CN106012077B - A kind of additive and its application method for producing melt spraying non-woven fabrics - Google Patents
A kind of additive and its application method for producing melt spraying non-woven fabrics Download PDFInfo
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- CN106012077B CN106012077B CN201610375131.7A CN201610375131A CN106012077B CN 106012077 B CN106012077 B CN 106012077B CN 201610375131 A CN201610375131 A CN 201610375131A CN 106012077 B CN106012077 B CN 106012077B
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of additives for producing melt spraying non-woven fabrics, are made including following components by weight proportion:Fatty acid amide 0.05 5% and dual-tert-butyl peroxide 95 99.5%.The invention also discloses a kind of application method for the additive for producing melt spraying non-woven fabrics, contain 0.3~10% additive in the pp material mixture of additive and low melt index.Using the present invention, the mobility of melt-blown raw material can be improved, melt spraying non-woven fabrics can be directly produced added in the polypropylene of low melt index, not only ensure product quality, but also simple flow, save cost, improve efficiency.
Description
Technical field
The present invention relates to field of textiles more particularly to a kind of additives for producing melt spraying non-woven fabrics, correspondingly, further relate to this
The application method of additive.
Background technology
SARS (SARS) and the type A avian influenza of 2009 (H5N1) of 2003 is lived through, melt spraying non-woven fabrics are because have
Good strainability, is used widely in disposable breathing mask and is recognized by most people.In recent years, melt spraying non-woven fabrics
Because of its good strainability, popularization energetically is not only obtained in the application of mask, but also in industrial (such as automobile, oil, sky
Tune, protective garment etc.), medical (such as operation dress), hygienic (the leakproof edge of such as baby diaper), life (such as air filtration, water
Filtering etc.) in be also widely used.With the improvement of people ' s living standards and prevent pollution realize continuous reinforcement, one
Secondary property medical treatment, the use of amenities are more and more common, and people are also higher and higher to the filtering accuracy of air and water.It is in this way, molten
The product consumption that blown non-woven fabric or melt spraying non-woven fabrics are combined with other non-woven fabrics increasingly rises, and produces the raw material of melt spraying non-woven fabrics
Demand also increasingly increases.Because of the particularity of melt spraying non-woven fabrics production technology, for producing the molten of the raw material of melt spraying non-woven fabrics
It is very high to melt index (MFR) requirement, generally requires MFR in more than 800g/10min.Thus the production to melt-blown raw material is brought
Bigger difficulty.
Before 10 years, the production for being meltblown raw material is all the method using monomer polymerization, i.e., adds in propylene list in a kettle
Then body adds in the polypropylene original that catalyst, antioxidant and peroxide etc. obtain MFR higher by polymerisation
Material.In the past 10 years, people are in order to save cost, simple flow, many people by using the polypropylene of low melt index as raw material,
The melt-blown raw material of high MFR is produced by the method for secondary response.
A kind of ultra-fine melt spraying non-woven fabrics mixing material, its melt-blown prepared as disclosed in 101665993 B of Chinese patent CN
Non-woven fabrics and its manufacturing method, by polypropylene I that melt index is 150~400g/10min and melt index be 1200~
The polypropylene II mixing of 1600g/10min, polypropylene I and polypropylene II are 10: 90~90 by weight:After 10 mixing, carry out
It is granulated.By the particulate material that above-mentioned granulation obtains after extruder heating melting, runner is distributed by the spinneret on die head through melt
Hole squeezes out, and surpasses a times drawing-off through thermal current, and the fiber cooling and solidifying of fine is deposited on collecting net equipment, winding networking to get to
Melt spraying non-woven fabrics.
A kind of for another example polypropylene mixtures of 102675732 B of Chinese patent CN and its preparation method and application, homopolymerization is gathered
Propylene, two benzal sorbic alcohols, thio-2 acid two (18) ester, calcium stearate, antioxidant are added in storage bin, after being stirred
It is added in double screw extruder, and adds in di-tert-butyl hydrogen peroxide thereto, then, squeezed what is obtained in double screw extruder
Go out product to be cooled down, be granulated, screening obtains polypropylene mixture, then heated and melted with the polypropylene mixture, and spinneret is made
Melt spraying non-woven fabrics.
Above two technical solution is all using the polypropylene of low melt index as raw material, is carried out by addition additive secondary
Reaction, re-melts, the polypropylene miser of high fusion index is made in pelletizing, then polypropylene miser is heated and is melted, through mould
Head sprays, and cools and solidifies and melt spraying non-woven fabrics are made.
The method that either polypropylene of monomer polymerization or low melt index adds in additive is first made poly- the third of high MFR
Alkene raw material, then melt spraying non-woven fabrics are prepared with the polypropylene of high MFR, all it is that production procedure is long, working hour is long, of high cost, is unfavorable for
Improve the efficiency of production.For this purpose, it is urgent to provide new technical solutions to solve above-mentioned existing technical problem.
Invention content
The technical problems to be solved by the invention are, provide a kind of additive for producing melt spraying non-woven fabrics, may be added to that
Melt spraying non-woven fabrics are directly produced in the polypropylene of low melt index, not only ensure product quality, but also simple flow, cost is saved, carries
High efficiency.
In order to solve the above technical problem, the present invention provides a kind of additive for producing melt spraying non-woven fabrics, including pressing weight
Following components of amount ratio are made:Fatty acid amide 0.05-5% and dual-tert-butyl peroxide 95-99.5%, the aliphatic acid
One kind or combination in the fatty acid amide that amide is represented for below formula I:
It is 13~53 that the range of x, which is the range of 6~26, y, in I formula;
One kind or group in the dual-tert-butyl peroxide that the dual-tert-butyl peroxide is represented for below formula II
It closes:
CxHyOz……Ⅱ
In II formulas, it be the range of 13~53, z is 2~6 that the range of x, which is the range of 6~26, y,.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, the fatty acid amide and dual-tert-butyl
The carbochain of peroxide is the structure of any alkane, alkene, alkynes or phenyl ring.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, the additive further include carrier, institute
Carrier is stated as one kind in polyolefin, polyolefin-wax or antioxidant or combination.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, the additive are made by the following method
:Fatty acid amide and dual-tert-butyl peroxide be mixed to get active ingredient mixture, then to the active ingredient
Carrier is added in mixture, is extruded into masterbatch mix.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, the masterbatch mix contain 1~50%
Active ingredient mixture.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, the fatty acid amide and dual-tert-butyl
Peroxide is separately added into carrier and the fatty acid amide master batch of any concentration and dual-tert-butyl peroxide master batch, 0.05- is made
5% fatty acid amide master batch and 95-99.5% dual-tert-butyl peroxide master batches mix by weight proportion.
The optimal technical scheme of additive as the production melt spraying non-woven fabrics, further includes brightening agent, heat-resistant agent and profit
One kind or combination in lubrication prescription.
Correspondingly, the present invention also provides the application method of the additive of the production melt spraying non-woven fabrics, including following step
Suddenly:The additive is added in the pp material of low melt index, and puts into extruder heating melting, distributed through melt
Runner is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off, is cooled and solidified, and melt spraying non-woven fabrics are made.
The polypropylene of the optimal technical scheme of application method as the additive, the additive and low melt index
Contain 0.3~10% additive in raw material mixture.
The optimal technical scheme of application method as the additive, the pp material of the low melt index melt
Melt index less than 800g/10min.
Implement the present invention, have the advantages that:
The present invention changes the habitual practice that the polypropylene miser of high fusion index is made in prior art, but creates one
Kind additive adds in the additive in the polypropylene of low melt index, passes through the conventional technique for producing melt spraying non-woven fabrics
Melt spraying non-woven fabrics, greatly simple flow are directly produced, shorten the production time, improve production efficiency, energy saving reduces life
Produce cost.
Additive of the present invention include fatty acid amide and dual-tert-butyl peroxide, low melt index it is polyacrylic
Strand is cut off, and molecular weight becomes smaller, and so as to improve the mobility of melt, achievees the purpose that improve melt index.It is and fatty
Sour amide has the function of lubrication so that melt polypropylene preferably drawing-off under high temperature and high speed hot-air, in fatty acid amide
Under the synergistic effect of dual-tert-butyl peroxide, the melt spraying non-woven fabrics produced show good ultimate strength, bursting
Strength and the performances such as hydrostatic pressing, have with the melt spraying non-woven fabrics directly produced with the pp material of high melting means same performance with
Effect.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, present invention work is further retouched in detail below
It states.
Melt spraying non-woven fabrics are that the polypropylene of high fusion index is used to distribute runner through melt after extruder heating melting
It is squeezed out by the spinneret orifice on die head, surpasses a times drawing-off through thermal current, the fiber cooling and solidifying of fine is deposited on collecting net equipment, receives
It is rolled into net and is made.Wherein, melt index (MFR) refers to a kind of numerical value for representing mobility when plastic material is processed.Melting
Exponential quantity is bigger, represents that the processing fluidity of the plastic material is better, on the contrary then poorer.The polypropylene price of high fusion index is held high
Expensive, preparation process is complicated, but its heating has good mobility and ductility, is very suitable for the system of melt spraying non-woven fabrics
It is standby;And the polypropylene of low melt index is cheap, derives from a wealth of sources, but poor fluidity during its processing, is not suitable for preparing melt-blown nothing
Woven fabric.For this purpose, how the polypropylene of low melt index is converted to the polypropylene of high fusion index by those skilled in the art's research
Mixture.
In the present invention, the polypropylene of high fusion index refers to that melt index is more than the polypropylene of 800g/10min, eutectic
The polypropylene for melting index refers to that melt index is less than the polypropylene of 800g/10min;The melt index refer to 230 DEG C,
Under 2.16kg pressure, the melt index that is measured according to the method for GB/T 3682-2000.
At present, the research emphasis in melt spraying non-woven fabrics field and direction are to make the polypropylene of low melt index by adding auxiliary agent
It is prepared into the polypropylene mixture of high fusion index, then the polypropylene mixture melting extrusion melt-blown nonwoven by high fusion index
Cloth.But time-consuming for such production method, and energy consumption is big, and flow is complicated, and production and transportation are of high cost, for this purpose, the present invention changes now
There is the point of penetration of research direction, no longer prepare the polypropylene mixture of high fusion index as intermediate product, but pass through eutectic
Melt spraying non-woven fabrics can directly be produced by melting the polypropylene addition additive of the present invention of index, simplified production procedure, reduced production
Cost is conducive to the development of melt spraying non-woven fabrics industry.
The present invention provides a kind of additives for producing melt spraying non-woven fabrics, are made including following components by weight proportion:
Fatty acid amide 0.05-5% and dual-tert-butyl peroxide 95-99.5%, the fatty acid amide are represented for below formula I
Fatty acid amide in one kind or combination:
It is 13~53 that the range of x, which is the range of 6~26, y, in I formula;
One kind or group in the dual-tert-butyl peroxide that the dual-tert-butyl peroxide is represented for below formula II
It closes:
CxHyOz……Ⅱ
In II formulas, it be the range of 13~53, z is 2~6 that the range of x, which is the range of 6~26, y,.
Wherein, the carbochain of the fatty acid amide and dual-tert-butyl peroxide is any alkane, alkene, alkynes or benzene
The structure of ring, x, y and z value change dependent on saturation degree.Also, carbochain can have appropriate alkyl substitution and bifurcated.
In the production process for preparing melt spraying non-woven fabrics, the polypropylene of additive of the present invention and low melt index is abundant
Mixing, adds in into screw extruder together.Melt stage, dual-tert-butyl peroxide and low melt are heated in screw extruder
The polypropylene of index chemically reacts, and the polyacrylic strand of low melt index is cut off, and molecular weight becomes smaller, so as to make to melt
The mobility of body improves, and achievees the purpose that improve melt index.And fatty acid amide has the function of lubrication so that polypropylene melt
Body preferably drawing-off under high temperature and high speed hot-air, it is raw under the synergistic effect of fatty acid amide and dual-tert-butyl peroxide
The melt spraying non-woven fabrics that output is come show the performances such as good ultimate strength, bursting strength and hydrostatic pressing, with directly with high melting means
Pp material production melt spraying non-woven fabrics have effects that same performance and.
It should be noted that the active ingredient of the additive is fatty acid amide and dual-tert-butyl peroxide, shape
Formula can be the mixture of fatty acid amide and dual-tert-butyl peroxide;Can also be fatty acid amide and dual-tert-butyl peroxide
The mixture of compound is combined with carrier, is extruded into the masterbatch mix of mixing;It can also be fatty acid amide and dual-tert-butyl mistake
Oxide is combined respectively with carrier, squeezes out fatty acid amide master batch and dual-tert-butyl peroxide master batch, then mix fat in proportion
Fat acid amide master batch and dual-tert-butyl peroxide master batch.
(1) mixture of fatty acid amide and dual-tert-butyl peroxide
0.05-5% fatty acid amides and 95-99.5% dual-tert-butyls peroxide are directly mixed by weight proportion
It closes, additive of the present invention is made;Preferably, the ratio of fatty acid amide and dual-tert-butyl peroxide is 1-3%:97-
99%.
It should be noted that brightening agent, resistance to can be also added in the mixture of fatty acid amide and dual-tert-butyl peroxide
One kind or combination in thermit powder and lubricant.
(2) masterbatch mix of fatty acid amide and dual-tert-butyl peroxide
0.05-5% fatty acid amides and 95-99.5% dual-tert-butyl peroxide are mixed by weight proportion, are made effective
Component mixture adds vector resin mixed milling, by the metering of the equipment such as extruder, mixing, melting, extrusion, pelletizing etc.
Masterbatch mix is made in process, and 1~50% active principle mixture is contained in the masterbatch mix, is made of the present invention and adds
Add agent.
Preferably, the vector resin is polyolefin, meanwhile, can also be added during masterbatch mix is prepared it is a kind of or
A variety of polyolefin-waxes and/or antioxidant.
(3) mixture of fatty acid amide master batch and dual-tert-butyl peroxide master batch
By fatty acid amide and dual-tert-butyl peroxide by the preparation method of above-mentioned masterbatch mix respectively with carrier tree
Fat combines, and forms fatty acid amide master batch and dual-tert-butyl peroxide master batch, then mix 0.05-5% fatty acid acyls in proportion
Additive of the present invention is made in amine master batch and 95-99.5% dual-tert-butyl peroxide master batches.
Correspondingly, the present invention also provides a kind of application method for the additive for producing melt spraying non-woven fabrics, include the following steps:
The additive is added in the pp material of low melt index, and puts into extruder heating melting, distributed and flow through melt
Road is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off, is cooled and solidified, and melt spraying non-woven fabrics are made.
Wherein, contain 0.3~10% additive in the additive and the pp material mixture of low melt index.
Preferably, adding proportion is 0.8% to 5%, preferably 1% to 3%.In this way, in the ratio added in production, aliphatic acid
Amide and dual-tert-butyl peroxide mixture ratio reach 0.003% to 5%.
The present invention had not only been suitable for the production of individual layer melt spraying non-woven fabrics and multilayer melt spraying non-woven fabrics, but also was suitable for SMS (S refers to
It is spunbond bonded non-woven fabrics, M refers to melt spraying non-woven fabrics, and S and M can be one or more layers) spinnings such as non-woven fabrics, SMMS non-woven fabrics melt
The production of joint product.
Below by way of specific embodiment, the present invention is further described.
Embodiment 1
2% fatty acid amide and 98% dual-tert-butyl peroxide are mixed by weight proportion, and additive A 1 is made.
Additive A 1 is made an addition in the pp material of low melt index, input extruder heating melting so that addition
Agent A1 reaches total proportion 1.8% of melt, and distribute runner through melt is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off,
The fiber cooling and solidifying of fine is deposited on collecting net equipment, winds networking, melt spraying non-woven fabrics are made.Routinely process again
52g/m is made2SMMS non-woven fabrics B1.
Embodiment 2
Additive A 1 in embodiment 1 is added in into polyolefin mixed milling, by the metering of the equipment such as extruder, mixing, is melted
Melt, squeeze out, masterbatch mix is made in the process such as pelletizing, 30% active principle mixture is contained in the masterbatch mix, is made
Additive A 2.
Additive A 2 is made an addition in the pp material of low melt index, input extruder heating melting so that addition
Agent A2 reaches total proportion 1.8% of melt, and distribute runner through melt is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off,
The fiber cooling and solidifying of fine is deposited on collecting net equipment, winds networking, melt spraying non-woven fabrics are made.Routinely process again
52g/m is made2SMMS non-woven fabrics B2.
Embodiment 3
Fatty acid amide and dual-tert-butyl peroxide are separately added into polyolefin mixed milling, by equipment such as extruders
Fatty acid amide master batch and dual-tert-butyl peroxide master batch, institute is made in the process such as metering, mixing, melting, extrusion, pelletizing
State contain in fatty acid amide master batch 30% fatty acid amide, contain in the dual-tert-butyl peroxide 30% dual-tert-butyl mistake
Oxide.2% fatty acid amide master batch and 98% dual-tert-butyl peroxide master batch are mixed by weight proportion, and additive is made
A3。
Additive A 3 is made an addition in the pp material of low melt index, input extruder heating melting so that addition
Agent A3 reaches total proportion 1.8% of melt, and distribute runner through melt is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off,
The fiber cooling and solidifying of fine is deposited on collecting net equipment, winds networking, melt spraying non-woven fabrics are made.Routinely process again
52g/m is made2SMMS non-woven fabrics B3.
Reference example
Using polypropylene mixture disclosed in 102675732 B of Chinese patent CN, input extruder heating melting, through molten
Body distributes runner and is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off, and the fiber cooling and solidifying of fine is deposited on collection net
On device, networking is wound, melt spraying non-woven fabrics are made.Routinely 52g/m is made in process again2SMMS non-woven fabrics C1.
SMMS non-woven fabrics B1, B2, B3 in embodiment and reference example C1 are tested below, compares and is added using the present invention
Add SMMS non-woven fabrics made from agent compared with SMMS non-woven fabrics performance made from existing conventional techniques.
Test object:
SMMS non-woven fabrics B1, B2, B3 and reference example C1 in embodiment.
Test method:
To test object carry out grammes per square metre, longitudinal fracture strength, Cross breaking strength, hydrostatic pressing, spray and bursting strength survey
Examination.
Test result:
Table 1 adds SMMS produced by the invention and the SMMS performance comparison tables of conventional meltblown raw material production
As shown in table 1, the SMMS non-woven fabrics B1 of embodiment 1, the SMMS non-woven fabrics B2 of embodiment 2, embodiment 3 SMMS without
Woven fabric B3 is compared with the SMMS non-woven fabrics C1 of reference example, SMMS non-woven fabrics made from three kinds of various forms of additive of the present invention
B1, B2 and B3 all show excellent physical property, especially weigh the hydrostatic pressing of one of the important indicator of meltblown layer barrier property,
Compared with the SMMS non-woven fabrics C1 of conventional meltblown raw material production, the two hydrostatic pressing data are close, it can be achieved that same effect.Together
When, B1, B2, B3 and C1 physical properties test result from table are it is found that using SMMS made from additive of the present invention
Non-woven fabrics B1, B2 and B3, standard deviation is significantly smaller, and quality fluctuation is small, and performance is more stable.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of range is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should
Understand, technical scheme of the present invention can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And range.
Claims (7)
1. a kind of additive for producing melt spraying non-woven fabrics, which is characterized in that be made including following components by weight proportion:Fat
Sour amide 0.05-5% and dual-tert-butyl peroxide 95-99.5%, the fatty acid amide are the fat that below formula I represents
One kind or combination in fat acid amide:
It is 13~53 that the range of x, which is the range of 6~26, y, in I formula;
One kind or combination in the dual-tert-butyl peroxide that the dual-tert-butyl peroxide is represented for below formula II:
CxHyOz……Ⅱ
In II formula, it be the range of 13~53, z is 2~6 that the range of x, which is the range of 6~26, y,;
The additive further includes carrier, and the carrier is one kind or combination in polyolefin, polyolefin-wax or antioxidant;
The additive is made by the following method:Fatty acid amide and dual-tert-butyl peroxide be mixed to get effectively
Constituents mixt, then carrier is added into the active ingredient mixture, it is extruded into masterbatch mix;
The masterbatch mix contains 1~50% active ingredient mixture.
2. the additive of production melt spraying non-woven fabrics as described in claim 1, which is characterized in that the fatty acid amide and double tertiary fourths
The carbochain of base peroxide is the structure of any alkane, alkene, alkynes or phenyl ring.
3. the additive of production melt spraying non-woven fabrics as described in claim 1, which is characterized in that the fatty acid amide and double tertiary fourths
Base peroxide is separately added into carrier and the fatty acid amide master batch of any concentration and dual-tert-butyl peroxide master batch is made,
0.05-5% fatty acid amides master batch and 95-99.5% dual-tert-butyl peroxide master batches mix by weight proportion.
4. as described in claim 1 production melt spraying non-woven fabrics additive, which is characterized in that further include brightening agent, heat-resistant agent and
One kind or combination in lubricant.
5. the application method of the additive of melt spraying non-woven fabrics, feature are produced as described in any one of Claims 1 to 4 claim
It is, includes the following steps:The additive is added in the pp material of low melt index, and puts into extruder heating
Melting distributes runner through melt and is squeezed out by the spinneret orifice on die head, and thermal current surpasses a times drawing-off, cools and solidifies, and melt-blown nonwoven is made
Cloth.
6. as claimed in claim 5 production melt spraying non-woven fabrics additive application method, which is characterized in that the additive with
Contain 0.3~10% additive in the pp material mixture of low melt index.
7. the application method of the additive of production melt spraying non-woven fabrics as claimed in claim 5, which is characterized in that the low melt refers to
The melt index of several pp materials is less than 800g/10min.
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CN107904686A (en) * | 2017-11-13 | 2018-04-13 | 肇庆市高要区精彩塑胶原料有限公司 | Fluffy dedicated additive of non-woven fabrics or fiber and preparation method thereof and non-woven fabrics |
CN110358189B (en) * | 2019-07-18 | 2022-04-12 | 广东一龙新材料科技有限公司 | Non-woven fabric soft master batch and preparation method thereof |
CN111455559B (en) * | 2020-04-15 | 2022-02-01 | 北京机科国创轻量化科学研究院有限公司德州分公司 | Short-process melt-blown non-woven fabric processing technology and device and non-woven fabric |
CN111514656A (en) * | 2020-04-17 | 2020-08-11 | 天华化工机械及自动化研究设计院有限公司 | Production process of one-step melt-blown polypropylene electret filter material |
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CN101624758A (en) * | 2009-08-06 | 2010-01-13 | 厦门创业人环保科技有限公司 | Non-woven fabric based on polypropylene non-woven fabric recycle and preparation method thereof |
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