CN106003313A - Flame-retarding composite material for forest fire protection and preparation method of flame-retarding composite material - Google Patents
Flame-retarding composite material for forest fire protection and preparation method of flame-retarding composite material Download PDFInfo
- Publication number
- CN106003313A CN106003313A CN201610331738.5A CN201610331738A CN106003313A CN 106003313 A CN106003313 A CN 106003313A CN 201610331738 A CN201610331738 A CN 201610331738A CN 106003313 A CN106003313 A CN 106003313A
- Authority
- CN
- China
- Prior art keywords
- composite material
- flame
- fire protection
- forest fire
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920002472 Starch Polymers 0.000 claims abstract description 8
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 8
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 8
- 239000008107 starch Substances 0.000 claims abstract description 8
- 235000019698 starch Nutrition 0.000 claims abstract description 8
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims abstract description 6
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011521 glass Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 239000001301 oxygen Substances 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 5
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 4
- 150000002910 rare earth metals Chemical class 0.000 abstract description 4
- 230000007480 spreading Effects 0.000 abstract description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 abstract 1
- 229920001276 ammonium polyphosphate Polymers 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- 241000219000 Populus Species 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 3
- 229940059574 pentaerithrityl Drugs 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 206010016807 Fluid retention Diseases 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a flame-retarding composite material for forest fire protection and a preparation method of the flame-retarding composite material. The flame-retarding composite material comprises, by weight, 40-50 parts of a high-hydrophilic material, 40-50 parts of a high-temperature expansion material, 3-7 parts of CE(HO)4, 1-3 parts of La2O3 and 1-5 parts of Y2O3. The high-hydrophilic material is composed of one of starch and polyvinylpyrrolidone or the combination of the starch and polyvinylpyrrolidone. The high-temperature expansion material is composed of one or more of ammonium polyphosphate, dipentaerythritol and melamine. The flame-retarding material can store a large amount of water, the material can be formed into a film and cover the surface of a combustible after the water evaporates, oxygen is isolated, meanwhile, the material expands heavily in the burning process so as to separate the combustible from air, the ignition point is lowered through application of a rare earth material, and the material has excellent flame-retarding and fireproof effects for spreading of a surface-fire in the forest.
Description
Technical field
The invention belongs to high molecular fire retardant field of material technology, be specifically related to a kind of forest fire protection resistance
Retardant composite material and preparation method thereof.
Background technology
According to statistics, the whole world is annual occurs forest fire more than 220,000 times, and overdo the gross area 300,000,000
Hectare～400,000,000 hectares, burn area of woods more than 6,400,000 hectares, and the plant of about 9,000,000,000 tons is raw
Thing amount is burnt.China occurs forest fire more than 10,000 to rise every year, more than the 60 of damaged forest face ten thousand
Hectare, because of calamity injures and deaths people more than 500.
The forest fire occurred because of factors such as thunders and lightnings is originally a kind of natural phenomena, but, China
The forest fire of 99% is caused by anthropic factor, and its basic characteristics are for be ignited by artificial naked light
Sylvosteppe surface-fire, surface-fire causes crown fire, if can not get in time at high-risk fire danger season
Control from little fire spread to big fire, and will once form extra big forest fires, and the intensity of a fire is lost the most
Control, current various countries are the most helpless to the intensity of a fire out of control, therefore, and control forest fire, control ground
Fiery the spreading of table is the most important thing of China's fire prevention of forest and steppe.But forest natively has big
Amount combustibles, trees itself are also combustibles, how to prevent and treat forest fire itself and exist certain
Difficulty.In terms of the research of forest fire protection material, the most less.
Summary of the invention
It is an object of the invention to provide a kind of forest fire protection flame-proof composite material and preparation side thereof
Method, adds to after this material disintegrating in combustibles, meets high volume when there is the condition of a fire the most swollen
Swollen, intercept combustibles and the contact of air, ignition point can be improved simultaneously, stop surface-fire to spread.
The present invention realizes especially by techniques below scheme:
A kind of forest fire protection flame-proof composite material, includes following components by weight:
Preferably, a kind of forest fire protection flame-proof composite material, include following components by weight:
High water wetted material of the present invention be the one in starch and polyvinylpyrrolidone or
The compositions of two kinds.High-temperature expansion material of the present invention be APP, Bis(pentaerythritol),
The compositions of one or more in tripolycyanamide.
Present invention also offers the preparation method of described a kind of forest fire protection flame-proof composite material, tool
Body comprises the following steps:
APP, Bis(pentaerythritol), tripolycyanamide are mixed with proportioning in sequence,
Load in ball grinder, stir with Glass rod, be then placed in appropriate steel ball, add a cover after tightening,
Rotational speed of ball-mill is adjusted to 120r/min, grinds 1h, prepare high-temperature expansion material.Again by height parent
Water material, Ce (HO)4、La2O3、Y2O3Put in proportion in aforementioned ball grinder, use glass
Rod stirs, and rotating speed is adjusted to 80r/min, grinds 1.5h.Finally sieve (40 μm),
Tinning, obtains a kind of forest fire protection flame-proof composite material.
Beneficial effects of the present invention: the present invention prepares a kind of high-temperature expansion material, this material powder
Add in combustibles volume in combustion after broken to acutely to expand, intercept combustibles and air
Contact, be combined by rare earth material and this macromolecular material, improve this material to ignition point
The ability of impact.Prepare a kind of high hydrophilic high molecular material simultaneously, these a large amount of water-retentions of material energy,
Time more than 100 DEG C, this material can dissolve in water, and after water evaporation, this material energy film forming is covered
It is placed on combustible surface, blocking oxygen.Bi-material is combined the composite flame-proof of the present invention obtained
Material, has the ignition point intercepting combustibles and air, can being covered in combustible surface and reduction
Feature.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, is only to this
The preferred embodiment of invention, not does the restriction of other forms to the present invention, any familiar
Professional and technical personnel is changed to become on an equal basis possibly also with the technology contents of the disclosure above
The Equivalent embodiments changed.Every without departing from the present invention program content, the technology according to the present invention is real
Any simple modification that confrontation following example are done or equivalent variations, all fall within the guarantor of the present invention
In the range of protecting.
Embodiment 1
A kind of forest fire protection flame-proof composite material (by weight) is by APP 20 parts, double
Tetramethylolmethane 15 parts, tripolycyanamide 10 parts, starch 20 parts, polyvinylpyrrolidone 25 parts,
Ce(HO)45 parts, La2O32 parts, Y2O33 parts formulated.Preparation method is with above-mentioned.
Embodiment 2
A kind of forest fire protection flame-proof composite material (by weight) is by APP 35 parts, double
Tetramethylolmethane 5, tripolycyanamide 5, starch 20 parts, polyvinylpyrrolidone 25 parts, Ce (HO)4
5 parts, La2O32 parts, Y2O33 parts formulated.Preparation method is with above-mentioned.
Embodiment 3
A kind of forest fire protection flame-proof composite material (by weight) is by APP 30 parts, double
Tetramethylolmethane 5, tripolycyanamide 15, starch 20 parts, polyvinylpyrrolidone 25 parts, Ce (HO)4
5 parts, La2O32 parts, Y2O33 parts formulated.Preparation method is with above-mentioned.
Embodiment 4
Embodiment 1, embodiment 2,3 three kinds of forest flame-proof composite materials of embodiment are made respectively
The fire retardant (solvent is water, volume fraction) of standby one-tenth 10% concentration, stand-by；By board using poplar board
(moisture content 12%, thickness 3mm) is prepared as the test specimen number of 150mm × 15mm × 3mm
Individual, stand-by；Then three test specimens are impregnated respectively in three kinds of fire retardants 24h, numbering 1,2,
3；Separately take a control sample, the water without any fire retardant impregnates 24h.Impregnated
Cheng Zhong, it is ensured that test specimen is fully located in solution.After having impregnated, air-dry about 5 days, until
Test specimen constant mass.
Test specimen is carried out combustibility test, and result shows, control sample fires the most rapidly
Burn, burning terminate after the most remaining ashes, and three test specimens soaked through three kinds of fire retardants are at point
The speed burnt away after combustion significantly slows down, and automatic distinguishing in a period of time the most after combustion,
Show that this series fire protection flame retarding composite all can significantly improve the fire resistance of poplar.Three examinations
The burning area of part is significantly different, for: No. 1 ＞ of No. 2 ＞ 3, show the resistance of No. 3 samples
Combustion performance the highest, 1 number it, No. 2 are minimum.
The SEM result of combustion product shows, the surface of three test specimens all occurs in that in various degree
Fine and close expand carbon-coating, consistency compares for No. 1 ＞ of No. 3 ＞ 2, No. 3 sample aperture minimums
The closeest, and it is thicker to expand carbon-coating, swelliong power is best.This fine and close appearance expanding carbon-coating,
Poplar can be intercepted contact with thermal source and source of the gas, thus reduce the combustibility of poplar.Expand carbon-coating
The thickest, the finest and close, then oxygen barrier, heat-insulating capability are the best, stop the effect of fire spreading to be got over
Significantly.
Embodiment 5
A kind of high-temperature expansion material (by weight) is by APP 30 parts, Bis(pentaerythritol)
5, tripolycyanamide 15 parts is formulated, and preparation method is with above-mentioned, and is prepared as 10% concentration
Fire retardant (solvent is water, volume fraction), numbering 4, stand-by.
On the basis of No. 4 high-temperature expansion materials, add Ce (HO)45 parts, La2O32 parts,
Y2O33 parts, preparation method is with above-mentioned, and (solvent is to be prepared as the fire retardant of 10% concentration
Water, volume fraction), numbering 5, stand-by.
The board using poplar board of above-mentioned processing is soaked respectively in 4, No. 5 fire retardants, soaking conditions
With process with above-mentioned.Two samples after processing are carried out combustibility test, and result shows, 5
The flame retardant effect of number fire retardant is better than No. 4 fire retardants.Rare earth material Ce (HO)4、La2O3And
Y2O3Interpolation, significantly improve the fire resistance of fire retardant, make the foaming of fire retardant and swollen
Swollen more abundant, the expansion carbon-coating of generation is the thickest finer and close, so that flame retardant effect is more preferable.
Embodiment 6
A kind of water wetted material (by weight) is by starch 20 parts and polyvinylpyrrolidone 25 parts
Mixed grinding forms, and is prepared into the solution (solvent is water, volume fraction) of 10% concentration,
Numbering 6, stand-by.
The board using poplar board of aforementioned processing is soaked respectively in No. 6 solution and aqueous solution, soaks bar
Part and process are with above-mentioned.Two samples after processing are carried out combustibility test, and result shows,
The sample soaked in aqueous solution burns the most rapidly, and burn the most remaining ashes after terminating,
And through the test specimen of No. 6 solution soaking, the speed burnt away after ignition has slowed down, and
Gradually extinguish after burning a period of time, show that this water wetted material has certain fire resistance.Should
After water wetted material is dissolved in water, at high temperature along with evaporation of water, on the poplar surface being burning
Forming thin film to cover thereon, this layer film serves certain blocking oxygen effect, from
And possess certain fire resistance.
Embodiment 7
On the basis of embodiment 4, further this kind of forest fire protection flame-proof composite material is fired
Burn performance test.Result shows, without the oxygen index (OI) of the poplar test specimen that this kind of fire proofing processes
About 20%, and the poplar test specimen after this kind of fire proofing processes, its oxygen index (OI) all increases to
More than 70%.In combustion, volume acutely expands this kind of forest fire protection flame-proof composite material,
Intercept comburant and the contact of air.Under the compound action of rare earth material, this forest fire protection hinders
The fire resistance of retardant composite material is greatly improved.Meanwhile, under the compound action of high water wetted material,
The ability of this forest fire protection flame-proof composite material blocking oxygen improves further.Finally make this
Bright composite flame-proof material, has obstruct combustibles and air, can be covered in combustible surface and fall
The feature of low ignition point.
Claims (5)
1. a forest fire protection flame-proof composite material, it is characterised in that include by weight with
Lower component:
A kind of forest fire protection flame-proof composite material the most according to claim 1, its feature
It is, includes following components by weight:
A kind of forest fire protection flame-proof composite material the most according to claim 1 and 2, its
Being characterised by, described high water wetted material is the one in starch and polyvinylpyrrolidone or two
The compositions planted.
A kind of forest fire protection flame-proof composite material the most according to claim 1 and 2, its
Being characterised by, described high-temperature expansion material is APP, Bis(pentaerythritol), tripolycyanamide
In the compositions of one or more.
5. a kind of forest fire protection flame-proof composite material described in claim 1, it is characterised in that
Comprise the following steps:
APP, Bis(pentaerythritol), tripolycyanamide are mixed with proportioning in sequence,
Load in ball grinder, stir with Glass rod, be then placed in appropriate steel ball, add a cover after tightening,
Rotational speed of ball-mill is adjusted to 120r/min, grinds 1h, prepare high-temperature expansion material.Again by height parent
Water material, Ce (HO)4、La2O3、Y2O3Put in proportion in aforementioned ball grinder, use glass
Rod stirs, and rotating speed is adjusted to 80r/min, grinds 1.5h.Finally sieve (40 μm),
Tinning, obtains a kind of forest fire protection flame-proof composite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610331738.5A CN106003313B (en) | 2016-05-18 | 2016-05-18 | A kind of forest fire protection flame retardant composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610331738.5A CN106003313B (en) | 2016-05-18 | 2016-05-18 | A kind of forest fire protection flame retardant composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106003313A true CN106003313A (en) | 2016-10-12 |
| CN106003313B CN106003313B (en) | 2019-09-10 |
Family
ID=57097721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610331738.5A Expired - Fee Related CN106003313B (en) | 2016-05-18 | 2016-05-18 | A kind of forest fire protection flame retardant composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106003313B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004520976A (en) * | 2001-03-21 | 2004-07-15 | ザ ユニバーシティー オブ メルボルン | Processed wood products and methods for their preparation |
| CN101143952A (en) * | 2007-09-12 | 2008-03-19 | 东北林业大学 | Flame-proof smoke-inhibiting wood-plastic composite material |
| CN102757563A (en) * | 2012-07-24 | 2012-10-31 | 成都硕屋科技有限公司 | Intumescent polymer phosphorus nitrogen halogen-free flame retardant and preparation method thereof |
| CN102964629A (en) * | 2012-11-23 | 2013-03-13 | 张家港顺昌化工有限公司 | Halogen-free flame retardant and method for preparing same |
| CN105037287A (en) * | 2015-07-08 | 2015-11-11 | 广东华南精细化工研究院有限公司 | Melamine polyphosphoric acid rare earth metal salt, synthetic method and application |
-
2016
- 2016-05-18 CN CN201610331738.5A patent/CN106003313B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004520976A (en) * | 2001-03-21 | 2004-07-15 | ザ ユニバーシティー オブ メルボルン | Processed wood products and methods for their preparation |
| CN101143952A (en) * | 2007-09-12 | 2008-03-19 | 东北林业大学 | Flame-proof smoke-inhibiting wood-plastic composite material |
| CN102757563A (en) * | 2012-07-24 | 2012-10-31 | 成都硕屋科技有限公司 | Intumescent polymer phosphorus nitrogen halogen-free flame retardant and preparation method thereof |
| CN102964629A (en) * | 2012-11-23 | 2013-03-13 | 张家港顺昌化工有限公司 | Halogen-free flame retardant and method for preparing same |
| CN105037287A (en) * | 2015-07-08 | 2015-11-11 | 广东华南精细化工研究院有限公司 | Melamine polyphosphoric acid rare earth metal salt, synthetic method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106003313B (en) | 2019-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Manzello et al. | Mass and size distribution of firebrands generated from burning Korean pine (Pinus koraiensis) trees | |
| Viegas et al. | Ignition of mediterranean fuel beds by several types of firebrands | |
| CN107127848B (en) | A kind of preparation method of flame-retardant smoke inhibition timber | |
| Choi et al. | Enhancing the thermal stability and fire retardancy of bio-based building materials through pre-biochar system | |
| Dubinin et al. | Experimental Investigation of the Flammable Properties and Factors of Wooden Products Exposed to the Fire Impact | |
| Grześkowiak | Evaluation of the effectiveness of the fire retardant mixture containing potassium carbonate using a cone calorimeter | |
| CN108262828A (en) | A kind of wood fire retardant and its application | |
| CN106003313A (en) | Flame-retarding composite material for forest fire protection and preparation method of flame-retarding composite material | |
| CN107652740B (en) | A kind of aqueous transparent ancient building fire retarding wood protection coating and preparation method thereof | |
| Manzello et al. | On the use of a firebrand generator to investigate the ignition of structures in wildland–urban interface (WUI) fires | |
| Karpovič et al. | Toxicity research of smouldering and flaming pine timber treated with fire retardant solutions | |
| Wang et al. | Fire-retardant and smoke-suppressant performance of an intumescent waterborne amino-resin fire-retardant coating for wood | |
| Min et al. | A study on fire performance evaluation of EIFS on anti-flaming finish by cone calorimeter test | |
| CN114654550B (en) | Flame-retardant wood, preparation method thereof and application of metal halide | |
| Gašpercová et al. | Influence of surface treatment of wood to the flame length and weight loss under load single-flame source | |
| CN106833259B (en) | A kind of frosting flame retardant coating and preparation method thereof | |
| Joseph et al. | Passive fire protection of ligno-cellulosic substrates using environmentally-friendly formulations | |
| WO2005054407A1 (en) | Fire extinguishing agent and treating agent preventing or diminishing fire danger | |
| Hou et al. | Probing the effects of density on combustion performance of cement-bonded particleboard produced from wood processing residues | |
| Ju et al. | Correlation analysis of heat flux and fire behaviour and hazards of polycrystalline silicon photovoltaic panels | |
| CN107638653B (en) | Preparation method of water-based fire extinguishing agent | |
| CN104922844B (en) | A kind of extinguishing chemical for putting out cotton spinning stacking fire | |
| KR102553127B1 (en) | Extinguishing foam composition when used on oil fires | |
| Okoye et al. | Effect of density on flame characteristics of some tropical timbers | |
| Ellis | A Review of Empirical Studies of Firebrand Behaviour |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190910 |