CN105985595A - Heatproof corrosion-resistant floor board for greenhouse and making method of floor board - Google Patents
Heatproof corrosion-resistant floor board for greenhouse and making method of floor board Download PDFInfo
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- CN105985595A CN105985595A CN201610009147.6A CN201610009147A CN105985595A CN 105985595 A CN105985595 A CN 105985595A CN 201610009147 A CN201610009147 A CN 201610009147A CN 105985595 A CN105985595 A CN 105985595A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
Abstract
The invention discloses a heatproof corrosion-resistant floor board for a greenhouse. Bisphenol A phosphite, cadmium stearate and hollow glass microbeads are added into the floor board, so that heatproof performance of the floor board is improved effectively; the floor board has certain heat insulativity, thereby being especially suitable for being used as a greenhouse floor board in cold regions.
Description
Technical field
The present invention relates to technical field of floor, particularly relate to a kind of greenhouse heat-resistant anticorrosive floor and preparation method thereof.
Background technology
PVC, as world's second largest general-purpose plastics, has a good combination property, and cheap, raw material sources are wide
The advantage such as general has given play to important function in all trades and professions.PVC expanded material not only inherits above all of advantage, and
There is defect or the deficiency of some performances, such as intensity, rigidity and thermodynamic property etc. do not reach the expectation of people, especially
Its PVC expanded material can discharge poisonous dense smoke burning when, and these the most seriously hinder PVC foamed materials
Development and application.Along with nanometer in recent years in the material shown by the great potential that goes out so that by modifications such as laminated inorganic matters
Form nano composite material to improve the combination property of material and become the focus of Recent study.Laminated inorganic matter is through organically-modified
After make the thermal stability of polymer composites, mechanical performance significantly improves, and particularly alpha zirconium phosphate has as one
The novel nano particle of unique texture and character, has purity high, and ion exchange capacity the most easily realizes intercalation or lift-off structure,
Compound with polymer easily form nanostructured, this not only give the excellent mechanical performance of polymeric material, barrier property but also
Laminar nano particle is applied in expanded material can also play the effect of foaming nucleation agent to such an extent as to reaches to optimize foaming matter
The purpose of amount.On the other hand, PVC expanded material, fire-retardant and press down the inferior position in terms of cigarette, also counteracts that it is further applied.
And add anti-flaming smoke-inhibiting agent and just can well solve this problem, the research of forefathers has established good base for us
Plinth, organic tin anti-flaming smoke-inhibiting agent and molybdenum class anti-flaming smoke-inhibiting agent have all shown outstanding flame-retardant smoke inhibition effect, special organic
Anti-flaming smoke-inhibiting agent be that same polymer has the good compatibility, this is that other fire retardants are unapproachable, therefore relative to it
He has suitable DEVELOPMENT PROSPECT for fire retardant, both flame-retardant smoke inhibition research being used in combination in PVC at present does not appears in the newspapers
Road.So, this paper is intended to introduce organically-modified alpha zirconium phosphate Nano filling, improve the foaming quality of PVC expanded material with
And mechanical property, thermal stability etc..
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of greenhouse heat-resistant anticorrosive floor and system thereof
Preparation Method.
The present invention is achieved by the following technical solutions:
Heat-resistant anticorrosive floor used by a kind of greenhouse, and it is made up of the raw material of following weight parts:
Phosphorous acid bisphenol-A ester 4-6, cadmium stearate 0.2-0.3, hydrochloric acid 10-15,80-of eight water zirconium oxychloride 17-20,40-47%
The phosphatase 79 0-100 of 85%, tetrakis hydroxymetyl phosphonium sulfuric 3-4,25-30% methylamine water solution 4-7, trifluoroethyl methacrylate 5-7,
Octylisothiazolinone 0.2-0.4, Ammonium persulfate. 0.06-0.1, divinylbenzene 0.01-0.02, azodicarbonamide 1-2, poly-
Vinyl chloride 130-200, stannous sulfide 1-2, polyvinyl butyral resin 4-6, diethylene glycol dibenzoate 2-3, hollow glass micropearl
5-7, trimethylolpropane 0.1-0.2.
The preparation method on a kind of described greenhouse heat-resistant anticorrosive floor, comprises the following steps:
(1) eight water zirconium oxychlorides are joined in 15-18 times of distilled water, stir, be sequentially added into above-mentioned 40-47% hydrochloric acid,
The phosphoric acid of 80-85%, electromagnetic agitation 3-4 days under room temperature, filter, being washed with deionized to PH is 5, and at 60-65 DEG C, vacuum is done
Dry, grind, obtain alpha zirconium phosphate；
(2) take the 30-40% of above-mentioned polyvinyl butyral resin weight, mix with diethylene glycol dibenzoate, stir, add
Octylisothiazolinone, rises high-temperature and is 80-90 DEG C, and insulated and stirred 3-5 minute joins the 20-of compound weight 3-4 times
In the ethanol solution of 30%, stir, obtain anticorrosion alcohol liquid；
(3) above-mentioned trifluoroethyl methacrylate is joined in the dehydrated alcohol of 2-3 times, stir, with above-mentioned anticorrosion alcohol
Liquid mixes, and rises high-temperature and is 70-75 DEG C, adds divinylbenzene, insulation reaction 3-4 hour, obtain anticorrosion monomer；
(4) above-mentioned phosphorous acid bisphenol-A ester is mixed with remaining polyvinyl butyral resin, stir, add trihydroxy methyl third
Alkane, 200-300 rev/min is stirred 10-17 minute, adds cadmium stearate, insulated and stirred 4-6 minute at 60-70 DEG C, obtains heat-resisting helping
Agent；
(5) above-mentioned alpha zirconium phosphate is joined in 90-100 times of deionized water, stir, add methylamine water solution, ultrasonic 30-
35 minutes, add tetrakis hydroxymetyl phosphonium sulfuric, dispersed with stirring 10-16 minute, add above-mentioned anticorrosion monomer, ultrasonic 3-5 minute, add
Ammonium persulfate., insulation reaction 6-10 hour at 75-80 DEG C, centrifugation, precipitate is washed, dries, obtain organically-modified phosphorus
Acid zirconium；
(6) by above-mentioned organically-modified zirconium phosphate, heat resistance accessory mixing, stir, add polrvinyl chloride, stannous sulfide, send into
In homogenizer, 1000-1200r/min stirs 20-30 minute, slowly rises high-temperature and is 120-130 DEG C, reduces rotating speed and is
300-400r/min, stirring is to 46-50 DEG C, then rises high-temperature and be 130-140 DEG C, adds and remains each raw material, heat-insulation preheating 50-60
Minute, melt extruded by extruder, through traction cutting, plucking, to obtain final product.
The invention have the advantage that
(1) floor of the present invention has a good heat-resistant stability:
Using tetrakis hydroxymetyl phosphonium sulfuric as modifying agent, interlayer does not has to be catalyzed the factor that polrvinyl chloride decomposes, and obtains organic
The layer structure of modified zirconium phosphate, it is possible to effectively play the iris action of energy and material；On the other hand, organically-modified α-phosphorus
The addition of acid zirconium improves the foaming quality of polyvinyl-chloride foam material so that uniform foam cell, occurs in that substantially between abscess
Boundary, i.e. closed pore quantity is increasing, and open-celled structure reduces, and this hole-closing structure absorbs a large amount of during heat transmits
Heat, stop heat propagation；Polrvinyl chloride composite foam material can be made to be subject to it addition, add organically-modified alpha zirconium phosphate
Can be good at keeping the shape of abscess when of to impact so that abscess keeps original rigidity and toughness, therefore improves
The thickness of polrvinyl chloride walls, enhances it and resists the ability that its generation is destroyed by outer position；
(2) floor of the present invention has good water-resistance:
Through organically-modified alpha zirconium phosphate, due to organic cation replace the H+ of interlayer or organic anion at α-phosphorus
Acid zirconium layer between adsorption and modified hydrophobicity is the most significantly improved；
(3) floor of the present invention has a good shock resistance:
The present invention uses tetrakis hydroxymetyl phosphonium sulfuric to significantly improve the foaming quality of polyvinyl-chloride foam material as modifying agent, bubble
Hole is more uniform, and cell wall presents spherical, and complete cell wall is by deforming upon absorption energy, then toughness increases；
(4) floor of the present invention has a good fire resistance:
Alpha zirconium phosphate self is layer structure, and through the certain lift-off structure of modified formation, be no matter layer structure also
It is lift-off structure, the existence of these structures, it is possible to matter and energy iris action can be played when polymer combustion, and poly-
HCl, HCL gas self can be discharged during vinyl chloride burning and there is obvious anti-flammability；
(5) first the present invention makes alpha zirconium phosphate colloidization with methylamine, then using trifluoroethyl methacrylate as anticorrosion monomer,
Embed in the course of the polymerization process and be stable in the presence of between modified alpha-zirconium phosphate layer, ensureing heat-resisting, the water resistant of modified alpha zirconium phosphate, anti-
Impact, fire-retardant while improve antiseptic property；
The sheet material of the present invention adds phosphorous acid bisphenol-A ester, cadmium stearate, hollow glass micropearl etc., can effectively improve into
The heat resistance of product sheet material, also has certain heat insulating ability, is therefore particularly suitable for cold district and uses as greenhouse floor.
Detailed description of the invention
Heat-resistant anticorrosive floor used by a kind of greenhouse, and it is made up of the raw material of following weight parts:
Phosphorous acid bisphenol-A ester 4, phosphatase 79 0, the four hydroxyl first of hydrochloric acid 10,80% of cadmium stearate 0.2, eight water zirconium oxychloride 17,40%
Base sulphuric acid phosphorus 3,25% methylamine water solution 4, trifluoroethyl methacrylate 5, octylisothiazolinone 0.2, Ammonium persulfate. 0.06,
Divinylbenzene 0.01, azodicarbonamide 1, polrvinyl chloride 130, stannous sulfide 1, polyvinyl butyral resin 4, diethylene glycol hexichol
Formic acid esters 2, hollow glass micropearl 5, trimethylolpropane 0.1.
The preparation method on a kind of described greenhouse heat-resistant anticorrosive floor, comprises the following steps:
(1) eight water zirconium oxychlorides are joined in 15 times of distilled water, stir, be sequentially added into above-mentioned 40% hydrochloric acid, 80%
Phosphoric acid, electromagnetic agitation 3 days under room temperature, filter, being washed with deionized to PH is 5, is vacuum dried, grinds, obtain α phosphorus at 60 DEG C
Acid zirconium；
(2) take the 30% of above-mentioned polyvinyl butyral resin weight, mix with diethylene glycol dibenzoate, stir, add octyl group
Isothiazolone, rising high-temperature is 80 DEG C, and insulated and stirred 3 minutes joins in the ethanol solution of 20% of compound weight 3 times,
Stir, obtain anticorrosion alcohol liquid；
(3) above-mentioned trifluoroethyl methacrylate is joined in the dehydrated alcohol of 2 times, stir, with above-mentioned anticorrosion alcohol liquid
Mixing, rising high-temperature is 70 DEG C, adds divinylbenzene, insulation reaction 3 hours, obtains anticorrosion monomer；
(4) above-mentioned phosphorous acid bisphenol-A ester is mixed with remaining polyvinyl butyral resin, stir, add trihydroxy methyl third
Alkane, 200 revs/min are stirred 10 minutes, add cadmium stearate, and at 60 DEG C, insulated and stirred 4 minutes, obtain heat resistance accessory；
(5) above-mentioned α zirconium phosphate is joined in 90 times of deionized waters, stir, addition methylamine water solution, ultrasonic 30 minutes,
Add tetrakis hydroxymetyl phosphonium sulfuric, dispersed with stirring 10 minutes, add above-mentioned anticorrosion monomer, ultrasonic 3 minutes, add Ammonium persulfate.,
Insulation reaction 6 hours at 75 DEG C, centrifugation, precipitate is washed, dries, obtain organically-modified zirconium phosphate；
(6) by above-mentioned organically-modified zirconium phosphate, heat resistance accessory mixing, stir, add polrvinyl chloride, stannous sulfide, send into
In homogenizer, 1000r/min stirs 20 minutes, and slowly rising high-temperature is 120 DEG C, and reduction rotating speed is 300r/min, stirring
To 46 DEG C, then to rise high-temperature be 130 DEG C, adds and remains each raw material, heat-insulation preheating 50 minutes, is melt extruded by extruder, warp
Cross traction cutting, plucking, to obtain final product.
Performance test:
Density: 0.9g/cm3；
Shore D hardness: 79 degree；
Camber intensity: 24.4MPa；
Unnotched impact strength: 77kJ/m2；
Water absorption rate: 0.484%；
Shock resistance: flawless；
Oxygen index (OI): 37.1%；
45 degree of angle burnings: difficult combustion；
Nail-holding ability: 2.2kN；
Environmental-protecting performance (methanol burst size, condensed steam water 9-11L): 0.2mg/L.
Claims (2)
1. heat-resistant anticorrosive floor used by a greenhouse, it is characterised in that it is made up of the raw material of following weight parts:
Phosphorous acid bisphenol-A ester 4-6, cadmium stearate 0.2-0.3, hydrochloric acid 10-15,80-of eight water zirconium oxychloride 17-20,40-47%
The phosphatase 79 0-100 of 85%, tetrakis hydroxymetyl phosphonium sulfuric 3-4,25-30% methylamine water solution 4-7, trifluoroethyl methacrylate 5-7,
Octylisothiazolinone 0.2-0.4, Ammonium persulfate. 0.06-0.1, divinylbenzene 0.01-0.02, azodicarbonamide 1-2, poly-
Vinyl chloride 130-200, stannous sulfide 1-2, polyvinyl butyral resin 4-6, diethylene glycol dibenzoate 2-3, hollow glass micropearl
5-7, trimethylolpropane 0.1-0.2.
2. the preparation method on a greenhouse heat-resistant anticorrosive floor as claimed in claim 1, it is characterised in that include following step
Rapid:
(1) eight water zirconium oxychlorides are joined in 15-18 times of distilled water, stir, be sequentially added into above-mentioned 40-47% hydrochloric acid,
The phosphoric acid of 80-85%, electromagnetic agitation 3-4 days under room temperature, filter, being washed with deionized to PH is 5, and at 60-65 DEG C, vacuum is done
Dry, grind, obtain alpha zirconium phosphate；
(2) take the 30-40% of above-mentioned polyvinyl butyral resin weight, mix with diethylene glycol dibenzoate, stir, add
Octylisothiazolinone, rises high-temperature and is 80-90 DEG C, and insulated and stirred 3-5 minute joins the 20-of compound weight 3-4 times
In the ethanol solution of 30%, stir, obtain anticorrosion alcohol liquid；
(3) above-mentioned trifluoroethyl methacrylate is joined in the dehydrated alcohol of 2-3 times, stir, with above-mentioned anticorrosion alcohol
Liquid mixes, and rises high-temperature and is 70-75 DEG C, adds divinylbenzene, insulation reaction 3-4 hour, obtain anticorrosion monomer；
(4) above-mentioned phosphorous acid bisphenol-A ester is mixed with remaining polyvinyl butyral resin, stir, add trihydroxy methyl third
Alkane, 200-300 rev/min is stirred 10-17 minute, adds cadmium stearate, insulated and stirred 4-6 minute at 60-70 DEG C, obtains heat-resisting helping
Agent；
(5) above-mentioned alpha zirconium phosphate is joined in 90-100 times of deionized water, stir, add methylamine water solution, ultrasonic 30-
35 minutes, add tetrakis hydroxymetyl phosphonium sulfuric, dispersed with stirring 10-16 minute, add above-mentioned anticorrosion monomer, ultrasonic 3-5 minute, add
Ammonium persulfate., insulation reaction 6-10 hour at 75-80 DEG C, centrifugation, precipitate is washed, dries, obtain organically-modified phosphorus
Acid zirconium；
(6) by above-mentioned organically-modified zirconium phosphate, heat resistance accessory mixing, stir, add polrvinyl chloride, stannous sulfide, send into
In homogenizer, 1000-1200r/min stirs 20-30 minute, slowly rises high-temperature and is 120-130 DEG C, reduces rotating speed and is
300-400r/min, stirring is to 46-50 DEG C, then rises high-temperature and be 130-140 DEG C, adds and remains each raw material, heat-insulation preheating 50-60
Minute, melt extruded by extruder, through traction cutting, plucking, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610009147.6A CN105985595A (en) | 2016-01-04 | 2016-01-04 | Heatproof corrosion-resistant floor board for greenhouse and making method of floor board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610009147.6A CN105985595A (en) | 2016-01-04 | 2016-01-04 | Heatproof corrosion-resistant floor board for greenhouse and making method of floor board |
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| CN105985595A true CN105985595A (en) | 2016-10-05 |
Family
ID=57039854
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610009147.6A Pending CN105985595A (en) | 2016-01-04 | 2016-01-04 | Heatproof corrosion-resistant floor board for greenhouse and making method of floor board |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727734A (en) * | 2018-05-25 | 2018-11-02 | 东南大学 | A kind of energy-saving self-luminous composite floor board and preparation method thereof |
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| CN103101896A (en) * | 2011-11-09 | 2013-05-15 | 上海纳米技术及应用国家工程研究中心有限公司 | Cubic zirconium phosphate and preparation method thereof |
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2016
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| CN102558758A (en) * | 2012-01-04 | 2012-07-11 | 上海柯瑞冶金炉料有限公司 | Phenolic resin foam material and preparing method thereof |
| CN104555970A (en) * | 2013-10-14 | 2015-04-29 | 青岛市首胜实业有限公司 | Preparation method of layered zirconium phosphate |
| CN104631775A (en) * | 2013-11-12 | 2015-05-20 | 江阴华诚汽车内饰件有限公司 | Coiled material floor having bacteria resistant function |
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| 李智: ""聚氯乙烯/α-磷酸锆纳米复合发泡材料的制备及阻燃抑烟性能研究"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727734A (en) * | 2018-05-25 | 2018-11-02 | 东南大学 | A kind of energy-saving self-luminous composite floor board and preparation method thereof |
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