CN106011324B - A kind of small sheep, cunning sub- mirabilite technique - Google Patents

A kind of small sheep, cunning sub- mirabilite technique Download PDF

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Publication number
CN106011324B
CN106011324B CN201610409557.XA CN201610409557A CN106011324B CN 106011324 B CN106011324 B CN 106011324B CN 201610409557 A CN201610409557 A CN 201610409557A CN 106011324 B CN106011324 B CN 106011324B
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skin
water
agent
steeped
discharged
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CN106011324A (en
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郑根学
李孝锋
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Tongxiang Hengqiu fur Product Co Ltd
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Tongxiang Hengqiu fur Product Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/02Fleshing, unhairing, samming, stretching-out, setting-out, shaving, splitting, or skiving skins, hides, or leather
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • C14C1/04Soaking
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C1/00Chemical treatment prior to tanning
    • C14C1/08Deliming; Bating; Pickling; Degreasing
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C3/00Tanning; Compositions for tanning
    • C14C3/02Chemical tanning
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • C14C9/02Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B2700/00Mechanical treatment or processing of skins, hides or leather in general; Pelt-shearing machines; Making driving belts; Machines for splitting intestines
    • C14B2700/01Machines or devices for treating skins, hides or leather in general, e.g. fleshing, unhairing, samming, stretching-out, setting-out

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Detergent Compositions (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of small sheep, cunning sub- mirabilite technique, it comprises the following steps:Gage, skin is washed, fleshing, degreasing first, is cleaned first, pickling softening, removed acid, secondary degreasing, skin is steeped in clear water, heat 36 38 DEG C, add degreasing agent, turned to stop, stop 2 and as a child go out skin, waste water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;Cleaning, multiple pickling softening, tanning, skin is steeped tanning of the reuse no more than one week to collect in water, be warmed to 33 DEG C, supplement add grease dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate, mould inhibitor, to pH value 3.8 3.9, overnight, go out skin, waste water is discharged into tanning water collecting pit;Wet-milling, rinsing, neutralization, stuffing, drying, arrange.The small sheep, cunning sub- mirabilite energy saving technology environmental protection, reduce cost of manufacture.

Description

A kind of small sheep, cunning sub- mirabilite technique
Technical field:
The present invention relates to leather and fur production field, is especially a kind of small sheep, cunning sub- mirabilite technique.
Background technology:
In the prior art, small sheep, cunning sub- the skin Treated sewage reusing in taw process is not thorough, can not meet energy-saving and emission-reduction It is required that, it is necessary to separately carry out water process, cost is not only added but also has wasted water resource.
The content of the invention:
The technical problems to be solved by the invention are to provide a kind of small sheep of energy-conserving and environment-protective, cunning sub- mirabilite technique.
The technical solution of the present invention is to provide a kind of small sheep, cunning sub- mirabilite technique, and it comprises the following steps:
The first step, gage, manually chop unnecessary head, leg, the length with ruler amount root of the tail to head and shoulder portion with knife, multiplied by with The width of middle mesothelium, the size of skin is drawn, be then watered 2.2-2.8kg by every 2 square chi of skin;
Second step, skin is washed, skin is steeped wash skin of the reuse no more than two days and collected in water, 20-27 DEG C of water temperature is controlled, adds Degreasing agent, bleeding agent, bactericide are rotated, and are then stood more than 4 hours, are gone out skin, waste water is discharged into treatment tank;
3rd step, fleshing, manually operated in the fleshing equipment equipped with return pipe water, accomplish flesh noodles totally without scratch, Oil-free is lacked, and treatment tank is emptied on the day of return pipe water;
4th step, degreasing first, skin is steeped in reclaimed water of the reuse no more than two days, 38-40 DEG C of heating, addition soda ash, Degreasing agent, bactericide are rotated, stand combination, go out skin after repeated multiple times, and with dewaterer water dumping 12-18 minutes, waste water is discharged into Treatment tank;
5th step, is cleaned first, and skin is steeped in clear water, heating 30-35 DEG C rotated, stand with reference to 30 minutes with On, waste water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;
6th step, pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, heats 30-35 DEG C, Add salt, formic acid, lactic acid, acidicenzym, grease release agent, fatting agent, be adjusted to pH value 2.7-2.8, overnight, secondary sunrise skin, control water, give up Water is discharged into pickling softening collecting pit;
7th step, removes acid, skin steep reuse no more than one week go acid collection water in, be warmed to 33 DEG C, add sodium bicarbonate, Soda ash, to pH value 6.5-7, overnight, go out skin, waste water is discharged into sour collecting pit;
8th step, secondary degreasing, skin is steeped in clear water, is heated 36-38 DEG C, is added degreasing agent, is turned, is stopped 2 and as a child go out skin, Waste water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleaning, skin is steeped in clear water, heats 30-35 DEG C, is turned, is stopped 30 minutes, waste water is discharged into degreasing first and given up Water collecting pit;
Tenth step, multiple pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, supplement adds Salt, formic acid, lactic acid, acidicenzym, grease dispersant, fatting agent, to pH value 2.7-2.8, overnight, secondary sunrise skin draining, waste water is arranged Enter pickling softening collecting pit;
11st step, tanning, skin is steeped tanning of the reuse no more than one week and collected in water, is warmed to 33 DEG C, supplement adds Enter grease dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate, mould inhibitor, to pH value 3.8- 3.9, overnight, go out skin, waste water is discharged into tanning water collecting pit;
12nd step, wet-milling, rinsing, neutralization, stuffing, drying, arrange.
Preferably, degreasing agent 1g/L in step 2, bleeding agent 0.5-1g/L, bactericide 0.5g/L.
Preferably, soda ash 1g/L degreasing agent 2.5g/L in step 4, bactericide 0.3g/L.
Preferably, salt 5-10g/L in step 6, formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2g/L, stuffing Agent 1-2g/L, grease dispersant 0.1-0.3g/L.
Preferably, sodium bicarbonate 1.5-2g/L in step 7, soda ash 0.5-1g/L.
Further, in step 11, the grease dispersant 0.3-0.5g/L of addition, fatting agent 1-2g/L, aluminum tanning are supplemented Agent 2-4g/L, chrome tanning agent 8-10g/L, syntans 1-2g/L, auxiliary tanning agent 1-2g/L, sodium bicarbonate 1-2g/L, mould inhibitor 0.3- 0.5g/L。
Compared with prior art, the present invention has following technique effect, by being used in backwater, it is possible to reduce the dosage of water, Moreover, Reusability backwater in some steps, it is possible to reduce the use of additive, reduce cost, energy-conserving and environment-protective.
Embodiment:
With reference to embodiment, the invention will be further described:
Embodiment
A kind of small sheep, cunning sub- mirabilite technique, it comprises the following steps:
The first step, gage, manually chop unnecessary head, leg, the length with ruler amount root of the tail to head and shoulder portion with knife, multiplied by with The width of middle mesothelium, the size of skin is drawn, be then watered 2.5kg by every 2 square chi of skin;
Second step, skin is washed, skin is steeped wash skin of the reuse no more than two days and collected in water, 25 DEG C of water temperature is controlled, adds de- Fat agent, bleeding agent, bactericide are rotated, and are then stood more than 4 hours, are gone out skin, waste water is discharged into treatment tank;
3rd step, fleshing, manually operated in the fleshing equipment equipped with return pipe water, accomplish flesh noodles totally without scratch, Oil-free is lacked, and treatment tank is emptied on the day of return pipe water;
4th step, degreasing first, skin is steeped in reclaimed water of the reuse no more than two days, 38-40 DEG C of heating, addition soda ash, Degreasing agent, bactericide are rotated, stand combination, go out skin after repeated multiple times, and with dewaterer water dumping 12-18 minutes, waste water is discharged into Treatment tank;
5th step, is cleaned first, and skin is steeped in clear water, heating 30-35 DEG C rotated, stand with reference to 30 minutes with On, waste water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;
6th step, pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, heats 30-35 DEG C, Add salt, formic acid, lactic acid, acidicenzym, grease release agent, fatting agent, be adjusted to pH value 2.7-2.8, overnight, secondary sunrise skin, control water, give up Water is discharged into pickling softening collecting pit;
7th step, removes acid, skin steep reuse no more than one week go acid collection water in, be warmed to 33 DEG C, add sodium bicarbonate, Soda ash, to pH value 6.5-7, overnight, go out skin, waste water is discharged into sour collecting pit;
8th step, secondary degreasing, skin is steeped in clear water, is heated 36-38 DEG C, is added degreasing agent, is turned, is stopped 2 and as a child go out skin, Waste water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleaning, skin is steeped in clear water, heats 30-35 DEG C, is turned, is stopped 30 minutes, waste water is discharged into degreasing first and given up Water collecting pit;
Tenth step, multiple pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, supplement adds Salt, formic acid, lactic acid, acidicenzym, grease dispersant, fatting agent, to pH value 2.7-2.8, overnight, secondary sunrise skin draining, waste water is arranged Enter pickling softening collecting pit;
11st step, tanning, skin is steeped tanning of the reuse no more than one week and collected in water, is warmed to 33 DEG C, supplement adds Enter grease dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate, mould inhibitor, to pH value 3.8- 3.9, overnight, go out skin, waste water is discharged into tanning water collecting pit;
12nd step, wet-milling, rinsing, neutralization, stuffing, drying, arrange.
Wherein, degreasing agent 1g/L in step 2, bleeding agent 0.5-1g/L, bactericide 0.5g/L.
Soda ash 1g/L in step 4, degreasing agent 2.5g/L, bactericide 0.3g/L.
Salt 5-10g/L in step 6, formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2g/L, fatting agent 1-2g/L, Grease dispersant 0.1-0.3g/L.
Sodium bicarbonate 1.5-2g/L in step 7, soda ash 0.5-1g/L.
In step 11, grease dispersant 0.3-0.5g/L, fatting agent 1-2g/L, the aluminium tanningagent 2-4g/L of addition are supplemented, Chrome tanning agent 8-10g/L, syntans 1-2g/L, auxiliary tanning agent 1-2g/L, sodium bicarbonate 1-2g/L, mould inhibitor 0.3-0.5g/L.

Claims (6)

1. a kind of small sheep, cunning sub- mirabilite technique, it is characterised in that:It comprises the following steps:
The first step, gage, manually chop unnecessary head, leg, the length with ruler amount root of the tail to head and shoulder portion with knife, multiplied by with centre The width of skin, the size of skin is drawn, be then watered 2.2-2.8kg by every 2 square chi of skin;
Second step, skin is washed, skin is steeped wash skin of the reuse no more than two days and collected in water, 20-27 DEG C of water temperature is controlled, adds degreasing Agent, bleeding agent, bactericide are rotated, and are then stood more than 4 hours, are gone out skin, waste water is discharged into treatment tank;
3rd step, fleshing, manually operated in the fleshing equipment equipped with return pipe water, accomplish flesh noodles totally without scratch, oil-free Lack, treatment tank is emptied on the day of return pipe water;
4th step, degreasing first, skin is steeped in reclaimed water of the reuse no more than two days, heats 38-40 DEG C, adds soda ash, degreasing Agent, bactericide are rotated, stand combination, go out skin after repeated multiple times, and with dewaterer water dumping 12-18 minutes, waste water is discharged into sewage Processing pond;
5th step, is cleaned first, and skin is steeped in clear water, and 30-35 DEG C of heating is rotated, stood with reference to more than 30 minutes, is given up Water, which is discharged into, washes severe edema due to hypofunction of the spleen collecting pit;
6th step, pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, 30-35 DEG C is heated, adds Salt, formic acid, lactic acid, acidicenzym, grease release agent, fatting agent, are adjusted to pH value 2.7-2.8, overnight, secondary sunrise skin, control water, waste water It is discharged into pickling softening collecting pit;
7th step, removes acid, and skin is steeped reuse and gone no more than one week in acid collection water, 33 DEG C is warmed to, adds sodium bicarbonate, pure Alkali, to pH value 6.5-7, overnight, go out skin, waste water is discharged into sour collecting pit;
8th step, secondary degreasing, skin is steeped in clear water, is heated 36-38 DEG C, is added degreasing agent, is turned, is stopped 2 and as a child go out skin, waste water It is discharged into and washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleaning, skin is steeped in clear water, heats 30-35 DEG C, is turned, is stopped 30 minutes, and waste water is discharged into degreasing waste water receipts first Ji Chi;
Tenth step, multiple pickling softening, skin is steeped pickling softening of the reuse no more than one week and collected in water, supplement adds salt, first Acid, lactic acid, acidicenzym, grease dispersant, fatting agent, to pH value 2.7-2.8, overnight, secondary sunrise skin draining, waste water is discharged into pickling Soften collecting pit;
11st step, tanning, skin is steeped tanning of the reuse no more than one week and collected in water, is warmed to 33 DEG C, supplement adds oil Fat dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate, mould inhibitor, to pH value 3.8-3.9, mistake At night, go out skin, waste water is discharged into tanning water collecting pit;
12nd step, wet-milling, rinsing, neutralization, stuffing, drying, arrange.
2. small sheep according to claim 1, cunning sub- mirabilite technique, it is characterised in that:Degreasing agent 1g/L in step 2, Bleeding agent 0.5-1g/L, bactericide 0.5g/L.
3. small sheep according to claim 1, cunning sub- mirabilite technique, it is characterised in that:Soda ash 1g/L in step 4, take off Fat agent 2.5g/L, bactericide 0.3g/L.
4. small sheep according to claim 1, cunning sub- mirabilite technique, it is characterised in that:Salt 5-10g/L in step 6, Formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2g/L, fatting agent 1-2g/L, grease dispersant 0.1-0.3g/L.
5. small sheep according to claim 1, cunning sub- mirabilite technique, it is characterised in that:Sodium bicarbonate 1.5- in step 7 2g/L, soda ash 0.5-1g/L.
6. small sheep according to claim 1, cunning sub- mirabilite technique, it is characterised in that:In step 11, supplement adds Grease dispersant 0.3-0.5g/L, fatting agent 1-2g/L, aluminium tanningagent 2-4g/L, chrome tanning agent 8-10g/L, syntans 1-2g/ L, auxiliary tanning agent 1-2g/L, sodium bicarbonate 1-2g/L, mould inhibitor 0.3-0.5g/L.
CN201610409557.XA 2016-06-12 2016-06-12 A kind of small sheep, cunning sub- mirabilite technique Active CN106011324B (en)

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CN106011324B true CN106011324B (en) 2017-11-28

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPM761094A0 (en) * 1994-08-23 1994-09-15 Tanning Technologies Pty Ltd Treatment of hides
CN102534056B (en) * 2010-12-14 2015-03-04 张壮斗 Tanning production process capable of recycling waste water repeatedly from soaking to dyeing
CN104673943B (en) * 2013-11-30 2017-12-01 孟州市光宇皮业有限公司 The preparation method of environmental and ecological aluming kip
CN104843807A (en) * 2014-02-15 2015-08-19 张壮斗 Cycle engineering for realization of tanning waste water near-zero emission

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