CN106025075A - Method for manufacturing high-performance perovskite solar energy cell in humid air - Google Patents
Method for manufacturing high-performance perovskite solar energy cell in humid air Download PDFInfo
- Publication number
- CN106025075A CN106025075A CN201610478846.5A CN201610478846A CN106025075A CN 106025075 A CN106025075 A CN 106025075A CN 201610478846 A CN201610478846 A CN 201610478846A CN 106025075 A CN106025075 A CN 106025075A
- Authority
- CN
- China
- Prior art keywords
- scn
- humid air
- high efficiency
- prepared
- tio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Abstract
The invention discloses a method for manufacturing a high-performance planar structure CH3NH3PbI3-X(SCN)x-based perovskite solar energy cell in the humid air. The method comprises steps that hydrolysis of titanium tetrachloride solution is firstly carried out to acquire TiO2 colloid, the colloid acquired through hydrolysis of the titanium tetrachloride solution is deposited on FTO electro-conductive glass to acquire a TiO2 compact layer, a CH3NH3PbI3-X(SCN)x perovskite layer is prepared on the TiO2 compact layer by employing a two-step solution method, a cavity conduction layer is coated on the perovskite layer in a spinning mode, a Ag electrode is prepared through thermal evaporation, and the perovskite cell is finally acquired. Compared with the prior art, the method is advantaged in that the production process is simple, and cost is low.
Description
Technical field
The invention belongs to area of solar cell, use low temperature solution polycondensation to prepare particularly to one in humid air high efficiency
The method of perovskite solaode (being called for short perovskite battery).
Background technology
In recent years, perovskite solaode receives much attention owing to having higher photoelectric transformation efficiency.Currently, report calcium titanium
Cell Experimentation An high conversion efficiency in ore deposit alreadys more than 20% (Yang W S, Noh J H, Jeon N J, et al.High-performance
photovoltaic perovskite layers fabricated through intramolecular exchange.Science,2015:
aaa9272).But, CH3NH3PbX3(halogen) calcium titanium ore bed poor stability in humid air, needs low lazy of humidity
Prepared by property gaseous environment, and inert atmosphere glove box group is expensive.And if directly perovskite can be prepared in malaria
Solaode, is possible not only to reduce the cost of battery, and easy to operate in preparation process.
Thiocyanate (SCN) is the class halide ion of a kind of stable performance, ionic radius and I-Close, chemical characteristic and halogen from
Son is similar, and SCN-Pb effect is more higher than I-Pb effect, therefore CH3NH3PbI3-x(SCN)xStructure more stable (Q.Jiang, D.
Rebollar,J.Gong,E.L.Piacentino,C.Zheng,T.Xu,Angew.Chem.Int.Ed.,2015,54,7617).Have
Research finds that introducing the group containing SCN in dye molecule can improve the absorption of its light, promote carrier conduction (X.S.Liu, Z.C.
Cao,H.L.Huang,X.X.Liu,Y.Z.Tan,H.J.Chen,Y.Pei and S.T.Tan,J.Power Sources,2014,
248,400).Ye You seminar once attempts using SCN part to replace CH3NH3PbI3I in molecule, discovery can significantly carry
High device preparation repeatability and battery stability in humid air (Y.Chen, B.Li, W.Huang, D.Gao, Z.Liang,
Chem.Commun.,2015,51,11997)。
At present, the TiO that prepared by low temperature solution polycondensation2Planar structure CH3NH3PbI3-x(SCN)xBased perovskite solaode yet there are no
Report.
Summary of the invention
The present invention solves the deficiencies in the prior art, it is provided that one prepares TiO by low temperature solution polycondensation2Compacted zone, and
Prepare CH in atmosphere3NH3PbI3-x(SCN)xCalcium titanium ore bed, thus the method preparing high efficiency perovskite solaode.
The purpose of the present invention is achieved through the following technical solutions:
A kind of method preparing high efficiency perovskite solaode in humid air, comprises the following steps:
(1) hydrolysis titanium tetrachloride solution, obtains TiO2Colloid；
(2) depositing Ti O on FTO (stannum oxide of the doping F) electro-conductive glass of cleaning2TiO prepared by colloid2Compacted zone；
(3) spin coating 0.3～0.6g/ml Pb (SCN) on the sample obtained by step (2)2Methyl sulfoxide solution, at 85-95 DEG C
Pb (SCN) is obtained after lower heat treatment2Film；
(4) at Pb (SCN)2On film, with the aqueous isopropanol of 3000～5000r/min spin coating 10mg/ml iodine methylamines；
(5) step (4) is repeated after 6～10 times, thin film obtained by heat treatment at 75-85 DEG C, obtain
CH3NH3PbI3-x(SCN)xCalcium titanium ore bed；
(6) CH prepared in step (5)3NH3PbI3-x(SCN)xHole-conductive layer is prepared on calcium titanium ore bed；
(7) use thermal evaporation to be deposited with one layer of silver electrode on the sample obtained by step (6), i.e. obtain perovskite solar energy
Battery.
Further, the TiO described in step (1)2Colloid is to add four chlorinations that volume ratio is 1.5-4% in mixture of ice and water
Titanium solution configuration forms.
Further, the TiO described in step (2)2Compacted zone is prepared by following steps: used by the FTO electro-conductive glass of cleaning
After uviol lamp shines 10～30min, put into the TiO that temperature is 65～75 DEG C2Colloid solution soaks 40～70min, takes out afterwards also
After flushing at 180～200 DEG C heat treatment 30～60min, obtain TiO2Compacted zone.
Preferably, the heat treatment time in step (3) is 30～60min.
Preferably, the heat treatment time in step (5) is 10～30min.
Further, the hole-conductive layer described in step (6), prepared by following steps: prepare in step (5)
CH3NH3PbI3-x(SCN)xThe 2,2' of spin coating 0.08M on calcium titanium ore bed, 7,7'-tetra-[N, N-bis-(4-methoxyphenyl) amino]-9,9'-spiral shell
Two fluorenes (spiro-OMeTAD), double trifluoromethanesulfonimide lithium salts (LiTFSI) of 0.064M and 0.064M tetrabutyl pyrrole
Chlorobenzene (TBP) mixed solution of pyridine, the sample obtained places 8～12h in the air that lucifuge is dried.
Preferably, the silver electrode thickness described in step (7) is 80～150nm.
Preferably, the thermal evaporation described in step (7) is carried out in thermal evaporation instrument, and at 6 × 10-6～the gas of 1 × 10-8 millitorr
Pressure, is deposited with the speed of 1～10nm/min.
Compared to prior art, the method preparing high efficiency perovskite solaode in the humid air that the present invention provides, have
Advantages below and beneficial effect:
(1) the method belongs to solwution method, simple to operate, is easily controlled；And the perovskite battery of whole planar structure is all low
The lower preparation of temperature, maximum heat treatment temperature is less than 200 DEG C.
(2)CH3NH3PbI3-x(SCN)xCalcium titanium ore bed is in the air of high humility (humidity more than 70%) of preparation, it is not necessary to
The inert gas environment of low humidity, simple, convenient, it is independent of the glove box group of costliness.
The present invention also provides for a kind of high efficiency perovskite solaode prepared according to above-mentioned preparation method.
Compared to prior art, high efficiency perovskite solaode of the present invention, it is prepared by low temperature solution polycondensation, grasps
Making simple, be easily controlled, cost is relatively low, and the photoelectric transformation efficiency of battery is high.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but the embodiment of invention is not limited to this.
Embodiment 1
In the present embodiment, a kind of method preparing high efficiency perovskite solaode in humid air, comprise the following steps:
(1) in the mixture of ice and water of 200ml, add the titanium tetrachloride solution of 5ml, be configured to TiO2Colloid；
(2), after the FTO electro-conductive glass of cleaning being shone 15min with uviol lamp, the TiO that temperature is 70 DEG C is put into2In colloid solution
Soak 60min, after taking out afterwards and rinsing at 200 DEG C heat treatment 30min, obtain TiO2Compacted zone；
(3) by Pb (SCN)2It is dissolved in methyl sulfoxide, is configured to the solution that concentration is 0.5g/ml, prepare in step (2)
TiO2Spin coating Pb (SCN) on compacted zone2Solution, then at 90 DEG C, heat treatment 30min obtains Pb (SCN)2Film；
(4) at Pb (SCN)2On film, with the aqueous isopropanol of the rotating speed spin coating 10mg/ml iodine methylamine of 3000r/min.
(5) after step (4) being repeated 6 times, thin film 20min obtained by heat treatment at 80 DEG C, obtain
CH3NH3PbI3-x(SCN)xCalcium titanium ore bed；
(6) in the CH prepared by step (5)3NH3PbI3-x(SCN)xThe 2,2' of spin coating 0.08M on calcium titanium ore bed, 7,7'-tetra-[N, N-
Two (4-methoxyphenyl) amino]-9,9'-spiral shell two fluorenes, double trifluoromethanesulfonimide lithium salts of 0.064M and 0.064M tetrabutyl pyrrole
The chlorobenzene mixed solution of pyridine, an evening placed in the air that lucifuge is dried by the sample obtained；
(7) use thermal evaporation to be deposited with silver (Ag) electrode of thick layer 80～150nm on step (6) gained sample, take
Go out the battery of steamed electrode, i.e. obtain perovskite solaode.
Under room temperature environment, use 91159 solar simulators of Newport company, be 100mW/cm in light intensity2Under the conditions of,
Analyzing the battery obtained by test, the effective area of battery is 0.06cm2.Test result display uses method system described in the present embodiment
The cell photoelectric conversion efficiency obtained is 10.12%.
Embodiment 2
In the present embodiment, a kind of method preparing high efficiency perovskite solaode in humid air, comprise the following steps:
(1) in the mixture of ice and water of 200ml, add the titanium tetrachloride solution of 5ml, be configured to TiO2Colloid；
(2), after the FTO electro-conductive glass of cleaning being shone 30min with uviol lamp, the TiO that temperature is 70 DEG C is put into2In colloid solution
Soak 40min, after taking out afterwards and rinsing at 190 DEG C heat treatment 40min, obtain TiO2Compacted zone；
(3) by Pb (SCN)2It is dissolved in methyl sulfoxide, is configured to the solution that concentration is 0.6g/ml, prepare in step (2)
TiO2Spin coating Pb (SCN) on compacted zone2Solution, then at 90 DEG C, heat treatment 60min obtains Pb (SCN)2Film；
(4) at Pb (SCN)2On film, with the aqueous isopropanol of the rotating speed spin coating 10mg/ml iodine methylamine of 4000r/min.
(5) after step (4) being repeated 8 times, thin film 30min obtained by heat treatment at 85 DEG C, obtain
CH3NH3PbI3-x(SCN)xCalcium titanium ore bed；
(6) in the CH prepared by step (5)3NH3PbI3-x(SCN)xThe 2,2' of spin coating 0.08M on calcium titanium ore bed, 7,7'-tetra-[N, N-
Two (4-methoxyphenyl) amino]-9,9'-spiral shell two fluorenes, double trifluoromethanesulfonimide lithium salts of 0.064M and 0.064M tetrabutyl pyrrole
The chlorobenzene mixed solution of pyridine, an evening placed in the air that lucifuge is dried by the sample obtained；
(7) use thermal evaporation to be deposited with silver (Ag) electrode of thick layer 80～150nm on step (6) gained sample, take
Go out the battery of steamed electrode, i.e. obtain perovskite solaode.
Under room temperature environment, use 91159 solar simulators of Newport company, be 100mW/cm in light intensity2Under the conditions of,
Analyzing the battery obtained by test, the effective area of battery is 0.06cm2.Test result display uses method system described in the present embodiment
The cell photoelectric conversion efficiency obtained is 9.02%.
Embodiment 3
In the present embodiment, a kind of method preparing high efficiency perovskite solaode in humid air, comprise the following steps:
(1) in the mixture of ice and water of 200ml, add the titanium tetrachloride solution of 3ml, be configured to TiO2Colloid；
(2), after the FTO electro-conductive glass of cleaning being shone 10min with uviol lamp, the TiO that temperature is 70 DEG C is put into2In colloid solution
Soak 70min, after taking out afterwards and rinsing at 180 DEG C heat treatment 60min, obtain TiO2Compacted zone；
(3) by Pb (SCN)2It is dissolved in methyl sulfoxide, is configured to the solution that concentration is 0.3g/ml, prepare in step (2)
TiO2Spin coating Pb (SCN) on compacted zone2Solution, then at 90 DEG C, heat treatment 60min obtains Pb (SCN)2Film；
(4) at Pb (SCN)2On film, with the aqueous isopropanol of the rotating speed spin coating 10mg/ml iodine methylamine of 5000r/min.
(5) after step (4) being repeated 10 times, thin film 10min obtained by heat treatment at 75 DEG C, obtain
CH3NH3PbI3-x(SCN)xCalcium titanium ore bed；
(6) in the CH prepared by step (5)3NH3PbI3-x(SCN)xThe 2,2' of spin coating 0.08M on calcium titanium ore bed, 7,7'-tetra-[N, N-
Two (4-methoxyphenyl) amino]-9,9'-spiral shell two fluorenes, double trifluoromethanesulfonimide lithium salts of 0.064M and 0.064M tetrabutyl pyrrole
The chlorobenzene mixed solution of pyridine, an evening placed in the air that lucifuge is dried by the sample obtained；
(7) use thermal evaporation to be deposited with silver (Ag) electrode of thick layer 80～150nm on step (6) gained sample, take
Go out the battery of steamed electrode, i.e. obtain perovskite solaode.
Under room temperature environment, use 91159 solar simulators of Newport company, be 100mW/cm in light intensity2Under the conditions of,
Analyzing the battery obtained by test, the effective area of battery is 0.06cm2.Test result display uses method system described in the present embodiment
The cell photoelectric conversion efficiency obtained is 6.74%.
In above-mentioned 3 embodiments, embodiment 1 is most preferred embodiment.
It should be noted that prepared by a kind of humid air of the present invention in the method for high efficiency perovskite solaode,
The temperature of heat treatment is less on prepared battery performance parameter impact, and wherein, in step (3), heat treatment temperature is at 75～95 DEG C of models
Enclose interior effect preferable；Heat treatment temperature in step (5) effect in the range of 75～85 DEG C is preferable.Additionally, in step (2)
TiO2The temperature of colloid solution controls in the range of 65～75 DEG C.Thermal evaporation described in step (7) is in thermal evaporation instrument
Carry out, and under the air pressure of 6 × 10-6～1 × 10-8 millitorr, be deposited with the speed of 1～10nm/min.
The heat treatment temperature of above-mentioned 3 embodiments all selects the parameter of optimum, is only presently preferred embodiments of the present invention, not
The present invention is done any pro forma restriction, those skilled in the art according to present invention select preferably other parameters also up to
To the purpose of the present invention.
The above, be only presently preferred embodiments of the present invention, and the present invention not does any pro forma restriction, thus all not
Depart from technical solution of the present invention content, according to the present invention technical spirit to any simple modification made for any of the above embodiments, etc.
With change and modification, all still fall within the range of technical solution of the present invention.
Claims (9)
1. the method preparing high efficiency perovskite solaode in a humid air, it is characterised in that comprise the following steps:
(1) hydrolysis titanium tetrachloride solution, obtains TiO2Colloid；
(2) depositing Ti O on the FTO electro-conductive glass of cleaning2TiO prepared by colloid2Compacted zone；
(3) spin coating 0.3～0.6g/ml Pb (SCN) on the sample obtained by step (2)2Methyl sulfoxide solution, at 85-95 DEG C
Pb (SCN) is obtained after lower heat treatment2Film；
(4) at Pb (SCN)2On film, with the aqueous isopropanol of 3000～5000r/min spin coating 10mg/ml iodine methylamines；
(5) step (4) is repeated after 6～10 times, thin film obtained by heat treatment at 75-85 DEG C, obtain
CH3NH3PbI3-x(SCN)xCalcium titanium ore bed；
(6) CH prepared in step (5)3NH3PbI3-x(SCN)xHole-conductive layer is prepared on calcium titanium ore bed；
(7) use thermal evaporation to be deposited with one layer of silver electrode on the sample obtained by step (6), i.e. obtain perovskite solar-electricity
Pond.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the TiO described in (1)2Colloid is to add the titanium tetrachloride solution configuration that volume ratio is 1.5-4% in mixture of ice and water to form.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the TiO described in (2)2Compacted zone is prepared by following steps: by the FTO electro-conductive glass of cleaning with uviol lamp according to 10～30min
After, put into the TiO that temperature is 65～75 DEG C2In colloid solution soak 40～70min, after taking out afterwards and rinsing
At 180～200 DEG C, heat treatment 30～60min, obtain TiO2Compacted zone.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the heat treatment time in (3) is 30～60min.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the heat treatment time in (5) is 10～30min.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the hole-conductive layer described in (6), is prepared by following steps: the CH prepared in step (5)3NH3PbI3-x(SCN)x
The 2,2' of spin coating 0.08M, 7,7'-tetra-[N, N-bis-(4-methoxyphenyl) amino]-9 on calcium titanium ore bed, 9'-spiral shell two fluorenes, 0.064M's
Double trifluoromethanesulfonimide lithium salts and the chlorobenzene mixed solution of 0.064M tetrabutyl pyridine, the sample obtained is dried in lucifuge
Air in place 8～12h.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the silver electrode thickness described in (7) is 80～150nm.
The method preparing high efficiency perovskite solaode in humid air the most according to claim 1, it is characterised in that: step
Suddenly the thermal evaporation described in (7) is carried out in thermal evaporation instrument, and 6 × 10-6～1 × 10-8Under the air pressure of millitorr, with
The speed of 1～10nm/min is deposited with.
9. a high efficiency perovskite solaode, it is characterised in that: by the method preparation described in any one of claim 1～8
Become.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610478846.5A CN106025075B (en) | 2016-06-24 | 2016-06-24 | The method of high efficiency perovskite solar battery is prepared in a kind of humid air |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610478846.5A CN106025075B (en) | 2016-06-24 | 2016-06-24 | The method of high efficiency perovskite solar battery is prepared in a kind of humid air |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106025075A true CN106025075A (en) | 2016-10-12 |
| CN106025075B CN106025075B (en) | 2018-12-11 |
Family
ID=57084562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610478846.5A Active CN106025075B (en) | 2016-06-24 | 2016-06-24 | The method of high efficiency perovskite solar battery is prepared in a kind of humid air |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106025075B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106784317A (en) * | 2016-11-29 | 2017-05-31 | 宁波大学 | The manufacture method of the perovskite solar cell of super-thin electronic transmission Rotating fields |
| CN106910828A (en) * | 2017-01-12 | 2017-06-30 | 华南师范大学 | A kind of solar cell with Double Perovskite membrane structure and preparation method thereof |
| CN107146852A (en) * | 2017-04-06 | 2017-09-08 | 华南师范大学 | It is a kind of by being introduced into the method that ammonium salt prepares high efficiency perovskite solar cell in humid air |
| CN107170889A (en) * | 2017-05-04 | 2017-09-15 | 华南师范大学 | It is a kind of by being introduced into the method that alkali metal ion prepares high efficiency perovskite solar cell in humid air |
| CN107706309A (en) * | 2017-09-15 | 2018-02-16 | 华南师范大学 | A kind of preparation method of plane perovskite solar cell |
| CN107799654A (en) * | 2017-09-15 | 2018-03-13 | 华南师范大学 | A kind of high efficiency plane perovskite solar cell and preparation method thereof |
| CN108054284A (en) * | 2017-12-19 | 2018-05-18 | 天津大学 | A kind of preparation method of big crystal grain perovskite thin film |
| CN109638161A (en) * | 2018-12-04 | 2019-04-16 | 储天新能源科技（长春）有限公司 | A kind of preparation method and perovskite solar battery of efficient perovskite solar battery |
| CN111129314A (en) * | 2019-12-30 | 2020-05-08 | 电子科技大学 | Preparation method of perovskite electron transport layer |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101521114A (en) * | 2009-03-31 | 2009-09-02 | 彩虹集团公司 | Preparation method for laminated photo-anode film of dye-sensitized solar cell |
| CN104795501A (en) * | 2015-04-22 | 2015-07-22 | 武汉理工大学 | Perovskite solar cell and method for manufacturing same |
| CN105428542A (en) * | 2015-12-09 | 2016-03-23 | 华南师范大学 | Preparation method of high-efficiency perovskite battery |
| CN105493213A (en) * | 2013-07-01 | 2016-04-13 | 洛桑联邦理工学院 | Solar cell and process for producing the same |
| EP3010054A1 (en) * | 2012-05-18 | 2016-04-20 | Isis Innovation Limited | Optoelectronic device |
| CN107799654A (en) * | 2017-09-15 | 2018-03-13 | 华南师范大学 | A kind of high efficiency plane perovskite solar cell and preparation method thereof |
-
2016
- 2016-06-24 CN CN201610478846.5A patent/CN106025075B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101521114A (en) * | 2009-03-31 | 2009-09-02 | 彩虹集团公司 | Preparation method for laminated photo-anode film of dye-sensitized solar cell |
| EP3010054A1 (en) * | 2012-05-18 | 2016-04-20 | Isis Innovation Limited | Optoelectronic device |
| CN105493213A (en) * | 2013-07-01 | 2016-04-13 | 洛桑联邦理工学院 | Solar cell and process for producing the same |
| CN104795501A (en) * | 2015-04-22 | 2015-07-22 | 武汉理工大学 | Perovskite solar cell and method for manufacturing same |
| CN105428542A (en) * | 2015-12-09 | 2016-03-23 | 华南师范大学 | Preparation method of high-efficiency perovskite battery |
| CN107799654A (en) * | 2017-09-15 | 2018-03-13 | 华南师范大学 | A kind of high efficiency plane perovskite solar cell and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| QINGLONG JIANG等: "Pseudohalide-induced moisture tolerance in perovskite CH3NH3Pb(SCN)2I thin films", 《ANGEWANDTE CHEMIE》 * |
| YANI CHEN等: "Efficient and reproducible CH3NH3PbI3-x(SCN)x perovskite based planar solar cells", 《CHEMICAL COMMUNICATIONS》 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106784317B (en) * | 2016-11-29 | 2019-08-09 | 宁波大学 | The manufacturing method of the perovskite solar battery of super-thin electronic transport layer structure |
| CN106784317A (en) * | 2016-11-29 | 2017-05-31 | 宁波大学 | The manufacture method of the perovskite solar cell of super-thin electronic transmission Rotating fields |
| CN106910828A (en) * | 2017-01-12 | 2017-06-30 | 华南师范大学 | A kind of solar cell with Double Perovskite membrane structure and preparation method thereof |
| CN106910828B (en) * | 2017-01-12 | 2019-10-11 | 华南师范大学 | A kind of solar battery and preparation method thereof with Double Perovskite membrane structure |
| CN107146852A (en) * | 2017-04-06 | 2017-09-08 | 华南师范大学 | It is a kind of by being introduced into the method that ammonium salt prepares high efficiency perovskite solar cell in humid air |
| CN107146852B (en) * | 2017-04-06 | 2020-02-28 | 华南师范大学 | Method for preparing high-efficiency perovskite solar cell in humid air by introducing ammonium salt |
| CN107170889A (en) * | 2017-05-04 | 2017-09-15 | 华南师范大学 | It is a kind of by being introduced into the method that alkali metal ion prepares high efficiency perovskite solar cell in humid air |
| CN107799654A (en) * | 2017-09-15 | 2018-03-13 | 华南师范大学 | A kind of high efficiency plane perovskite solar cell and preparation method thereof |
| CN107706309A (en) * | 2017-09-15 | 2018-02-16 | 华南师范大学 | A kind of preparation method of plane perovskite solar cell |
| CN107706309B (en) * | 2017-09-15 | 2020-05-26 | 华南师范大学 | Preparation method of planar perovskite solar cell |
| CN108054284A (en) * | 2017-12-19 | 2018-05-18 | 天津大学 | A kind of preparation method of big crystal grain perovskite thin film |
| CN109638161A (en) * | 2018-12-04 | 2019-04-16 | 储天新能源科技（长春）有限公司 | A kind of preparation method and perovskite solar battery of efficient perovskite solar battery |
| CN111129314A (en) * | 2019-12-30 | 2020-05-08 | 电子科技大学 | Preparation method of perovskite electron transport layer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106025075B (en) | 2018-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106025075A (en) | Method for manufacturing high-performance perovskite solar energy cell in humid air | |
| CN103700769B (en) | A kind of hybrid perovskite solar cell and preparation method thereof | |
| CN106299136B (en) | A kind of method that room-temperature dissolution lead iodide prepares adulterated with Ca and Ti ore hull cell | |
| CN109888105B (en) | Passivated perovskite solar cell and preparation method thereof | |
| CN106410046B (en) | A kind of perovskite solar battery and preparation method thereof containing hydrophobic electrode decorative layer | |
| CN107240643B (en) | Bromo element adulterates methylamine lead iodine perovskite solar battery and preparation method thereof | |
| CN110350089B (en) | Bi2O2S-modified SnO2Perovskite solar cell of electron transport layer and preparation method | |
| CN105336864B (en) | A kind of perovskite solar battery structure and preparation method thereof | |
| CN108565339B (en) | Perovskite solar cell containing fullerene derivative and preparation method thereof | |
| CN105336862A (en) | Integrated stack double-junction perovskite solar cell and preparation method thereof | |
| CN106025076A (en) | Method for manufacturing SnO2 planar structure high-performance perovskite solar energy cell in humid air | |
| CN105870360B (en) | A kind of perovskite solar cell and preparation method thereof | |
| CN103400697A (en) | All-solid-state flexible sensitized solar cell and preparation method thereof | |
| CN108206094B (en) | Preparation method of cobalt-doped TiO2 nanotube | |
| CN105006524A (en) | Method for preparing perovskite layer of perovskite solar cell by using solid-mist interfacial reaction | |
| CN105140406A (en) | Perovskite solar cell capable of light incoming from double surfaces and fabrication method thereof | |
| CN106098943A (en) | A kind of high stable mixing dimension perovskite material and application | |
| CN105826476B (en) | A kind of preparation method of the perovskite solar cell based on composite hole transporting layer | |
| CN104183704A (en) | Preparation method for quantum dot co-sensitization type perovskite solar cell | |
| CN107146852B (en) | Method for preparing high-efficiency perovskite solar cell in humid air by introducing ammonium salt | |
| CN109103280B (en) | Solar cell with all-inorganic perovskite ferroelectric fiber composite structure and preparation method thereof | |
| CN109755394A (en) | A method of perovskite solar battery is prepared using air knife coating | |
| CN104347275A (en) | All-solid-state sensitized solar cell and preparation method thereof | |
| CN110556479B (en) | Tin dioxide-based mesoporous perovskite solar cell and preparation method thereof | |
| CN111525038B (en) | Perovskite solar cell doped with multifunctional additive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |