CN105986334A - Antibacterial soft magnetic door gauze and preparation method thereof - Google Patents
Antibacterial soft magnetic door gauze and preparation method thereof Download PDFInfo
- Publication number
- CN105986334A CN105986334A CN201610111726.1A CN201610111726A CN105986334A CN 105986334 A CN105986334 A CN 105986334A CN 201610111726 A CN201610111726 A CN 201610111726A CN 105986334 A CN105986334 A CN 105986334A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- minute
- parts
- acid
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses antibacterial soft magnetic door gauze. The gauze comprises the following raw materials in parts by weight: 1-2 parts of fatty acid diethanol amide, 0.5-1 part of calcium propionate, 7-10 parts of 0.1-0.15mol/l ammonium persulfate aqueous solution, 70-74 parts of aniline, 2-3 parts of 0.5-0.6mol/l hydrochloric acid, 1-2 parts of carbon nanotube, 140-160 parts of 80-90% formic acid, 40-50 parts of nylon 6, 0.6-1 part of octyl isothiazolone, 0.2-0.3 part of vinyl succinate, 0.1-0.2 part of triphenylphosphine, 1-2 parts of ascorbic acid, 0.3-0.4 part of zinc pyrithione and 0.2-0.5 part of dodecafluoroheptyl-propyl-trimethoxysilane. The gauze has the advantages that the antibacterial property of the finished product can be well improved due to addition of octyl isothiazolone, calcium propionate, triphenylphosphine, and the like.
Description
Technical field
The present invention relates to gauze technical field, particularly relate to a kind of antibacterial soft magnetism door gauze and preparation method thereof.
Background technology
Although Conductive Polyaniline Fibers has preferable electric conductivity, but the poor stability of polyaniline solutions, when solid is dense
When degree is more than 6%, after the short time places, spinning liquid will produce gel, dense needed for solvent spinning technology shaped fibers
Degree (> 10%) under, the formation of gel hinders the use of solution, the most difficult with its spinning, to solvent and spinning equipment requirement
Height, and the physical and mechanical properties of the fiber prepared is poor, intensity is low, and fragility is big, spins it, weaves Deng Hou road processing phase
Work as difficulty.In order to improve the physical and mechanical properties of fiber and improve its application, can be by polyaniline and general fibroblast copolymer
Composite conducting fiber is prepared by co-blended spinning.
Electromagnetic radiation is ubiquitous, and thunder and lightning in nature, Sunspot Activities etc. all can produce electromagnetic radiation, and at electricity
Today that scarabaeidae skill, the network communications technology develop rapidly, increasing electrical equipment, communication apparatus etc. incorporate the life of people
Living, these equipment, while offering convenience to user, also bring a certain degree of harm.They operationally none examples
Other places can be to emission certain frequency and the electromagnetic wave of certain energy, and in electronic technology, communication technology highly developed today,
Electromagnetic radiation is flooded with each space, has become as the fourth-largest environment after water pollution, atmospheric pollution, sound pollution dirty
Dye.The normal work of the equipment such as broadcast, TV, communication not only can be impacted by electromagnetic radiation, and can directly make human body
Become injury, by heat effect, non-thermal effect, accumulative effect etc., to the nervous system of human body, cardiovascular system, hormonal system,
Reproductive system etc. all can cause injury in various degree.For reducing hazards of electromagnetic radiation, on the one hand people take the initiative protection, i.e.
Electromagnetic radiation source is shielded, reduces the leakage of electromagnetic wave outside circle as far as possible, alleviate the harm to environment;On the other hand then adopt
Take passive protection, be primarily referred to as utilizing electromagnetic shielding protective material that specific region or specific crowd are taked shielding protection, reduce
The electromagnetic wave electromagnetic radiation pollution to human body;
The present Research of electromagnetic radiation protective materiall be directed to develop " light, soft, thin, wide " new material, i.e. pursue lightweight,
Flexibility, thin-walled, the architectural feature of wideband, and use gradient-structure to absorb and reflection electromagnetic wave, it is achieved high shield effectiveness.Conduction
Fiber, as a kind of softness, the new material of light weight, is just playing the most important effect in electromagnetic shielding material field;Profit
With electromagnetic wave shielding and the absorption property of conductive fiber, there are fabric and the fibre reinforced composites of electro-magnetic screen function in a large number
It is manufactured.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of antibacterial soft magnetism door gauze and preparation side thereof
Method.
The present invention is achieved by the following technical solutions:
A kind of antibacterial soft magnetism door gauze, it is made up of the raw material of following weight parts:
Fatty diglycollic amide 1-2, the ammonium persulfate aqueous solution 7-10 of calcium propionate 0.5-1,0.1-0.15mol/l, aniline 70-
74, the hydrochloric acid 2-3 of 0.5-0.6mol/l, the formic acid 140-160 of CNT 1-2,80-90%, nylon 6 40-50, the different thiophene of octyl group
Oxazoline ketone 0.6-1, alkenyl succinic acid ester 0.2-0.3, triphenylphosphine 0.1-0.2, ascorbic acid 1-2, Zinc Pyrithione 0.3-
0.4, ten difluoro heptyl propyl trimethoxy silicane 0.2-0.5.
The preparation method of a kind of described antibacterial soft magnetism door gauze, comprises the following steps:
(1) taking volume ratio is the sulphuric acid of 3-4:1, salpeter solution mixing, stirs, and described sulfuric acid concentration is 90-95%, nitre
Acid concentration is 60-70%;
(2) by above-mentioned Zinc Pyrithione, calcium propionate mixing, joining in the deionized water of compound weight 10-14 times, stirring is all
Even, obtain saline solution;
(3) above-mentioned CNT is joined in above-mentioned mixed acid solution, at 50-60 DEG C ultrasonic 200-250 minute, centrifugal point
From, lower sediment is joined in above-mentioned saline solution, insulated and stirred 20-30 minute at 60-70 DEG C, filter, precipitation is spent
Ionized water washs 3-4 time, puts in the thermostatic drying chamber of 80-90 DEG C and dries, obtains purifying carbon nano-tube;
(4) take above-mentioned octylisothiazolinone, join in the dehydrated alcohol of its weight 4-10 times, stir, add triphen
Base phosphine, is incubated 4-7 minute at 50-60 DEG C, obtains antibacterial alcohol liquid;
(5) above-mentioned purifying carbon nano-tube is joined in the formic acid of above-mentioned 80-90%, ultrasonic 60-70 minute, add nylon 6, base
Succinate, magnetic agitation 3-5 minute, add above-mentioned antibacterial alcohol liquid, continue ultrasonic 30-40 minute, obtain spinning liquid, by spinning liquid
Carry out spinning, obtain initial fiber;
(6) above-mentioned initial fiber being sent in plasma processor, be 70-75w at power, oxygen pressure is to locate under 40-45pa
Manage 1-2 minute;
(7) initial fiber after above-mentioned plasma pretreatment is joined in above-mentioned aniline, soak 100-120 minute, in addition
State the hydrochloric acid of the ammonium persulfate aqueous solution of 0.1-0.15mol/l, 0.5-0.6mol/l, be placed in the water bath with thermostatic control of 20-26 DEG C, stir
Mixing reaction 120-130 minute, discharging, add and remain each raw material, 400-500 rev/min is stirred 2-3 minute, takes out fiber, washes 3-
4 times, room temperature dries, tidy, is placed on braider density rule little progress row weaving as requested, is placed in boiling after weaving
Thermal finalization 1-2 hour in water, to obtain final product.
The invention have the advantage that
First CNT mixed acid solution is processed by the present invention, after carboxyl is introduced carbon nano tube surface, is re-dissolved in
In formic acid solution, stable dispersion liquid can be obtained;Then the initial fiber obtained is carried out plasma treatment, due to plasma
Corrasion make fiber surface coarse, and be introduced into segment polarity group and cause its surface to improve, thus contribute to aniline
Monomer, in fiber surface absorption fastness and the raising of uniformity, advantageously forms continuous whole polyaniline film, and polyaniline is led
Electric layer is well combined with fiber surface, and resistance reduces, and composite fibre electric conductivity increases, and the present invention is with hydrochloric acid for doping
Acid, Ammonium persulfate. is oxidant, and when the fiber being adsorbed with aniline monomer immerses reactant liquor, the outermost aniline monomer of fiber is first
First contact with reactant liquor and react generation polyaniline, and along with the carrying out of reaction, reactant liquor diffuses to whole aniline adsorption layer
In, fully, polyaniline film thickness improves in reaction, improves with the absorption fastness of matrix fiber, and difficult drop-off during washing, thin film is complete
Whole, it is possible to provide good conductive channel, the gauze of fibrage of the present invention has good electromagnetic radiation protection effect, greatly
Reduce the electromagnetic wave electromagnetic radiation pollution to human body.The octylisothiazolinone of present invention addition, calcium propionate, triphenylphosphine
Deng, the anti-microbial property of finished product can well be improved.
Detailed description of the invention
A kind of antibacterial soft magnetism door gauze, it is made up of the raw material of following weight parts:
Fatty diglycollic amide 1, calcium propionate 0.5, the ammonium persulfate aqueous solution 7 of 0.1mol/l, aniline 70, the salt of 0.5mol/l
Acid 2, the formic acid 140 of CNT 1,80%, nylon 6 40, octylisothiazolinone 0.6, alkenyl succinic acid ester 0.2, triphenyl
Phosphine 0.1, ascorbic acid 1, Zinc Pyrithione 0.3, ten difluoro heptyl propyl trimethoxy silicane 0.2.
The preparation method of a kind of described antibacterial soft magnetism door gauze, comprises the following steps:
(1) taking volume ratio is the sulphuric acid of 3:1, salpeter solution mixing, stirs, and described sulfuric acid concentration is 90%, concentration of nitric acid
It is 60%;
(2) by above-mentioned Zinc Pyrithione, calcium propionate mixing, join in the deionized water of compound weight 10 times, stir,
Obtain saline solution;
(3) above-mentioned CNT is joined in above-mentioned mixed acid solution, at 50 DEG C ultrasonic 200 minutes, centrifugation, will under
Layer precipitation joins in above-mentioned saline solution, and insulated and stirred 20 minutes at 60 DEG C are filtered, and precipitate with deionized water are washed 3 times,
Put in the thermostatic drying chamber of 80 DEG C and dry, obtain purifying carbon nano-tube;
(4) take above-mentioned octylisothiazolinone, join in the dehydrated alcohol of its weight 4 times, stir, add triphenyl
Phosphine, is incubated 4 minutes at 50 DEG C, obtains antibacterial alcohol liquid;
(5) above-mentioned purifying carbon nano-tube is joined in the formic acid of above-mentioned 80%, ultrasonic 60 minutes, add nylon 6, base succinic acid
Ester, magnetic agitation 3 minutes, add above-mentioned antibacterial alcohol liquid, continue ultrasonic 30 minutes, obtain spinning liquid, spinning liquid is carried out spinning,
Initial fiber;
(6) above-mentioned initial fiber being sent in plasma processor, be 70w at power, oxygen pressure is to process 1 point under 40pa
Clock;
(7) initial fiber after above-mentioned plasma pretreatment is joined in above-mentioned aniline, soak 100 minutes, add above-mentioned
The ammonium persulfate aqueous solution of 0.1mol/l, the hydrochloric acid of 0.5mol/l, be placed in the water bath with thermostatic control of 20 DEG C, stirring reaction 120 minutes,
Discharging, adds and remains each raw material, and 400 revs/min are stirred 2 minutes, take out fiber, wash 3 times, and room temperature dries, tidy, is placed in
On braider as requested density rule little progress row weaving, be placed in thermal finalization 1 hour in boiling water after weaving, to obtain final product.
The performance test of monfil:
Electrical conductivity 1.3 × 10-1-1.5×10-1S/cm;
Fracture strength reaches 3.0-3.5cN/dtex;
Extension at break is 20-30%;
Fracture strength 130-150MPa.
Claims (2)
1. an antibacterial soft magnetism door gauze, it is characterised in that it is made up of the raw material of following weight parts:
Fatty diglycollic amide 1-2, the ammonium persulfate aqueous solution 7-10 of calcium propionate 0.5-1,0.1-0.15mol/l, aniline 70-
74, the hydrochloric acid 2-3 of 0.5-0.6mol/l, the formic acid 140-160 of CNT 1-2,80-90%, nylon 6 40-50, the different thiophene of octyl group
Oxazoline ketone 0.6-1, alkenyl succinic acid ester 0.2-0.3, triphenylphosphine 0.1-0.2, ascorbic acid 1-2, Zinc Pyrithione 0.3-
0.4, ten difluoro heptyl propyl trimethoxy silicane 0.2-0.5.
2. the preparation method of an antibacterial soft magnetism door gauze as claimed in claim 1, it is characterised in that comprise the following steps:
(1) taking volume ratio is the sulphuric acid of 3-4:1, salpeter solution mixing, stirs, and described sulfuric acid concentration is 90-95%, nitre
Acid concentration is 60-70%;
(2) by above-mentioned Zinc Pyrithione, calcium propionate mixing, joining in the deionized water of compound weight 10-14 times, stirring is all
Even, obtain saline solution;
(3) above-mentioned CNT is joined in above-mentioned mixed acid solution, at 50-60 DEG C ultrasonic 200-250 minute, centrifugal point
From, lower sediment is joined in above-mentioned saline solution, insulated and stirred 20-30 minute at 60-70 DEG C, filter, precipitation is spent
Ionized water washs 3-4 time, puts in the thermostatic drying chamber of 80-90 DEG C and dries, obtains purifying carbon nano-tube;
(4) take above-mentioned octylisothiazolinone, join in the dehydrated alcohol of its weight 4-10 times, stir, add triphen
Base phosphine, is incubated 4-7 minute at 50-60 DEG C, obtains antibacterial alcohol liquid;
(5) above-mentioned purifying carbon nano-tube is joined in the formic acid of above-mentioned 80-90%, ultrasonic 60-70 minute, add nylon 6, base
Succinate, magnetic agitation 3-5 minute, add above-mentioned antibacterial alcohol liquid, continue ultrasonic 30-40 minute, obtain spinning liquid, by spinning liquid
Carry out spinning, obtain initial fiber;
(6) above-mentioned initial fiber being sent in plasma processor, be 70-75w at power, oxygen pressure is to locate under 40-45pa
Manage 1-2 minute;
(7) initial fiber after above-mentioned plasma pretreatment is joined in above-mentioned aniline, soak 100-120 minute, in addition
State the hydrochloric acid of the ammonium persulfate aqueous solution of 0.1-0.15mol/l, 0.5-0.6mol/l, be placed in the water bath with thermostatic control of 20-26 DEG C, stir
Mixing reaction 120-130 minute, discharging, add and remain each raw material, 400-500 rev/min is stirred 2-3 minute, takes out fiber, washes 3-
4 times, room temperature dries, tidy, is placed on braider density rule little progress row weaving as requested, is placed in boiling after weaving
Thermal finalization 1-2 hour in water, to obtain final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610111726.1A CN105986334A (en) | 2016-02-29 | 2016-02-29 | Antibacterial soft magnetic door gauze and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610111726.1A CN105986334A (en) | 2016-02-29 | 2016-02-29 | Antibacterial soft magnetic door gauze and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105986334A true CN105986334A (en) | 2016-10-05 |
Family
ID=57044080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610111726.1A Pending CN105986334A (en) | 2016-02-29 | 2016-02-29 | Antibacterial soft magnetic door gauze and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105986334A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106589665A (en) * | 2016-11-17 | 2017-04-26 | 安徽北马科技有限公司 | Bacteriostatic and self-cleaned plastic sheet material and preparation method therefor |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101845680A (en) * | 2010-04-08 | 2010-09-29 | 苏州大学 | Carbon nano tube/polyamide 6 composite nano fiber filament yarn and preparation method thereof |
CN102720066A (en) * | 2012-07-05 | 2012-10-10 | 苏州大学 | Method for preparing ultra-high molecular weight polyethylene/polyaniline composite conductive fibre |
CN103924444A (en) * | 2014-04-24 | 2014-07-16 | 南雄鼎成化工有限公司 | Preparation method and application of hydrophilic anti-bacteria conditioner for fabric |
CN104195708A (en) * | 2014-07-16 | 2014-12-10 | 浙江玛雅布业有限公司 | Method for manufacturing window screen |
CN105019802A (en) * | 2015-06-18 | 2015-11-04 | 东北大学 | Dustproof screen window |
-
2016
- 2016-02-29 CN CN201610111726.1A patent/CN105986334A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101845680A (en) * | 2010-04-08 | 2010-09-29 | 苏州大学 | Carbon nano tube/polyamide 6 composite nano fiber filament yarn and preparation method thereof |
CN102720066A (en) * | 2012-07-05 | 2012-10-10 | 苏州大学 | Method for preparing ultra-high molecular weight polyethylene/polyaniline composite conductive fibre |
CN103924444A (en) * | 2014-04-24 | 2014-07-16 | 南雄鼎成化工有限公司 | Preparation method and application of hydrophilic anti-bacteria conditioner for fabric |
CN104195708A (en) * | 2014-07-16 | 2014-12-10 | 浙江玛雅布业有限公司 | Method for manufacturing window screen |
CN105019802A (en) * | 2015-06-18 | 2015-11-04 | 东北大学 | Dustproof screen window |
Non-Patent Citations (1)
Title |
---|
禹茂章等: "《新编世界精细化学品手册》", 30 April 2000, 国家药品监督管理局信息中心 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106589665A (en) * | 2016-11-17 | 2017-04-26 | 安徽北马科技有限公司 | Bacteriostatic and self-cleaned plastic sheet material and preparation method therefor |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103806266B (en) | A kind of method utilizing ultraviolet light to prepare graphene oxide conductive fiber cellulose fabric | |
CN105177745A (en) | Novel electromagnetic shielding nanocarbon conductive fibrous material and preparation method thereof | |
CN109881493A (en) | A kind of MXene base flexible translucent electromagnetic shielding fabric of LBL self-assembly and preparation method thereof | |
CN102220690A (en) | Method for manufacturing electromagnetic radiation resistant fabric | |
CN108385370A (en) | A kind of carbon nano-tube/poly urethane elastic conductive fiber and preparation method thereof | |
CN101775670B (en) | Method for preparing polyimide/silver composite electrical conductivity fibers | |
CN103981719B (en) | A kind of preparation method of polyaniline titanium dioxide UV resistance conductive fabric | |
CN104878587A (en) | Pretreatment of supercritical fluid nano silver textile fabric and microwave preparation method of supercritical fluid nano silver textile fabric | |
CN105484015A (en) | Preparation method of layered composite shielding fabric | |
CN105671686A (en) | Preparation method of alginate-graphene-nano-cuprous oxide composite antibacterial fiber | |
CN110258105A (en) | Multifunctional compound fabric and preparation method thereof | |
CN114775267A (en) | Electromagnetic shielding non-woven fabric and preparation method thereof | |
CN105986334A (en) | Antibacterial soft magnetic door gauze and preparation method thereof | |
CN103882711A (en) | Silk wrinkle-resistant finishing method | |
CN107142720A (en) | A kind of preparation method of graphene exposure suit | |
CN106381684A (en) | Multilayer radiation-resistant fiber based on ferrites and nanometer materials and preparation method thereof | |
CN106012090A (en) | Preparation method of conductive graphene composite fibers | |
CN105986467A (en) | Macromolecular soft magnetic door gauze element and preparation method thereof | |
CN205134069U (en) | Electromagnetic shielding cloth | |
CN104695211A (en) | Chemical plating activation process for fabric by using supercritical carbon dioxide fluid | |
CN105714404B (en) | A kind of preparation method of cuprous sulfide/PET composite conducting fibers | |
CN105986466A (en) | Scrubbing resistant soft magnetic door gauze and preparation method thereof | |
CN105986470A (en) | Water-resistant soft magnetic door gauze element and preparation method thereof | |
CN115233335B (en) | Flexible liquid metal/seaweed composite fiber and preparation method thereof | |
CN105986332A (en) | Insect-proof soft magnetic door gauze element and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161005 |