CN106010044A - High-speed train self-cleaning anti-fouling paint containing trace bio-fungicide - Google Patents

High-speed train self-cleaning anti-fouling paint containing trace bio-fungicide Download PDF

Info

Publication number
CN106010044A
CN106010044A CN201610454919.7A CN201610454919A CN106010044A CN 106010044 A CN106010044 A CN 106010044A CN 201610454919 A CN201610454919 A CN 201610454919A CN 106010044 A CN106010044 A CN 106010044A
Authority
CN
China
Prior art keywords
component
containing trace
cleaning anti
train self
biofungicide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610454919.7A
Other languages
Chinese (zh)
Other versions
CN106010044B (en
Inventor
宋伟
陆阿定
胡建坤
李娟�
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Marine Development Research Institute
Original Assignee
Zhejiang Marine Development Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Marine Development Research Institute filed Critical Zhejiang Marine Development Research Institute
Priority to CN201610454919.7A priority Critical patent/CN106010044B/en
Publication of CN106010044A publication Critical patent/CN106010044A/en
Application granted granted Critical
Publication of CN106010044B publication Critical patent/CN106010044B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to an anti-fouling paint, in particular to a high-speed train self-cleaning anti-fouling paint containing trace bio-fungicide. The high-speed train self-cleaning anti-fouling paint containing trace bio-fungicide is prepared by mixing a first component and a second component by mass. The first component includes 40-50% of ternary random copolymer acrylic resin, 4-8% of hydroxyl silicone oil, 2-6% of fluorocarbon resin, 2-5% of acrylamide, 2-8% of an adhesion promoter, 3-5% of pyridine-triphenylborane, 3-5% of zineb, 3-5% of talcum powder, 15-25% of titanium dioxide, 0-8% of pigment and 1-6% of polyamide wax paste. The second component is an aliphatic isocyanate trimer. The mass ratio of the first component to the second component is (2-4):1.

Description

A kind of bullet train self-cleaning anti-pollution coating containing trace biofungicide
Technical field
The present invention relates to a kind of antifouling paint, particularly to a kind of bullet train containing trace biofungicide with self-cleaning Antifouling paint.
Background technology
Along with the fast development of national economy, bullet train traffic coverage and operation mileage are continuously increased.At running In, bullet train surface can be by the adhesion of multiple pollutant (such as: dust, earth, rainwater etc.) and pollution, for ensureing vehicle (high ferro that particularly development in recent years is swift and violent and motor-car) aesthetic in appearance, needs to clean vehicle crust every day, the most both wastes of manpower, Material resources, the damage to car paint is bigger again.
Research and development bullet train self-cleaning anti-pollution railway coating, is possible not only to meet bullet train and wants the high-performance of coating Ask, railway traffic transport is developed rapidly simultaneously and the development of China's coating has the meaning that technology promotes to improve with industry Justice.For a long time, known self-cleaning anti-pollution coating is mainly used in the fields such as building, ceramic sanitary appliance, anti-fouling paint peculiar to vessel, closely Nian Lai, gradually expands in the range of application of train.It is mainly used in railcar abroad, and range of application and circuit have Limit, is mainly used in anti-graffiti function.The domestic show-how also not having Related product and technology application, in state-owned railroads standard Also the performance indications without self-cleaning anti-pollution coating require and relevant technical checking method.
Summary of the invention
It is an object of the invention to provide a kind of bullet train self-cleaning anti-pollution coating containing trace biofungicide, should Coating has high performance self-cleaning characteristic.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of described bullet train self-cleaning anti-pollution coating containing trace biofungicide, this coating be by as follows with The first component of mass fraction meter is mixed to prepare with second component: first component:
Second component: aliphatic isocyanates trimer, wherein first component is 2-4:1 with the mass ratio of second component.
First and second components, according to certain mass ratio mixing, are constructed after stirring, are bullet train self-cleaning anti-pollution and are coated with Material.Pigment can be specific to Sexual behavior mode according to color selection requirements.
As preferably, described pigment selected from phthalocyanine blue, lemon yellow or indigo in one or more.
As preferably, described ternary random copolymerization acrylic resin is to be prepared by following raw material in terms of mass fraction:
Described ternary random copolymerization acrylic resin compounds through rational component, it is achieved thereby that sterilizing function, it is to ring Border is friendly, without poisonous and harmful substance, waterproof.
As preferably, ternary random copolymerization acrylic resin is prepared by following methods: equipped with agitator, reflux condensation mode Pipe, constant pressure funnel four-hole boiling flask in add azodiisobutyronitrile, lauryl mercaptan, butyl acetate, be warming up to after mixing 100-110 DEG C, it is subsequently adding 2-(Acryloyloxy)ethanol, acrylic acid trichlorine phenyl ester, butyl acrylate, isobornyl acrylate, azo Bis-isobutyronitrile and the mixed liquor of AMBN, wherein the addition of AMBN is the 90%-95% of formula ratio, uses Constant pressure funnel is complete through constant speed dropping in 2.5-3 hour, adds the AMBN of surplus, continues isothermal reaction 0.5- After 0.6 hour, being warming up to 110-115 DEG C, after continuing reaction 2.5-3 hour, be cooled to room temperature, completing reaction, to obtain ternary random Co-polypropylene acid resin.Through the preparation of this law, obtain a kind of special biological antibiotic type acrylic acid tree with sterilizing function Fat, the order of addition of each raw material and temperature, the control of time, obtain product playing vital effect.Azo two is different The addition at twice of valeronitrile, can avoid by-product generate and obtain properties of product more preferably, quality C.T.
The invention has the beneficial effects as follows: the present invention is research and development experience based on self-cleaning anti-pollution paint peculiar to vessel, combine other necks The antifouling sterilization technology in territory, thus have developed high performance self-cleaning anti-pollution coating system.
The invention is characterized in that:
(1) matrix resin system introduces a kind of Hydroxylated acrylic resin containing trace biofungicide, make resin Matrix is provided with sterilization anti-fouling effect；
(2) utilize chemical reaction to introduce a kind of hydroxy silicon oil, make resin have and be stained desorption ability, improve simultaneously The stability of machine silicone elastomer；
(3) utilizing appropriate aliphatic isocyanates trimer is cross-linking agent, improves the compactness of paint film, enhances paint film Resistance to water and surface gloss；
(4) fluorocarbon resin is utilized to improve the weatherability of paint film；
(5) the butadiene-styrene rubber binding agent utilizing high molecular improves the adhesive force of resin.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.Should be appreciated that this Bright enforcement is not limited to the following examples, and any pro forma accommodation and/or the change of being made the present invention all will fall Enter scope.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, the equipment used and raw material etc. All it is commercially available or commonly used in the art.Method in following embodiment, if no special instructions, is the normal of this area Rule method.
The synthesis of embodiment 1 ternary random copolymerization acrylic resin (PAA)
The formula of ternary random copolymerization acrylic resin is shown in Table 1, equipped with agitator, reflux condensing tube, constant pressure addition leakage The four-hole boiling flask of bucket adds 0.2g azodiisobutyronitrile (AIBN), 2.0g lauryl mercaptan, 200g butyl acetate, rises after mixing Temperature, to 100 DEG C, then weighs and comprises 12g 2-(Acryloyloxy)ethanol, 37g acrylic acid trichlorine phenyl ester, 100g butyl acrylate, 51g third Olefin(e) acid isobornyl thiocyanoacetate, 1.7g azodiisobutyronitrile and the mixed liquor of 1.7g AMBN, with constant pressure funnel through 3 hours Constant speed dropping is complete, adds 0.1g AMBN, after continuing isothermal reaction 0.5 hour, is warming up to 110 DEG C, continues anti- After answering 2.5 hours, it is cooled to room temperature, completes reaction.Reaction scheme is shown below:
Detecting through IR and GPC, the biological antibiotic type acrylic resin double bond of the present embodiment is polymerized completely, number-average molecular weight Mn Being 7128, weight average molecular weight is 16964, polydispersity coefficient Mw\MnIt is 2.38.
The raw material that embodiment 1-3 uses is shown in Table 1.
Table 1
The synthesis of embodiment 2-3 ternary random copolymerization acrylic resin (PAA)
The formula of ternary random copolymerization acrylic resin is shown in Table 1, and concrete grammar is with embodiment 1, and wherein raw material azo two is different Valeronitrile puts at twice, and the addition of AMBN is the 90%-95% of formula ratio for the first time, and second time adds surplus AMBN.
Embodiment 4
A kind of bullet train self-cleaning anti-pollution coating containing trace biofungicide, this coating is by first component and second group Divide and be mixed to prepare, white, the light blue and green bullet train antifouling paint first component formula containing trace biofungicide Composition is shown in Table 2, and second component is aliphatic isocyanates trimer (Bayer Bayer N3390).The hydroxyl silicon selected in this formula The molecular weight of oil is 5000.
Table 2 (unit: kg)
First component is 3:1 with the mass ratio of component B, constructs after stirring.
After testing, the bullet train antifouling paint quality index testing result of the present invention is as shown in table 3:
Table 3
Inspection project Measured result The method of inspection
Adhesive force/level ≤2 GB/T1720-79
Resistance to impact/(kg cm) ≥45 GB/T1732-93
Pliability/mm ≤2 GB/T1731-79
Contact angle/(°) ≤110 GB/T23764
Oil resistivity (room temperature, 30d) Coating is unchanged GB/T1734-93
Resistance to water (100 DEG C, 72h) Coating is unchanged GB/T1733-93
Resistance to salt water (10%NaCl, room temperature, 30d) Coating is unchanged GB/T1763-79
As shown in Table 3, the bullet train self-cleaning anti-pollution coating of the present invention has high performance self-cleaning characteristic, with similar product Condition ratio, this product, rich in biofungicide, has biological attachment rejection ability, rationally compounding and can play in component Splendid anti-fouling effect.The most also having extraordinary oil resistivity, this coating exists for the coating obtained after train enclosure coater Soaking 30 days in oil-based solvent, coating is without foaming, swelling and obscission.Have slowly it addition, the characteristic of resin gives coating Automatically cleaning ability, the intractable spot of removable surface attachment, surface can long term maintenance initial film color and luster.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma Limit, on the premise of without departing from the technical scheme described in claim, also have other variant and remodeling.

Claims (4)

1. the bullet train self-cleaning anti-pollution coating containing trace biofungicide, it is characterised in that this coating is by as follows First component in terms of mass fraction is mixed to prepare with second component:
First component:
Ternary random copolymerization acrylic resin 40-50%
Hydroxy silicon oil 4-8%
Fluorocarbon resin 2-6%
Acrylamide 2-5%
Adhesion promoter 2-8%
Triphenylboron pyridine 3-5%
Zineb 3-5%
Pulvis Talci 3-5%
Titanium dioxide 15-25%
Pigment 0-8%
Polyamide wax pulp 1-6%；
Second component: aliphatic isocyanates trimer,
Wherein first component is 2-4:1 with the mass ratio of second component.
Bullet train self-cleaning anti-pollution coating containing trace biofungicide the most according to claim 1, its feature exists In: described pigment selected from phthalocyanine blue, lemon yellow or indigo in one or more.
Bullet train self-cleaning anti-pollution coating containing trace biofungicide the most according to claim 1, its feature exists In: described ternary random copolymerization acrylic resin is to be prepared by following raw material in terms of mass fraction:
Azodiisobutyronitrile 0.35-0.45%,
AMBN 0.38-0.48%,
Lauryl mercaptan 0.49-1.2%,
Butyl acetate 47-50%,
2-(Acryloyloxy)ethanol 2.3-3.6%,
Acrylic acid trichlorine phenyl ester 9-10%,
Butyl acrylate 24-28%,
Isobornyl acrylate 10-13%.
Bullet train self-cleaning anti-pollution coating containing trace biofungicide the most according to claim 3, its feature exists Preparation method in described ternary random copolymerization acrylic resin is: equipped with agitator, reflux condensing tube, constant pressure funnel Four-hole boiling flask in add azodiisobutyronitrile, lauryl mercaptan, butyl acetate, be warming up to 100-110 DEG C after mixing, be subsequently adding 2-(Acryloyloxy)ethanol, acrylic acid trichlorine phenyl ester, butyl acrylate, isobornyl acrylate, azodiisobutyronitrile and azo two are different The mixed liquor of valeronitrile, wherein the addition of AMBN is the 90%-95% of formula ratio, with constant pressure funnel through 2.5-3 The dropping of hour constant speed is complete, adds the AMBN of surplus, after continuing isothermal reaction 0.5-0.6 hour, is warming up to 110-115 DEG C, after continuing reaction 2.5-3 hour, it is cooled to room temperature, completes reaction and obtain ternary random copolymerization acrylic resin.
CN201610454919.7A 2016-06-21 2016-06-21 A kind of self-cleaning anti-pollution coating of the bullet train containing micro biological bactericide Active CN106010044B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610454919.7A CN106010044B (en) 2016-06-21 2016-06-21 A kind of self-cleaning anti-pollution coating of the bullet train containing micro biological bactericide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610454919.7A CN106010044B (en) 2016-06-21 2016-06-21 A kind of self-cleaning anti-pollution coating of the bullet train containing micro biological bactericide

Publications (2)

Publication Number Publication Date
CN106010044A true CN106010044A (en) 2016-10-12
CN106010044B CN106010044B (en) 2018-09-18

Family

ID=57085753

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610454919.7A Active CN106010044B (en) 2016-06-21 2016-06-21 A kind of self-cleaning anti-pollution coating of the bullet train containing micro biological bactericide

Country Status (1)

Country Link
CN (1) CN106010044B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280148A (en) * 2008-05-06 2008-10-08 常州市天安特种涂料有限公司 Long-acting antifouling paint
CN103396712A (en) * 2013-07-15 2013-11-20 抚顺市海丰化工有限公司 Hydrolyzed marine antifouling paint and preparation method thereof
CN105367706A (en) * 2015-12-11 2016-03-02 舟山市恒泰漆业有限责任公司 Preparation method of acrylic acid antifouling resin, environment friendly ship bottom anti-fouling paint for reducing dosage of antifouling agent and preparation method of environment friendly ship bottom anti-fouling paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280148A (en) * 2008-05-06 2008-10-08 常州市天安特种涂料有限公司 Long-acting antifouling paint
CN103396712A (en) * 2013-07-15 2013-11-20 抚顺市海丰化工有限公司 Hydrolyzed marine antifouling paint and preparation method thereof
CN105367706A (en) * 2015-12-11 2016-03-02 舟山市恒泰漆业有限责任公司 Preparation method of acrylic acid antifouling resin, environment friendly ship bottom anti-fouling paint for reducing dosage of antifouling agent and preparation method of environment friendly ship bottom anti-fouling paint

Also Published As

Publication number Publication date
CN106010044B (en) 2018-09-18

Similar Documents

Publication Publication Date Title
CN105949382B (en) A kind of biological antibiotic type acrylic resin and the marine antifouling coating compositions using its preparation
CN101353545B (en) UV curing antibiotic coating and preparation thereof
CN101955697B (en) Ceramic non-stick coating with bacteriostasis action and coating method thereof
CN104293062B (en) Soft raw matter antifouling paint of aqueous and preparation method thereof
CN105392852A (en) Antifouling paint composition, antifouling paint film, substrate having an antifouling paint film, and production method for said substrate
CN105542607A (en) Betaine type zwitterion-modified acrylate-containing self-polishing antifouling coating and preparation method thereof
CN104725640A (en) Hydrophilic modified silica sol and application thereof in preparation for hydrophilic anti-fog wear-resistant coating
CN104371472A (en) Weather-resistant paint and preparation method thereof
CN109593420A (en) Organosilicon modified crylic acid resin antifouling paint and preparation method thereof
CN108117835A (en) A kind of chromium-free fingerprint-resistant environmental protection coating material and preparation method thereof
CN102911544B (en) Modified epoxy solvent-free coating
CN103897569A (en) Exterior wall coating and preparation method and application method thereof
CN107033296A (en) Extra-weather-proof polysiloxane-modified acrylic resin and finish paint preparation method
CN101270247B (en) Water-proof emulsion for coal pile in the open air
CN101659726B (en) Benzene-free acrylic resin and preparation method thereof
CN107936814A (en) The net taste woodcare paint of high hardness polyurethane that a kind of POSS is modified
CN105367706B (en) A kind of preparation method of acrylic acid antifouling resin and environmentally friendly ship bottom anti-fouling paint of reduction anti-fouling agent consumption and preparation method thereof
CN106010044A (en) High-speed train self-cleaning anti-fouling paint containing trace bio-fungicide
CN102477238B (en) Water-based varnish
CN112980261A (en) Production process of coating
CN108285674A (en) A kind of environment-friendly type anti-blue light antibacterial self-drying paint and preparation method thereof
CN107793896A (en) A kind of high-weatherability titanium white powder coating and preparation method thereof
CN103910859A (en) Novel alkyd resin and preparation method thereof
CN106243868A (en) A kind of fork truck steel ring antifouling paint
CN106634562B (en) A kind of Capsaicinoid parents network marine anti-pollution coating and its methods for making and using same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Lu Ading

Inventor after: Hu Jiankun

Inventor after: Li Juan

Inventor after: Song Wei

Inventor before: Song Wei

Inventor before: Lu Ading

Inventor before: Hu Jiankun

Inventor before: Li Juan

GR01 Patent grant
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20161012

Assignee: ZHEJIANG HAIFU MARINE BIOTECHNOLOGY Co.,Ltd.

Assignor: ZHEJIANG MARINE DEVELOPMENT Research Institute

Contract record no.: X2022330000405

Denomination of invention: A self-cleaning antifouling paint for high-speed trains containing trace biocides

Granted publication date: 20180918

License type: Common License

Record date: 20220811