CN106032407A - Flexible transparent electric conduction film coating material doping graphene and white graphene - Google Patents
Flexible transparent electric conduction film coating material doping graphene and white graphene Download PDFInfo
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Abstract
The invention relates to a flexible transparent electric conduction film coating material doping graphene and white graphene, wherein the flexible transparent electric conduction film coating material is used for a liquid coating process. The flexible transparent electric conduction film coating material comprises a PET or composite base material layer, wherein the surface of the PET or composite base material layer is subjected to a corona treatment and is coated with an electric conduction coating material layer, and the electric conduction coating material layer comprises the following raw materials by weight: 20-50% of isopropyl alcohol, 20-50% of n-butanol, 10-20% of ethylene glycol monoethyl ether, 1-5% of acetyl tributyl citrate, 5-10% of an adhesive, 1-5% of sorbitan trioleate, 0.8-5% of ethyl cellulose, 4-10% of 20-30 nanometer silver powder, 15-20% of 100-400 nanometer silver powder, 0.5-5% of a graphene homogeneous solution, and 0.5-5% of a white graphene homogeneous solution. According to the present invention, the electric conduction film material has characteristics of stable electric conduction performance of the formed film surface, low resistivity, high light transmittance, and strong adhesion; and the film material completely utilizes the special performances of the materials such as the graphene and the white graphene, such that the multiple effects of high performance, transparency, electric conduction, heat dissipating, wear resistance and the like are achieved after the film is formed.
Description
Technical field
The present invention relates to flexible transparent conducting film field, it is provided that a kind of doped graphene that can be used for liquid coating processes and the flexible transparent conducting film coating material of white graphite alkene.
Background technology
That be nearly at monopoly position in transparent conductive film market at present is the rare metal oxide ITO (tin indium oxide) using the method for vacuum evaporating to prepare.ITO with the following drawback that:
1, rare metal price rapidly raises up.Due to developing rapidly of flat display products and thin-film solar cells industry, ITO demand grows with each passing day.The essential element indium of ITO is rare metal, and earth reserves are few.In Guo Qujinian, the price of indium quickly goes up, and the reserves verified will be exhausted at coming 10 years.
2, production technology investment is huge, and process is wasted.Traditional ITO uses the method for vacuum sputtering to produce, and invests huge.Production process is wasted the energy and raw material, produces a lot of waste material simultaneously.The recovery of rare metal is refined much more expensive again.
3, ITO is frangible easily broken.In long-time bending, or under frequent click, ITO easily produces local chips.So can cause the insensitive of touch screen, the efficiency of solaode declines.Flexible is the challenge that ITO is maximum, because photovoltaic manufacture has become as the most coilable trend of industry on flexible substrate.
4, coating size limitation.Due to the limitation of production technology, vacuum evaporating method can only do the coating of little area, it is impossible to carries out complete uniform coating over a large area.
Patent of the present invention is adopted new technology, new material, new technique produces high performance white Graphene and Graphene composite Nano conductive film material, wherein involved Graphene (graphene) is a kind of novel charcoal material, and it has the bi-dimensional cellular shape crystal structure tightly packed by monolayer carbon atom.Graphene is unique and perfect structure makes it have the characteristics such as electricity, mechanics, calorifics and the optics of excellence, and Graphene shows huge application potential in terms of flexible transparent conductive film in recent years.
White graphite alkene involved by patent of the present invention, be otherwise known as six side's boron nitrogen, and the unit constituting it have boron and two kinds of nitrogen, and the Graphene constituted with carbon is isoelectronic species.They have six same side's planar structures, therefore have similarity in many physical propertys.Such as, they can bend Guan Bi and be referred to as nanotube, all have the highest thermal conductivity, all have the strongest mechanical performance, all have extremely strong character high temperature resistant, corrosion resistant.But, different from the high conductivity of Graphene, white graphite alkene is good insulant, and its bandwidth is up to 5.5 electron volts.This unique insulating properties of white graphite alkene so that it is in the application aspect of composite film material, become effectively supplementing of Graphene.
Summary of the invention
Present invention aims to defect and the deficiency of conventional fabrication techniques of existing ITO conducting film, it is provided that a kind of novel can be used for doped graphene and the flexible transparent conducting film masking liquid of white graphite alkene that liquid phase coats on a large scale.It is stable that this conducting membrane material has film formation surface electric conductivity, and resistivity is low, and light transmittance is high, the feature that adhesive force is strong, meanwhile, membrane material makes full use of the property of white graphite alkene and grapheme material, it is achieved after film forming, high-performance is transparent, conduct electricity, dispel the heat, the multiple effect such as wear-resisting.
The present invention is achieved through the following technical solutions.
A kind of flexible transparent conducting film coating material of doped graphene and white graphite alkene, including surface through the PET of sided corona treatment or composite base sheet material layers, PET or composite base sheet material layers surface-coated conductive paint, conductive paint includes the raw material of following percentage by weight:
Isopropanol
20～50%
N-butyl alcohol
20～50%
Ethylene glycol monoethyl ether 10～20%
Tributyl 2-acetylcitrate 1～5%
Adhesive
5～10%
Span 85
1～5%
Ethyl cellulose
0.8～5%
20-30 nanometer silver powder 4～10%
100-400 nanometer silver powder 15～20%
Graphene homogeneous phase solution 0.5～5%
White graphite alkene homogeneous phase solution 0.5～5%
Wherein, the base material thickness of described PET or composite base sheet material layers is
50-280 μm, width is
95-1500cm, light transmittance >=92%.Preferably, the thickness of the PET base material of described PET substrate layer is 100-150 μm, and the light transmittance of PET base material is 94 ~ 96%.
Wherein, described cement is organic silicone oil, acrylic acid glue or polyurethane glue, and the viscosity of described cement is 2-5cps, and solid content is less than 65%.Preferably, the viscosity of cement is 3-4 cps, and solid content is 30-40%.
Wherein, described Graphene homogeneous phase solution comprises graphite oxide, graphene-based nano particle and silver ion composite solution, and solid content is less than 30%.
Wherein, described white graphite alkene homogeneous phase solution, include six side's boron-nitrogen nanowire particles, a size of 20-50 nanometer, it is preferable that a size of 30-40 nanometer.
Preferably, a kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20～40%
N-butyl alcohol
20～40%
Ethylene glycol monoethyl ether 10～20%
Tributyl 2-acetylcitrate 2～5%
Adhesive
6～10%
Span 85
3～5%
Ethyl cellulose
1～2%
20-30 nanometer silver powder 5～10%
100-400 nanometer silver powder 12～20%
Graphene homogeneous phase solution 2～5%
White graphite alkene homogeneous phase solution 2～5%
It is highly preferred that a kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
25～40%
N-butyl alcohol
25～40%
Ethylene glycol monoethyl ether 12～20%
Tributyl 2-acetylcitrate 3～4%
Adhesive
6～8%
Span 85
3～4%
Ethyl cellulose
1～1.5%
20-30 nanometer silver powder 5～8%
100-400 nanometer silver powder 16～18%
Graphene homogeneous phase solution 2～5%
White graphite alkene homogeneous phase solution 3～5%.
Accompanying drawing explanation
Comparison diagram before and after the nano silver particles sintering of Fig. 1: the flexible transparent conducting film of a kind of doped graphene and white graphite alkene；
Sectional view after the flexible transparent conducting film film forming of Fig. 2: a kind of doped graphene and white graphite alkene
Detailed description of the invention
Following example are the optimization formulas of the flexible transparent conducting film coating material of a kind of doped graphene and white graphite alkene; these formula are indefiniteness real-time mode; its knowledge is used for illustrating the present invention, and those skilled in the art can be protection scope of the present invention according to the formula that the thinking of the present invention and proportioning of selecting materials filter out completely.
Embodiment 1
A kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20%
N-butyl alcohol
20%
Ethylene glycol monoethyl ether 10%
Tributyl 2-acetylcitrate 5%
Adhesive
5%
Span 85
5%
Ethyl cellulose
1%
20-30 nanometer silver powder 5%
100-400 nanometer silver powder 15%
Graphene homogeneous phase solution 3%
White graphite alkene homogeneous phase solution 5%
(1)
Proportionally weigh the raw material of above-mentioned formula ratio, above-mentioned nanometer silver powder is respectively put into 150 DEG C of baking boxs, places the moisture removed in raw material for 30 minutes in an oven；
(2)
Add load weighted isopropanol, n-butyl alcohol, ethylene glycol monoethyl ether, ethyl cellulose in a reservoir, this mixture is put in special blender with
1000rpm rotating speed stirring 20min,
(3)
In said mixture, be sequentially added into the argentum powder of particle diameter 30 nanometer, the argentum powder of particle diameter 200 nanometer and organic silicone oil, in agitator with
1000rpm rotating speed stirring 30min；
(4)
In said mixture, add Graphene and white graphite alkene homogeneous phase solution, in agitator, stir 30min with 1000rpm rotating speed；
(5)
Adding Span 85 and tributyl 2-acetylcitrate in said mixture, use ultrasound wave mode to disperse, jitter time is 150 minutes, obtains electrically-conducting paint.
The nanometer silver flexible conductive paint that the present invention prepares is particle diameter 200nm, and pH value is 6.4, and solid content is 20%, and density is the colourless transparent liquid of 1.015g/ml.This liquid is put in special liquid phase coating equipment, carries out film, i.e. can get flexible transparent conducting film.
Embodiment 2
A kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20%
N-butyl alcohol
20%
Ethylene glycol monoethyl ether 10%
Tributyl 2-acetylcitrate 5%
Adhesive
5%
Span 85
4.6%
Ethyl cellulose
1.4%
20-30 nanometer silver powder 4.5%
100-400 nanometer silver powder 14.5%
Graphene homogeneous phase solution 2.5%
White graphite alkene homogeneous phase solution 5.5%
(1)
Proportionally weigh the raw material of above-mentioned formula ratio, above-mentioned nanometer silver powder is respectively put into 150 DEG C of baking boxs, places the moisture removed in raw material for 30 minutes in an oven；
(2)
Add load weighted isopropanol, n-butyl alcohol, ethylene glycol monoethyl ether, ethyl cellulose in a reservoir, this mixture is put in special blender with
1000rpm rotating speed stirring 20min,
(3)
In said mixture, be sequentially added into the argentum powder of particle diameter 30 nanometer, the argentum powder of particle diameter 200 nanometer and organic silicone oil, in agitator with
1000rpm rotating speed stirring 30min；
(4)
In said mixture, add Graphene and white graphite alkene homogeneous phase solution, in agitator, stir 30min with 1000rpm rotating speed；
(5)
Adding Span 85 and tributyl 2-acetylcitrate in said mixture, use ultrasound wave mode to disperse, jitter time is 150 minutes, obtains electrically-conducting paint.
The nanometer silver flexible conductive paint that the present invention prepares is particle diameter 190nm, and pH value is 6.5, and solid content is 20%, and density is the colourless transparent liquid of 1.01g/ml.This liquid is put in special liquid phase coating equipment, carries out film, i.e. can get flexible transparent conducting film.
Embodiment 3
A kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20%
N-butyl alcohol
20%
Ethylene glycol monoethyl ether 10%
Tributyl 2-acetylcitrate 5%
Adhesive
5%
Span 85
4.3%
Ethyl cellulose
1.7%
20-30 nanometer silver powder 6%
100-400 nanometer silver powder 16%
Graphene homogeneous phase solution 1%
White graphite alkene homogeneous phase solution 1%
(1)
Proportionally weigh the raw material of above-mentioned formula ratio, above-mentioned nanometer silver powder is respectively put into 150 DEG C of baking boxs, places the moisture removed in raw material for 30 minutes in an oven；
(2)
Add load weighted isopropanol, n-butyl alcohol, ethylene glycol monoethyl ether, ethyl cellulose in a reservoir, this mixture is put in special blender with
1000rpm rotating speed stirring 20min,
(3)
In said mixture, be sequentially added into the argentum powder of particle diameter 30 nanometer, the argentum powder of particle diameter 200 nanometer and organic silicone oil, in agitator with
1000rpm rotating speed stirring 30min；
(4)
In said mixture, add Graphene and white graphite alkene homogeneous phase solution, in agitator, stir 30min with 1000rpm rotating speed；
(5)
Adding Span 85 and tributyl 2-acetylcitrate in said mixture, use ultrasound wave mode to disperse, jitter time is 150 minutes, obtains electrically-conducting paint.
The nanometer silver flexible conductive paint that the present invention prepares is particle diameter 250nm, and pH value is 6.8, and solid content is 20%, and density is the colourless transparent liquid of 1.02g/ml.This liquid is put in special liquid phase coating equipment, carries out film, i.e. can get flexible transparent conducting film.
Embodiment 4
A kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20%
N-butyl alcohol
20%
Ethylene glycol monoethyl ether 10%
Tributyl 2-acetylcitrate 5%
Adhesive
5%
Span 85
4%
Ethyl cellulose
2%
20-30 nanometer silver powder 6%
100-400 nanometer silver powder 16%
Graphene homogeneous phase solution 0.5%
White graphite alkene homogeneous phase solution 1.5%
(1)
Proportionally weigh the raw material of above-mentioned formula ratio, above-mentioned nanometer silver powder is respectively put into 150 DEG C of baking boxs, places the moisture removed in raw material for 30 minutes in an oven；
(2)
Add load weighted isopropanol, n-butyl alcohol, ethylene glycol monoethyl ether, ethyl cellulose in a reservoir, this mixture is put in special blender with
1000rpm rotating speed stirring 20min,
(3)
In said mixture, be sequentially added into the argentum powder of particle diameter 30 nanometer, the argentum powder of particle diameter 200 nanometer and organic silicone oil, in agitator with
1000rpm rotating speed stirring 30min；
(4)
In said mixture, add Graphene and white graphite alkene homogeneous phase solution, in agitator, stir 30min with 1000rpm rotating speed；
(5)
Adding Span 85 and tributyl 2-acetylcitrate in said mixture, use ultrasound wave mode to disperse, jitter time is 150 minutes, obtains electrically-conducting paint.
The nanometer silver flexible conductive paint that the present invention prepares is particle diameter 210nm, and pH value is 6.5, and solid content is 20%, and density is the colourless transparent liquid of 0.995g/ml.This liquid is put in special liquid phase coating equipment, carries out film, i.e. can get flexible transparent conducting film.
Embodiment 5
A kind of doped graphene and the flexible transparent conducting film of white graphite alkene, described conductive paint includes the raw material of following percentage by weight:
Isopropanol
20%
N-butyl alcohol
20%
Ethylene glycol monoethyl ether 10%
Tributyl 2-acetylcitrate 5%
Adhesive
5%
Span 85
1%
Ethyl cellulose
1%
20-30 nanometer silver powder 5%
100-400 nanometer silver powder 14%
Graphene homogeneous phase solution 4%
White graphite alkene homogeneous phase solution 5%
(1)
Proportionally weigh the raw material of above-mentioned formula ratio, above-mentioned nanometer silver powder is respectively put into 150 DEG C of baking boxs, places the moisture removed in raw material for 30 minutes in an oven；
(2)
Add load weighted isopropanol, n-butyl alcohol, ethylene glycol monoethyl ether, ethyl cellulose in a reservoir, this mixture is put in special blender with
1000rpm rotating speed stirring 20min,
(3)
In said mixture, be sequentially added into the argentum powder of particle diameter 30 nanometer, the argentum powder of particle diameter 200 nanometer and organic silicone oil, in agitator with
1000rpm rotating speed stirring 30min；
(4)
In said mixture, add Graphene and white graphite alkene homogeneous phase solution, in agitator, stir 30min with 1000rpm rotating speed；
(5)
Adding Span 85 and tributyl 2-acetylcitrate in said mixture, use ultrasound wave mode to disperse, jitter time is 150 minutes, obtains electrically-conducting paint.
The nanometer silver flexible conductive paint that the present invention prepares is particle diameter 230nm, and pH value is 7, and solid content is 20%, and density is the colourless transparent liquid of 1.018g/ml.This liquid is put in special liquid phase coating equipment, carries out film, i.e. can get flexible transparent conducting film.
According to the transparent flexible conducting film obtained by embodiment 1-5,750 grams of pencil hardness >=2H, adhesive force >=4B, sheet resistance are 0.1 Ω/, percent thermal shrinkage MD≤0.8%, TD≤0.8%, light transmittance >=92%.
The above embodiment, the simply better embodiment of the present invention, not limit the scope of the present invention, therefore all equivalences done according to the structure described in scope of the present invention patent, feature and principle change or modify, in the range of all should including present patent application.
Claims (6)
1. a flexible transparent conducting film coating material for doped graphene and white graphite alkene, its feature includes that surface is through the PET of sided corona treatment or composite base sheet material layers, PET or the conductive paint of composite base sheet material layers surface-coated.
2., according to right 1 PET to be stated or composite base sheet material layers, its base material thickness is 50-280 μm, and width is 95-1500cm, light transmittance >=92%；Preferably, the thickness of the PET base material of described PET substrate layer is 100-150 μm, and the light transmittance of PET base material is 94 ~ 96%.
3. according to the conductive coating materials described in right 1, raw material including following percentage by weight: isopropanol 20～50%, n-butyl alcohol 20～50%, ethylene glycol monoethyl ether 10～20%, tributyl 2-acetylcitrate 1～5%, adhesive 5～10%, Span 851～5%, ethyl cellulose 0.8～5%, 20-30 nanometer silver powder 4～10%, 100-400 nanometer silver powder 15～20%, Graphene homogeneous phase solution 0.5～5%, white graphite alkene homogeneous phase solution 0.5～5%.
4. being organic silicone oil, acrylic acid glue or polyurethane glue according to the cement described in right 3, the viscosity of described cement is 2-5cps, and solid content is less than 65%；Preferably, the viscosity of cement is 3-4 cps, and solid content is 30-40%.
5. comprising graphite oxide, graphene-based nano particle and silver ion composite solution according to the Graphene homogeneous phase solution described in right 3, solid content is less than 30%.
6. the white graphite alkene homogeneous phase solution described in, includes six side's boron-nitrogen nanowire particles, a size of 20-50 nanometer, it is preferable that a size of 30-40 nanometer.
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| CN106998598A (en) * | 2017-05-18 | 2017-08-01 | 韩恺 | A kind of intelligent heating body, its preparation method and application |
| CN107248421A (en) * | 2017-06-09 | 2017-10-13 | 江苏东昇光伏科技有限公司 | A kind of thin-film solar cells conducting film and preparation method thereof |
| WO2018090407A1 (en) * | 2016-11-17 | 2018-05-24 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy composite anticorrosive coating and preparation method and application of same |
| CN108288666A (en) * | 2018-01-26 | 2018-07-17 | 扬州乾照光电有限公司 | A kind of light emitting diode and electronic equipment of included radiator structure |
| CN109087723A (en) * | 2018-07-01 | 2018-12-25 | 长沙新材料产业研究院有限公司 | A kind of gold electrocondution slurry and preparation method thereof |
| CN111524447A (en) * | 2016-06-27 | 2020-08-11 | 唯亚威通讯技术有限公司 | Magnetic article |
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| CN111524447A (en) * | 2016-06-27 | 2020-08-11 | 唯亚威通讯技术有限公司 | Magnetic article |
| US11214689B2 (en) | 2016-06-27 | 2022-01-04 | Viavi Solutions Inc. | High chroma flakes |
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| WO2018090407A1 (en) * | 2016-11-17 | 2018-05-24 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy composite anticorrosive coating and preparation method and application of same |
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| CN107248421A (en) * | 2017-06-09 | 2017-10-13 | 江苏东昇光伏科技有限公司 | A kind of thin-film solar cells conducting film and preparation method thereof |
| CN107248421B (en) * | 2017-06-09 | 2018-12-18 | 句容协鑫集成科技有限公司 | A kind of thin-film solar cells conductive film and preparation method thereof |
| CN108288666A (en) * | 2018-01-26 | 2018-07-17 | 扬州乾照光电有限公司 | A kind of light emitting diode and electronic equipment of included radiator structure |
| CN109087723A (en) * | 2018-07-01 | 2018-12-25 | 长沙新材料产业研究院有限公司 | A kind of gold electrocondution slurry and preparation method thereof |
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Application publication date: 20161019 |