CN106045117A - Method for treating waste liquor with floating coagulation method - Google Patents
Method for treating waste liquor with floating coagulation method Download PDFInfo
- Publication number
- CN106045117A CN106045117A CN201610546434.0A CN201610546434A CN106045117A CN 106045117 A CN106045117 A CN 106045117A CN 201610546434 A CN201610546434 A CN 201610546434A CN 106045117 A CN106045117 A CN 106045117A
- Authority
- CN
- China
- Prior art keywords
- waste liquid
- coagulation
- filter cotton
- waste liquor
- floccule body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention relates to a method for treating waste liquor with a floating coagulation method, and belongs to the field of waste liquor treatment. According to the method for treating the waste liquor with the floating coagulation method, the waste liquor is treated through the coagulation method, in the process of treating the waste liquor, flocculating constituent obtained through coagulation floats to the surface of the waste liquor, and then sheets having the function of adsorbing the flocculating constituent and arranged on the surface of the waste liquor are used for adsorbing the flocculating constituent. The floating coagulation method can increase the probability of contact between the flocculating constituent and colloidal matter, and the time for water body clarifying is shorter than that of free sedimentation.
Description
Technical field
The present invention relates to a kind of method utilizing floating type Coagulation with Treatment waste liquid, belong to field of waste liquid treatment.
Background technology
Coagulation is one of cell process of many water treatment procedures, directly affects equipment investment and operating cost.Coagulation Method
It is the isolation technics to colloidal attitude pollutant, refers under the effect of coagulant, make the colloid in waste liquid and fine suspension cohesion
Become floccule body, the water treating method being then separated off.Coagulation Method application in liquid waste processing is the most widely, and it is main
Want equipment to have coagulant and the mixing channel of waste liquid hybrid reaction process and reaction tank, and complete what water separated with floccule body
Sedimentation tanks etc., its equipment investment is bigger.
Summary of the invention
For solving above-mentioned technical problem, the present invention provides a kind of method of floating type Coagulation with Treatment waste liquid, and floating type mixes
Solidifying method can save the investment of the aspect such as equipment, construction, and has process time short advantage.
The method utilizing floating type Coagulation with Treatment waste liquid, is the method utilizing Coagulation with Treatment waste liquid, is disposing waste liquid
During, the floccule body making coagulation obtain floats up to waste liquid surface, and what recycling was arranged at waste liquid surface has adsorption-flocculation
The sheet material floccule body of body function.
Floating type Coagulation Method of the present invention refers to when with Coagulation with Treatment waste liquid, arranges and have absorption in reaction tank
The sheet material of floccule body function so that it is be suspended in waste liquid surface.When carrying out liquid waste processing, the floccule body making coagulation obtain floats up to
Waste liquid surface, floccule body is brought to behind waste liquid surface by sheet-adhesion, float and glue in the adsorbable water of floccule body being attached
The Organic substances such as figure.
In technique scheme, preferably described in have the sheet material of adsorption-flocculation body function be filter cotton.Mistake of the present invention
Filter pulp is for having adsorption function filter cotton, and it has the function of adsorption-flocculation body, commercially available.Floccule body after adhesion and mistake
Synergism is had, such as: process the same volume surfactant with concentration with the polyaluminum sulfate aluminium flocculating agent of same amount between filter pulp
Waste water, the effect of floating type Coagulation Method is better than conventional Coagulation Method,
Further, it is preferable to described filter cotton to be synthetic fibers filter cotton, non-woven fabrics filter cotton, glass fiber filter cotton or
Activated carbon filter cotton.
Further, described filter cotton can retain the particle diameter material more than 5 μm, and the thickness of filter cotton is 0.3~20mm.
The floccule body that the preferred described method of floating type Coagulation Method of the present invention makes coagulation obtain by stirring or air-blowing method
Float up to waste liquid surface.
Utilization stirring or air-blowing method make waste water form eddy current, and after forming eddy current, floccule body is brought to quilt behind waste liquid surface
Sheet-adhesion, the Organic substance such as float and colloidal attitude in the adsorbable water of floccule body being attached.
The invention have the benefit that
1) in conventional Coagulation Method, floccule body only plays a secondary net and catches adsorption, and the adsorption of floccule body is the most fully sent out
Wave, and floating type Coagulation Method can increase the touch opportunity of floccule body and colloidal attitude;
2) time that floating type Coagulation Method makes water body clarify is shorter than free style sedimentation;
3) can avoid using for the Sedimentation tank separated with waste liquid by floccule body, reduce equipment investment.Filter cotton can be repeatedly
Use, and be convenient for changing.
Detailed description of the invention
Following non-limiting example can make those of ordinary skill in the art that the present invention be more fully understood, but not with
Any mode limits the present invention.
Test method described in following embodiment, if no special instructions, is conventional method;Described reagent and material, as
Without specified otherwise, the most commercially obtain.
NACF filter cotton described in following embodiment is purchased from air filting material company limited of Guangzhou HTC, commodity
Model hd-6.
Glass fiber filter cotton described in following embodiment is purchased from air filting material company limited of Guangzhou HTC, commodity-type
Number hd-4.
Synthetic fibers filter cotton described in following embodiment is purchased from Shanghai Bie Zhong Industrial Co., Ltd., marque BZ004.
Embodiment 1
Taking the Liaohe Oil Field oil extraction waste water 500mL that COD is 620mg/L, adjusting pH is 7.0, adds 0.3g polyaluminium sulfate and mixes
Close uniformly, after having floccule body to generate, add hd-6 NACF filter cotton and be suspended in the water surface, turn on agitator, water body after 10min
Being become clarification by muddiness, it is 181.6mg/L that COD is surveyed in 40min sampling.
Being not added with filter cotton, with allowing the method for floccule body free settling, after 40min, water sample is clarified, and sampling is surveyed COD and is
197.3mg/L。
Embodiment 2
Taking the Liaohe Oil Field oil extraction waste water 500mL that COD is 620mg/L, adjusting pH is 7.0, adds the mixing of 0.4g iron sulfate all
Even, after having floccule body to generate, add hd-6 NACF filter cotton and be suspended in the water surface, turn on agitator, after 10min, water body is by muddy
Turbid change is clarified, and it is 225.4mg/L that COD is surveyed in 40min sampling.
Being not added with filter cotton, with allowing the method for floccule body free settling, after 40min, water sample is clarified, and sampling is surveyed COD and is
252.2mg/L。
Embodiment 3
Taking the Liaohe Oil Field oil extraction waste water 500mL that COD is 630mg/L, adjusting pH is 7.0, adds 0.3g polyaluminium sulfate and mixes
Close uniformly, after having floccule body to generate, add hd-4 glass fiber filter cotton and be suspended in the water surface, turn on agitator, after 10min water body by
Muddy change is clarified, and it is 196.2mg/L that COD is surveyed in 40min sampling.
Being not added with filter cotton, with allowing the method for floccule body free settling, after 40min, water sample is clarified, and sampling is surveyed COD and is
200.9mg/L。
Embodiment 4
Taking the Liaohe Oil Field oil extraction waste water 500mL that COD is 600mg/L, adjusting pH is 7.0, adds 0.3g polyaluminium sulfate and mixes
Close uniformly, after having floccule body to generate, add BZ004 synthetic fibers filter cotton and be suspended in the water surface, turn on agitator, water body after 10min
Being become clarification by muddiness, it is 180.2mg/L that COD is surveyed in 40min sampling.
Being not added with filter cotton, with allowing the method for floccule body free settling, after 40min, water sample is clarified, and sampling is surveyed COD and is
184.7mg/L。
Claims (5)
1. the method utilizing floating type Coagulation with Treatment waste liquid, is the method utilizing Coagulation with Treatment waste liquid, it is characterised in that:
During disposing waste liquid, the floccule body making coagulation obtain floats up to waste liquid surface, and recycling is arranged at having of waste liquid surface
The sheet material floccule body of adsorption-flocculation body function.
Method the most according to claim 1, it is characterised in that there is the sheet material of adsorption-flocculation body function for filtering described in:
Cotton.
Method the most according to claim 1, it is characterised in that: described filter cotton is synthetic fibers filter cotton, non-woven fabrics mistake
Filter pulp, glass fiber filter cotton or activated carbon filter cotton.
Method the most according to claim 3, it is characterised in that: described filter cotton can retain the particle diameter material more than 5 μm, mistake
The thickness of filter pulp is 0.3~20mm.
Method the most according to claim 1, it is characterised in that: described method makes coagulation obtain by stirring or air-blowing method
Floccule body floats up to waste liquid surface.
Priority Applications (1)
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CN201610546434.0A CN106045117A (en) | 2016-07-12 | 2016-07-12 | Method for treating waste liquor with floating coagulation method |
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CN201610546434.0A CN106045117A (en) | 2016-07-12 | 2016-07-12 | Method for treating waste liquor with floating coagulation method |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111847713A (en) * | 2020-07-16 | 2020-10-30 | 大连海事大学 | Method for treating wastewater by combining floating coagulation and active carbon |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1962493A (en) * | 2005-11-08 | 2007-05-16 | 栗田工业株式会社 | Drainage processing device and drainage processing method |
CN101786751A (en) * | 2010-03-05 | 2010-07-28 | 泉州师范学院 | Emergency repair process for treating pollution of natural water body emulsified oil |
RU2011117864A (en) * | 2011-05-03 | 2012-11-10 | Государственное образовательное учреждение высшего профессионального образования "Сургутский государственный университет Ханты-Ман | GALVANOFLOTOAGULATOR |
CN104418450A (en) * | 2013-08-23 | 2015-03-18 | 山东拓普石油装备有限公司 | Fracturing flowback fluid recovery treatment reusing process method |
-
2016
- 2016-07-12 CN CN201610546434.0A patent/CN106045117A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1962493A (en) * | 2005-11-08 | 2007-05-16 | 栗田工业株式会社 | Drainage processing device and drainage processing method |
CN101786751A (en) * | 2010-03-05 | 2010-07-28 | 泉州师范学院 | Emergency repair process for treating pollution of natural water body emulsified oil |
RU2011117864A (en) * | 2011-05-03 | 2012-11-10 | Государственное образовательное учреждение высшего профессионального образования "Сургутский государственный университет Ханты-Ман | GALVANOFLOTOAGULATOR |
CN104418450A (en) * | 2013-08-23 | 2015-03-18 | 山东拓普石油装备有限公司 | Fracturing flowback fluid recovery treatment reusing process method |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111847713A (en) * | 2020-07-16 | 2020-10-30 | 大连海事大学 | Method for treating wastewater by combining floating coagulation and active carbon |
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Application publication date: 20161026 |