CN106011976B - A kind of high precision spring surface handling process - Google Patents
A kind of high precision spring surface handling process Download PDFInfo
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- CN106011976B CN106011976B CN201610530692.XA CN201610530692A CN106011976B CN 106011976 B CN106011976 B CN 106011976B CN 201610530692 A CN201610530692 A CN 201610530692A CN 106011976 B CN106011976 B CN 106011976B
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- Prior art keywords
- spring
- high precision
- drying
- handling process
- solution
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Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/02—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor involving rotary barrels
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/62—Treatment of iron or alloys based thereon
Abstract
The present invention provides a kind of high precision spring surface handling process, is related to spring processing and manufacturing field.Step is：(1) glazing；(2) degreasing, descale；(3) washing drying；(4) oxidation processes；(5) double washings；(6) dry；(7) plating paint；(8) deoil；(9) drying storage.Present invention process is simple, and antiseptic property is good, and Technological adaptability is strong, effectively extends the service life of high precision spring.
Description
Technical field
The present invention relates to spring to fabricate field, and in particular to a kind of high precision spring surface handling process.
Background technology
The exposed corrosion easy in atmosphere of spring, the type that the corrosion of spring is reacted by it can be divided into chemical attack and electrification
Learn corrosion.Chemical attack refers to that spring metal surface only occurs chemical reaction with surrounding medium merely and causes spring to corrode, such as
Spring oxidation generation oxide-film in especially dry air, and spring in non-electrolyte liquid with the liquid or the liquid
In impurity chemical change etc. occurs, belong to chemical attack.When electrochemical corrosion refers to spring with electrolyte solution contacts, by
Make the corrosion of spring generation in the effect of micro cell, when such as spring is with acid or salt electrolyte solution contacts, due to bullet
Spring surface existing defects or impurity can form the different electrode of potential difference, make spring surface that electrolysis occur, and cause spring rotten
Erosion；When and for example spring is in moist atmosphere, vapor in the atmosphere can congeal into moisture film or the globule in spring surface, and in air
Corrosive gas (salt fog in sulfur dioxide and hydrogen sulfide or marine atmosphere in such as industrial waste gas) be dissolved in moisture film or
Electrolyte can be formed in the globule, the impurity or defect plus spring metal form the different electrode of potential difference, will make spring
Generation electrolytic etching.Spring is often corroded during manufacturing, deposit, using etc. by surrounding medium.Because spring exists
It is to be played a role by elastic force during work, elastic force can change and loss of function after spring is corroded, therefore prevent spring from corroding
Spring steady operation can be ensured, and extend its service life.
A kind of spring surface processing method is disclosed in the A of Chinese patent application prospectus CN 104060316, is wrapped
Include following steps：Phosphatization pretreatment-originally washing-deionization washing-electrophoretic paint electrophoresis-recovery-ultrafiltrate washes-deionized water
Wash-dry-baking-curing-cooling.This method is handled by carrying out phosphatization and plating paint to spring, spring is kept relatively stable
Performance.
The shortcomings that prior art is present be：Spring can produce substantial amounts of hydrogen in parkerizing process, therefore after phosphatization
Spring has Hydrogen Brittleness Phenomena, influences the toughness of spring；And during phosphatization, the size and finish of workpiece have shadow to the quality of spring
Ring, so this surface treatment method is not particularly suited for the spring of high precision.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of technique simple, and antiseptic property is good, and Technological adaptability is stronger
High precision spring surface handling process.
To realize object above, the present invention is achieved by the following technical programs：
A kind of high precision stainless steel spring process of surface treatment, step are：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 3-5h；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 15-30min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：Spring after drying is put into 600-650g/L sodium hydroxide and 80~120g/L nitrous
In sour sodium mixed solution, solution is heated to 135-140 DEG C, is incubated, 45-60 minutes；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 90~100 DEG C, and cleaning 1~
2 minutes；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 70-75V voltage, electrophoresis time 45-120s, is existed using electrophoresis
Spring surface forms enamelled coating, using water soluble coating, paint solution 4-5h circulation primaries,；
(8) deoil：Immersion 90-150min is carried out with gasoline, then carries out cleaning of deoiling with degreaser, is further taken out with originally
Water is cleaned；
(9) drying storage.
Further, described high precision spring surface handling process, in polishing step, the volume of spring and fine grinding material
Than for 1：3, the dosage of brightener is the 1%--2% of spring weight.
Further, in described high precision spring surface handling process oxidation processes, NaOH and NaNO2Ratio be
7-9:1。
Spring is subjected to upper light processing in the process of surface treatment, so that spring surface is typically bright as nickel plating
According to people.In addition, oxidation processes influence less, to be more suitable for the easy winding spring of high precision compared with phosphorating treatment on the quality of spring
Surface treatment, Technological adaptability is stronger.Spring aoxidizes in alkaline solution, is about 0.5~1.5um's in Surface Creation thickness
Protective oxide film, the material inside spring can be effectively protected, reach oxidation resistant effect, it is high-accuracy so as to extend
Spend the service life of spring.
The beneficial effects of the invention are as follows the process of surface treatment of further Optimal Spring, is allowed to be more suitable for high precision bullet
The anti-corrosion of spring, present invention process is simple, and antiseptic property is good, and Technological adaptability is strong, can effectively extend making for high precision spring
Use the life-span.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the implementation of the present invention
Example, the technical scheme in the embodiment of the present invention is clearly and completely described.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to protection of the present invention
Scope.
Embodiment 1：
A kind of high precision stainless steel spring process of surface treatment, step are：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 3h, spring
Volume ratio with fine grinding material is 1：3, the dosage of brightener is the 1% of spring weight；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 15min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：The natrium nitrosum of spring after drying is put into 600g/L sodium hydroxide and 80g/L mixes molten
In liquid, solution is heated to 135 DEG C, is incubated, 45 minutes NaOH and NaNO2Ratio be 7:1；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 90 DEG C, is cleaned 1 minute；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 70V voltage, electrophoresis time 45s, using electrophoresis in spring surface
Enamelled coating is formed, using water soluble coating, paint solution 4h circulation primaries, voltage is arranged to；
(8) deoil：Immersion 90min is carried out with gasoline, then carries out cleaning of deoiling with degreaser, is further taken out with originally washing
Only；
(9) drying storage.
Embodiment 2：
A kind of high precision stainless steel spring process of surface treatment, step are：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 3.5h, bullet
The volume ratio of spring and fine grinding material is 1：3, the dosage of brightener is the 1.5% of spring weight；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 20min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：The natrium nitrosum of spring after drying is put into 610g/L sodium hydroxide and 90g/L mixes molten
In liquid, solution is heated to 135 DEG C, is incubated, 50 minutes, NaOH and NaNO2Ratio be 7.5:1；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 90 DEG C, is cleaned 1 minute；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 72V voltage, electrophoresis time 60s, using electrophoresis in spring surface
Enamelled coating is formed, uses water soluble coating, paint solution 4.5h circulation primaries；
(8) deoil：Immersion 100min is carried out with gasoline, then cleaning of deoiling is carried out with degreaser, further takes out and use running water
Clean；
(9) drying storage.
Embodiment 3：
A kind of high precision stainless steel spring process of surface treatment, it is characterised in that step is：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 4h, spring
Volume ratio with fine grinding material is 1：3, the dosage of brightener is the 1% of spring weight；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 25min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：The natrium nitrosum of spring after drying is put into 620g/L sodium hydroxide and 100g/L mixes
In solution, solution is heated to 140 DEG C, is incubated, 50 minutes, NaOH and NaNO2Ratio be 8:1；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 100 DEG C, is cleaned 2 minutes；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 75V voltage, electrophoresis time 80s, using electrophoresis in spring surface
Enamelled coating is formed, uses water soluble coating, paint solution 5h circulation primaries；
(8) deoil：Immersion 110min is carried out with gasoline, then cleaning of deoiling is carried out with degreaser, further takes out and use running water
Clean；
(9) drying storage.
Embodiment 4：
A kind of high precision stainless steel spring process of surface treatment, it is characterised in that step is：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 4.5h, bullet
The volume ratio of spring and fine grinding material is 1：3, the dosage of brightener is the 2% of spring weight；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 30min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：The natrium nitrosum of spring after drying is put into 630g/L sodium hydroxide and 110g/L mixes
In solution, solution is heated to 135 DEG C, is incubated 55 minutes, NaOH and NaNO2Ratio be 9:1；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 100 DEG C, is cleaned 2 minutes；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 70V voltage, electrophoresis time 90s, using electrophoresis in spring surface
Enamelled coating is formed, uses water soluble coating, paint solution 5h circulation primaries；
(8) deoil：Immersion 120min is carried out with gasoline, then cleaning of deoiling is carried out with degreaser, further takes out and use running water
Clean；
(9) drying storage.
Embodiment 5：
A kind of high precision spring surface handling process, it is characterised in that step is：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 5h, spring
Volume ratio with fine grinding material is 1：3, the dosage of brightener is the 2% of spring weight；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent
The proportioning of middle cleaning, cleaning agent and running water is 1：25, scavenging period 30min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then entered with air inducing equipment
Row drying；
(4) oxidation processes：The natrium nitrosum of spring after drying is put into 650g/L sodium hydroxide and 120g/L mixes
In solution, solution is heated to 140 DEG C, is incubated, 60 minutes, NaOH and NaNO2Ratio be 9:1；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 100 DEG C, is cleaned 2 minutes；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 75V voltage, electrophoresis time 120s, using electrophoresis in spring table
Face forms enamelled coating, uses water soluble coating, paint solution 5h circulation primaries；
(8) deoil：Immersion 150min is carried out with gasoline, then cleaning of deoiling is carried out with degreaser, further takes out and use running water
Clean；
(9) drying storage.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (3)
1. a kind of high precision spring surface handling process, it is characterised in that step is：
(1) glazing：Spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive, rolls 3-5h；
(2) degreasing, descale：Spring is taken out out of hexagonal plating barrel, is put into the ultrasonic equipment added with cleaning agent clear
Wash, the proportioning of cleaning agent and running water is 1：25, scavenging period 15-30min；
(3) washing drying：It is rinsed with giant, tap water rinse is reused, is then blown with air inducing equipment
It is dry；
(4) oxidation processes：Spring after drying is put into 600-650g/L sodium hydroxide and 80~120g/L natrium nitrosum
In mixed solution, solution is heated to 135-140 DEG C, is incubated, 45-60 minutes；
(5) double washings：After tap water rinse one time, reusable heat is washed one time, and hot water temperature is 90~100 DEG C, cleans 1~2 point
Clock；
(6) dry；
(7) plating paint：Spring is done into negative electrode, applies 70-75V voltage, electrophoresis time 45-120s, using electrophoresis in spring
Surface forms enamelled coating, uses water soluble coating, paint solution 4-5h circulation primaries；
(8) deoil：Immersion 90-150min is carried out with gasoline, then carries out cleaning of deoiling with degreaser, is further taken out with originally washing
Only；
(9) drying storage.
A kind of 2. high precision spring surface handling process as claimed in claim 1, it is characterised in that spring in step (1)
Volume ratio with coarse grained abrasive is 1：3, the dosage of brightener is the 1%-2% of spring weight.
A kind of 3. high precision spring surface handling process as claimed in claim 1, it is characterised in that in step (4), NaOH
With NaNO2Ratio be 7-9:1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610530692.XA CN106011976B (en) | 2016-07-06 | 2016-07-06 | A kind of high precision spring surface handling process |
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| CN201610530692.XA CN106011976B (en) | 2016-07-06 | 2016-07-06 | A kind of high precision spring surface handling process |
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| CN106011976B true CN106011976B (en) | 2018-01-05 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106736302A (en) * | 2017-01-19 | 2017-05-31 | 浙江金昌弹簧有限公司 | A kind of spring production process |
| CN108392016B (en) * | 2018-03-02 | 2020-12-04 | 南京林业大学 | Health-care sofa cushion with adjustable hardness and preparation method thereof |
| CN108754476A (en) * | 2018-08-06 | 2018-11-06 | 苏州捷捷威自动化装备有限公司 | A kind of numerical control cutting machine height-regulating device spring surface treatment process |
| CN109732457B (en) * | 2018-12-28 | 2020-11-06 | 华讯方舟科技有限公司 | Cleaning method for plastic color mixer |
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| CN101831684A (en) * | 2010-05-28 | 2010-09-15 | 河海大学常州校区 | Microarc-oxidation electrophoretic-coating composite processing method of surface of Q 235 steel part |
| CN103243372A (en) * | 2013-04-24 | 2013-08-14 | 常熟市长发铝业有限公司 | Electrophoresis film-painting method |
| CN104060316A (en) * | 2014-05-26 | 2014-09-24 | 安徽红桥金属制造有限公司 | Surface treatment method for spring |
| CN104278306A (en) * | 2014-09-26 | 2015-01-14 | 无锡市天力五金弹簧厂 | Surface treatment process for spring |
| WO2015089827A1 (en) * | 2013-12-20 | 2015-06-25 | 邓志刚 | Method and system for lacquering outer tube of rod core of gas spring |
| CN103352217B (en) * | 2013-06-21 | 2016-01-20 | 安徽省六安市朝晖机械制造有限公司 | Turn blue anti-corrosion treatment process for a kind of surface of workpiece |
-
2016
- 2016-07-06 CN CN201610530692.XA patent/CN106011976B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831684A (en) * | 2010-05-28 | 2010-09-15 | 河海大学常州校区 | Microarc-oxidation electrophoretic-coating composite processing method of surface of Q 235 steel part |
| CN103243372A (en) * | 2013-04-24 | 2013-08-14 | 常熟市长发铝业有限公司 | Electrophoresis film-painting method |
| CN103352217B (en) * | 2013-06-21 | 2016-01-20 | 安徽省六安市朝晖机械制造有限公司 | Turn blue anti-corrosion treatment process for a kind of surface of workpiece |
| WO2015089827A1 (en) * | 2013-12-20 | 2015-06-25 | 邓志刚 | Method and system for lacquering outer tube of rod core of gas spring |
| CN104060316A (en) * | 2014-05-26 | 2014-09-24 | 安徽红桥金属制造有限公司 | Surface treatment method for spring |
| CN104278306A (en) * | 2014-09-26 | 2015-01-14 | 无锡市天力五金弹簧厂 | Surface treatment process for spring |
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Denomination of invention: A high-precision spring surface treatment process Effective date of registration: 20220825 Granted publication date: 20180105 Pledgee: China Postal Savings Bank Limited by Share Ltd. Ningguo branch Pledgor: ANHUI HONGQIAO METAL MANUFACTURING Co.,Ltd. Registration number: Y2022980013601 |