CN106009901A - LED UV curing glass ink - Google Patents
LED UV curing glass ink Download PDFInfo
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- CN106009901A CN106009901A CN201610474014.6A CN201610474014A CN106009901A CN 106009901 A CN106009901 A CN 106009901A CN 201610474014 A CN201610474014 A CN 201610474014A CN 106009901 A CN106009901 A CN 106009901A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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Abstract
The invention provides LED UV curing glass ink and mainly solves the technical problems that thermo-curing ink is universally in the existing glass ink industry, the energy consumption is high, the efficiency is low and the like. The main point of the technical scheme is that the glass ink is prepared from the raw materials, by weight, of 30%-60% of resin, 3%-20% of UV monomer, 1%-10% of photoinitiator, 0.1%-5% of auxiliary, 0.1%-10% of pigment and 5%-30% of filler, and the resin comprises organic silicone modified epoxy acrylic resin, polyester acrylic resin, acrylic modified alkyd resin and acrylic modified silicone resin; the UV monomer comprises IBXA, acryloyl morpholine, spiro orthocarbonate, DPHA, (EO)n-TMPTA, tetrahydrofuran acrylate, lauryl acrylate and 9,9'-bis[4-(2'-hydroxy-3'-methacryloyloxypropoxy)phenyl]fluorene. The glass ink is manufactured with an LED UV curing method, has the advantages that energy is saved and the environmental protection efficiency is high and is mainly applied to the glass ink industry.
Description
Technical field
The present invention relates to a kind of glass ink, particularly a kind of LED UV curing glass printing ink.
Background technology
UV is the abbreviation of ultraviolet, and in chemical industry field of polymer technology, UV is also by the abbreviation as radiation curing, and UV is namely
UV ultraviolet light polymerization, utilize in UV ultraviolet light, shortwave (300-800 nanometer) under uv radiation, the light in liquid UV material
Initiator irriate becomes free radical or cation, thus causes the macromolecular material (resin) containing active function groups to aggregate into not
The process of molten/insoluble solid paint film, be a kind of sixties in 20th century rise, environmental protection, the new technique of low VOC emission, 20
80 years centuries were developed rapidly in China later.21 century UV solidification mostly uses novel UV LED to solidify, and has UV LED
Point source, line source, area source.Mercury lamp, Halogen light is slowly eliminated.
The resin system that UV curing technology is used relates to a kind of basic oligomer, substantially it is a kind of low-molecular-weight
The prepolymer of (about 2500), conventional has urethane acrylate (urethane acrylate), epoxy acrylate, polyester
Acrylate or polyether acrylate, those oligomer without acrylate of vinyl ethers etc, the most just gradually adopted.Low
The viscosity of polymers is higher, for ease of construction and raising crosslinking curing speed, needs to add monomer and adjusts as reactive diluent
The rheological characteristic of resin.The structure of the reactive diluent performance such as mobility to final film, slipping, wettability, swellability, receive
Animal migration within contracting, adhesive force and film has a major impact.Reactive diluent can be single functionality, it is possible to
To be polyfunctionality, the latter is preferable, because it can make degree of cross linking during solidification improve.Performance requirement to reactive diluent
There are dilution capacity, dissolubility, abnormal smells from the patient, the ability of reduction dielectric viscosity, volatility, degree of functionality, surface tension, contraction during polymerization
Property, the vitrification point (Tg) of homopolymer, power of influence and the toxicity to whole curing rate.The monomer used should be to skin
Zest also measures its value monomer less than 3 grades through Draize.Typical monomers as reactive diluent is tripropylene glycol two
Acrylate (TPGDA) kind.
In terms of the elicitation technique of UV system, research is the use of cation light initiator.Triaryl sulfonium salts is this kind of
The exemplary of light trigger.In this cationic systems, activation process is similar to radical polymerization process, it may be assumed that light absorbs,
Sensibilization, causes, transmission and last chain termination.One advantage of cationic system is that reaction will not be suppressed by oxygen,
And traditional free-radical initiator can be by the inhibitory action of oxygen.But, cationic initiator is but all to the impurity of nucleophilicity
As water is very sensitive, this kind of impurity can neutralize cation makes chain increase in generation eventually.Cationic initiator is relatively expensive in price,
The most also it is of little use.
But at present, glass ink industry generally utilizes thermo-cured ink, energy consumption shortcoming high, inefficient.
Summary of the invention
It is an object of the invention to provide a kind of energy-saving and environmental protection, the LED UV curing glass printing ink that efficiency is high.
The technical solution adopted for the present invention to solve the technical problems is: it uses and includes resin, UV monomer, light-initiated
The LED UV curing glass printing ink that agent, auxiliary agent, pigment and filler are made, it is made up of the raw material of following weight proportioning:
Resin 30-60, UV monomer 3-20, light trigger 1-10, auxiliary agent 0.1-5, pigment 0.1-10%, filler 5-30；Its technical process
It is: first control temperature and be less than 60 DEG C, resin dispersion is stirred；Adding UV monomer, control temperature and be less than 60 DEG C, dispersion is all
Even；Add light trigger, auxiliary agent and pigment, control temperature and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness little
In 5 microns；Add filler, control temperature and be less than 60 DEG C, be uniformly dispersed, three-roller is ground to fineness less than 5 microns；Tree
Fat includes organic-silicon-modified epoxy acrylic resin, polyester acrylate resin, acrylic acid modified alkyd resin, acrylic acid modified has
Machine silicones, or the most any combination in any of more than two kinds；UV monomer includes isobornyl acrylate (IBXA), acryloyl
Quinoline, KBM303, spiro orthocarbonate, phosphoric acrylic ester monomer (DPHA), (EO) n-TMPTA, acrylic acid tetrahydrofuran ester, third
Olefin(e) acid lauryl and bisphenol fluorene double methyl methacrylate, or the most any combination in any of more than two kinds；Light trigger includes
907, ITX, DETX, TPO, 784,261, MBF, 819, camphorquinone (CQ) and 2-ethyl anthracene ester, or the most of more than two kinds
Meaning combination；Auxiliary agent includes aqueous levelling agent BYK-333, levelling agent BYK-310, levelling agent BYK354, TEGO Foamex N, gathers
Acrylate levelling agent BYK358N, defoamer KS66 and dispersant A nti-Terra-204, or the most of more than two kinds
Meaning combination；Pigment includes white carbon black, iron oxide black, titanium dioxide, phthalocyanine blue and permanent bordeaux, or the most any combination in any of more than two kinds；
Filler includes nano-calcium carbonate, nano aluminium oxide, nanometer stone cottonrose hibiscus powder, nano barium sulfate and nano-ceramic powder, or the most any 2 kinds
Above combination in any.
Described LED UV curing glass printing ink, the preferred weight proportioning of the most each raw material respectively: resin 35-50%, UV
Monomer 10-15%, light trigger 2-8%, auxiliary agent 0.3-1%, pigment 3-8%, filler 10-20%.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
Spiro orthocarbonate 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
819 1-4,261 0.1-1,
CQ 0.1-1, TPO 05-2,
TEGO Foamex N 0.1-0.5, KBM303 0.1-1.5,
White carbon black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 25-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 5-7, (EO) n-TMPTA 5-8,
819 1-4,784 0.2-1,
TPO 0.8-3, TEGO Foamex N 0.3-1,
White carbon black 3-6,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: polyester acrylate resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK358N 0.1-1.5,
Phthalocyanine blue 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano aluminium oxide 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: silicon-modified epoxy acrylic resin 6-10, polyester acrylate resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
784 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Permanent bordeaux 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-calcium carbonate 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
MBF 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Iron black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Described LED UV curing glass printing ink can be made by following processing step: first, by following weight proportion
Extraction resin: silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Polyester acrylate resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, IBXA 3-5,
(EO) 3-TMPTA 1-3, bisphenol fluorene double methyl methacrylate 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, Anti-Terra-204 0.1-1.5
Titanium dioxide 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano aluminium oxide 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
(EO) n-TMPTA includes: ethoxylated trimethylolpropane triacrylate (EO3-TMPTA), ethoxylation
Trimethylolpropane trimethacrylate (EO9-TMPTA), activity dilution property monomer ethoxylated trimethylolpropane tris acrylic acid
Ester (EO-TMPTA) etc.；KBM303 refers to that methacryloxypropyl trimethoxy silane, the present invention are especially refered in particular to: γ-(first
Base acryloxy) propyl trimethoxy silicane；Light trigger 261 refers to that η 6-isopropylbenzene cyclopentadienyl ferrum (II) hexafluorophosphate is ferrum
The most representational light trigger in aromatic hydrocarbons series, trade name Irgacure 261；2-ethyl anthracene ester refers to light trigger 2-
EAQ；Anti204 refers to Anti-Terra-204 dispersant；TEGO Foamex N refers to that Germany wins wound Degussa enlightening height froth breaking
Agent.
The invention has the beneficial effects as follows: it has high viscosity, hardness is high, heat-resist；The high spy of energy-saving and environmental protection efficiency
Point.Especially splendid to the adhesive force of glass, curing rate is fast.It can be widely used for the fields such as glass evacuated plating and industry.
Detailed description of the invention
The present invention uses and includes the LED UV that resin, UV monomer, light trigger, auxiliary agent, pigment and filler are made
Curing glass printing ink, it is made up of the raw material of following weight proportioning: resin 30-60, UV monomer 3-20, light trigger 1-10,
Auxiliary agent 0.1-5, pigment 0.1-10%, filler 5-30；Its technical process is: first controls temperature and is less than 60 DEG C, resin dispersion is stirred
Uniformly；Add UV monomer, control temperature and be less than 60 DEG C, be uniformly dispersed；Add light trigger, auxiliary agent and pigment, control temperature
Degree, less than 60 DEG C, is uniformly dispersed, and is ground to fineness less than 5 microns on three-roller；Add filler, control temperature less than 60
DEG C, it is uniformly dispersed, three-roller is ground to fineness less than 5 microns；Resin includes organic-silicon-modified epoxy acrylic resin, gathers
Ester acrylic resin, acrylic acid modified alkyd resin, acryl-modified silicone resin resin, or the most any of more than two kinds arbitrarily
Combination；UV monomer includes isobornyl acrylate (IBXA), acryloyl morpholine, KBM303, spiro orthocarbonate, phosphorous propylene
Acid ester monomer (DPHA), (EO) n-TMPTA, acrylic acid tetrahydrofuran ester, lauryl acrylate and bisphenol fluorene methacrylate
Ester, or the most any combination in any of more than two kinds；Light trigger includes 907, ITX, DETX, TPO, 784,261, MBF, 819,
Camphorquinone (CQ) and 2-ethyl anthracene ester, or the most any combination in any of more than two kinds；Auxiliary agent include aqueous levelling agent BYK-333,
Levelling agent BYK-310, levelling agent BYK354, TEGO Foamex N, polyacrylate flow agent BYK358N, defoamer KS66 and
Dispersant A nti-Terra-204, or the most any combination in any of more than two kinds；Pigment includes white carbon black, iron oxide black, titanium dioxide, phthalein
Cyanines indigo plant and permanent bordeaux, or the most any combination in any of more than two kinds；Filler includes nano-calcium carbonate, nano aluminium oxide, nanometer stone
Cottonrose hibiscus powder, nano barium sulfate and nano-ceramic powder, or the most any combination in any of more than two kinds.It has high viscosity, and hardness is high,
Heat-resist；Energy-saving and environmental protection efficiency high.Especially splendid to the adhesive force of glass, curing rate is fast.It can be widely used for
The fields such as glass evacuated plating and industry.
Embodiment 1, LED UV curing glass printing ink of the present invention, the weight proportion of the most each raw material respectively: tree
Fat 35-50%, UV monomer 10-15%, light trigger 2-8%, auxiliary agent 0.3-1%, pigment 3-8%, filler 10-20%.
Embodiment 2, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
Spiro orthocarbonate 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
819 1-4,261 0.1-1,
CQ 0.1-1, TPO 05-2,
TEGO Foamex N 0.1-0.5, KBM303 0.1-1.5,
White carbon black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 3, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 25-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 5-7, (EO) n-TMPTA 5-8,
819 1-4,784 0.2-1,
TPO 0.8-3, TEGO Foamex N 0.3-1,
White carbon black 3-6,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 4, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Polyester acrylate resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK358N 0.1-1.5,
Phthalocyanine blue 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano aluminium oxide 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 5, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Silicon-modified epoxy acrylic resin 6-10, polyester acrylate resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
784 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Permanent bordeaux 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-calcium carbonate 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 6, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
MBF 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Iron black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 7, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Polyester acrylate resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, IBXA 3-5,
(EO) 3-TMPTA 1-3, bisphenol fluorene double methyl methacrylate 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, Anti-Terra-204 0.1-1.5
Titanium dioxide 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano aluminium oxide 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 8, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Acryl-modified silicone resin resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, DETX 0.1-1,
MBF 0.1-1, TPO 05-2,
TEGO Foamex N 0.1-0.5, defoamer KS66 0.1-1.5,
Phthalocyanine blue 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano-calcium carbonate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Embodiment 9, LED UV curing glass printing ink of the present invention can be made by following processing step: first,
By following weight proportion extraction resin:
Polyester acrylate resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
Acryloyl morpholine 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, IBXA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
ITX 1-4, DETX 0.1-1,
MBF 0.1-1,784 05-2,
TEGO Foamex N 0.1-0.5, Anti-Terra-204 0.1-1.5,
Titanium dioxide 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano aluminium oxide 5-10,
Nano-calcium carbonate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
Protection scope of the present invention, is not only limited to the content of technical scheme shown in above-mentioned any embodiment, as long as adopt
With by " employing weight proportion is: resin 30-60, UV monomer 3-20, light trigger 1-10, auxiliary agent 0.1-5, pigment 0.1-
10%, filler 5-30 " product of the LED UV curing glass printing ink that is made and the equal protection scope of the present invention of process it
In.
Claims (10)
1. a LED UV curing glass printing ink, is characterized in that: it uses and includes resin, UV monomer, light trigger, auxiliary agent, color
Element and the LED UV curing glass printing ink that is made of filler, it is made up of the raw material of following weight proportioning: resin 30-60,
UV monomer 3-20, light trigger 1-10, auxiliary agent 0.1-5, pigment 0.1-10%, filler 5-30；Its technical process is: first control temperature
Resin dispersion, less than 60 DEG C, is stirred by degree；Add UV monomer, control temperature and be less than 60 DEG C, be uniformly dispersed；Add light
Initiator, auxiliary agent and pigment, control temperature and be less than 60 DEG C, be uniformly dispersed, and is ground to fineness less than 5 microns on three-roller；Again
Add filler, control temperature and be less than 60 DEG C, be uniformly dispersed, three-roller is ground to fineness less than 5 microns；
Resin includes organic-silicon-modified epoxy acrylic resin, polyester acrylate resin, acrylic acid modified alkyd resin, acrylic acid
Modified organic silicone resin, or the most any combination in any of more than two kinds；
UV monomer includes isobornyl acrylate (IBXA), acryloyl morpholine, spiro orthocarbonate, phosphoric acrylic ester monomer
(DPHA), (EO) n-TMPTA, acrylic acid tetrahydrofuran ester, lauryl acrylate and bisphenol fluorene double methyl methacrylate, or wherein
Any combination in any of more than two kinds；
Light trigger includes 907, ITX, DETX, TPO, 784, MBF, 819, camphorquinone (CQ) and 2-ethyl anthracene ester, or wherein appoints
Anticipate combination in any of more than two kinds；
Auxiliary agent includes aqueous levelling agent BYK-333, levelling agent BYK-310, levelling agent BYK354, TEGO Foamex N, polypropylene
Acid esters levelling agent BYK358N and defoamer KS66, or the most any combination in any of more than two kinds；
Pigment includes white carbon black, titanium dioxide, phthalocyanine blue and permanent bordeaux, or the most any combination in any of more than two kinds；
Filler includes nano-calcium carbonate, nano aluminium oxide, nanometer stone cottonrose hibiscus powder and nano barium sulfate, or the most of more than two kinds
Combination in any.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: the weight proportion of the most each raw material is respectively
It is: resin 35-50%, UV monomer 10-15%, light trigger 2-8%, auxiliary agent 0.3-1%, pigment 3-8%, filler 10-20%.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
Spiro orthocarbonate 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
819 1-4,261 0.1-1,
CQ 0.1-1, TPO 05-2,
TEGO Foamex N 0.1-0.5, KBM303 0.1-1.5,
White carbon black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Silicon-modified epoxy acrylic resin 10-20, acrylic acid modified alkyd resin 25-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 5-7, (EO) n-TMPTA 5-8,
819 1-4,784 0.2-1,
TPO 0.8-3, TEGO Foamex N 0.3-1,
White carbon black 3-6,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Polyester acrylate resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK358N 0.1-1.5,
Phthalocyanine blue 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano aluminium oxide 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Silicon-modified epoxy acrylic resin 6-10, polyester acrylate resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
784 1-4, ITX 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Permanent bordeaux 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-calcium carbonate 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Acryl-modified silicone resin resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, acryloyl morpholine 3-5,
(EO) 9-TMPTA 1-3, acrylic acid tetrahydrofuran ester 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
MBF 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, BYK-333 0.1-1.5
Iron black 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano barium sulfate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Silicon-modified epoxy acrylic resin 6-10, acrylic acid modified alkyd resin 10-20,
Polyester acrylate resin 8-12,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
KBM303 3-5, IBXA 3-5,
(EO) 3-TMPTA 1-3, bisphenol fluorene double methyl methacrylate 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, CQ 0.1-1,
2-ethyl anthracene ester 0.1-1, DETX 05-2,
TEGO Foamex N 0.1-0.5, Anti-Terra-204 0.1-1.5
Titanium dioxide 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano-ceramic powder 5-10,
Nano aluminium oxide 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, by following weight proportion extraction resin:
Acryl-modified silicone resin resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
IBXA 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, DPHA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
907 1-4, DETX 0.1-1,
MBF 0.1-1, TPO 05-2,
TEGO Foamex N 0.1-0.5, defoamer KS66 0.1-1.5,
Phthalocyanine blue 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nanometer stone cottonrose hibiscus powder 5-10,
Nano-calcium carbonate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
LED UV curing glass printing ink the most according to claim 1, is characterized in that: first, extracts by following weight proportion
Resin:
Polyester acrylate resin 10-20, acrylic acid modified alkyd resin 20-30,
Disperseed to stir；Control temperature and be less than 60 DEG C, then by following weight proportion addition UV monomer:
Acryloyl morpholine 3-5, bisphenol fluorene double methyl methacrylate 3-5,
(EO) 3-TMPTA 1-3, IBXA 0.5-2,
It is uniformly dispersed；Control temperature and be less than 60 DEG C, then by following weight proportion addition light trigger, auxiliary agent and pigment:
ITX 1-4, DETX 0.1-1,
MBF 0.1-1,784 05-2,
TEGO Foamex N 0.1-0.5, Anti-Terra-204 0.1-1.5,
Titanium dioxide 2-5,
After being uniformly dispersed, three-roller is ground to fineness less than 5 microns；Filler is added again by following weight proportion
Nano aluminium oxide 5-10,
Nano-calcium carbonate 5-10,
Temperature will be controlled and be less than 60 DEG C, be uniformly dispersed, three-roller be ground to fineness less than 5 microns.
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| CN107699040A (en) * | 2017-10-17 | 2018-02-16 | 浙江浦江永进工贸有限公司 | A kind of preparation method of polyurethane-type ink |
| CN108504171A (en) * | 2018-04-18 | 2018-09-07 | 中山火炬职业技术学院 | UV-L ED glass substrate white ink and preparation method thereof |
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| CN109321145A (en) * | 2017-07-31 | 2019-02-12 | 东洋油墨Sc控股株式会社 | Optics active energy ray polymerism bonding agent and optical laminated body |
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| CN112795229A (en) * | 2021-03-30 | 2021-05-14 | 中山市中益油墨涂料有限公司 | UV-LED heat-conducting ink and preparation method thereof |
| CN113583554A (en) * | 2021-07-21 | 2021-11-02 | 深圳市金达盛化工有限公司 | Preparation and application method of LED cold light source cured glass coating material |
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| CN109321145A (en) * | 2017-07-31 | 2019-02-12 | 东洋油墨Sc控股株式会社 | Optics active energy ray polymerism bonding agent and optical laminated body |
| CN109321145B (en) * | 2017-07-31 | 2022-01-04 | 东洋油墨Sc控股株式会社 | Active energy ray-polymerizable adhesive for optical use and optical laminate |
| CN107699040A (en) * | 2017-10-17 | 2018-02-16 | 浙江浦江永进工贸有限公司 | A kind of preparation method of polyurethane-type ink |
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| CN113999563B (en) * | 2018-04-18 | 2022-09-16 | 中山火炬职业技术学院 | Anti-yellowing UV-LED glass substrate white ink |
| CN108864821A (en) * | 2018-06-05 | 2018-11-23 | 东莞市绿泉实业有限公司 | A kind of acrylic glass UV ink coating |
| CN110698911A (en) * | 2019-11-24 | 2020-01-17 | 邵美忠 | Double-curing glass printing ink and preparation method thereof |
| CN111100498A (en) * | 2019-12-16 | 2020-05-05 | 珠海格力电器股份有限公司 | UV-LED curing ink and application thereof |
| CN112795229A (en) * | 2021-03-30 | 2021-05-14 | 中山市中益油墨涂料有限公司 | UV-LED heat-conducting ink and preparation method thereof |
| CN113583554A (en) * | 2021-07-21 | 2021-11-02 | 深圳市金达盛化工有限公司 | Preparation and application method of LED cold light source cured glass coating material |
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Application publication date: 20161012 |