CN106012085A - Polylactic acid fiber fabric for automobile seat cushion - Google Patents

Polylactic acid fiber fabric for automobile seat cushion Download PDF

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Publication number
CN106012085A
CN106012085A CN201610598676.4A CN201610598676A CN106012085A CN 106012085 A CN106012085 A CN 106012085A CN 201610598676 A CN201610598676 A CN 201610598676A CN 106012085 A CN106012085 A CN 106012085A
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China
Prior art keywords
polylactic acid
acid fiber
powder
spinning
fabric
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Pending
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CN201610598676.4A
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Chinese (zh)
Inventor
张蒙
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Individual
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Individual
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Priority to CN201610598676.4A priority Critical patent/CN106012085A/en
Publication of CN106012085A publication Critical patent/CN106012085A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/12Stretch-spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D7/00Collecting the newly-spun products
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Woven Fabrics (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

The invention discloses a preparation method of a heat-resistant and flame-retardant polylactic acid fiber fabric for an automobile seat cushion. The method comprises the following steps of (1) preparing raw materials in parts by weight: 80 to 86 parts of PLA polylactic acid, 2 to 3 parts of sisal fiber powder, 0.8 part of bamboo powder, 0.5 to 0.8 part of lupeose, 0.8 part of mica powder and 1 part of CMA flame-retardant agnets; then, adding the materials into a high-speed mixing machine to be uniformly dispersed to obtain modified polylactic acid mixed raw materials; (2) performing melt blending and extrusion on the uniformly mixed polylactic acid mixed raw materials through a double-screw extruding machine to prepare modified polylactic acid master batches; performing vacuum drying; performing spinning on the mixture on a melt spinning machine through round spinning holes to obtain modified polylactic acid fiber, wherein the spinning temperature is 220 DEG C, the winding speed is 1600 m/min, the traction temperature is 85 DEG C, and the traction times is 2.5 times; (3) spinning the modified polylactic acid fiber into an automobile seat cushion fabric.

Description

A kind of automobile cushion polylactic acid fiber fabric
Technical field
The present invention relates to a kind of automobile cushion polylactic acid fiber fabric, belong to field of textiles.
Background technology
The raw materials for production lactic acid of acid fiber by polylactic (PLA) is to prepare from corn starch, so also by this fibre Dimension is referred to as corn fiber, can make through glucose fermentation with garden beet or corn etc., prepares lactic acid with reduction and gathers Fit cost.High score can be obtained by the chemical polymerization of lactic acid Cyclodimerization thing or the direct polymerization of lactic acid The polylactic acid of son amount.The goods obtained for raw material with polylactic acid, have good biocompatibility and biology can Absorbability, and biocidal property, anti-flammability, and in biodegradable thermoplastic polymer material, PLA has Best heat resistance.
Along with the raising of people's living standard, the development of mankind's traffic technique and progress, people are to vehicle Demand and rely on day by day increase.The economic sustained and rapid development of China in Recent Years, promotes China to become the world The automobile production state of upper maximum and country of sale.The quality of inside gadget quality directly influence vehicle comfort level and The safety of occupants.Although up to the present, domestic or even the most unified inside gadget matter Amount requires standard, but this does not hinder increasing country and area pay attention to and pay close attention to the quality of interior material Performance.
Interior material combustion completion performance increasingly comes into one's own, such as horizontal firing performance, vertical burn flammability Energy, molten drop test, smoke density, oxygen index (OI), burning grade separation etc..Wherein combustion completion performance is as weight Wanting index, be particularly subject to the common concern of people, the combustibility method of testing of interior material is the most numerous Country enacts regulation or mandatory standard is enforced.
GB 8,410 2006 " combustion characteristics of automotive interior material " is the mandatory of China's automotive upholstery Standard, it is adaptable to all automotive interior materials.This standard NEQ Federal Motor Vehicle safety post Quasi-FMVSS 571.302.This standard uses so far, has obtained being widely recognized as of car industry, numerous states Producing automobile brand all uses this standard to test the combustibility of interior material, and its horizontal firing test has become The project must examined for domestic automobile inside gadget supply and marketing both sides.It addition, this standard formally became me in 2003 The appointment detection project of first 3C Product certification of state.
In recent years, polylactic acid is due to its excellent biodegradability, abundant source and good machining Performance and paid close attention to widely.At present, as general thermoplastic polyester, polylactic acid Thin film, sheet material, bar etc. can be prepared as under different method for processing forming.Its fiber through thermoforming, In the field also day such as weaving, packaging, agricultural, health care, daily living article after the secondary operations such as spinning Benefit is employed widely.In current plastics industry circle, polylactic acid is referred to as that the most promising " green is moulded Material ".But polylactic acid easily burns, limited oxygen index only has 19%, it is impossible to reach the mark of automotive trim Accurate.
It is desirable to provide the polylactic acid fiber fabric of a kind of heat-proof combustion-resistant, it is especially suitable for automobile cushion and uses.
Summary of the invention
The present invention is directed to shortcoming of the prior art, it is desirable to provide the polylactic acid of a kind of heat-proof combustion-resistant is fine Dimension fabric, is especially suitable for automobile cushion and uses.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 80-86 part;
Sisal fiber powder 2-3 part;
Bamboo powder 0.8 part;
Stachyose 0.5-0.8 part;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
The invention have benefit that:
(1) the modified polylactic acid fiber fabric that the present invention prepares has good heat-proof combustion-resistant effect, additionally There is Yi Shangran, the advantage of good spinnability.
(2) present invention process is simple, it is easy to industrialization operates, and fire retardant has only to use very low amount, just Extraordinary flame retardant effect, energy-conserving and environment-protective can be reached.
Detailed description of the invention
Embodiment 1:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 86 parts;
3 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.5 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 53mm/min, and limited oxygen index is 28%, dye-uptake 95%, washing fastness (AATCC test) Reach 5 grades.
Embodiment 2:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 80 parts;
2 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.8 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 21mm/min, and limited oxygen index is 51%, dye-uptake 89%, washing fastness (AATCC test) Reach 5 grades.
Embodiment 3:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 85 parts;
3 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.6 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 38mm/min, and limited oxygen index is 35%, dye-uptake 90%, washing fastness (AATCC test) Reach 5 grades.
Embodiment 4:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 81 parts;
2 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.7 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 51mm/min, and limited oxygen index is 50%, dye-uptake 94%, washing fastness (AATCC test) Reach 5 grades.
Embodiment 5:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 84 parts;
3 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.5 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 44mm/min, and limited oxygen index is 42%, dye-uptake 91%, washing fastness (AATCC test) Reach 5 grades.
Embodiment 6:
A kind of preparation method of the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) being equipped with raw material by following parts by weight, being subsequently adding in high-speed mixer is uniformly dispersed obtains modification Polylactic acid mixing raw material:
PLA polylactic acid 82 parts;
2 parts of sisal fiber powder;
Bamboo powder 0.8 part;
0.8 part of stachyose;
Mica powder 0.8 part;
CMA fire retardant 1 part;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
Described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature is 85 DEG C, drawing-off Multiple is 2.5 times;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
Result: according to GB 8,410 2006 " combustion characteristics of automotive interior material " standard, maximum horizontal Burning velocity is 29mm/min, and limited oxygen index is 33%, dye-uptake 93%, washing fastness (AATCC test) Reach 5 grades.
As can be seen here, the modified polylactic acid fiber fabric that the present invention prepares has good heat-proof combustion-resistant effect, Additionally there is Yi Shangran, the advantage of good spinnability.Present invention process is simple, it is easy to industrialization operates, resistance Combustion agent has only to use very low amount, it is possible to reach extraordinary flame retardant effect, energy-conserving and environment-protective.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (4)

1. a preparation method for the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant, its step is as follows:
(1) be equipped with raw material, being subsequently adding in high-speed mixer is uniformly dispersed obtain polydactyl acid mixing former Material:
PLA polylactic acid;
Sisal fiber powder;
Bamboo powder;
Stachyose;
Mica powder;
CMA fire retardant;
(2) by above-mentioned mixed uniformly polydactyl acid mixing raw material by double screw extruder melt blending, Extrusion prepares polydactyl acid master batch, and is vacuum dried, mixture on melt spinning machine through circular spinneret orifice Spinning obtains modified polylactic acid fiber;
(3) above-mentioned acid fiber by polylactic is woven into automobile cushion fabric.
2. the preparation side of the polylactic acid fiber fabric of the automobile cushion heat-proof combustion-resistant described in claim 1 Method, it is characterised in that:
Described step (2) described spinning temperature is 220 DEG C, and winding speed is 1600m/min;Drawing temperature Being 85 DEG C, drafting multiple is 2.5 times.
3. the preparation side of the polylactic acid fiber fabric of the automobile cushion heat-proof combustion-resistant described in claim 1 or 2 Method, it is characterised in that:
In step (1), it is equipped with raw material by following parts by weight, is subsequently adding in high-speed mixer and is uniformly dispersed Obtain polydactyl acid mixing raw material:
PLA polylactic acid 80-86 part;
Sisal fiber powder 2-3 part;
Bamboo powder 0.8 part;
Stachyose 0.5-0.8 part;
Mica powder 0.8 part;
CMA fire retardant 1 part.
4. prepared by the polylactic acid fiber fabric of automobile cushion heat-proof combustion-resistant described in any one of claim 1-3 The fabric obtained.
CN201610598676.4A 2016-07-27 2016-07-27 Polylactic acid fiber fabric for automobile seat cushion Pending CN106012085A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610598676.4A CN106012085A (en) 2016-07-27 2016-07-27 Polylactic acid fiber fabric for automobile seat cushion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610598676.4A CN106012085A (en) 2016-07-27 2016-07-27 Polylactic acid fiber fabric for automobile seat cushion

Publications (1)

Publication Number Publication Date
CN106012085A true CN106012085A (en) 2016-10-12

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107630261A (en) * 2017-10-24 2018-01-26 安徽亚源印染有限公司 A kind of preparation method of high intensity acid fiber by polylactic
CN107868993A (en) * 2017-10-24 2018-04-03 安徽亚源印染有限公司 A kind of flame-proof polylactic acid fabric lining and preparation method thereof
CN108301067A (en) * 2018-03-21 2018-07-20 浙江艾卡医学科技有限公司 A kind of novel acid fiber by polylactic and preparation method thereof, application
CN108342788A (en) * 2017-01-22 2018-07-31 香港理工大学 A kind of flame-retardant smoke inhibition enhanced polylactic acid acid composite fibre and preparation method thereof
CN109457322A (en) * 2018-10-27 2019-03-12 安徽豹子头服饰有限公司 A kind of sun-proof cool fiber and preparation method thereof
CN111235679A (en) * 2020-03-31 2020-06-05 孙阁 Antifouling functional fiber and preparation method thereof
CN113789586A (en) * 2021-09-23 2021-12-14 烟台明远创意生活科技股份有限公司 Corn fiber, preparation method and fabric thereof

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CN105256401A (en) * 2015-11-02 2016-01-20 湖州浩铭纺织有限公司 Biological modification process of lactic acid fibers with good spinnability

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108342788A (en) * 2017-01-22 2018-07-31 香港理工大学 A kind of flame-retardant smoke inhibition enhanced polylactic acid acid composite fibre and preparation method thereof
CN107630261A (en) * 2017-10-24 2018-01-26 安徽亚源印染有限公司 A kind of preparation method of high intensity acid fiber by polylactic
CN107868993A (en) * 2017-10-24 2018-04-03 安徽亚源印染有限公司 A kind of flame-proof polylactic acid fabric lining and preparation method thereof
CN108301067A (en) * 2018-03-21 2018-07-20 浙江艾卡医学科技有限公司 A kind of novel acid fiber by polylactic and preparation method thereof, application
CN108301067B (en) * 2018-03-21 2020-12-29 浙江施维康医学科技有限公司 Polylactic acid fiber and preparation method and application thereof
CN109457322A (en) * 2018-10-27 2019-03-12 安徽豹子头服饰有限公司 A kind of sun-proof cool fiber and preparation method thereof
CN111235679A (en) * 2020-03-31 2020-06-05 孙阁 Antifouling functional fiber and preparation method thereof
CN113789586A (en) * 2021-09-23 2021-12-14 烟台明远创意生活科技股份有限公司 Corn fiber, preparation method and fabric thereof
CN113789586B (en) * 2021-09-23 2022-09-16 烟台明远创意生活科技股份有限公司 Corn fiber, preparation method and fabric thereof

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Application publication date: 20161012