CN105999987A - Adsorption purification system - Google Patents

Adsorption purification system Download PDF

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Publication number
CN105999987A
CN105999987A CN201610625735.2A CN201610625735A CN105999987A CN 105999987 A CN105999987 A CN 105999987A CN 201610625735 A CN201610625735 A CN 201610625735A CN 105999987 A CN105999987 A CN 105999987A
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regeneration gas
adsorption tower
gas
regeneration
adsorption
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CN201610625735.2A
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CN105999987B (en
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张惊涛
黄文俊
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Chengdu Sepmem Sci & Tech Co Ltd
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Chengdu Sepmem Sci & Tech Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • B01D53/261Drying gases or vapours by adsorption
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/104Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/106Removal of contaminants of water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/41Further details for adsorption processes and devices using plural beds of the same adsorbent in series

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

The invention provides an adsorption purification system, which comprises a plurality of adsorption towers, a feed gas pipeline, a purified gas pipeline, a regenerated gas input pipeline, a regenerated gas output pipeline, a regenerated gas cooling system and a regenerated gas heating system. Each adsorption tower has a first interface and a second interface, the feed gas pipeline and the regenerated gas output pipeline are connected to the first interfaces and are selectively communicated with the inner cavities of the adsorption towers, the regenerated gas input pipeline and the purified gas pipeline are both connected to the second interfaces and are selectively communicated with the inner cavities of the adsorption towers, the inlets of the regenerated gas cooling system and the regenerated gas heating system are both connected to the second interfaces and are selectively communicated with the inner cavities of the adsorption towers, and the outlets of the regenerated gas cooling system and the regenerated gas heating system are both connected to the first interfaces and are selectively communicated with the inner cavities of the adsorption towers. During work, part of the adsorption towers are in series connection with the regenerated gas cooling system to perform cold blowing, and are then connected in series with part of the adsorption towers and the regenerated gas heating system to perform hot blowing, part of the adsorption towers are subjected to adsorption, and the consumption of regenerated gas is reduced.

Description

A kind of adsorption cleaning system
Technical field
The present invention relates to gas purification technique field, in particular to a kind of adsorption cleaning system.
Background technology
At present in gas purifying process, remove the CO in unstripped gas frequently with adsorbent2With moisture etc. Impurity, unstripped gas includes but not limited to natural gas.Absorption can be related in existing purification technological process The step of agent regeneration: unstripped gas is sent out-of-bounds, then by water saturation after adsorbent purifies Adsorbent passes through regeneration step, is separated by water from adsorbent.The regeneration step of adsorbent is divided into Hot blow and cold blowing: during hot blow, regeneration gas is directly entered adsorption tower heating absorption by heater after being heated Agent, after adsorbent is heated, the water in adsorbent evaporates and is reproduced the band of gas to walk and send out-of-bounds;Cold blowing Time, cooled regeneration gas is directly entered adsorption tower cooling adsorbent, the suction after hot blow and cold blowing Attached dose can be utilized again.The shortcoming of this technique is: regeneration gas consumes big, and regeneration is the most thorough.
Summary of the invention
The first object of the present invention is to provide a kind of adsorption cleaning system, and this adsorption cleaning system has Need less regeneration gas, to the advantage such as the regeneration of adsorbent is more thorough.
The present invention is achieved in that
A kind of adsorption cleaning system, including multiple adsorption towers, unstripped gas pipeline, purify air pipe, Regeneration gas intake line, regeneration gas output pipe, regeneration gas cooling system and regeneration gas heating are System;Adsorption tower has first interface and the second interface, unstripped gas pipeline and regeneration gas output pipe Be connected with first interface and optionally with the inner space of adsorption tower, regeneration gas intake line and Purify air pipe be all connected with the second interface and optionally with the inner space of adsorption tower;Regeneration The entrance of air cooling system and regeneration gas heating system is all connected with the second interface and optionally With the inner space of adsorption tower, the outlet of regeneration gas cooling system and regeneration gas heating system all with First interface connect and optionally with the inner space of adsorption tower;
When adsorption cleaning system is in running order: multiple adsorption towers include the absorption for cold blowing Tower, for the adsorption tower of hot blow with for the adsorption tower of adsorption cleaning, for cold blowing adsorption tower, Adsorption tower for hot blow, the adsorption tower for adsorption cleaning all with regeneration gas cooling system and Regeneration gas heating system serial communication, and regeneration gas cooling system is connected on the suction for cold blowing Between attached tower, regeneration gas heating system is connected between the adsorption tower of hot blow and for cold The adsorption tower that blows and between the adsorption tower of hot blow.
Further, in preferred embodiment of the present invention, unstripped gas pipeline includes that unstripped gas is total Pipe, multiple unstripped gas arm and multiple unstripped gas valve, the two ends of unstripped gas arm are respectively with former Material gas house steward and first interface connect, and unstripped gas valve is installed on unstripped gas arm and makes unstripped gas House steward's selectivity and the inner space of adsorption tower.
Further, in preferred embodiment of the present invention, purify air pipe and include that purification gas is total Pipe, multiple purification gas branch pipe and multiple purification air valve, purify the two ends of gas branch pipe respectively with only Activating QI house steward and the second interface connect, and purify air valve and are installed on purification gas branch pipe and make purification gas House steward's selectivity and the inner space of adsorption tower.
Further, in preferred embodiment of the present invention, regeneration gas intake line includes first Regeneration gas house steward, multiple first regeneration gas arm and multiple first regeneration gas valve, the first regeneration The two ends of gas branch pipe are connected with the first regeneration gas house steward and the second interface respectively, the first regeneration air valve Door is installed on the first regeneration gas arm and makes the interior of first regeneration gas house steward's selectivity and adsorption tower Chamber connects.
Further, in preferred embodiment of the present invention, regeneration gas output pipe includes second Regeneration gas house steward, multiple second regeneration gas arm and multiple second regeneration gas valve, the second regeneration The two ends of gas branch pipe are connected with the second regeneration gas house steward and first interface respectively, the second regeneration air valve Door is installed on the second regeneration gas arm and makes the interior of second regeneration gas house steward's selectivity and adsorption tower Chamber connects.
Further, in preferred embodiment of the present invention, regeneration gas cooling system includes regeneration Air cooling device, multiple 3rd regeneration gas arm, multiple 3rd regeneration gas valve, the multiple 4th Regeneration gas arm and multiple 4th regeneration gas valve, the two ends of the 3rd regeneration gas arm respectively with again Angry chiller and first interface connect, and the 3rd regeneration gas valve is installed on the 3rd regeneration gas and props up Manage and make the inner space of regeneration gas chiller selectivity and adsorption tower, the 4th regeneration gas arm Two ends be connected with regeneration gas chiller and the second interface respectively, the 4th regeneration gas valve install In the 4th regeneration gas arm the inner space that makes regeneration gas chiller selectivity and adsorption tower.
Further, in preferred embodiment of the present invention, regeneration gas heating system includes regeneration Gas heater, multiple 5th regeneration gas arm, multiple 5th regeneration gas valve, the multiple 6th Regeneration gas arm and multiple 6th regeneration gas valve, the two ends of the 5th regeneration gas arm respectively with again Angry heater and first interface connect, and the 5th regeneration gas valve is installed on the 5th regeneration gas and props up Manage and make the inner space of regeneration gas heater selectivity and adsorption tower, the 6th regeneration gas arm Two ends be connected with regeneration gas heater and the second interface respectively, the 6th regeneration gas valve install In the 6th regeneration gas arm the inner space that makes regeneration gas heater selectivity and adsorption tower.
Further, in preferred embodiment of the present invention, adsorption cleaning system includes 4-12 Individual adsorption tower.
Further, in preferred embodiment of the present invention, adsorption tower include adsorption tower body and Heat-exchanger rig, heat-exchanger rig includes the many heating members being arranged in adsorption tower, described heating member Between there is the space for filling adsorbent;Described heating member is heat exchanger tube or electrically heated rod.
Further, in preferred embodiment of the present invention, adsorption tower also includes being arranged on absorption The heat exchange jacket of the outer wall of tower body.
Further, in preferred embodiment of the present invention, the inwall of adsorption tower body is provided with Insulation insulating lining.
Further, in preferred embodiment of the present invention, adsorption tower is the most internal to be provided with by inhaling The multiple-hearth of attached dose of composition.
Further, in preferred embodiment of the present invention, regeneration gas is unstripped gas, purifies gas and outer Carry out at least one in gas.
Unstripped gas refers to the gas of process to be clean, purifies gas and refers to that purified gas, extraneous gas are Refer to other gases in addition to unstripped gas and purification gas.Preferably, extraneous gas is hydrogen, synthesis gas, sky In gas and nitrogen any one.The adsorption tower of the present invention and adsorption cleaning system may be used for the absorption of gas Purified treatment, be particularly suited for gas decarburization, be dehydrated, the de-technique such as heavy hydrocarbon, desulfurization.Unstripped gas Include but not limited to natural gas.
The invention has the beneficial effects as follows: the adsorption cleaning system that the present invention is obtained by above-mentioned design, make Used time, can will need adsorption tower that adsorbent is resolved and regeneration gas cooling system and regeneration Gas heating system is together in series, and regeneration gas can be introduced into the adsorption tower of hot blow and carry out cold blowing, so After through regeneration gas cooling system, then cooled regeneration gas enters other adsorption towers completing hot blow Carrying out cold blowing, then regeneration gas has entered suction through regeneration gas heating system, heated regeneration gas Attached adsorption tower carries out hot blow, and last regeneration gas is discharged.The adsorption cleaning system of the present invention can be filled Divide and utilize regeneration gas to carry out cold blowing and hot blow in system, and then need less compared to prior art Regeneration gas.
Accompanying drawing explanation
In order to be illustrated more clearly that the technical scheme of embodiment of the present invention, below will be in embodiment The required accompanying drawing used is briefly described, it will be appreciated that the following drawings illustrate only the present invention's Some embodiment, is therefore not construed as the restriction to scope, for those of ordinary skill in the art From the point of view of, on the premise of not paying creative work, it is also possible to obtain other according to these accompanying drawings and be correlated with Accompanying drawing.
Fig. 1 is the schematic diagram of the adsorption cleaning system that embodiment of the present invention provides;
Fig. 2 is the first the gas stream during adsorption tower cleaning system work of embodiment of the present invention offer To schematic diagram;
Fig. 3 is the schematic diagram after simplifying Fig. 2;
Fig. 4 is the second gas stream during adsorption tower cleaning system work of embodiment of the present invention offer To schematic diagram;
Fig. 5 is the schematic diagram after simplifying Fig. 3.
Figure acceptance of the bid note is respectively as follows:
Adsorption tower 1,2,3,4,5;Regeneration gas chiller 6;Regeneration gas heater 7,8;Former Material gas house steward 10;Unstripped gas arm 11,12,13,14,15;Purify gas house steward 20;Purification gas props up Pipe 21,22,23,24,25;First regeneration gas house steward 30;Regeneration gas main valve 300;First regeneration Gas branch pipe 31,32,33,34,35;First regeneration gas valve 301,302,303,304,305; Second regeneration gas house steward 60;Second regeneration gas arm 61,62,63,64,65;Second regeneration air valve Door 601a, 602a, 603a, 604a, 605a;3rd regeneration gas valve 301a, 302a, 303a, 304a、305a;4th regeneration gas valve 401,402,403,404,405;5th regeneration gas valve 401a、402a、403a、404a、405a、501a、502a、503a、504a、505a;6th again Angry valve 501,502,503,504,505,601,602,603,604,605.
Detailed description of the invention
For making the purpose of embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with Accompanying drawing in embodiment of the present invention, carries out clear, complete to the technical scheme in embodiment of the present invention Describe, it is clear that described embodiment is a part of embodiment of the present invention rather than complete wholely The embodiment in portion.Based on the embodiment in the present invention, those of ordinary skill in the art are not making Go out the every other embodiment obtained under creative work premise, broadly fall into the model of present invention protection Enclose.Therefore, below the detailed description of the embodiments of the present invention provided in the accompanying drawings is not intended to Limit the scope of claimed invention, but be merely representative of the selected embodiment of the present invention.Base Embodiment in the present invention, those of ordinary skill in the art are not making creative work premise Lower obtained every other embodiment, broadly falls into the scope of protection of the invention.
Additionally, term " first ", " second " etc. are only used for describing purpose, and it is not intended that refer to Show or imply relative importance or the implicit quantity indicating indicated technical characteristic.Thus, limit The feature having " first ", " second " etc. can express or implicitly include one or more This feature.In describing the invention, " multiple " are meant that two or more, unless separately There is the most concrete restriction.
As it is shown in figure 1, the adsorption cleaning system that embodiments of the invention provide includes: adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4, adsorption tower 5, unstripped gas pipeline, purification gas Pipeline, regeneration gas intake line, regeneration gas output pipe, regeneration gas cooling system and regeneration gas Heating system.
Adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 in the present embodiment Structure identical, so only describing its structure as a example by one of them adsorption tower.Such as, Adsorption tower 1 includes adsorption tower body (not marking in figure) and heat-exchanger rig (not shown), heat exchange Device includes the many heat exchanger tubes being arranged in adsorption tower, has for filling suction between heat exchanger tube The space of attached dose.Further, in preferred embodiment of the present invention, adsorption tower also includes setting Put the heat exchange jacket of outer wall at adsorption tower body.Further, preferably implement in the present invention In example, the inwall of adsorption tower body is provided with insulation insulating lining.Further, in the present invention In preferred embodiment, adsorption tower is the most internal is provided with the multiple-hearth being made up of adsorbent.
Further, adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4, adsorption tower 5 It is respectively provided with first interface and the second interface.First interface and the second interface are correspondingly arranged at suction respectively The bottom of attached tower and top.When unstripped gas is carried out adsorption cleaning, first interface and second connects Mouth is unstripped gas entrance and the clean gas outlet of adsorption tower respectively;When to the adsorbent in adsorption tower When resolving, first interface and the second interface are regeneration gas outlet and the regeneration of adsorption tower respectively Gas entrance.Additionally, the position of first interface and the second interface can also be exchanged with each other setting.
Unstripped gas pipeline and regeneration gas output pipe be connected with first interface and optionally with suction The inner space of attached tower, regeneration gas intake line and purification air pipe are all connected also with the second interface Optionally with the inner space of adsorption tower;Regeneration gas cooling system and regeneration gas heating system Entrance be all connected with the second interface and optionally with the inner space of adsorption tower, regeneration gas cools down The outlet of system and regeneration gas heating system be all connected with first interface and optionally with absorption The inner space of tower.
Referring to Fig. 1, the adsorption cleaning system of the present embodiment is described in further detail.
Further, unstripped gas pipeline includes unstripped gas house steward 10, unstripped gas arm 11, former Material gas branch pipe 12, unstripped gas arm 13, unstripped gas arm 14, unstripped gas arm 15, raw material Air valve 101, unstripped gas valve 102, unstripped gas valve 103, unstripped gas valve 104, former Material air valve 105.
The two ends of unstripped gas arm 11 first connecing with unstripped gas house steward 10 and adsorption tower 1 respectively Mouth connects.Unstripped gas valve 101 is installed on unstripped gas arm 11 and makes unstripped gas house steward 10 select Selecting property and the inner space of adsorption tower 1.
The two ends of unstripped gas arm 12 first connecing with unstripped gas house steward 10 and adsorption tower 2 respectively Mouth connects.Unstripped gas valve 102 is installed on unstripped gas arm 12 and makes unstripped gas house steward 10 Selectivity and the inner space of adsorption tower 2.
The two ends of unstripped gas arm 13 first connecing with unstripped gas house steward 10 and adsorption tower 3 respectively Mouth connects.Unstripped gas valve 103 is installed on unstripped gas arm 13 and makes unstripped gas house steward 10 Selectivity and the inner space of adsorption tower 3.
The two ends of unstripped gas arm 14 first connecing with unstripped gas house steward 10 and adsorption tower 4 respectively Mouth connects.Unstripped gas valve 104 is installed on unstripped gas arm 14 and makes unstripped gas house steward 10 Selectivity and the inner space of adsorption tower 4.
The two ends of unstripped gas arm 15 first connecing with unstripped gas house steward 10 and adsorption tower 5 respectively Mouth connects.Unstripped gas valve 105 is installed on unstripped gas arm 15 and makes unstripped gas house steward 10 Selectivity and the inner space of adsorption tower 5.
By above design, unstripped gas house steward 10 can with selectivity and adsorption tower 1, adsorption tower 2, One or more inner space in adsorption tower 3, adsorption tower 4 and adsorption tower 5.And then, Unstripped gas house steward 10 can be optionally to adsorption tower 1, adsorption tower 2, adsorption tower 3, absorption One or more transferring raw material gas in tower 4 and adsorption tower 5.
Further, purify air pipe to include purifying gas house steward 20, purify gas branch pipe 21, clean Activating QI arm 22, purification gas branch pipe 23, purification gas branch pipe 24, purification gas branch pipe 25, purification Air valve 201, purification air valve 202, purification air valve 203, purification air valve 204 and Purify air valve 205.
The two ends purifying gas branch pipe 21 connect with purify gas house steward 20 and adsorption tower 1 second respectively Mouth connects.Purify air valve 201 be installed on purification gas branch pipe 21 and make purification gas house steward 20 Selectivity and the inner space of adsorption tower 1.
The two ends purifying gas branch pipe 22 connect with purify gas house steward 20 and adsorption tower 2 second respectively Mouth connects.Purify air valve 202 be installed on purification gas branch pipe 22 and make purification gas house steward 20 Selectivity and the inner space of adsorption tower 2.
The two ends purifying gas branch pipe 23 connect with purify gas house steward 20 and adsorption tower 3 second respectively Mouth connects.Purify air valve 203 be installed on purification gas branch pipe 23 and make purification gas house steward 20 Selectivity and the inner space of adsorption tower 3.
The two ends purifying gas branch pipe 24 connect with purify gas house steward 20 and adsorption tower 4 second respectively Mouth connects.Purify air valve 204 be installed on purification gas branch pipe 24 and make purification gas house steward 20 Selectivity and the inner space of adsorption tower 4.
The two ends purifying gas branch pipe 25 connect with purify gas house steward 20 and adsorption tower 5 second respectively Mouth connects.Purify air valve 205 be installed on purification gas branch pipe 25 and make purification gas house steward 20 Selectivity and the inner space of adsorption tower 5.
By above design, purify gas house steward 20 can with selectivity and adsorption tower 1, adsorption tower 2, One or more inner space in adsorption tower 3, adsorption tower 4 and adsorption tower 5.And then, Purifying gas house steward 20 can be optionally from adsorption tower 1, adsorption tower 2, adsorption tower 3, absorption One or more output in tower 4 and adsorption tower 5 purifies gas.It should be noted that absorption Purify under duty, with same absorption while of unstripped gas house steward 10 and purification gas house steward 20 The inner space of tower.
Further, in preferred embodiment of the present invention, regeneration gas intake line includes first Regeneration gas house steward the 30, first regeneration gas arm the 31, first regeneration gas arm 32, first regenerates Gas branch pipe the 33, first regeneration gas arm the 34, first regeneration gas arm 35, first regenerates air valve Door 301, first regeneration gas valve the 302, first regeneration gas valve 303, first regenerates air valve Door 304 and the first regeneration gas valve 305.It is provided with regeneration gas on first regeneration gas house steward 30 Main valve 300.
The two ends of the first regeneration gas arm 31 respectively with the first regeneration gas house steward 30 and adsorption tower 1 Second interface connect.First regeneration gas valve 301 is installed on the first regeneration gas arm 31 also Make the inner space of the first regeneration gas house steward 30 selectivity and adsorption tower 1.
The two ends of the first regeneration gas arm 32 respectively with the first regeneration gas house steward 30 and adsorption tower 2 Second interface connect.First regeneration gas valve 302 is installed on the first regeneration gas arm 32 also Make the inner space of the first regeneration gas house steward 30 selectivity and adsorption tower 2.
The two ends of the first regeneration gas arm 33 respectively with the first regeneration gas house steward 30 and adsorption tower 3 Second interface connect.First regeneration gas valve 303 is installed on the first regeneration gas arm 33 also Make the inner space of the first regeneration gas house steward 30 selectivity and adsorption tower 3.
The two ends of the first regeneration gas arm 34 respectively with the first regeneration gas house steward 30 and adsorption tower 4 Second interface connect.First regeneration gas valve 304 is installed on the first regeneration gas arm 34 also Make the inner space of the first regeneration gas house steward 30 selectivity and adsorption tower 4.
The two ends of the first regeneration gas arm 35 respectively with the first regeneration gas house steward 30 and adsorption tower 5 Second interface connect.First regeneration gas valve 305 is installed on the first regeneration gas arm 35 also Make the inner space of the first regeneration gas house steward 30 selectivity and adsorption tower 5.
By above design, the first regeneration gas house steward 30 can be with selectivity and adsorption tower 1, suction One or more inner chamber in attached tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 is even Logical.And then, the first regeneration gas house steward 30 can optionally to adsorption tower 1, adsorption tower 2, One or more conveying regeneration gas in adsorption tower 3, adsorption tower 4 and adsorption tower 5.
Further, in preferred embodiment of the present invention, regeneration gas output pipe includes second Regeneration gas house steward the 60, second regeneration gas arm the 61, second regeneration gas arm 62, second regenerates Gas branch pipe the 63, second regeneration gas arm the 64, second regeneration gas arm 65, second regenerates air valve Door 601a, the second regeneration gas valve 602a, the second regeneration gas valve 603a, the second regeneration gas Valve 604a and the second regeneration gas valve 605a.
The two ends of the second regeneration gas arm 61 respectively with the second regeneration gas house steward 60 and adsorption tower 1 Second interface connect.Second regeneration gas valve 601a is installed on the second regeneration gas arm 61 also Make the inner space of the second regeneration gas house steward 60 selectivity and adsorption tower 1.
The two ends of the second regeneration gas arm 62 respectively with the second regeneration gas house steward 60 and adsorption tower 2 Second interface connect.Second regeneration gas valve 602a is installed on the second regeneration gas arm 62 also Make the inner space of the second regeneration gas house steward 60 selectivity and adsorption tower 2.
The two ends of the second regeneration gas arm 63 respectively with the second regeneration gas house steward 60 and adsorption tower 3 Second interface connect.Second regeneration gas valve 603a is installed on the second regeneration gas arm 63 also Make the inner space of the second regeneration gas house steward 60 selectivity and adsorption tower 3.
The two ends of the second regeneration gas arm 64 respectively with the second regeneration gas house steward 60 and adsorption tower 4 Second interface connect.Second regeneration gas valve 604a is installed on the second regeneration gas arm 64 also Make the inner space of the second regeneration gas house steward 60 selectivity and adsorption tower 4.
The two ends of the second regeneration gas arm 65 respectively with the second regeneration gas house steward 60 and adsorption tower 5 Second interface connect.Second regeneration gas valve 605a is installed on the second regeneration gas arm 65 also Make the inner space of the second regeneration gas house steward 60 selectivity and adsorption tower 5.
By above design, the second regeneration gas house steward 60 can be with selectivity and adsorption tower 1, suction One or more inner chamber in attached tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 is even Logical.And then, the second regeneration gas house steward 60 can optionally from adsorption tower 1, adsorption tower 2, One or more output regeneration gas in adsorption tower 3, adsorption tower 4 and adsorption tower 5.
Further, in preferred embodiment of the present invention, regeneration gas cooling system includes regeneration 6, five the 3rd regeneration gas arms (not marking in figure) of air cooling device, the 3rd regeneration air valve Door 301a, the 3rd regeneration gas valve 302a, the 3rd regeneration gas valve 303a, the 3rd regeneration gas Valve 304a, the 3rd regeneration gas valve 305a, five the 4th regeneration gas arms (are not marked in figure Note), the 4th regeneration gas valve the 401, the 4th regeneration gas valve the 402, the 4th regeneration gas valve 403, the 4th regeneration gas valve 404 and the 4th regeneration gas valve 405.
One end of above-mentioned five the 3rd regeneration gas arms respectively with the entering of regeneration gas chiller 6 Mouthful connect, and the other end of above-mentioned five the 3rd regeneration gas arms respectively with adsorption tower 1, inhale First interface in attached tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 connects.3rd again Angry valve 301a, the 3rd regeneration gas valve 302a, the 3rd regeneration gas valve 303a, the 3rd Regeneration gas valve 304a and the 3rd regeneration gas valve 305a is respectively correspondingly arranged on above-mentioned five 3rd regeneration gas arm, and the 3rd regeneration gas valve 301a, the 3rd regeneration gas valve 302a, 3rd regeneration gas valve 303a, the 3rd regeneration gas valve 304a and the 3rd regeneration gas valve 305a Make regeneration gas chiller 6 optionally with adsorption tower 1, adsorption tower 2, adsorption tower 3, inhale Attached tower 4 and one or more inner space of adsorption tower 5.It is to say, regeneration gas can With optionally from adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 In one or more enter regeneration gas chiller 6, regeneration gas chiller 6 is to regeneration Gas cools down.
One end of above-mentioned five the 4th regeneration gas arms respectively with the going out of regeneration gas chiller 6 Mouthful connect, and the other end of above-mentioned five the 4th regeneration gas arms respectively with adsorption tower 1, inhale The second interface in attached tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 connects.4th again Angry valve the 401, the 3rd regeneration gas valve the 402, the 3rd regeneration gas valve the 403, the 3rd is again Angry valve 404 and the 3rd regeneration gas valve 405 are respectively correspondingly arranged on above-mentioned five the 4th Regeneration gas arm, and the 3rd regeneration gas valve the 401, the 3rd regeneration gas valve the 402, the 3rd Regeneration gas valve the 403, the 3rd regeneration gas valve 404 and the 3rd regeneration gas valve 405 make regeneration Air cooling device 6 optionally with adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4 One or more inner space with adsorption tower 5.It is to say, regeneration gas can be from again Angry chiller 6 is selectively entered adsorption tower 1, adsorption tower 2, adsorption tower 3, absorption One or more in tower 4 and adsorption tower 5.It should be noted that under cold blowing state, the Three regeneration gas arms and the 4th regeneration gas arm and the inner space of different adsorption towers.
Further, in preferred embodiment of the present invention, regeneration gas heating system includes regeneration Gas heater 7,8, ten the 5th regeneration gas arms of regeneration gas heater (are not marked in figure Note), the 5th regeneration gas valve 401a, the 5th regeneration gas valve 402a, the 5th regeneration gas valve 403a, the 5th regeneration gas valve 404a, the 5th regeneration gas valve 405a, the 5th regeneration air valve Door 501a, the 5th regeneration gas valve 502a, the 5th regeneration gas valve 503a, the 5th regeneration gas Valve 504a, the 5th regeneration gas valve 505a, ten the 6th regeneration gas arms (are not marked in figure Note) and the 6th regeneration gas valve the 501, the 6th regeneration gas valve the 502, the 6th regeneration gas valve 503, the 6th regeneration gas valve the 504, the 6th regeneration gas valve the 505, the 6th regeneration gas valve 601, the 6th regeneration gas valve the 602, the 6th regeneration gas valve the 603, the 6th regeneration gas valve 604, the 6th regeneration gas valve 605.Regeneration gas heating system and annexation and regeneration gas Cooling system is similar to, and specifically refer to Fig. 1, does not repeats them here.
By above design, the 5th regeneration gas valve 401a, the 5th regeneration gas valve 402a, 5th regeneration gas valve 403a, the 5th regeneration gas valve 404a and the 5th regeneration gas valve 405a Make regeneration gas heater 7 inlet selective with adsorption tower 1, adsorption tower 2, absorption One or more inner space in tower 3, adsorption tower 4 and adsorption tower 5.5th regeneration Air valve 501a, the 5th regeneration gas valve 502a, the 5th regeneration gas valve 503a, the 5th again Angry valve 504a and the 5th regeneration gas valve 505a makes the outlet of regeneration gas heater 7 Optionally with in adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 One or more inner space.6th regeneration gas valve the 501, the 6th regeneration gas valve 502, the 6th regeneration gas valve the 503, the 6th regeneration gas valve 504 and the 6th regeneration gas valve 505 egress selections making regeneration gas heater 8 with adsorption tower 1, adsorption tower 2, One or more inner space in adsorption tower 3, adsorption tower 4 and adsorption tower 5.6th Regeneration gas valve the 601, the 6th regeneration gas valve the 602, the 6th regeneration gas valve the 603, the 6th Regeneration gas valve 604 and the 6th regeneration gas valve 605 make the entrance of regeneration gas heater 8 Optionally with in adsorption tower 1, adsorption tower 2, adsorption tower 3, adsorption tower 4 and adsorption tower 5 One or more inner space.It should be noted that under hot blow state, the 5th regeneration Gas branch pipe and the 6th regeneration gas arm and the inner space of different adsorption towers.
Adsorption cleaning below as a example by the duty shown in Fig. 2 and Fig. 3, to the present embodiment Work process and the principle of system are described further.
In duty shown in Fig. 2, adsorption tower 1 carries out absorption process, adsorption tower 2 Carry out cold blowing operation, adsorption tower 4 and adsorption tower 5 with adsorption tower 3 and carry out hot blow operation.
For the ease of understanding the connection feelings of each pipeline of adsorption cleaning system under this duty The opening and closing situation of condition and valve, gives the rough schematic view that Fig. 3, Fig. 3 are Fig. 2.Figure The valve remained in 3 is all opened, valve not shown in Fig. 3 shown in Fig. 2 It is all Guan Bi, and then, the connection of pipeline can also be found out with being apparent from by the opening and closing of valve Situation.
Below in conjunction with Fig. 3, further illustrate in absorption process, cold blowing operation and hot blow operation Gas flow.
Absorption process: unstripped gas sequentially passes through unstripped gas house steward 10 and raw material from unstripped gas entrance Gas branch pipe 11 enters into and carries out adsorption cleaning process in adsorption tower 1, is cleaned the raw material of process Gas becomes purification gas and sequentially passes through purification gas branch pipe 21 and purify gas house steward 20 and go out from purifying gas Mouth is discharged.
Cold blowing operation: regeneration gas from regeneration gas entrance sequentially pass through the first regeneration gas house steward 30, First regeneration gas arm 31 and purification gas branch pipe 22 enter in adsorption tower 2 and carry out cold to adsorbent Blowing, then unstripped gas arm 12 and the 3rd is discharged and sequentially passed through to this regeneration gas from adsorption tower 2 Regeneration gas arm enters regeneration gas chiller 6, and regeneration gas is carried out by regeneration gas chiller 6 Cooling, then cooled regeneration gas sequentially passes through the 4th regeneration gas arm and purifies gas branch pipe 23 entrance adsorption towers 3 carry out cold blowing to adsorbent.
Hot blow operation: the regeneration gas discharged from adsorption tower 3 is through unstripped gas arm 13 and the Five enter regeneration gas heater 7 heats, and heated regeneration gas sequentially passes through the 6th again Angry arm and purification gas branch pipe 24 enter in adsorption tower 4 and adsorbent are carried out hot blow;Connect , regeneration gas sequentially passes through unstripped gas arm 14 and the 5th regeneration gas arm enters regeneration gas and adds Thermal 8 heats, and heated regeneration gas sequentially passes through the 6th regeneration gas arm and purification Gas branch pipe 25 enters and carries out hot blow in adsorption tower 5, and last regeneration gas sequentially passes through unstripped gas and props up Pipe 15 and the second regeneration gas house steward 60 discharge from regeneration gas outlet.
Shown in Fig. 4 is the subsequent work state of the duty shown in Fig. 2, and Fig. 5 is to figure 3 simplify after schematic diagram.In the duty shown in Fig. 4, adsorption tower 3 is carried out Absorption process, adsorption tower 2 and adsorption tower 4 carry out cold blowing operation, adsorption tower 1 and adsorption tower 5 carry out hot blow operation.
Can be clear that from Fig. 3 and Fig. 5, no matter under which duty, then Angry chiller 6, regeneration gas heater 7 and regeneration gas heater 8 can and its In four adsorption towers be in series connection, only just complete four absorption by a small amount of regeneration gas Tower carries out the work of desorption, and therefore, this adsorption cleaning system of the present embodiment is to regeneration gas Consumption greatly reduce.
The foregoing is only the preferred embodiment of the present invention, be not limited to this Bright, for a person skilled in the art, the present invention can have various modifications and variations.All Within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, Should be included within the scope of the present invention.

Claims (10)

1. an adsorption cleaning system, it is characterised in that include multiple adsorption tower, unstripped gas Pipeline, purification air pipe, regeneration gas intake line, regeneration gas output pipe, regeneration gas cooling System and regeneration gas heating system;Described adsorption tower has first interface and the second interface, described Unstripped gas pipeline and described regeneration gas output pipe are connected with described first interface and optionally Equal with the inner space of described adsorption tower, described regeneration gas intake line and described purification air pipe Be connected with described second interface and optionally with the inner space of described adsorption tower;Described regeneration The entrance of air cooling system and described regeneration gas heating system is all connected also with described second interface Optionally with the inner space of described adsorption tower, described regeneration gas cooling system and described regeneration The outlet of gas heating system be all connected with described first interface and optionally with described adsorption tower Inner space;
When described adsorption cleaning system is in running order: multiple described adsorption towers include for cold Adsorption tower, the adsorption tower for hot blow and the adsorption tower for adsorption cleaning blown, for cold blowing Described adsorption tower, the described adsorption tower for hot blow, the described adsorption tower for adsorption cleaning All with described regeneration gas cooling system and described regeneration gas heating system serial communication, and institute Stating regeneration gas cooling system to be connected between the described adsorption tower of cold blowing, described regeneration gas adds Hot systems be connected between the adsorption tower of hot blow and for cold blowing described adsorption tower and Between the described adsorption tower of hot blow.
Adsorption cleaning system the most according to claim 1, it is characterised in that described former Material air pipe includes unstripped gas house steward, multiple unstripped gas arm and multiple unstripped gas valve, described The two ends of unstripped gas arm are connected with described unstripped gas house steward and described first interface respectively, described Unstripped gas valve is installed on described unstripped gas arm and makes described unstripped gas house steward's selectivity and institute State the inner space of adsorption tower.
Adsorption cleaning system the most according to claim 1, it is characterised in that described only Activating QI pipeline includes purifying gas house steward, multiple purification gas branch pipe and multiple purification air valve, described The two ends purifying gas branch pipe are connected with described purification gas house steward and described second interface respectively, described Purify air valve be installed on described purification gas branch pipe and make described purification gas house steward's selectivity and institute State the inner space of adsorption tower.
Adsorption cleaning system the most according to claim 1, it is characterised in that described again Angry intake line includes the first regeneration gas house steward, multiple first regeneration gas arm and multiple first Regeneration gas valve, the two ends of described first regeneration gas arm respectively with described first regeneration gas house steward Connecting with described second interface, described first regeneration gas valve is installed on described first regeneration gas and props up Manage and make the inner space of described first regeneration gas house steward's selectivity and described adsorption tower.
Adsorption cleaning system the most according to claim 1, it is characterised in that described again Angry output pipe includes the second regeneration gas house steward, multiple second regeneration gas arm and multiple second Regeneration gas valve, the two ends of described second regeneration gas arm respectively with described second regeneration gas house steward Connecting with described first interface, described second regeneration gas valve is installed on described second regeneration gas and props up Manage and make the inner space of described second regeneration gas house steward's selectivity and described adsorption tower.
Adsorption cleaning system the most according to claim 1, it is characterised in that described again Angry cooling system include regeneration gas chiller, multiple 3rd regeneration gas arm, the multiple 3rd Regeneration gas valve, multiple 4th regeneration gas arm and multiple 4th regeneration gas valve, the described 3rd The two ends of regeneration gas arm are connected with described regeneration gas chiller and described first interface respectively, Described 3rd regeneration gas valve is installed on described 3rd regeneration gas arm and makes described regeneration air cooling Radiator cooler selectivity and the inner space of described adsorption tower, the two ends of described 4th regeneration gas arm It is connected with described regeneration gas chiller and described second interface respectively, described 4th regeneration air valve Door is installed on described 4th regeneration gas arm and makes described regeneration gas chiller selectivity and institute State the inner space of adsorption tower.
Adsorption cleaning system the most according to claim 1, it is characterised in that described again Angry heating system include regeneration gas heater, multiple 5th regeneration gas arm, the multiple 5th Regeneration gas valve, multiple 6th regeneration gas arm and multiple 6th regeneration gas valve, the described 5th The two ends of regeneration gas arm are connected with described regeneration gas heater and described first interface respectively, Described 5th regeneration gas valve is installed on described 5th regeneration gas arm and makes described regeneration gas add Thermal selectivity and the inner space of described adsorption tower, the two ends of described 6th regeneration gas arm It is connected with described regeneration gas heater and described second interface respectively, described 6th regeneration air valve Door is installed on described 6th regeneration gas arm and makes described regeneration gas heater selectivity and institute State the inner space of adsorption tower.
8. according to the adsorption cleaning system described in any one of claim 1-7, it is characterised in that Described adsorption cleaning system includes 4-12 described adsorption tower.
9. according to the adsorption cleaning system described in any one of claim 1-7, it is characterised in that Described adsorption tower includes that adsorption tower body and heat-exchanger rig, described heat-exchanger rig include many settings Heating member in described adsorption tower, has the sky for filling adsorbent between described heating member Gap;Described heating member is heat exchanger tube or electrically heated rod.
Adsorption cleaning system the most according to claim 9, it is characterised in that described suction Attached tower also includes the insulating lining being arranged on the inwall of described adsorption tower body.
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CN107008104A (en) * 2017-05-23 2017-08-04 成都赛普瑞兴科技有限公司 A kind of pressure-swing absorption apparatus and effective gas recovery method
CN111744318A (en) * 2020-06-30 2020-10-09 四川杰瑞恒日天然气工程有限公司 Odor treatment process for landfill gas

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CN103007676A (en) * 2012-12-19 2013-04-03 中国科学院理化技术研究所 Movable skid-mounted natural/coal bed gas adsorption and purification system with external medium heat exchange function
CN205832892U (en) * 2016-08-02 2016-12-28 成都赛普瑞兴科技有限公司 A kind of adsorption cleaning system

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CN201634651U (en) * 2010-01-15 2010-11-17 北京长征天民高科技有限公司 Natural gas liquification decarburization and dehydration device
CN103007676A (en) * 2012-12-19 2013-04-03 中国科学院理化技术研究所 Movable skid-mounted natural/coal bed gas adsorption and purification system with external medium heat exchange function
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CN107008104A (en) * 2017-05-23 2017-08-04 成都赛普瑞兴科技有限公司 A kind of pressure-swing absorption apparatus and effective gas recovery method
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CN111744318A (en) * 2020-06-30 2020-10-09 四川杰瑞恒日天然气工程有限公司 Odor treatment process for landfill gas
CN111744318B (en) * 2020-06-30 2022-06-24 四川杰瑞恒日天然气工程有限公司 Odor treatment process for landfill gas

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