A kind of high-strength high temperature-resistant 3D printing clay green-sand material and preparation method thereof
Invention field
The present invention relates to a kind of molding sand, concretely relate to a kind of high-strength high temperature-resistant 3D printing clay green-sand material
And preparation method thereof.
Background technology
Molding sand is used for the material of moulding in 3D printing.Molding sand is generally by Foundry sand, moulding sand binder and additional thing
Equal Modeling Materials mix according to a certain percentage.Molding sand is different by binder used, can be divided into clay-bonded sand, water-glass sand, water
Silt particle, resin sand etc..With the most of clay-bonded sand, water-glass sand and resin sand.Effect of the molding sand in Foundry Production is extremely heavy
It wants, casting wasted product caused by due to the poor quality of molding sand accounts for about the 30-50% of the total waste product of casting.Usually it is to the requirement of molding sand:
With higher intensity and thermal stability, to bear the effect of various external force and high temperature;Good mobility, i.e., molding sand is in external force
Or the ability being mutually shifted between sand grains under gravity itself;Certain plasticity, i.e. molding sand deform under external force, when outer
The ability of shape to be administered can be kept after power removal;Preferable gas permeability, i.e. molding sand hole penetrate the ability of gas;High bursts
Property, also known as knockability are dissipated, i.e., whether molding sand is easily destroyed after casting solidification, if be easy the performance removed from casting.
Green casting method has many advantages:Without drying, drying equipment and fuel can be saved, extends sandbox and molding sand
Service life, improve worker's working condition, process is simple, and productivity is high, with short production cycle, is convenient for tissue Production line, easily
In the mechanical chemical combination automation for realizing production process.Therefore, green casting is used widely in cast steel.Although wet type with it is dry
Type, which is compared, to be had many advantages, such as, but it does not pass through drying and processing, therefore, when high-temperature molten steel pours fashionable, the interface of metal and wet type
Action-reaction is more strong, and casting is susceptible to some defects.Such as:The water content of green-sand than dry sand be higher by very much, when
When being up to 1500 DEG C of molten steel with temperature and meeting, moisture evaporation, volume is suddenly swollen, and steel-casting is easily made to generate gas hole defect;Clay-bonded sand
Wet strength it is lower than dry strength, under external force be easy drop, formed sand hole;And the sand grains of running gate system wall is in gold
Belong to and being easy to fall off under the souring of liquid stream, is brought by molten metal and form sand holes in casting.Since green-sand itself exists
Disadvantages described above is novel printed material this requires developing a kind of high-strength high temperature-resistant clay green-sand, is made up to preferable
Using effect, to obtain the higher casting of surface quality.
Invention content
The object of the present invention is to provide a kind of high-strength high temperature-resistant 3D printing clay green-sand materials and preparation method thereof.
In order to achieve the above objectives, the technical solution used in the present invention is:
A kind of high-strength high temperature-resistant 3D printing clay green-sand material, which is characterized in that in parts by weight, by following weight
Raw material is formulated:240-260 parts of kibushi clay, 11-13 parts of bentonite, 20-30 parts of ceramic microspheres, magnesium silicate 20-25
Part, 10-14 parts of Serpenggiante, 12-18 parts of volcanic tuff, 3-4 parts of dead plaster, 5-9 parts of hydroxyapatite crystal whisker, andalusite
15-25 parts, 10-15 parts of nanometer fluorite powder, 10-14 parts of precipitated calcium carbonate, 7-9 parts of expanded graphite, 6-8 parts of sodium metaaluminate, point it is brilliant
8-12 parts of stone, 5-10 parts of Dry Flo PC, 3-5 parts of carboxymethyl cellulose, 2-4 parts of polyethyleneimine, water 10-20
Part.
A kind of preparation method of high-strength high temperature-resistant 3D printing clay green-sand material, it is characterised in that including following step
Suddenly:
(1)Serpenggiante, volcanic tuff, andalusite, spinelle are put into 800-900 DEG C of calcining furnace and calcined 4-5 hours,
Then, it takes out, is ground into 60-80 mesh powder, is then put into togerther with kibushi clay, bentonite, ceramic microspheres, magnesium silicate
In stirred tank under the rotating speed of 200-250r/min dry-mixed 8-10min, obtain premix;
(2)By dead plaster, hydroxyapatite crystal whisker, expanded graphite, sodium metaaluminate, Dry Flo PC,
Carboxymethyl cellulose, polyethyleneimine pour into ball mill after grinding distribution 20-30min, with premix, nanometer fluorite powder, light
Remaining raw material mixing such as matter calcium carbonate, adds water wet mixing 10-15min to get high-strength high temperature-resistant 3D printing clay green-sand
Material.
Beneficial effects of the present invention:
By the present invention in that with raw materials such as ceramic microspheres, nanometer fluorite powder, volcanic tuffs, molding sand is set to have good
Gas permeability, mobility, in combination with use precipitated calcium carbonate and Dry Flo PC make molding sand have good height
Warm collapsibility, with excellent Sand sticking-resistant ability, can adapt to a variety of hardening modes, spinelle, Serpenggiante, the red column of addition
The raw materials such as stone, hydroxyapatite crystal whisker improve the green tensile strength and heat resistance of molding sand, the carboxymethyl cellulose used, poly- second
Alkene imines grinding distribution, increases its plasticity, dispersibility.The green-sand of the present invention has heat-resist, intensity height, gas permeability
The advantages that good, good dispersion, bleb phenomenon is few.
Specific implementation mode
Technical solution of the present invention is further described with reference to specific embodiment.
Embodiment 1:
A kind of high-strength high temperature-resistant 3D printing clay green-sand material, in parts by weight, by the preparation of following weight raw material
At:240 parts of kibushi clay, 11 parts of bentonite, 20 parts of ceramic microspheres, 20 parts of magnesium silicate, 10 parts of Serpenggiante, volcanic tuff
12 parts, 3 parts of dead plaster, 5 parts of hydroxyapatite crystal whisker, 15 10 parts of part, nanometer fluorite powder of andalusite, precipitated calcium carbonate 10
Part, is gathered 7 parts of expanded graphite, 6 parts of sodium metaaluminate, 8 parts of spinelle, 5 parts of Dry Flo PC, 3 parts of carboxymethyl cellulose
2 parts of aziridine, 10 parts of water.
A kind of preparation method of high-strength high temperature-resistant 3D printing clay green-sand material, includes the following steps:
(1)Serpenggiante, volcanic tuff, andalusite, spinelle are put into 800-900 DEG C of calcining furnace and calcined 4-5 hours,
Then, it takes out, is ground into 60-80 mesh powder, is then put into togerther with kibushi clay, bentonite, ceramic microspheres, magnesium silicate
In stirred tank under the rotating speed of 200-250r/min dry-mixed 8-10min, obtain premix;
(2)By dead plaster, hydroxyapatite crystal whisker, expanded graphite, sodium metaaluminate, Dry Flo PC,
Carboxymethyl cellulose, polyethyleneimine pour into ball mill after grinding distribution 20-30min, with premix, nanometer fluorite powder, light
Remaining raw material mixing such as matter calcium carbonate, adds water wet mixing 10-15min to get high-strength high temperature-resistant 3D printing clay green-sand
Material.
Embodiment 2:
A kind of high-strength high temperature-resistant 3D printing clay green-sand material, in parts by weight, by the preparation of following weight raw material
At:250 parts of kibushi clay, 12 parts of bentonite, 25 parts of ceramic microspheres, 22 parts of magnesium silicate, 12 parts of Serpenggiante, volcanic tuff
16 parts, 3.5 parts of dead plaster, 7 parts of hydroxyapatite crystal whisker, 20 12 parts of part, nanometer fluorite powder of andalusite, precipitated calcium carbonate 12
Part, 8 parts of expanded graphite, 7 parts of sodium metaaluminate, 10 parts of spinelle, 8 parts of Dry Flo PC, 4 parts of carboxymethyl cellulose,
3 parts of polyethyleneimine, 15 parts of water.
The preparation method is the same as that of Example 1.
Embodiment 3:
A kind of high-strength high temperature-resistant 3D printing clay green-sand material, in parts by weight, by the preparation of following weight raw material
At:260 parts of kibushi clay, 13 parts of bentonite, 30 parts of ceramic microspheres, 25 parts of magnesium silicate, 14 parts of Serpenggiante, volcanic tuff
18 parts, 4 parts of dead plaster, 9 parts of hydroxyapatite crystal whisker, 25 15 parts of part, nanometer fluorite powder of andalusite, precipitated calcium carbonate 14
Part, 9 parts of expanded graphite, 8 parts of sodium metaaluminate, 12 parts of spinelle, 10 parts of Dry Flo PC, 5 parts of carboxymethyl cellulose,
4 parts of polyethyleneimine, 20 parts of water.
The preparation method is the same as that of Example 1.
The performance test results of high-strength high temperature-resistant 3D printing clay green-sand material made from above-described embodiment 1-3 are as follows
Shown in table: