CN106009331A - Wear-resistant rubber shock absorption material and preparation method thereof - Google Patents
Wear-resistant rubber shock absorption material and preparation method thereof Download PDFInfo
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- CN106009331A CN106009331A CN201610601577.7A CN201610601577A CN106009331A CN 106009331 A CN106009331 A CN 106009331A CN 201610601577 A CN201610601577 A CN 201610601577A CN 106009331 A CN106009331 A CN 106009331A
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- absorptive material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/30—Applications used for thermoforming
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a wear-resistant rubber shock absorption material and a preparation method thereof. The wear-resistant rubber shock absorption material comprises the following raw materials in parts by weight: 100 parts of butyl rubber, 20 to 40 parts of natural rubber, 5 to 10 parts of calcium carbonate whiskers, 5 to 10 parts of carbon black, 4 to 7 parts of crystalline flake graphite, 5 to 8 parts of mineral fiber, 3 to 5 parts of epoxy soybean oil acrylate, 2 to 4 parts of titanium dioxide, 2 to 3 parts of zirconium dioxide, 3 to 6 parts of magnesium oxide, 2 to 4 parts of zinc oxide, 1 to 3 parts of aluminum-zirconium coupling agents, 2 to 4 parts of polyethyleneglycol stearate, 0.5 to 1.5 parts of cross-linking agents, 1 to 2 parts of antioxidants and 1 to 2 parts of accelerants. The wear-resistant rubber shock absorption material has the advantages that the recipe is reasonable; the compatibility of all ingredients is good; the prepared shock absorption material has the advantages of great damping coefficient, strong rebounding force, shock absorption performance, high-temperature-resistant performance, aging-resistant performance, creep-deformation-resistant performance, good fire-resistant performance and the like, and is suitable for automobile shock absorption products; the market prospects are very wide.
Description
Technical field
The present invention relates to vibration-absorptive material technical field, specifically a kind of abrasive rubber vibration-absorptive material and preparation method.
Background technology
Along with developing rapidly of modern industry, vibrations and noise have become as the serious problems of every field, and it will drop
Low performance accuracy, affect product quality, shorten life of product, make high-precision instrument cisco unity malfunction, jeopardize safety, make to set
Standby or construction early damage, pollute environment and affect health of human body etc..Therefore, how research absorbs, cuts down vibrations and noise
Become current research direction.Current most widely used shock-dampening method general, maximally effective is to use various anti-vibration articles, especially
Rubber damping product, it can be effectively isolated vibrations and excitaton source, it is also possible to relaxes the vibrations of vibration body, is therefore widely used
The fields such as motor vehicles, railway, household, bridge, athletic protective equipment.
Automobile, as daily a kind of walking-replacing tool, is applied extremely wide in daily life, and automobile is daily travels on public affairs
Lu Shang, encounters various road conditions, thus in vehicle traveling process, the location that especially road conditions are poor, automobile is travelling
Shi Jiyi jolts, so that the life-span of automobile shortens significantly.Therefore, it is extremely necessary for installing damping device on automobile,
Present automobile shock-absorber is to use amortisseur mostly, thus the damping effect of automobile is played greatly by the material of amortisseur
Effect.But existing automobile-used vibration-absorptive material exists, and rubber viscous is big, oil resistivity is poor, technological operation is difficult, product damping performance,
The problems such as ageing-resistant performance, impact resistance and flex fatigue property are poor, cost is higher.
Summary of the invention
The present invention is directed to the problem that existing vibration-absorptive material exists, it is provided that one is ageing-resistant, mechanical property strong, anti-fatigue performance
The simple and environmentally-friendly nontoxic rubber damping material of good, wear-resisting, with low cost, preparation technology.
In order to realize object above, the technical solution used in the present invention is as follows:
A kind of abrasive rubber vibration-absorptive material, including the raw material of following parts by weight:
Butyl rubber 100 parts, natural rubber 20-40 part, calcium carbonate crystal whisker 5-10 part, white carbon black 5-10 part, crystalline flake graphite 4-7 part,
Mineral fibres 5-8 part, epoxy soybean oil acrylate 3-5 part, titanium dioxide 2-4 part, zirconium dioxide 2-3 part, magnesium oxide 3-6
Part, zinc oxide 2-4 part, aluminum-zirconium coupling agent 1-3 part, polyglycol distearate 2-4 part, cross-linking agent 0.5-1.5 part, antioxidation
Agent 1-2 part and accelerator 1-2 part.
Preferably, the above aluminum-zirconium coupling agent be aluminium methacrylate-zirconium coupling agent, adipic acid aluminum-zirconium coupling agent and
One in aluminium stearate-zirconium coupling agent.
Preferably, the above cross-linking agent is Aronix M 240.
Preferably, the above accelerator is dibenzothiazyl disulfide zinc or PZ.
Preferably, during the above antioxidant is antioxidant 1010, antioxidant 1076 and antioxidant CA
Kind.
Preferably, the above vibration-absorptive material also includes copolymer of maleic anhydride and acrylic acid 2-4 part.
Preferably, the above vibration-absorptive material also includes alkyl phenol polyethylene glycol oxide ether 1-2 part;Described alkyl phenol polyoxygenated
Vinyl Ether includes NPE, OPEO and alkylpolyoxyethylene.
The preparation method of a kind of abrasive rubber vibration-absorptive material, comprises the following steps:
(1) stir mixing: weigh each raw material according to above-mentioned formula, adds high force dispersion blender by each raw material, in temperature is
120-140 DEG C, vacuum be 0.08-0.10Mpa, rotating speed be under 100-300rpm stirring 30-60min, obtain mix raw material;
(2) hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 145-165 DEG C, pressure be under 15-20MPa
Hot-forming 3-5min, obtains semifinished product;
(3) microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment and enters at temperature is 140-180 DEG C
Row solidification heat treatment, is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
Preferably, the above solidification heat treatment is to be incubated 1h, 1.5h and 2h respectively at 140 DEG C, 160 DEG C and 180 DEG C.
Preferably, the heating rate of the above step (3) is 3-5 DEG C/min.
Compared with prior art, the invention have the benefit that
1, the formula of the present invention is butyl rubber high with oil resistivity, that air-tightness is good, heat-resisting, ageing-resistant and coordinates resilience, absolutely
Edge, the natural rubber that waterproof, plasticity is excellent as primary raw material, add calcium carbonate crystal whisker, white carbon black, crystalline flake graphite,
The adjuvants such as mineral fibres, this formula is reasonable, and each component compatibility is good, and the vibration-absorptive material of preparation has that damped coefficient is big, resilience force
The advantages such as height, damping, high temperature resistant, ageing-resistant, creep resistant, fire resistance are good, it is adaptable to automobile shock goods, market prospect pole
For wide.
2, the formula of the present invention is using crystalline flake graphite as packing material, it is possible to the abrasion and the reduction that reduce vibration-absorptive material are made an uproar
Sound, can improve the damped coefficient of material simultaneously.
3, inventive formulation addition mineral fibres is as packing material, is possible not only to improve the mechanical property of vibration-absorptive material,
The anti-wear performance of material can also be improved.
4, the formula of the present invention adds aluminum-zirconium coupling agent, is possible not only to the dispersibility of improvement system and reduces system viscosity,
Improve the adhesion of filler and rubber, improve the mechanical property of vibration-absorptive material, the most also there is the ageing-resistant performance of excellence.
5, the formula of the present invention is additionally added copolymer of maleic anhydride and acrylic acid so that each component compatibility is more preferable, can guarantee that
Vibration-absorptive material has good processing characteristics and mechanical property, can also improve the creep resistance of material simultaneously.
6, the formula of the present invention adds alkyl phenol polyethylene glycol oxide ether, can not only improve the processing characteristics of vibration-absorptive material, also
The ageing-resistant performance of material can be improved.
7, the preparation method of the present invention uses high force dispersion blender to carry out batch mixing, not only low cost, production efficiency height, consumption
Can be low, moreover it is possible to making the mixing of each component more uniform, rubber is more tight with the interface cohesion of other components, and then improves damping
The mechanical property of material.
8, the vibration-absorptive material that the present invention prepares has excellent performance, and wherein the hardness of vibration-absorptive material is 65-75IRHD, draws
Stretch intensity be 30-40MPa, break-draw rate be 400-500%, damped coefficient be 1.1-1.3, rebound degree be 8-11% and hot-air
Aging be 100 DEG C, 72h Tensile strength be 20-25MPa.
9, this preparation method use microwave combustion method have energy-conservation, production efficiency is high, homogeneous heating, easily realize automatization control
The advantages such as system, and be incubated in different temperature ranges, reduce the crackle that rubber damping material produces because of thermal expansion.
10, the present invention also has that raw material sources are extensive, with low cost, preparation technology simple, production efficiency advantages of higher, holds
Easily realize industrialized production.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described, but is not limited to protection scope of the present invention.
Embodiment 1
A kind of abrasive rubber vibration-absorptive material, by the raw material of following parts by weight: butyl rubber 100 parts, natural rubber 30 parts, carbonic acid
Calcium pyroborate 5 parts, white carbon black 8 parts, crystalline flake graphite 5 parts, mineral fibres 6 parts, epoxy soybean oil acrylate 4 parts, titanium dioxide 2 parts,
Zirconium dioxide 2 parts, magnesium oxide 4 parts, zinc oxide 2 parts, aluminium methacrylate-zirconium coupling agent 1 part, polyglycol distearate 2 parts,
Aronix M 240 cross-linking agent 1 part, 1010 antioxidant 1.5 parts and PZ accelerator 1 part.
Its preparation method, comprises the following steps:
(1) stir mixing: weigh each raw material according to above-mentioned formula, adds high force dispersion blender by each raw material, is 120 in temperature
DEG C, vacuum be 0.10Mpa, rotating speed be under 300rpm stirring 50min, obtain mix raw material;
(2) hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 145 DEG C, pressure be to be hot pressed under 20MPa
Type 5min, obtains semifinished product;
(3) microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment, respectively 140 DEG C, 160 DEG C and
It is incubated 1h, 1.5h and 2h at 180 DEG C to carry out solidifying heat treatment, is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
Embodiment 2
A kind of abrasive rubber vibration-absorptive material, by the raw material of following parts by weight: butyl rubber 100 parts, natural rubber 20 parts, carbonic acid
Calcium pyroborate 6 parts, white carbon black 5 parts, crystalline flake graphite 6 parts, mineral fibres 5 parts, epoxy soybean oil acrylate 5 parts, titanium dioxide 3 parts,
Zirconium dioxide 2 parts, magnesium oxide 3 parts, zinc oxide 3 parts, adipic acid aluminum-zirconium coupling agent 2 parts, polyglycol distearate 3 parts, four sweet
Alcohol diacrylate crosslinking agents 0.5 part, 1076 antioxidant 1 part, copolymer of maleic anhydride and acrylic acid 3 parts and Methyl disulfide
For carbaminate accelerator 1.5 parts.
Its preparation method, comprises the following steps:
(1) stir mixing: weigh each raw material according to above-mentioned formula, adds high force dispersion blender by each raw material, is 130 in temperature
DEG C, vacuum be 0.08Mpa, rotating speed be under 100rpm stirring 60min, obtain mix raw material;
(2) hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 150 DEG C, pressure be to be hot pressed under 20MPa
Type 5min, obtains semifinished product;
(3) microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment, respectively 140 DEG C, 160 DEG C and
It is incubated 1h, 1.5h and 2h at 180 DEG C to carry out solidifying heat treatment, is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
Embodiment 3
A kind of abrasive rubber vibration-absorptive material, by the raw material of following parts by weight: butyl rubber 100 parts, natural rubber 40 parts, carbonic acid
Calcium pyroborate 10 parts, white carbon black 9 parts, crystalline flake graphite 4 parts, mineral fibres 8 parts, epoxy soybean oil acrylate 4 parts, titanium dioxide 4 parts,
Zirconium dioxide 3 parts, magnesium oxide 5 parts, zinc oxide 4 parts, aluminium stearate-zirconium coupling agent 3 parts, polyglycol distearate 4 parts, four sweet
Alcohol diacrylate crosslinking agents 1.5 parts, CA antioxidant 1 part, copolymer of maleic anhydride and acrylic acid 4 parts, Nonyl pheno
2 parts of ether and 2 parts of dibenzothiazyl disulfide zinc.
Its preparation method, comprises the following steps:
(1) stir mixing: weigh each raw material according to above-mentioned formula, adds high force dispersion blender by each raw material, is 130 in temperature
DEG C, vacuum be 0.08Mpa, rotating speed be under 300rpm stirring 45min, obtain mix raw material;
(2) hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 155 DEG C, pressure be to be hot pressed under 18MPa
Type 3min, obtains semifinished product;
(3) microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment, respectively 140 DEG C, 160 DEG C and
It is incubated 1h, 1.5h and 2h at 180 DEG C to carry out solidifying heat treatment, is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
Embodiment 4
A kind of abrasive rubber vibration-absorptive material, by the raw material of following parts by weight: butyl rubber 100 parts, natural rubber 35 parts, carbonic acid
Calcium pyroborate 8 parts, white carbon black 10 parts, crystalline flake graphite 7 parts, mineral fibres 6 parts, epoxy soybean oil acrylate 3 parts, titanium dioxide 3 parts,
Zirconium dioxide 3 parts, magnesium oxide 6 parts, zinc oxide 3 parts, aluminium stearate-zirconium coupling agent 2.5 parts, polyglycol distearate 3 parts, four
Glycol diacrylate crosslinking agents 1 part, 1010 antioxidant 1.5 parts, copolymer of maleic anhydride and acrylic acid 1 part, polyoxyethylene nonyl phenyl
Vinyl Ether 2 parts and 1 part of dibenzothiazyl disulfide zinc.
Its preparation method, comprises the following steps:
(1) stir mixing: weigh each raw material according to above-mentioned formula, adds high force dispersion blender by each raw material, is 140 in temperature
DEG C, vacuum be 0.08Mpa, rotating speed be under 300rpm stirring 30min, obtain mix raw material;
(2) hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 165 DEG C, pressure be to be hot pressed under 15MPa
Type 3min, obtains semifinished product;
(3) microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment, respectively 140 DEG C, 160 DEG C and
It is incubated 1h, 1.5h and 2h at 180 DEG C to carry out solidifying heat treatment, is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
Rubber damping material obtained by above-described embodiment 1-4 is according to industry standard test performance, and test is such as following table institute
Show:
Sample | Hardness (IRHD) | Hot strength (MPa) | Elongation at break (%) | Damped coefficient | Rebound degree (%) | 100 DEG C, 72h Tensile strength (MPa) |
Embodiment 1 | 66 | 31.6 | 412 | 1.18 | 10.7 | 21.9 |
Embodiment 2 | 69 | 38.9 | 456 | 1.16 | 9.9 | 20.4 |
Embodiment 3 | 75 | 39.2 | 497 | 1.28 | 8.9 | 24.8 |
Embodiment 4 | 71 | 33.4 | 489 | 1.21 | 8.3 | 23.2 |
Drawing from the above, vibration-absorptive material prepared by the present invention has mechanics and damping performance, the wide market of excellence.
Above content is it cannot be assumed that the present invention is embodied as being confined to these explanations, for the technical field of the invention
Those of ordinary skill for, without departing under present inventive concept premise, it is also possible to make some simple deduction or replace, all answer
When being considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (10)
1. an abrasive rubber vibration-absorptive material, it is characterised in that: include the raw material of following parts by weight:
Butyl rubber 100 parts, natural rubber 20-40 part, calcium carbonate crystal whisker 5-10 part, white carbon black 5-10 part, crystalline flake graphite 4-7 part,
Mineral fibres 5-8 part, epoxy soybean oil acrylate 3-5 part, titanium dioxide 2-4 part, zirconium dioxide 2-3 part, magnesium oxide 3-6
Part, zinc oxide 2-4 part, aluminum-zirconium coupling agent 1-3 part, polyglycol distearate 2-4 part, cross-linking agent 0.5-1.5 part, antioxidation
Agent 1-2 part and accelerator 1-2 part.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described aluminum-zirconium coupling agent is metering system
One in acid aluminum-zirconium coupling agent, adipic acid aluminum-zirconium coupling agent and aluminium stearate-zirconium coupling agent.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described cross-linking agent is tetraethylene glycol (TEG) diacrylate
Ester.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described accelerator is diphenyl disulfide thiophene
Azoles zinc or PZ.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described antioxidant is antioxidant
1010, the one in antioxidant 1076 and antioxidant CA.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described vibration-absorptive material also includes maleic acid
Acid anhydride-acrylic copolymer 2-4 part.
Abrasive rubber vibration-absorptive material the most according to claim 1, it is characterised in that: described vibration-absorptive material also includes that alkyl phenol gathers
Ethylene oxide ether 1-2 part;Described alkyl phenol polyethylene glycol oxide ether include NPE, OPEO and
Alkylpolyoxyethylene.
The preparation method of a kind of abrasive rubber vibration-absorptive material the most as claimed in claim 1, it is characterised in that: comprise the following steps:
Stir mixing: weigh each raw material according to the formula of claim 1, adds high force dispersion blender by each raw material, in temperature
For 120-140 DEG C, vacuum be 0.08-0.10Mpa, rotating speed be stirring 30-60min under 100-300rpm, obtain mixing former
Material;
Hot-forming: above-mentioned mixing raw material is added in mold cavity, temperature be 145-165 DEG C, pressure be heat under 15-20MPa
Molded 3-5min, obtains semifinished product;
Microwave combustion method: the semifinished product that step (2) obtains is put into microwave heating equipment and carries out solid at temperature is 140-180 DEG C
Heat-transformation processes, and is cooled to room temperature, obtains abrasive rubber vibration-absorptive material.
The preparation method of abrasive rubber vibration-absorptive material the most according to claim 8, it is characterised in that: described solidification heat treatment is
1h, 1.5h and 2h it is incubated respectively at 140 DEG C, 160 DEG C and 180 DEG C.
The preparation method of abrasive rubber vibration-absorptive material the most according to claim 8 or claim 9, it is characterised in that: described step (3)
Heating rate be 3-5 DEG C/min.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107540962A (en) * | 2017-08-29 | 2018-01-05 | 无为县大江橡塑制品有限公司 | A kind of automobile shock elastomeric material |
CN107722306A (en) * | 2017-10-27 | 2018-02-23 | 山东通泰橡胶股份有限公司 | A kind of anti-oxidation treatment method of isoprene rubber |
CN108250501A (en) * | 2017-12-26 | 2018-07-06 | 建新赵氏集团有限公司 | A kind of double damped coefficient rubber and preparation method thereof |
CN109401087A (en) * | 2018-10-10 | 2019-03-01 | 安徽鼎封橡胶减震技术有限公司 | A kind of rubber absorbers and preparation method thereof |
CN116285033A (en) * | 2023-04-26 | 2023-06-23 | 广东鑫辉科技股份有限公司 | High damping ratio shock absorption rubber and preparation method and application thereof |
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CN103194010A (en) * | 2013-04-02 | 2013-07-10 | 华东理工大学 | Damping material based on blending of butyl rubber and natural rubber and preparation method thereof |
CN104140575A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | Wear-resistant shock-absorbing foaming rubber material |
CN105153503A (en) * | 2015-08-18 | 2015-12-16 | 合肥市再德高分子材料有限公司 | Special high-damping rubber material for seismic isolation rubber bearing of bridge |
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2016
- 2016-07-27 CN CN201610601577.7A patent/CN106009331A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103194010A (en) * | 2013-04-02 | 2013-07-10 | 华东理工大学 | Damping material based on blending of butyl rubber and natural rubber and preparation method thereof |
CN104140575A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | Wear-resistant shock-absorbing foaming rubber material |
CN105153503A (en) * | 2015-08-18 | 2015-12-16 | 合肥市再德高分子材料有限公司 | Special high-damping rubber material for seismic isolation rubber bearing of bridge |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107540962A (en) * | 2017-08-29 | 2018-01-05 | 无为县大江橡塑制品有限公司 | A kind of automobile shock elastomeric material |
CN107722306A (en) * | 2017-10-27 | 2018-02-23 | 山东通泰橡胶股份有限公司 | A kind of anti-oxidation treatment method of isoprene rubber |
CN108250501A (en) * | 2017-12-26 | 2018-07-06 | 建新赵氏集团有限公司 | A kind of double damped coefficient rubber and preparation method thereof |
CN109401087A (en) * | 2018-10-10 | 2019-03-01 | 安徽鼎封橡胶减震技术有限公司 | A kind of rubber absorbers and preparation method thereof |
CN116285033A (en) * | 2023-04-26 | 2023-06-23 | 广东鑫辉科技股份有限公司 | High damping ratio shock absorption rubber and preparation method and application thereof |
CN116285033B (en) * | 2023-04-26 | 2023-12-22 | 广东鑫辉科技股份有限公司 | High damping ratio shock absorption rubber and preparation method and application thereof |
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Application publication date: 20161012 |