Organic substance disposal unit also includes: desiccation apparatus and incinerator, and described desiccation apparatus is with de- Water device is connected, and described incinerator is connected with desiccation apparatus.
Further, described primary sedimentation defecator is connected with secondary precipitation device, described secondary precipitation defecator Being connected with three settlers, by that analogy, N-1 time precipitation defecator is connected with n times settler, and n times precipitation filters dress Put and be connected with effluent holding reservoir.
Further, described primary sedimentation defecator is connected with effluent holding reservoir, and described secondary precipitation defecator is with dirty Water reservoir is connected, and by that analogy, n times precipitation defecator is connected with effluent holding reservoir.
Further, described inorganic salt extraction element includes: liquid mixes pond and depositing reservoir, and described liquid mixes pond and is arranged at each nothing The front end of machine salt extraction element, described depositing reservoir is arranged at the rear end of each inorganic salt extraction element.
Further, it is the storage mud groove of one or more pyramidal structure bottom described depositing reservoir, the bottom of described storage mud groove It is provided with sludge pump.
Further, described inorganic salt extraction element also includes: sedimentation device, and described sedimentation device is arranged in depositing reservoir For solid-liquid separation.
Present invention also offers the processing method of above-mentioned Novel reclamation sludge treating system, comprise the following steps:
A. the mud of municipal wastewater or trade effluent or water supply plant is collected together, be stored in warehouse of sludge (1);
B. the mud in warehouse of sludge is transported in adjusting means, mixes homogenizing process through one section, by sludge conditioning To moisture content more than 85%;
C. the sludge solutions of moisture content more than 85% is pumped into inorganic salt dissolver, and pump in inorganic salt dissolver Enter inorganic salt lytic agent, through stirring by the inorganic salt dissolution in mud to liquid phase, remove extracellular polymeric simultaneously, obtain The pH < 3 of inorganic salt solution, the time of staying is 30min~90min;
D. the sludge solutions through pretreatment carries out inorganic salt extraction by inorganic salt extraction element, and the time of staying is 20min~90min;
E. the inanimate matter solution extracted through inorganic salt extraction element enters inanimate matter solution reservoir, and the mud of precipitation enters and removes Sand device;
F. the entrance of the inorganic salt solution in inanimate matter solution reservoir primary sedimentation device carries out precipitation, and precipitate passes through Primary sedimentation defecator recycles;Supernatant in primary sedimentation device enters secondary precipitation device and carries out precipitation, Precipitate recycles through secondary precipitation defecator;By that analogy, the supernatant in previous step is entered n times precipitation dress Putting and carry out precipitation, precipitate recycles through n times precipitation defecator, and the sewage that inorganic matter disposal unit produces neutralizes Rear entrance effluent holding reservoir, (N >=2);
G. entering the mud of desanding device in step e through desanding, organic sludge is partially into the storage of Organic Sludge solution Pond, bulky grain solid silt particle can do construction material;
H. the organic sludge after desanding can be directly used for anaerobic methane production gas, or recycles as carbon source, or by organic dirt Mud is back to Sewage Plant;Can also pass through dehydration device to be for further processing, the organic sludge after dehydration can carry out compost, or As earthworm feedstuff after process;Can also pass through desiccation apparatus to be for further processing, the mud after mummification can be through pelletize conduct Bio-fuel;Can also pass through incinerator to be for further processing, the product after burning can do construction material, burns and produces heat Can be used for the thermal source of desiccation apparatus;
I. the sewage produced in whole system enters effluent holding reservoir, through the process of sewage disposal system, reaches discharge mark Accurate;
J. after sewage disposal is up to standard, a part is back to the regulation homogenizing of pretreatment, and a part is back to inorganic salt and extracts, Another part discharges.
Further, the extracellular polymeric in mud is removed by described step c.
Further, the microbial cell in described step c retains intact.
Further, the number of times that the inorganic salt in described step d extracts is 1~7 time.
Further, every time extract addition water in described step d quality is raw sewage solution quality 2~7 times.
Further, in described step h, the content of microorganisms in organic sludge after desanding rises to the 40% of raw sewage Above.
Further, the Heavy Metals in Sludge after being dehydrated in described step h removes more than 90%.
Relative to prior art, present invention have the advantage that
(1), after mud enters the sludge treating system of the present invention, its product is construction material, biogas, carbon source, fertilizer, life Available raw material and the sewage of qualified discharge such as thing fuel, useful inorganic salt, the useful resource in whole processing system obtains Sufficiently utilize;
(2) extracellular polymeric removal pretreating process is while reducing sewage sludge viscosity, does not destroy cellularity, by micro-life The Cytoplasm of thing cell is greatly retained in mud solid phase so that in separative element product, organic components obtains to the limit Reservation, improve organic utilization rate in mud;
(3) the repeatedly depositing technology of inanimate matter is by the most sharp for the inorganic salts such as the phosphorus of inorganic part, ferrum, aluminum, copper, chromium in mud Use, on the one hand solve the problem that heavy metal hinders organic sludge as resources to utilize, on the other hand improve nothing in mud The utilization ratio of machine matter, has i.e. reached effective utilization of resource, has solved again the secondary pollution that organic sludge utilizes from root Problem;
(4) the highest due to the moisture content of mud, sludge handling process certainly will produce substantial amounts of waste water, the most treated Cannot directly discharge;Owing to the water yield is relatively big, if being exhausted directly to sewage treatment plant, the process of sewage treatment plant certainly will be increased Load, and, owing to native system has water demand at pretreatment unit and separative element, if waste water system produced is in addition Process, reapply in native system, both saved the cost purchasing fresh water, alleviate again the load of sewage treatment plant, and Environment is not polluted.
(5) inanimate matter in mud and organic matter are efficiently separated and are utilized respectively by the present invention, in sewage sludge harmlessness and decrement Also can accomplish the disposal of resources of mud while change, reach the purpose that cleaning produces, produce the most economic, society and environment Benefit.
Accompanying drawing explanation
The accompanying drawing of the part constituting the present invention is used for providing a further understanding of the present invention, and the present invention's is schematic real Execute example and illustrate for explaining the present invention, being not intended that inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the process chart of the present invention.
Fig. 2 is the process chart of embodiments of the invention one.
Fig. 3 is the process chart of embodiments of the invention two.
Fig. 4 is the process chart of embodiments of the invention three.
Fig. 5 is the process chart of embodiments of the invention four.
Fig. 6 is the structural representation that the liquid of embodiments of the invention four mixes pond and depositing reservoir.
In figure: (1) warehouse of sludge;(2) adjusting means;(3) inorganic salt dissolver;(4) inorganic salt lytic agent storage tank; (5) inorganic salt extraction element;(51) liquid mixes pond;(52) depositing reservoir;(521) storage mud groove;(522) sedimentation device;(53) sludge pump; (6) desanding device;(7) Organic Sludge solution reservoir;(8) dehydration device;(9) desiccation apparatus;(10) incinerator;(11) nothing Machine matter solution reservoir;(121) primary sedimentation device;Secondary precipitation device (122);……;(12n) n times settler;(131) Primary sedimentation defecator;(132) secondary precipitation defecator;(13n) n times precipitation defecator;(14) effluent holding reservoir;(15) Sewage disposal system.
Detailed description of the invention
The present invention is described in further detail below in conjunction with the accompanying drawings.
As it is shown in figure 1, a kind of Novel reclamation sludge treating system, including sludge pretreatment unit, separative element, organic Thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Described sludge pretreatment unit includes warehouse of sludge 1, adjusting means 2 and the inorganic salt dissolver 3 being sequentially connected with, Inorganic salt lytic agent storage tank 4 is connected on described inorganic salt dissolver 3;
Described separative element includes inorganic salt extraction element 5 and desanding device 6, and described inorganic salt extraction element 5 is at least One, and be sequentially connected, described inorganic salt extraction element 5 is connected with inorganic salt dissolver 3;
Described Organic substance disposal unit includes organic matter sludge solution reservoir 7, described Organic Sludge solution reservoir 7 with remove Sand device 6 is connected;
Described inorganic matter disposal unit includes inanimate matter solution reservoir 11, the primary sedimentation device 121 and being sequentially connected with Secondary precipitation defecator 131, described inanimate matter solution reservoir 11 is connected with inorganic salt extraction element 5, described primary sedimentation device 121 are connected with secondary precipitation device 122, and described secondary precipitation device 122 is connected with secondary precipitation defecator 132, with this type of Pushing away, N-1 time settler is connected with n times settler, and described n times settler is connected with n times precipitation defecator, (N >= 2);
Described sewage disposal unit includes effluent holding reservoir 14 and sewage disposal system 15, described effluent holding reservoir 14 and inorganic matter Disposal unit is connected, and described sewage disposal system 15 is connected with adjusting means 2 and inorganic salt extraction element 5 respectively.
Further, described Organic substance disposal unit also includes: dehydration device 8, described dehydration device 8 respectively with organic matter Sludge solutions reservoir 7 is connected with effluent holding reservoir 14.
Further, described Organic substance disposal unit also includes: desiccation apparatus 9 and incinerator 10, described desiccation apparatus 9 Being connected with dehydration device 8, described incinerator 10 is connected with desiccation apparatus 9.
Further, described primary sedimentation defecator 131 is connected with secondary precipitation device 122, described secondary precipitation Filter device 132 is connected with three settlers 123, by that analogy, and N-1 precipitation defecator 13n-1 and n times settler 12n is connected, and n times precipitation defecator 13n is connected with effluent holding reservoir 14.
Further, described primary sedimentation defecator 131 is connected with effluent holding reservoir 14, described secondary precipitation defecator 132 are connected with effluent holding reservoir 14, and by that analogy, n times precipitation defecator 13n is connected with effluent holding reservoir 14.
Further, described inorganic salt extraction element 5 includes: liquid mixes pond 51 and depositing reservoir 52, and described liquid mixes pond 51 and arranges In the front end of each inorganic salt extraction element 5, described depositing reservoir 52 is arranged at the rear end of each inorganic salt extraction element 5.
Further, it is the storage mud groove 521 of one or more pyramidal structure bottom described depositing reservoir 52, described storage mud groove The bottom of 521 is provided with sludge pump 53.
Further, described inorganic salt extraction element 5 also includes: sedimentation device 522, and described sedimentation device 522 is arranged at For solid-liquid separation in depositing reservoir 52.
The processing method of above-mentioned Novel reclamation sludge treating system, comprises the following steps:
A. the mud of municipal wastewater or trade effluent or water supply plant is collected together, be stored in warehouse of sludge (1);
B. the mud in warehouse of sludge 1 is transported in adjusting means 2, mixes homogenizing process through one section, mud is adjusted Joint is to moisture content more than 85%;
C. the sludge solutions of moisture content more than 85% is pumped into inorganic salt dissolver 3, and in inorganic salt dissolver 3 Pump into inorganic salt lytic agent, through stirring by the inorganic salt dissolution in mud to liquid phase, remove extracellular polymeric simultaneously, obtain The pH < 3 of inorganic salt solution, the time of staying is 30min~90min;
D. the sludge solutions through pretreatment carries out inorganic salt extraction by inorganic salt extraction element 5, and the time of staying is 20min~90min;
E. the inanimate matter solution extracted through inorganic salt extraction element 5 enters inanimate matter solution reservoir 11, and the mud of precipitation enters Enter desanding device 6;
F. the entrance of the inorganic salt solution in inanimate matter solution reservoir 11 primary sedimentation device 121 carries out precipitation, precipitation Thing recycles through primary sedimentation defecator 131;Supernatant in primary sedimentation device 121 enters secondary precipitation device 122 carry out precipitation, and precipitate recycles through secondary precipitation defecator 132;By that analogy, by previous step Supernatant enters n times settler 12n and carries out precipitation, and precipitate recycles through n times precipitation defecator 13n, nothing In the sewage that machine thing disposal unit produces and rear entrance effluent holding reservoir 14, (N >=2);
G. in step e, the mud of entrance desanding device 6 is through desanding, and organic sludge is partially into the storage of Organic Sludge solution Pond 7, bulky grain solid silt particle can do construction material;
H. the organic sludge after desanding can be directly used for anaerobic methane production gas, or recycles as carbon source, or by organic dirt Mud is back to Sewage Plant;Can also pass through dehydration device 8 to be for further processing, the organic sludge after dehydration can carry out compost, Or as earthworm feedstuff after processing;Can also pass through desiccation apparatus 9 to be for further processing, the mud after mummification can be made through pelletize For bio-fuel;Can also pass through incinerator 10 to be for further processing, the product after burning can do construction material, burns and produces Heat can be used for the thermal source of desiccation apparatus 9;
I. the sewage produced in whole system enters effluent holding reservoir 14, through the process of sewage disposal system 15, reaches row Put standard;
J. after sewage disposal is up to standard, a part is back to the regulation homogenizing of pretreatment, and a part is back to inorganic salt and extracts, Another part discharges.
Embodiment 1
As in figure 2 it is shown, a kind of Novel reclamation sludge treating system, including sludge pretreatment unit, separative element, organic Thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Sludge pretreatment unit includes warehouse of sludge 1, adjusting means 2 and the inorganic salt dissolver 3 being sequentially connected with, inorganic Inorganic salt lytic agent storage tank 4 is connected on salt dissolver 3;
Separative element includes inorganic salt extraction element 5 and desanding device 6, and inorganic salt extraction element 5 is one, and inorganic salt carries Fetching is put 5 and is connected with inorganic salt dissolver 3;
Organic substance disposal unit includes Organic Sludge solution reservoir 7, dehydration device 8, desiccation apparatus 9 and being sequentially connected with Incinerator 10, Organic Sludge solution reservoir 7 is connected with desanding device 6;
Inorganic matter disposal unit includes the inanimate matter solution reservoir 11 being sequentially connected with, primary sedimentation device 121 and once sinks Shallow lake defecator 131, inanimate matter solution reservoir 11 is connected with inorganic salt extraction element 5, primary sedimentation device 121 and secondary precipitation Device 122 is connected, and secondary precipitation device 122 is connected with secondary precipitation defecator 132, secondary precipitation device 122 and three times heavy Shallow lake device 123 is connected, and three times settler 123 is connected with three precipitation defecators 133, three settlers 123 and four times Settler 124 is connected, and four times settler 124 is connected with four precipitation defecators 134, primary sedimentation defecator 131 Being connected with secondary precipitation device 122, secondary precipitation defecator 132 is connected with three settlers 123, and three times precipitation filters dress Put 133 to be connected with four settlers 124;
Sewage disposal unit includes effluent holding reservoir 14 and sewage disposal system 15, effluent holding reservoir 14 respectively with dehydration device 8 Being connected with four precipitation defecators 134, sewage disposal system 15 is connected with adjusting means 2 and inorganic salt extraction element 5 respectively.
Mud used is from the excess sludge after the sludge dewatering of certain sewage treatment plant's concentration basin, and its moisture content is after measured More than 80%, the inorganic constituents in mud includes Hg, Cd, Cr, As, Zn, Cu, Ni, Fe, Al, Pb, P etc., and wherein Fe content is high Reaching 1.7g/kg, Al content and be up to 9.4g/kg, measure mud organic substance content 40%~45%, dry base heat value is 1500kcal/ Kg~1700kcal/kg.The mud of municipal wastewater or trade effluent or water supply plant is collected together, is stored in warehouse of sludge 1 In;Mud in warehouse of sludge 1 is transported in adjusting means 2, mixes homogenizing process through one section, by sludge conditioning to aqueous Rate 95%;The sludge solutions of moisture content 95% is pumped into inorganic salt dissolver 3, and pumps in inorganic salt dissolver 3 The sulphuric acid of 20%, through stirring by the inorganic salt dissolution in mud to liquid phase, removes extracellular polymeric simultaneously, and regulation pH is 2.0, the time of staying that inorganic salt dissolves is 30min;Sludge solutions through pretreatment carries out nothing by inorganic salt extraction element 5 Machine salt extracts, and the time of staying is 20min;The inanimate matter solution extracted through inorganic salt extraction element 5 enters inanimate matter solution reservoir 11, the mud of precipitation enters desanding device 6, and mud can do construction material through desanding device 6 desanding, bulky grain solid silt particle, Organic sludge is partially into Organic Sludge solution reservoir 7;Organic sludge after desanding enters dry after entering dehydration device 8 dehydration Gasifying device 9, the water that dehydration device 8 obtains enters effluent holding reservoir 14, measures content of organics in mud after drying and other treatment > 60%, < 10%, the mud dry base heat value after mummification reaches 3200kcal/kg~3700kcal/kg to inorganic salt total content, controls oneself Combustion efficiency is good, and the bio-fuel entrance incinerator 10 obtained through pelletize burns, and the product after burning does construction material, Burn generation heat and can meet heat energy needed for desiccation apparatus 9 completely;Inorganic salt solution in inanimate matter solution reservoir 11 enters Primary sedimentation device 121, adds oxidant, forms iron phosphate precipitation, and iron phosphate precipitation enters primary sedimentation defecator 131 times Receiving and utilize, the sewage of generation enters secondary precipitation device 122;Supernatant in primary sedimentation device 121 enters secondary precipitation dress Putting 122, add sodium hydroxide solution, regulate pH to 4.0, obtain ferric hydroxide precipitate, ferric hydroxide precipitate enters secondary precipitation Defecator 132 recycles, and the sewage of generation enters three settlers 123;Supernatant in secondary precipitation device 122 enters Enter three settlers 123, add sodium hydroxide solution, regulate pH to 5.2, form aluminum hydroxide precipitation, aluminum hydroxide precipitation Entering three precipitation defecators 133 to recycle, the sewage of generation enters four settlers 124, three settlers 123 In supernatant enter four settlers 124, add sodium hydroxide solution, regulate pH > 9.5, the precipitation obtained through four times sink Shallow lake defecator 134 is used as construction material after leaching, measure after four settlers 124 inorganic salt total amount in solution < 2000mg/kg, with rear entrance effluent holding reservoir 14 in the sewage of generation;The sewage produced in whole system enters effluent holding reservoir 14, Through the process of sewage disposal system 15, reach discharge standard;After sewage disposal is up to standard, a part is back to the regulation of pretreatment Homogenizing, a part is back to inorganic salt and extracts, and another part discharges.
Embodiment 2
As it is shown on figure 3, a kind of Novel reclamation sludge treating system, including sludge pretreatment unit, separative element, organic Thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Sludge pretreatment unit includes warehouse of sludge 1, adjusting means 2 and the inorganic salt dissolver 3 being sequentially connected with, inorganic Inorganic salt lytic agent storage tank 4 is connected on salt dissolver 3;
Separative element includes inorganic salt extraction element 5 and desanding device 6, and inorganic salt extraction element 5 is one, and inorganic salt carries Fetching is put 5 and is connected with inorganic salt dissolver 3;
Organic substance disposal unit includes Organic Sludge solution reservoir 7 and dehydration device 8, the Organic Sludge being sequentially connected with Solution reservoir 7 is connected with desanding device 6;
Inorganic matter disposal unit includes the inanimate matter solution reservoir 11 being sequentially connected with, primary sedimentation device 121 and once sinks Shallow lake defecator 131, inanimate matter solution reservoir 11 is connected with inorganic salt extraction element 5, primary sedimentation device 121 and secondary precipitation Device 122 is connected, and secondary precipitation device 122 is connected with secondary precipitation defecator 132, secondary precipitation device 122 and three times heavy Shallow lake device 123 is connected, and three times settler 123 is connected with three precipitation defecators 133, three settlers 123 and four times Settler 124 is connected, and four times settler 124 is connected with four precipitation defecators 134, four settlers 124 and five Secondary settler 125 is connected, and five times settler 125 is connected with five precipitation defecators 135;
Sewage disposal unit includes effluent holding reservoir 14 and sewage disposal system 15, effluent holding reservoir 14 respectively with dehydration device 8, Primary sedimentation defecator 131, secondary precipitation defecator 133, four precipitation defecators of 132, three precipitation defecators 134 are connected with five precipitation defecators 135, sewage disposal system 15 respectively with adjusting means 2 and inorganic salt extraction element 5 phase Even.
Mud used is from the excess sludge after the sludge dewatering of certain sewage treatment plant's concentration basin, and its moisture content is after measured More than 80%, the inorganic constituents in mud includes Hg, Cd, Cr, As, Zn, Cu, Ni, Fe, Al, Pb, P etc., and wherein Fe content is up to 1.7g/kg, Al content is up to 9.4g/kg, measures mud organic substance content 40%~45%, and dry base heat value is 1500kcal/kg ~1700kcal/kg.Mud processes (processing method and separation method are with embodiment one) through pretreatment and separative element, this reality Executing adjusting means 2 in example to regulate moisture percentage in sewage sludge to 90%, inorganic salt lytic agent used is the hydrochloric acid of 6mol/L, and regulation pH is 1.0, the time of staying that inorganic salt dissolves is 90min, and the time of staying that inorganic salt extracts is 60min;Through inorganic salt extraction element 5 The inanimate matter solution extracted enters inanimate matter solution reservoir 11, and the mud of precipitation enters desanding device 6, and mud is through desanding device 6 desanding, bulky grain solid silt particle can do construction material, and organic sludge is partially into Organic Sludge solution reservoir 7;After desanding Organic sludge enters dehydration device 8, and the water that dehydration device 8 obtains enters effluent holding reservoir 14, the organic sludge after dehydration Regulation pH is neutral, and the organic sludge moisture content 40% after dehydration, carbon-nitrogen ratio is 30:1, takes part and measures dirt after drying and other treatment Content of organics in mud>60%, Hg content<5mg/kg, Cd content<5mg/kg, Cr content<20mg/kg, As content<10mg/ Kg, Zn content < 50mg/kg, Cu content < 20mg/kg, Ni content < 20mg/kg, Fe content < 50mg/kg, Al content < 20mg/ < 50mg/kg meets " pollutant catabolic gene standard in agricultural sludge ", can be used for compost kg, Pb content;Inanimate matter solution reservoir 11 In inorganic salt solution enter primary sedimentation device 121, add sodium sulfide, regulate pH to 2.0, formed copper sulfide precipitation, sulfuration Copper precipitation enters primary sedimentation defecator 131 and recycles, with rear entrance effluent holding reservoir 14 in the sewage of generation;Primary sedimentation Supernatant in device 121 enters secondary precipitation device 122, adds calcium oxide, regulates pH to 4.0, obtains ferric hydroxide precipitate, Ferric hydroxide precipitate enters secondary precipitation defecator 132 and recycles, with rear entrance effluent holding reservoir 14 in the sewage of generation;Two Supernatant in secondary settler 122 enters three settlers 123, adds sodium hydroxide solution, regulates pH to 5.2, is formed Aluminum hydroxide precipitation, aluminum hydroxide precipitation enters three precipitation defecators 133 and recycles, with rear entrance in the sewage of generation Effluent holding reservoir 14, the supernatant in three settlers 123 enters four settlers 124, adds sodium sulfide, and regulation pH is extremely 7.0, form zinc sulfide precipitation, zinc sulfide precipitation enters four precipitation defecators 134, recycles, and the sewage of generation neutralizes Rear entrance effluent holding reservoir 14, the supernatant in four settlers 124 enters five settlers 125, adds sodium hydroxide molten Liquid, regulates pH > 9.5, and the precipitation obtained is used as construction material after five precipitation defecators 135 leach, through five precipitation dresses < 2000mg/kg, with rear entrance effluent holding reservoir 14 in the sewage of generation to measure inorganic salt total amount in solution after putting 125;Whole system The sewage of middle generation enters effluent holding reservoir 14, through the process of sewage disposal system 15, reaches discharge standard;Sewage disposal is up to standard After, a part is back to the regulation homogenizing of pretreatment, and a part is back to inorganic salt and extracts, and another part discharges.
Embodiment 3
As shown in Figure 4, a kind of Novel reclamation sludge treating system, including sludge pretreatment unit, separative element, organic Thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Sludge pretreatment unit includes warehouse of sludge 1, adjusting means 2 and the inorganic salt dissolver 3 being sequentially connected with, inorganic Inorganic salt lytic agent storage tank 4 is connected on salt dissolver 3;
Separative element includes inorganic salt extraction element 5 and desanding device 6, and inorganic salt extraction element 5 is three, and phase successively Even, inorganic salt extraction element 5 is connected with inorganic salt dissolver 3;
Organic substance disposal unit includes organic matter sludge solution reservoir 7, Organic Sludge solution reservoir 7 and desanding device 6 It is connected;
Inorganic matter disposal unit includes the inanimate matter solution reservoir 11 being sequentially connected with, primary sedimentation device 121 and once sinks Shallow lake defecator 131, inanimate matter solution reservoir 11 is connected with inorganic salt extraction element 5, primary sedimentation device 121 and secondary precipitation Device 122 is connected, and secondary precipitation device 122 is connected with secondary precipitation defecator 132, secondary precipitation device 122 and three times heavy Shallow lake device 123 is connected, and three times settler 123 is connected with three precipitation defecators 133;
Sewage disposal unit includes effluent holding reservoir 14 and sewage disposal system 15, effluent holding reservoir 14 respectively with dehydration device 8, Primary sedimentation defecator 131,132, three precipitation defecators of secondary precipitation defecator 133 are connected, sewage disposal system 15 are connected with adjusting means 2 and inorganic salt extraction element 5 respectively.
Mixing sludge its moisture content after measured used is more than 80%, measures mud organic substance content 47%, dry base heat value For 2000kcal/kg.Mud processes (processing method and separation method are with embodiment one) through pretreatment and separative element, this reality Executing adjusting means 2 in example to regulate moisture percentage in sewage sludge to 95%, inorganic salt lytic agent used is the sulphuric acid of 50%, and regulation pH is 2.0, the time of staying that inorganic salt dissolves is 60min, and the time of staying that inorganic salt extracts is 80min;Through inorganic salt extraction element 5 The inanimate matter solution extracted enters inanimate matter solution reservoir 11, and the mud of precipitation enters desanding device 6, and mud is through desanding device The desanding of 6, bulky grain solid silt particle can do construction material, and organic sludge is partially into Organic Sludge solution reservoir 7;After desanding Organic sludge regulation pH be neutrality, be back to sewage treatment plant as carbon source;Inorganic salt in inanimate matter solution reservoir 11 is molten Liquid enters primary sedimentation device 121, adds sodium hydroxide regulation pH to 4.0, forms ferric hydroxide precipitate, and ferric hydroxide precipitate is entered Enter primary sedimentation defecator 131 to recycle, with rear entrance effluent holding reservoir 14 in the sewage of generation;Primary sedimentation device 121 In supernatant enter secondary precipitation device 122, add calcium oxide, regulate pH to 5.2, obtain aluminum hydroxide precipitation, hydroxide Aluminum precipitation enters secondary precipitation defecator 132 and recycles, with rear entrance effluent holding reservoir 14 in the sewage of generation;Secondary precipitation Supernatant in device 122 enters three settlers 123, adds calcium oxide solution, regulates pH to 9.5, and the precipitation of formation is done Construction material, with rear entrance effluent holding reservoir 14 in the sewage of generation;The sewage produced in whole system enters effluent holding reservoir 14, warp Cross the process of sewage disposal system 15, reach discharge standard;After sewage disposal is up to standard, the regulation that a part is back to pretreatment is equal Matter, a part is back to inorganic salt and extracts, and another part discharges.
Embodiment 4
As shown in Figure 5,6, a kind of Novel reclamation sludge treating system, including sludge pretreatment unit, separative element, have Machine thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Sludge pretreatment unit includes warehouse of sludge 1, adjusting means 2 and the inorganic salt dissolver 3 being sequentially connected with, inorganic Inorganic salt lytic agent storage tank 4 is connected on salt dissolver 3;
Separative element includes inorganic salt extraction element 5 and desanding device 6, and inorganic salt extraction element 5 is three, and phase successively Even, inorganic salt extraction element 5 is connected with inorganic salt dissolver 3, and inorganic salt extraction element 5 includes: liquid mixes pond 51 and depositing reservoir 52, liquid mixes pond 51 and is arranged at the front end of each inorganic salt extraction element 5, and depositing reservoir 52 is arranged at each machine salt extraction element 5 Rear end, is the storage mud groove 521 of a pyramidal structure bottom depositing reservoir 52, and the bottom of storage mud groove 521 is provided with sludge pump 53, inorganic salt Extraction element 5 also includes: sedimentation device 522, and sedimentation device 522 is arranged in depositing reservoir 52 for solid-liquid separation;
Organic substance disposal unit includes organic matter sludge solution reservoir 7, Organic Sludge solution reservoir 7 and desanding device 6 It is connected;
Inorganic matter disposal unit includes the inanimate matter solution reservoir 11 being sequentially connected with, primary sedimentation device 121 and once sinks Shallow lake defecator 131, inanimate matter solution reservoir 11 is connected with inorganic salt extraction element 5, primary sedimentation device 121 and secondary precipitation Device 122 is connected, and secondary precipitation device 122 is connected with secondary precipitation defecator 132, secondary precipitation device 122 and three times heavy Shallow lake device 123 is connected, and three times settler 123 is connected with three precipitation defecators 133;
Sewage disposal unit includes effluent holding reservoir 14 and sewage disposal system 15, effluent holding reservoir 14 respectively with dehydration device 8, Primary sedimentation defecator 131,132, three precipitation defecators of secondary precipitation defecator 133 are connected, sewage disposal system 15 are connected with adjusting means 2 and inorganic salt extraction element 5 respectively;
Mud used is from the excess sludge after the sludge dewatering of certain sewage treatment plant's concentration basin, and its moisture content is after measured 84%, measure mud organic substance content 45%, inorganic salt content 36%, dry base heat value is 1900kcal/kg.Mud is through pre-place Reason and separative element process, (preprocess method is with embodiment one), and in the present embodiment, moisture percentage in sewage sludge is regulated extremely by adjusting means 2 97%, inorganic salt lytic agent used is the nitric acid of 20%, and regulation pH is 0.5, and the time of staying that inorganic salt dissolves is 90min;Warp The inanimate matter solution that inorganic salt extraction element 5 extracts enters inanimate matter solution reservoir 11, and the mud of precipitation enters desanding device 6, Mud can do construction material through desanding device 6 desanding, bulky grain solid silt particle, and it is molten that organic sludge is partially into Organic Sludge Liquid reservoir 7;Content of organics in mud is measured after organic sludge part drying and other treatment after desanding>70%, inorganic salt total content< 5%, the organic sludge obtained is used for producing biogas, after system balancing, CH in the biogas of output4Content > 65%;Inanimate matter is molten Inorganic salt solution in liquid reservoir 11, through three precipitations, obtains to make the iron phosphate precipitation of phosphate fertilizer raw material, can making flocculant Aluminum hydroxide precipitation and building material, measure inorganic salt total amount in solution < 2000mg/kg, for the first time precipitation after three precipitations Precipitant be hydrogen peroxide, second time precipitation and third time precipitation precipitant be sodium hydroxide;In system, sewage is after treatment Reach discharge standard.
Pretreated mud enters the liquid of first inorganic salt extraction element and mixes in pond 51, and in liquid mixes pond 51, solid phase is dirty Mud and liquid phase inorganic salt extracting solution are stirred so that the inorganic salt in mud is preferably dissolved in liquid phase, after being sufficiently stirred for Sludge solutions enter first inorganic salt extraction element depositing reservoir 52 in, mud and nothing under the effect of settler 522 Machine salt extracting solution separates, and the inorganic salt extracting solution in depositing reservoir 52 is flowed in inanimate matter solution reservoir 11, and sludge solutions passes through Sludge pump 53 pumps into the liquid of second inorganic salt extraction element and mixes in pond 51, mixes the sludge solutions after pond is sufficiently stirred for through liquid and enters Entering in the depositing reservoir 52 of second inorganic salt extraction element, under the effect of settler 522, mud divides with inorganic salt extracting solution From, the liquid that sludge solutions pumps into the 3rd inorganic salt extraction element by sludge pump 53 mixes in pond 51, and supernatant enters first The liquid of inorganic salt extraction element mixes in pond 51;Liquid to the 3rd inorganic salt extraction element mixes pond 51 and injects fresh water as inorganic The water inlet of salt extraction element, mixes the sludge solutions after pond is sufficiently stirred for through liquid and enters the clarification of the 3rd inorganic salt extraction element In pond 52, under the effect of settler 522, mud separates with inorganic salt extracting solution, and sludge solutions enters as organic sludge and removes In sand device 6, supernatant enters the liquid of second inorganic salt extraction element and mixes in pond 51.During the stop that inorganic salt extracts each time Between for 90min (from enter each liquid mix the time that pond starts to discharge from this secondary clearing pond to sludge solutions).
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (10)

1. a Novel reclamation sludge treating system, it is characterised in that include sludge pretreatment unit, separative element, organic Thing disposal unit, inorganic matter disposal unit and sewage disposal unit,
Described sludge pretreatment unit includes warehouse of sludge (1), adjusting means (2) and the inorganic salt dissolver being sequentially connected with (3), described inorganic salt dissolver (3) is upper connects inorganic salt lytic agent storage tank (4);
Described separative element includes inorganic salt extraction element (5) and desanding device (6), and described inorganic salt extraction element (5) is at least Being one, and be sequentially connected, described inorganic salt extraction element (5) is connected with inorganic salt dissolver (3);
Described Organic substance disposal unit includes organic matter sludge solution reservoir (7), described Organic Sludge solution reservoir (7) with remove Sand device (6) is connected;
Described inorganic matter disposal unit includes inanimate matter solution reservoir (11), the primary sedimentation device (121) and being sequentially connected with Secondary precipitation defecator (131), described inanimate matter solution reservoir (11) is connected with inorganic salt extraction element (5), described once sinks Shallow lake device (121) is connected with secondary precipitation device (122), described secondary precipitation device (122) and secondary precipitation defecator (132) being connected, by that analogy, N-1 time settler is connected with n times settler, and described n times settler and n times precipitated Filter device is connected, (N >=2);
Described sewage disposal unit includes effluent holding reservoir (14) and sewage disposal system (15), and described effluent holding reservoir (14) is with inorganic Thing disposal unit is connected, and described sewage disposal system (15) is connected with adjusting means (2) and inorganic salt extraction element (5) respectively.
A kind of Novel reclamation sludge treating system the most according to claim 1, it is characterised in that described Organic substance is disposed Unit also includes: dehydration device (8), described dehydration device (8) respectively with Organic Sludge solution reservoir (7) and effluent holding reservoir (14) it is connected.
A kind of Novel reclamation sludge treating system the most according to claim 2, it is characterised in that described Organic substance is disposed Unit also includes: desiccation apparatus (9) and incinerator (10), described desiccation apparatus (9) with dehydration device (8) be connected, described in burn Burn device (10) to be connected with desiccation apparatus (9).
A kind of Novel reclamation sludge treating system the most according to claim 1, it is characterised in that described primary sedimentation mistake Filter device (131) is connected with secondary precipitation device (122), described secondary precipitation defecator (132) and three settlers (123) being connected, by that analogy, N-1 time precipitation defecator (13n-1) is connected with n times settler (12n), and n times precipitation filters Device (13n) is connected with effluent holding reservoir (14).
A kind of Novel reclamation sludge treating system the most according to claim 1, it is characterised in that described primary sedimentation mistake Filter device (131) is connected with effluent holding reservoir (14), and described secondary precipitation defecator (132) is connected with effluent holding reservoir (14), with This analogizes, and n times precipitation defecator (13n) are connected with effluent holding reservoir (14).
A kind of Novel reclamation sludge treating system the most according to claim 1, it is characterised in that described inorganic salt extracts Device (5) including: liquid mixes pond (51) and depositing reservoir (52), and described liquid mixes pond (51) and is arranged at each inorganic salt extraction element (5) Front end, described depositing reservoir (52) is arranged at the rear end of each inorganic salt extraction element (5).
A kind of Novel reclamation sludge treating system the most according to claim 6, it is characterised in that described depositing reservoir (52) Bottom is storage mud groove (521) of one or more pyramidal structure, and the bottom of described storage mud groove (521) is provided with sludge pump (53).
A kind of Novel reclamation sludge treating system the most according to claim 6, it is characterised in that described inorganic salt extracts Device (5) also includes: sedimentation device (522), and described sedimentation device (522) is arranged in depositing reservoir (52) for solid-liquid separation.
9. a processing method for the Novel reclamation sludge treating system as described in any one of claim 1-8, its feature exists In, comprise the following steps:
A. the mud of municipal wastewater or trade effluent or water supply plant is collected together, be stored in warehouse of sludge (1);
B. the mud in warehouse of sludge (1) is transported in adjusting means (2), mixes homogenizing process through one section, mud is adjusted Joint is to moisture content more than 85%;
C. the sludge solutions of moisture content more than 85% is pumped into inorganic salt dissolver (3), and in inorganic salt dissolver (3) Pump into inorganic salt lytic agent, through stirring by the inorganic salt dissolution in mud to liquid phase, remove extracellular polymeric simultaneously, obtain The pH < 3 of inorganic salt solution, the time of staying is 30min~90min;
D. the sludge solutions through pretreatment carries out inorganic salt extraction by inorganic salt extraction element (5), and the time of staying is 20min ~90min;
E. the inanimate matter solution extracted through inorganic salt extraction element (5) enters inanimate matter solution reservoir (11), and the mud of precipitation enters Enter desanding device (6);
F. entrance primary sedimentation device of the inorganic salt solution in inanimate matter solution reservoir (11) (121) carries out precipitation, precipitation Thing recycles through primary sedimentation defecator (131);Supernatant in primary sedimentation device (121) enters secondary precipitation dress Putting (122) and carry out precipitation, precipitate recycles through secondary precipitation defecator (132);By that analogy, by previous step Supernatant in Zhou enters n times settler (12n) and carries out precipitation, and precipitate precipitates defecator (13n) through n times and returns Receive and utilize, in the sewage that inorganic matter disposal unit produces and rear entrance effluent holding reservoir (14), (N >=2);
G. in step e, the mud of entrance desanding device (6) is through desanding, and organic sludge is partially into Organic Sludge solution reservoir (7), bulky grain solid silt particle can do construction material;
H. the organic sludge after desanding can be directly used for anaerobic methane production gas, or recycles as carbon source, or is returned by organic sludge For Sewage Plant;Can also pass through dehydration device (8) to be for further processing, the organic sludge after dehydration can carry out compost, or As earthworm feedstuff after process;Can also pass through desiccation apparatus (9) to be for further processing, the mud after mummification can be made through pelletize For bio-fuel;Can also pass through incinerator (10) to be for further processing, the product after burning can do construction material, burns and produces Heat amount can be used for the thermal source of desiccation apparatus (9);
I. the sewage produced in whole system enters effluent holding reservoir (14), through the process of sewage disposal system (15), reaches row Put standard;
J. after sewage disposal is up to standard, a part is back to the regulation homogenizing of pretreatment, and a part is back to inorganic salt and extracts, another Partial discharge.
The processing method of a kind of Novel reclamation sludge treating system the most according to claim 9, it is characterised in that institute The content of microorganisms stated in step h in the organic sludge after desanding rises to more than the 40% of raw sewage.
CN201610559694.1A 2016-07-15 2016-07-15 Novel recycling sludge treatment system and treatment method Pending CN106045249A (en)

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CN108996865B (en) * 2018-09-13 2023-08-25 天津壹新环保工程有限公司 Pretreatment method and device for biogas production from sludge
CN110683622A (en) * 2019-10-11 2020-01-14 天津壹新环保工程有限公司 Method for extracting aluminum in sludge to prepare aluminum-containing flocculant

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