CN106041047A - Powder metallurgy high-strength bearing material and preparation method thereof - Google Patents

Powder metallurgy high-strength bearing material and preparation method thereof Download PDF

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Publication number
CN106041047A
CN106041047A CN201610387274.XA CN201610387274A CN106041047A CN 106041047 A CN106041047 A CN 106041047A CN 201610387274 A CN201610387274 A CN 201610387274A CN 106041047 A CN106041047 A CN 106041047A
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Prior art keywords
powder
parts
bearing material
mixed
preparation
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Pending
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CN201610387274.XA
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Chinese (zh)
Inventor
郑之松
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HEFEI ZHENGHAO MACHINERY TECHNOLOGY CO LTD
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HEFEI ZHENGHAO MACHINERY TECHNOLOGY CO LTD
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Priority to CN201610387274.XA priority Critical patent/CN106041047A/en
Publication of CN106041047A publication Critical patent/CN106041047A/en
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    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02Compacting only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/1003Use of special medium during sintering, e.g. sintering aid
    • B22F3/1007Atmosphere
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/05Mixtures of metal powder with non-metallic powder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/001Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0084Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ carbon or graphite as the main non-metallic constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a powder metallurgy high-strength bearing material and a preparation method thereof. The powder metallurgy high-strength bearing material is prepared from the following raw materials of, by weight, 85-90 parts of aluminum, 5-8 parts of iron, 3-4 parts of copper, 1-2 parts of silicon, 0.5-1 parts of magnesium, 3-4 parts of polytetrafluoroethylene powder, 0.8-1.5 parts of molybdenum disulfide, 2-3 parts of stearic acid, 0.6-1 part of methyl cellulose, 1-1.5 parts of graphite, 1-2 parts of pine sawdust, 0.3-0.4 part of yttrium oxide, 0.8-1.5 parts of carbon microspheres and an appropriate amount of oleic acid. The bearing material prepared through the preparation method has the characteristics such as smaller particle size, uniform distribution, high hardness, high flexure strength, high fracture toughness and good high-low-temperature stability, and is worth popularizing.

Description

A kind of powder metallurgy high rigidity bearing material and preparation method thereof
Technical field
The present invention relates to powder metallurgical technology, particularly relate to a kind of powder metallurgy high rigidity bearing material and preparation thereof Method.
Background technology
Metal sintering oiliness bearing, is using metal dust as raw material, the class sintering material made with powder metallurgical technique Material.Metal sintering oily preparation inherently porous, and there is the quantity in the most freely adjustable space, size And the advantage of distribution.Sintering metal oiliness bearing has been widely used in automobile, household electrical appliances, Transport Machinery, agricultural machinery, instrument instrument The various fields such as table.The sintering metal oiliness bearing that modern industry mainly uses can be divided into cuprio, iron-based, copper ferrum by matrix material Base etc..Aluminum is to be distributed one of widest element in the earth's crust, and the content in the earth's crust is only second to oxygen and silicon, occupies the 3rd.At gold Belonging in kind, aluminum is the big metal of Equations of The Second Kind being only second to iron and steel.Aluminum is a kind of wide variety of industrial materials, and fine aluminium is the softest, by force Spend the highest, have good ductility, after adding the element such as copper, silicon in aluminum, it is possible to effectively improve its mechanical property.Aluminum base Sliding bearing is little due to its density, and intensity is high, and rotproofness is good, and low cost and other advantages, is allowed in some antifriction field, its performance More excellent than copper-based bearings material.Although aluminum-based bearing material has a lot of excellent performance, but is as aluminum-based powder smelting Gold utensil has the limitation of self, also has the biggest gap from reality application, and due to the problem in manufacturing process, the quality of burned product is also Have much room for improvement, need to improve performance large-scale production further and expand its range of application.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of powder metallurgy high rigidity bearing material and Its preparation method.
The present invention is achieved by the following technical solutions:
A kind of powder metallurgy high rigidity bearing material and preparation method thereof, is prepared by the raw materials in: aluminum 85- 90, ferrum 5-8, copper 3-4, silicon 1-2, magnesium 0.5-1, polytetrafluoroethylene powder 3-4, molybdenum bisuphide 0.8-1.5, stearic acid 2-3, methyl fibre Dimension element 0.6-1, graphite 1-1.5, pine sawdust 1-2, yittrium oxide 0.3-0.4, carbon microspheres 0.8-1.5, oleic acid are appropriate;
Described a kind of powder metallurgy high rigidity bearing material and preparation method thereof, is made up of step in detail below:
(1) aluminum, ferrum, copper, magnesium and silica flour are poured ground and mixed in mortar into uniform, then this mixed-powder is added to ball milling In machine, adding appropriate ethanol and carry out wet ball grinding, ball milling speed is 20 revolutions per seconds, is added to by mixed powder after ball milling 1-1.5h Place standby after vacuum drying oven is dried at 70 DEG C;
(2) oleic acid and graphite mixing are added to ultrasonic disperse in ultrasonic wave concussion device uniform, add prepared by step (1) Mixed-powder supersound process 30-45min, standby after ultrasonic end solid-liquid separation;
(3) polytetrafluoroethylene powder is put in blender and mix 5-10min under 11000 revs/min, add molybdenum bisuphide Continue mixing 10-15min, the powder of mix homogeneously is placed in thermostatic drying chamber drying for standby at 80 DEG C;
(4) by stearic acid and methylcellulose Hybrid Heating, step (3) and remaining remaining material mix and blend are added Uniformly, make granule, then be added in batch mixer mix homogeneously by the mixed-powder that this granule is prepared with step (2);
(5) mixed-powder prepared by step (4) is put in mould, to press under the pressure of 200-300Mpa in hydraulic press Making type, it is thus achieved that green compact, sent in vacuum sintering furnace by the green compact after molding and be sintered, agglomerating chamber's vacuum is 1.0 × 10-2- 1.0 × 10-3Pa, sintering temperature heats up with the speed of 10 DEG C/min, reaches insulation 4-5 hour when 550-650 DEG C, afterwards Cool to room temperature with the furnace;
(6) blank prepared by step (5) carries out surfacing, deburring processes, and then immersion oil i.e. can get bearing material Material.
The invention have the advantage that the present invention uses aluminium powder as matrix, add ferrum, copper, magnesium and silicon and improve the strong of aluminum base Degree, relative density, porosity, crushing strength and the effect of reduction sintering temperature, the plasticity of aluminum is high, is easily bonded on mould, Causing demoulding difficulty, the present invention utilizes oleic acid and graphite to be mixed to form good adsorption and is coated on metal-powder surface, energy Enough improve the problem that powder body easily adheres to, also use the mixture of politef and molybdenum bisuphide to make granule and metal powder mixing Sintering, is greatly enhanced the self-lubricity of aluminum-based bearing, reduces contractility, controls pore size and the uniformity of matrix, adds Yittrium oxide, pine sawdust and carbon microspheres can be greatly improved the anti-corrosive properties of alumina-base material, hardness, hole and wearability, the present invention Preparation bearing material have granularity tiny and be evenly distributed, high rigidity, high-flexural strength, high-fracture toughness, good height The features such as temperature stability, are worthy to be popularized.
Detailed description of the invention
A kind of powder metallurgy high rigidity bearing material and preparation method thereof, is made up of the raw material of following weight portion (kilogram): Aluminum 85, ferrum 5, copper 3, silicon 1, magnesium 0.5, polytetrafluoroethylene powder 3, molybdenum bisuphide 0.8, stearic acid 2, methylcellulose 0.6, graphite 1, Pine sawdust 1, yittrium oxide 0.3, carbon microspheres 0.8, oleic acid are appropriate;
Described a kind of powder metallurgy high rigidity bearing material and preparation method thereof, is made up of step in detail below:
(1) aluminum, ferrum, copper, magnesium and silica flour are poured ground and mixed in mortar into uniform, then this mixed-powder is added to ball mill In, adding appropriate ethanol and carry out wet ball grinding, ball milling speed is 20 revolutions per seconds, after ball milling 1h, mixed powder is added to vacuum and does Place standby after dry case is dried at 70 DEG C;
(2) oleic acid and graphite mixing are added to ultrasonic disperse in ultrasonic wave concussion device uniform, add prepared by step (1) Mixed-powder supersound process 30min, standby after ultrasonic end solid-liquid separation;
(3) polytetrafluoroethylene powder is put in blender and mix 5min under 11000 revs/min, add molybdenum bisuphide and continue Continuous mixing 10min, is placed in thermostatic drying chamber drying for standby at 80 DEG C by the powder of mix homogeneously;
(4) by stearic acid and methylcellulose Hybrid Heating, step (3) and remaining remaining material mix and blend are added Uniformly, make granule, then be added in batch mixer mix homogeneously by the mixed-powder that this granule is prepared with step (2);
(5) mixed-powder prepared by step (4) is put in mould, to be pressed under the pressure of 200Mpa in hydraulic press Green compact after molding are sent in vacuum sintering furnace and are sintered by type, it is thus achieved that green compact, and agglomerating chamber's vacuum is 1.0 × 10 × 10Pa, Sintering temperature heats up with the speed of 10 DEG C/min, reaches insulation 4 hours when 550 DEG C, cools to room temperature afterwards with the furnace;
(6) blank prepared by step (5) carries out surfacing, deburring processes, and then immersion oil i.e. can get bearing material Material.
Preparing volume aluminum-based bearing material according to embodiment, it is carried out performance test, result is as follows:
Vickers hardness: 42, crushing strength: 187Mpa, tensile strength: 116Mpa, oil content capacity: 20%.

Claims (2)

1. powder metallurgy high rigidity bearing material and preparation method thereof, it is characterised in that by the raw material system of following weight portion Become: aluminum 85-90, ferrum 5-8, copper 3-4, silicon 1-2, magnesium 0.5-1, polytetrafluoroethylene powder 3-4, molybdenum bisuphide 0.8-1.5, stearic acid 2- 3, methylcellulose 0.6-1, graphite 1-1.5, pine sawdust 1-2, yittrium oxide 0.3-0.4, carbon microspheres 0.8-1.5, oleic acid are appropriate.
A kind of powder metallurgy high rigidity bearing material and preparation method thereof, it is characterised in that by with Lower concrete steps are made:
(1) aluminum, ferrum, copper, magnesium and silica flour are poured ground and mixed in mortar into uniform, then this mixed-powder are added in ball mill, Adding appropriate ethanol and carry out wet ball grinding, ball milling speed is 20 revolutions per seconds, after ball milling 1-1.5h, mixed powder is added to vacuum and does Place standby after dry case is dried under 70 ° of C;
(2) oleic acid and graphite mixing are added to ultrasonic disperse in ultrasonic wave concussion device uniform, add mixing prepared by step (1) Powder ultrasonic processes 30-45min, standby after ultrasonic end solid-liquid separation;
(3) polytetrafluoroethylene powder is put in blender and mix 5-10min under 11000 revs/min, add molybdenum bisuphide and continue Mixing 10-15min, is placed in thermostatic drying chamber drying for standby under 80 ° of C by the powder of mix homogeneously;
(4) by stearic acid and methylcellulose Hybrid Heating, add step (3) and remaining remaining material mix and blend is equal Even, make granule, then be added in batch mixer mix homogeneously by the mixed-powder that this granule is prepared with step (2);
(5) mixed-powder prepared by step (4) is put in mould, to be pressed under the pressure of 200-300Mpa in hydraulic press Green compact after molding are sent in vacuum sintering furnace and are sintered by type, it is thus achieved that green compact, and agglomerating chamber's vacuum is 1.0 × 10-2-1.0 × 10-3Pa, sintering temperature heats up with the speed of 10 ° of C/min, reaches insulation 4-5 hour during 550-650 ° of C, afterwards with stove It is cooled to room temperature;
(6) blank prepared by step (5) carries out surfacing, deburring processes, and then immersion oil i.e. can get bearing material.
CN201610387274.XA 2016-05-31 2016-05-31 Powder metallurgy high-strength bearing material and preparation method thereof Pending CN106041047A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106521290A (en) * 2016-12-23 2017-03-22 南京信息工程大学 Corrosion-resistant alloy material and purpose for preparing salted egg cleaning machine
CN106636969A (en) * 2016-11-16 2017-05-10 马鞍山市恒欣减压器制造有限公司 High-hardness iron-based powder metallurgy self-lubricating CNG engine valve seat ring and manufacturing method thereof
CN106777807A (en) * 2017-01-13 2017-05-31 北京航空航天大学 A kind of random size distribution 3D finite element modelings of powder metallurgy and emulation mode
CN108315615A (en) * 2018-03-27 2018-07-24 中南大学 A kind of rare earth oxide strengthens powder metallurgy Al-Cu-Mg alloy and preparation method thereof
CN113305290A (en) * 2021-05-27 2021-08-27 海安县鹰球粉末冶金有限公司 Manufacturing method of aluminum-based powder metallurgy high-precision oil-retaining bearing

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CN104439250A (en) * 2014-12-31 2015-03-25 扬州立德粉末冶金股份有限公司 Method for manufacturing dispersion strengthening copper-based oil bearing
CN105256186A (en) * 2015-11-16 2016-01-20 利辛县江淮扬天汽车有限公司 Powder metallurgy bearing material and preparation method thereof
CN105328180A (en) * 2015-11-16 2016-02-17 利辛县江淮扬天汽车有限公司 High-strength wear-resisting aluminum-based powder metallurgy bearing material
CN105369091A (en) * 2015-11-16 2016-03-02 利辛县江淮扬天汽车有限公司 Aluminum-based composite bearing material high in high-resistance-stability
CN105400978A (en) * 2015-11-16 2016-03-16 利辛县江淮扬天汽车有限公司 Wide-adaptability double-mechanism self-lubricating bearing material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104439250A (en) * 2014-12-31 2015-03-25 扬州立德粉末冶金股份有限公司 Method for manufacturing dispersion strengthening copper-based oil bearing
CN105256186A (en) * 2015-11-16 2016-01-20 利辛县江淮扬天汽车有限公司 Powder metallurgy bearing material and preparation method thereof
CN105328180A (en) * 2015-11-16 2016-02-17 利辛县江淮扬天汽车有限公司 High-strength wear-resisting aluminum-based powder metallurgy bearing material
CN105369091A (en) * 2015-11-16 2016-03-02 利辛县江淮扬天汽车有限公司 Aluminum-based composite bearing material high in high-resistance-stability
CN105400978A (en) * 2015-11-16 2016-03-16 利辛县江淮扬天汽车有限公司 Wide-adaptability double-mechanism self-lubricating bearing material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106636969A (en) * 2016-11-16 2017-05-10 马鞍山市恒欣减压器制造有限公司 High-hardness iron-based powder metallurgy self-lubricating CNG engine valve seat ring and manufacturing method thereof
CN106521290A (en) * 2016-12-23 2017-03-22 南京信息工程大学 Corrosion-resistant alloy material and purpose for preparing salted egg cleaning machine
CN106521290B (en) * 2016-12-23 2018-03-09 南京信息工程大学 A kind of anti-corrosive alloy material, preparation method and the purposes for preparing salted egg's cleaning machine
CN106777807A (en) * 2017-01-13 2017-05-31 北京航空航天大学 A kind of random size distribution 3D finite element modelings of powder metallurgy and emulation mode
CN106777807B (en) * 2017-01-13 2020-09-25 北京航空航天大学 Powder metallurgy random particle size distribution 3D finite element modeling and simulation method
CN108315615A (en) * 2018-03-27 2018-07-24 中南大学 A kind of rare earth oxide strengthens powder metallurgy Al-Cu-Mg alloy and preparation method thereof
CN108315615B (en) * 2018-03-27 2019-12-24 中南大学 Rare earth element oxide reinforced powder metallurgy Al-Cu-Mg alloy and preparation method thereof
CN113305290A (en) * 2021-05-27 2021-08-27 海安县鹰球粉末冶金有限公司 Manufacturing method of aluminum-based powder metallurgy high-precision oil-retaining bearing
CN113305290B (en) * 2021-05-27 2023-01-24 海安县鹰球粉末冶金有限公司 Manufacturing method of aluminum-based powder metallurgy high-precision oil-retaining bearing

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Application publication date: 20161026