CN106009925A - Heavy metal-free black ink for ceramic inkjet printing and preparation method thereof - Google Patents
Heavy metal-free black ink for ceramic inkjet printing and preparation method thereof Download PDFInfo
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- CN106009925A CN106009925A CN201610377232.8A CN201610377232A CN106009925A CN 106009925 A CN106009925 A CN 106009925A CN 201610377232 A CN201610377232 A CN 201610377232A CN 106009925 A CN106009925 A CN 106009925A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
- C09D11/326—Inkjet printing inks characterised by colouring agents containing carbon black characterised by the pigment dispersant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Inks, Pencil-Leads, Or Crayons (AREA)
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Abstract
The invention discloses a heavy metal-free black ink for ceramic inkjet printing and a preparation method thereof. The black ink comprises the following components by mass percentage: 3-5% of a dispersant, 50-60% of a solvent, 2-5% of a surface additive, 0.5-2% of a binder, 30-40% of heavy metal-free black ceramic toner, 0.1-0.5% of a leveling agent, 0.3-0.8% of a defoaming agent, and 0.08-0.1% of an anti-settling agent. The black toner adopted by the invention uses a multi-walled carbon nanotube/carbon black compound as the coloration body, achieves the purpose of effective reduction of cost, and solves the problems of low encapsulation rate and easy generation of agglomeration during preparation of the multi-walled carbon nanotube/carbon black compound. The prepared black ink for ceramic inkjet printing has good quality stability, can be stored for a long time, and has good inkjet printing performance, also the ink has low viscosity, uniform particle size distribution, and pure color, is cheap and easily available, green and environment-friendly, thus further expanding its use.
Description
Technical field
The present invention relates to technology of ceramic tile decoration field, particularly relate to a kind of ceramic ink jet printing with without heavy metal black ink and preparation method thereof.
Background technology
Along with the development of modern society, the use field of wall brick is also constantly being widened, and the thing followed is the practicality of wall brick basic demand to be met, this two big base attribute of aesthetic property, and beneficial environmental properties also becomes increasingly important.And the wall brick without heavy metal, exactly cater to modern and life staying idle at home has been pursued to the requirement of " green, environmental protection ".This product of wall brick is made to become " health escorts envoy " of people.
Instantly the ink that the black ceramic ink used on market is mainly fired into colorant by the heavy metallic oxide that can develop the color, silicate and aluminate etc. with other auxiliary materials and makes.During colorant made by heavy metal compound raw materials such as using Zn, Pb, Cd, Sn, pollution to environment, injury to producers' health, all governs the development of ceramic ink, now needs a kind of method making nontoxic colorant without heavy metal raw material of research and development badly.
Summary of the invention
The technical problem to be solved there is provided a kind of ceramic ink jet printing with without heavy metal black ink, overcomes above-mentioned weak point.Present invention also offers a kind of ceramic ink jet printing preparation method without heavy metal black ink.
The technical problem to be solved is achieved by the following technical programs:
A kind of ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: dispersant 3 ~ 5%, solvent 50 ~ 60%, surface additive 2 ~ 5%, bonding agent 0.5 ~ 2%, without heavy metal black ceramic toner 30 ~ 40%, levelling agent 0.1～0.5%, defoamer 0.3～0.8%, anti-settling agent 0.08～0.1%；Wherein,
Without the preparation method of heavy metal black ceramic toner, it comprises the steps:
(1) preparation of multi-walled carbon nano-tubes/carbon black complex: carbon black, multi-walled carbon nano-tubes are refluxed 7 hours with concentrated nitric acid respectively, with deionized water sucking filtration until neutrality, dry for standby, wherein, carbon black is 10:1 with the weight ratio of multi-walled carbon nano-tubes；By carboxylated carbon black and KH540 under 72 DEG C of nitrogen protective conditions, water-bath 3 hours, with deionized water sucking filtration until neutrality；By the carbon black hydrolysis of grafting KH540 in the ethanol solution of dilution, dried with functionalized multi-wall carbonnanotubes in toluene, 62 DEG C of reactions 5 hours, after by product deionized water, dimethylbenzene sucking filtration until neutrality, remove unreacted carbon black, CNT, prepare coating particles multi-walled carbon nano-tubes/carbon black complex；
(2) preparation of multi-walled carbon nano-tubes/carbon black complex dispersion liquid: pour the solvent of the 91.3% of weight percent content, the dispersant of 0.7% in high speed dispersion tank pretreatment, make dispersant be dissolved completely in solvent；Add the multi-walled carbon nano-tubes/carbon black complex of weight percent content 8% in described dispersant solvent, carry out disperseing pretreatment with high-speed dispersion equipment, time 90min, dispersion frequency 40HZ, obtain multi-walled carbon nano-tubes/carbon black complex dispersion liquid A that solid content is 8%；
(3) according to tetraethyl orthosilicate: ethanol: the mass ratio=2.5:4:1 of water mixes, heating in water bath to 85 DEG C, with dust technology as catalyst, reflux 8 hours and obtain Ludox；Then adding aluminum nitrate in Ludox, aluminum nitrate is the 5.5% of Ludox by mass percentage, and stirring and dissolving obtains solution B；Basic zirconium chloride is dissolved in ethanol: the volume ratio of water is in the mixed solvent of 1:1, obtains saturated solution C；By dispersion liquid A, solution B, solution C mixing, wherein mol ratio=1:(0.35 ~ 0.8 of Si:Zr in solution B, solution C), volume ratio=1:(125 ~ 135 of dispersion liquid A: solution B)；Heating mixed solution seethes with excitement to ethanol, then lights ethanol and stops heating, i.e. obtaining the initial powder of black after ethanol burns completely；Initial powder is ground to 250 mesh, calcines 1 hour in temperature 800 ~ 1000 DEG C under argon shield, then cool down under argon shield, i.e. obtain ceramic black colorant.
In the present invention, described dispersant is any one of water solublity and oil-soluble high score subclass, polyacrylic acid and copolymer, benzoic acid and derivant thereof.The trade name that dispersant can list includes BYK161, BYK163, BYK164, BYK168, EFKA4310, EFKA 4400, EFKA4401, Nuosperse FX9086, Solsperse 24000, Tego710, Tego671, but is not limited to this.
In the present invention, described surface additive is amino or amido and salt thereof.Surface additive is at least one in NP-4, Span-80, AEO-3 and SRE-48000.
In the present invention, at least one during described solvent is de-aromatic hydrocarbon solvent, environmental protection hydrocarbon solvent, alcohols, cycloalkane solvent.
In the present invention, bonding agent generally uses polymerizing resin, as at least one in alkyd resin, acrylic resin, vinyl chloride-vinyl acetate resin, polymerizing resin plays combination and scattered dual function, its trade name that can list includes Novalkyd 2550X70C, NeoCryl B725, Wacker H14/36, but it is not limited to this.Levelling agent is polyether modified siloxane, and the trade name that levelling agent can list includes BYK306, BYK333, Levaslip 8629, but is not limited to this.Defoamer is the polymer-type defoamer without organosilicon, and the trade name that defoamer can list includes BYK051, BYK052, but is not limited to this.Anti-settling agent is at least one in polyamide wax, oxidic polyethylene, and the trade name that anti-settling agent can list includes Disparlon NS-5501, Disparlon 6650, but is not limited to this.
A kind of ceramic ink jet printing preparation method without heavy metal black ink, it comprises the following steps: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink；
Ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: dispersant 3 ~ 5%, solvent 50 ~ 60%, surface additive 2 ~ 5%, bonding agent 0.5 ~ 2%, without heavy metal black ceramic toner 30 ~ 40%, levelling agent 0.1～0.5%, defoamer 0.3～0.8%, anti-settling agent 0.08～0.1%.
In the present invention, the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
There is advantages that black toner of the present invention is using multi-walled carbon nano-tubes/carbon black complex as in colour solid, realize effectively reducing the purpose of cost, and solve the highest problem of encapsulation ratio and multi-walled carbon nano-tubes/carbon black complex is easier to produce the problem reunited in preparation process；The ceramic ink jet printing black ink quality stability prepared is good, can preserve for a long time, and have good Ink Jet Printing Performance, and the viscosity of ink is low, even particle size distribution, has pure color, the cheap and easy to get and advantage of environmental protection, widens its purposes further.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
Embodiment 1
A kind of without heavy metal black ceramic toner, it wraps up black pigment for Zirconium orthosilicate., and described black pigment is multi-walled carbon nano-tubes and carbon black complex.The preparation process of this black ceramic toner is as follows:
(1) preparation of multi-walled carbon nano-tubes/carbon black complex: carbon black, multi-walled carbon nano-tubes are refluxed 7 hours with concentrated nitric acid respectively, with deionized water sucking filtration until neutrality, dry for standby, wherein, carbon black is 10:1 with the weight ratio of multi-walled carbon nano-tubes；By carboxylated carbon black and KH540 under 72 DEG C of nitrogen protective conditions, water-bath 3 hours, with deionized water sucking filtration until neutrality；By the carbon black hydrolysis of grafting KH540 in the ethanol solution of dilution, dried with functionalized multi-wall carbonnanotubes in toluene, 62 DEG C of reactions 5 hours, after by product deionized water, dimethylbenzene sucking filtration until neutrality, remove unreacted carbon black, CNT, prepare coating particles multi-walled carbon nano-tubes/carbon black complex；
(2) preparation of multi-walled carbon nano-tubes/carbon black complex dispersion liquid: pour the solvent of the 91.3% of weight percent content, the dispersant of 0.7% in high speed dispersion tank pretreatment, make dispersant be dissolved completely in solvent；Add the multi-walled carbon nano-tubes/carbon black complex of weight percent content 8% in described dispersant solvent, carry out disperseing pretreatment with high-speed dispersion equipment, time 90min, dispersion frequency 40HZ, obtain multi-walled carbon nano-tubes/carbon black complex dispersion liquid A that solid content is 8%；
(3) according to tetraethyl orthosilicate: ethanol: the mass ratio=2.5:4:1 of water mixes, heating in water bath to 85 DEG C, with dust technology as catalyst, reflux 8 hours and obtain Ludox；Then adding aluminum nitrate in Ludox, aluminum nitrate is the 5.5% of Ludox by mass percentage, and stirring and dissolving obtains solution B；Basic zirconium chloride is dissolved in ethanol: the volume ratio of water is in the mixed solvent of 1:1, obtains saturated solution C；By dispersion liquid A, solution B, solution C mixing, the wherein mol ratio=1:0.35 of Si:Zr in solution B, solution C, the volume ratio=1:135 of dispersion liquid A: solution B；Heating mixed solution seethes with excitement to ethanol, then lights ethanol and stops heating, i.e. obtaining the initial powder of black after ethanol burns completely；Initial powder being ground to 250 mesh, calcines 1 hour in temperature 800 ~ 1000 DEG C, then cool down under argon shield, i.e. obtain ceramic black colorant under argon shield, its colorant colour generation is pure stable.
Embodiment 2
Based on embodiment 1, the difference is that only: the mol ratio=1:0.5 of Si:Zr, the volume ratio=1:125 of dispersion liquid A: solution B in solution B, solution C；This colorant colour generation is pure stable.
Embodiment 3
Based on embodiment 1, the difference is that only: the mol ratio=1:0.8 of Si:Zr, the volume ratio=1:130 of dispersion liquid A: solution B in solution B, solution C；This colorant colour generation is pure stable.
Embodiment 4
Based on embodiment 1, the difference is that only: the mol ratio=1:0.5 of Si:Zr, the volume ratio=1:130 of dispersion liquid A: solution B in solution B, solution C；This colorant colour generation is pure stable.
Comparative example 1
Based on embodiment 1, the difference is that only: the volume ratio=1:100 of dispersion liquid A: solution B；This pure degree of colorant colour generation is inadequate.
Comparative example 2
Based on embodiment 1, the difference is that only: the volume ratio=1:200 of dispersion liquid A: solution B；This pure degree of colorant colour generation is inadequate.
Comparative example 3
Based on embodiment 1, the difference is that only: remove multi-walled carbon nano-tubes；This colorant colour generation poor instability of pure degree.
Embodiment 5
A kind of ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: BYK161 4%, hydrocarbon organic solvent 20%, alcohol solvent 30%, NP-4 2%, Novalkyd
2550X70C 1%, black pigment 40%, polyether modified siloxane 0.5%, BYK051 0.4%, Disparlon
NS-5501 0.1%；Described black pigment is the ceramic black colorant obtained by embodiment 1.
The preparation method of ceramic ink jet printing black ink is as follows: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink.Wherein, the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
Embodiment 6
A kind of ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: BYK161 4%, hydrocarbon organic solvent 25%, alcohol solvent 30%, NP-4 2%, Novalkyd
2550X70C 1%, black pigment 35%, polyether modified siloxane 0.5%, BYK051 0.4%, Disparlon
NS-5501 0.1%；Described black pigment is the ceramic black colorant obtained by embodiment 2.
The preparation method of ceramic ink jet printing black ink is as follows: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink.Wherein, the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
Embodiment 7
A kind of ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: BYK161 4%, hydrocarbon organic solvent 25%, alcohol solvent 35%, NP-4 2%, Novalkyd
2550X70C 1%, black pigment 30%, polyether modified siloxane 0.5%, BYK051 0.4%, Disparlon
NS-5501 0.1%；Described black pigment is the ceramic black colorant obtained by embodiment 3.
The preparation method of ceramic ink jet printing black ink is as follows: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink.Wherein, the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
Embodiment 8
A kind of ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: BYK161 4%, hydrocarbon organic solvent 23%, alcohol solvent 35%, NP-4 2%, Novalkyd
2550X70C 1%, black pigment 32%, polyether modified siloxane 0.5%, BYK051 0.4%, Disparlon
NS-5501 0.1%；Described black pigment is the ceramic black colorant obtained by embodiment 1.
The preparation method of ceramic ink jet printing black ink is as follows: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink.Wherein, the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
Ceramic ink jet printing black ink prepared by embodiment 5 ~ 8 is carried out performance test, and test result see table.As seen from table, the black ink of the ceramic ink jet printing prepared by the present invention has good stability and Ink Jet Printing Performance.
Embodiment described above only have expressed embodiments of the present invention; it describes more concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme using the form of equivalent or equivalent transformation to be obtained, all should fall within the scope and spirit of the invention.
Claims (6)
1. ceramic ink jet printing is with without a heavy metal black ink, containing the component of following mass percent: dispersant 3 ~ 5%, solvent 50 ~ 60%, surface additive 2 ~ 5%, bonding agent 0.5 ~ 2%, without heavy metal black ceramic toner 30 ~ 40%, levelling agent 0.1～0.5%, defoamer 0.3～0.8%, anti-settling agent 0.08～0.1%；Wherein,
Without the preparation method of heavy metal black ceramic toner, it comprises the steps:
(1) preparation of multi-walled carbon nano-tubes/carbon black complex: carbon black, multi-walled carbon nano-tubes are refluxed 7 hours with concentrated nitric acid respectively, with deionized water sucking filtration until neutrality, dry for standby, wherein, carbon black is 10:1 with the weight ratio of multi-walled carbon nano-tubes；By carboxylated carbon black and KH540 under 72 DEG C of nitrogen protective conditions, water-bath 3 hours, with deionized water sucking filtration until neutrality；By the carbon black hydrolysis of grafting KH540 in the ethanol solution of dilution, dried with functionalized multi-wall carbonnanotubes in toluene, 62 DEG C of reactions 5 hours, after by product deionized water, dimethylbenzene sucking filtration until neutrality, remove unreacted carbon black, CNT, prepare coating particles multi-walled carbon nano-tubes/carbon black complex；
(2) preparation of multi-walled carbon nano-tubes/carbon black complex dispersion liquid: pour the solvent of the 91.3% of weight percent content, the dispersant of 0.7% in high speed dispersion tank pretreatment, make dispersant be dissolved completely in solvent；Add the multi-walled carbon nano-tubes/carbon black complex of weight percent content 8% in described dispersant solvent, carry out disperseing pretreatment with high-speed dispersion equipment, time 90min, dispersion frequency 40HZ, obtain multi-walled carbon nano-tubes/carbon black complex dispersion liquid A that solid content is 8%；
(3) according to tetraethyl orthosilicate: ethanol: the mass ratio=2.5:4:1 of water mixes, heating in water bath to 85 DEG C, with dust technology as catalyst, reflux 8 hours and obtain Ludox；Then adding aluminum nitrate in Ludox, aluminum nitrate is the 5.5% of Ludox by mass percentage, and stirring and dissolving obtains solution B；Basic zirconium chloride is dissolved in ethanol: the volume ratio of water is in the mixed solvent of 1:1, obtains saturated solution C；By dispersion liquid A, solution B, solution C mixing, wherein mol ratio=1:(0.35 ~ 0.8 of Si:Zr in solution B, solution C), volume ratio=1:(125 ~ 135 of dispersion liquid A: solution B)；Heating mixed solution seethes with excitement to ethanol, then lights ethanol and stops heating, i.e. obtaining the initial powder of black after ethanol burns completely；Initial powder is ground to 250 mesh, calcines 1 hour in temperature 800 ~ 1000 DEG C under argon shield, then cool down under argon shield, i.e. obtain ceramic black colorant.
Ceramic ink jet printing the most according to claim 1 is with without heavy metal black ink, it is characterised in that described dispersant is any one of water solublity and oil-soluble high score subclass, polyacrylic acid and copolymer, benzoic acid and derivant thereof.
Ceramic ink jet printing the most according to claim 1 is with without heavy metal black ink, it is characterised in that described surface additive is amino or amido and salt thereof.
Ceramic ink jet printing the most according to claim 1 is with without heavy metal black ink, it is characterised in that described solvent is at least one in de-aromatic hydrocarbon solvent, environmental protection hydrocarbon solvent, alcohols, cycloalkane solvent.
5. a ceramic ink jet printing preparation method without heavy metal black ink, it comprises the following steps: component each in formula proportionally weighed, and then carries out disperseing 40min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 10h, obtain the ink semi-finished product of particle diameter distribution≤1 μm；The agitator tank of semi-finished product ink is filled malleation, uses the strainer filtering of aperture≤1 μm, obtain finished product ink；
Ceramic ink jet printing is with without heavy metal black ink, containing the component of following mass percent: dispersant 3 ~ 5%, solvent 50 ~ 60%, surface additive 2 ~ 5%, bonding agent 0.5 ~ 2%, without heavy metal black ceramic toner 30 ~ 40%, levelling agent 0.1～0.5%, defoamer 0.3～0.8%, anti-settling agent 0.08～0.1%.
The ceramic ink jet printing the most according to claim 5 preparation method without heavy metal black ink, it is characterised in that the grinding bead of described grinder is the zirconium oxide bead of diameter 0.5 ~ 2nm, controls temperature of charge≤40 DEG C in process of lapping.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108530992A (en) * | 2018-01-23 | 2018-09-14 | 佛山市华意陶瓷颜料有限公司 | A kind of black ceramic colorant, black ceramic ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241529A (en) * | 2011-05-20 | 2011-11-16 | 景德镇陶瓷学院 | Preparation method of ceramic pigment wrapping carbon black |
| CN102321398A (en) * | 2011-09-02 | 2012-01-18 | 广东工业大学 | A kind of preparation method of carbon black enveloped carbon nanometer tube heat conductive filler |
| CN103555066A (en) * | 2013-10-30 | 2014-02-05 | 澧县新鹏陶瓷有限公司 | Colored glaze mixed type ink for ceramic ink-jet printing and preparation method thereof |
-
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- 2016-06-01 CN CN201610377232.8A patent/CN106009925A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241529A (en) * | 2011-05-20 | 2011-11-16 | 景德镇陶瓷学院 | Preparation method of ceramic pigment wrapping carbon black |
| CN102321398A (en) * | 2011-09-02 | 2012-01-18 | 广东工业大学 | A kind of preparation method of carbon black enveloped carbon nanometer tube heat conductive filler |
| CN103555066A (en) * | 2013-10-30 | 2014-02-05 | 澧县新鹏陶瓷有限公司 | Colored glaze mixed type ink for ceramic ink-jet printing and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108530992A (en) * | 2018-01-23 | 2018-09-14 | 佛山市华意陶瓷颜料有限公司 | A kind of black ceramic colorant, black ceramic ink and preparation method thereof |
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