CN105984979A - Dyeing wastewater biomass treatment technique - Google Patents

Dyeing wastewater biomass treatment technique Download PDF

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Publication number
CN105984979A
CN105984979A CN201610480672.6A CN201610480672A CN105984979A CN 105984979 A CN105984979 A CN 105984979A CN 201610480672 A CN201610480672 A CN 201610480672A CN 105984979 A CN105984979 A CN 105984979A
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CN
China
Prior art keywords
waste water
dyeing
water
cistern
sand filtration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610480672.6A
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Chinese (zh)
Inventor
金建国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deqing County Xingxinda Silk Pint Co Ltd
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Deqing County Xingxinda Silk Pint Co Ltd
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Application filed by Deqing County Xingxinda Silk Pint Co Ltd filed Critical Deqing County Xingxinda Silk Pint Co Ltd
Priority to CN201610480672.6A priority Critical patent/CN105984979A/en
Publication of CN105984979A publication Critical patent/CN105984979A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F7/00Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/70Treatment of water, waste water, or sewage by reduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Sludge (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention relates to a dyeing wastewater biomass treatment technique. The technique for treating dyeing wastewater comprises the following steps: primary filtration, reducing decolorization, water storage tank sand filtration, activated carbon adsorption and cation adsorption. Dyeing sludge applied to poplar planting provides calcium, magnesium and other beneficial substances required by poplar planting, and the high adsorptivity of the poplar for heavy metals is utilized, thereby lowering the textile heavy metal treatment cost and changing wastes into valuable substances. The spunlace nonwoven fabric blended from terylene fiber scraps and bamboo fiber scraps is adopted, thereby reducing the waste, and enhancing the adsorption capacity for magnesium, calcium and other elements in water.

Description

A kind of dyeing waste water biomass processes technique
Technical field
The present invention relates to textile printing and dyeing water-treatment technology field, particularly relate to a kind of dyeing waste water biomass processes technique.
Background technology
Textile industry is one of pillar in current economic development, but a lot of sewage can be produced in terms of weaving face fabric printing and dyeing and cause extremely serious environmental pollution, even the water eutrophication in river still can be made after treated sewage discharge, thus cause the overpreading of the plant such as Herba Eichhorniae, cyanophyceae, affect whole ecosystem, also have a lot of manufacturers to select not process sewage for very small profits and silently discharge.Therefore arranging a low cost, the waste water treatment process that waste water can be made to be utilized effectively extremely is necessary.
At present, the process technique of dyeing waste water is a lot, and representative one is to directly utilize the traditional approach that chemical method carries out processing, and which recovery utilization rate is low, and the waste water processed of discharge still contains substantial amounts of harmful substance, and cost is high, and efficiency is low;Two is to utilize plasma exchange process, and this kind of method requires height to operator, is accomplished by strengthening the input in terms of the high talent for current textile industry in this respect, and waste water is in the state of eutrophication after having processed.
Summary of the invention
In order to solve the problem in background technology, the present invention provides a kind of dyeing waste water biomass processes technique.
A kind of dyeing waste water biomass processes technique, comprises the following steps:
A, the waste water introducing filtering ponds discharged by printing and dyeing workshop, add filter aid in waste water, filter, float therein filtered out after sewage flocculation, obtain precipitate, remaining containing coloured fine suspension and solute;
B, waste water after single filter add reproducibility decolorising agent, processes direct dyeing waste water, be allowed to react with direct dyes generation reduction-decolor therein, so that the dye molecule formation deoxidization, degradation product in waste water;
C, being passed through by tap water in sealing cistern, described sealing columns base is Sand Filtration System, is ceaselessly passed through in cistern by carbon dioxide, processes 5-8min, and installs gas recovery system and reclaim carbon dioxide;
D, the water processed in cistern is passed through activated carbon adsorption system, is 0.2-0.5m/min by flow rate set, is set as 3-5min by the time;
E, the water that activated carbon adsorption system processed is passed through cation-adsorption resin;
F, by water resin processed for cation-adsorption, be re-used in dyeing and printing process.
Preferably, the described precipitate in step A is as the main component in the plantation base manure of cottonwood or base manure.
Preferably, in the described water in the cistern in step C, the concentration of EDTA is set as 0.5-1.5g/L, and the concentration of sodium gluconate is set as 1-6g/L, sodium tert-butoxide 0.1-1.5g/L.
Preferably, consisting of of the described Sand Filtration System in step C, upper strata is fine sand, and middle level is the spun-laced nonwoven fabric of polyster fibre leftover pieces and bamboo fibre leftover pieces blending, and lower floor is gravel.
Preferably, the described upper strata in Sand Filtration System and middle level, to change once every the 1-3 month, the Sand Filtration System changed can be as the main component in the base manure of plantation cottonwood or base manure.
What beauty etc. analyzes gray poplar, Populus deltoides Bartr.cv., European-American Poplar, 84K poplar, Populus nigra, the six kinds of willows of the Populus popularis molecular physiology response mechanism to Cd stress, finds that these six kinds of willows all have higher toleration and enriching (He J, Ma C, Ma to Cd Y, et al. Cadmium tolerance in six poplar species[J]. Environmental Science and Pollution Research, 201320 (1): 163-174.).Wu Yanhua etc. have studied south, capital Soils In The Region Characteristics of Heavy Metal Pollution and willow recovery dynatron effect, find that cottonwood is leaf to the absorption content sequence of Cd in soil > branch skin > root bark > root timber > peel of stem > branch material > stem material (Wu Yanhua. south, capital Soils In The Region Characteristics of Heavy Metal Pollution and willow recovery dynatron effect [master thesis]. The Chinese Geology Univ. (Beijing), 2005).
Willow is a kind of to have certain heavy metal accumulation ability plant, its biological study also there is certain basis, therefore the present invention chooses willow and the heavy metal pollution produced in textile industry is carried out biomass processes, heavy metal is extracted from soil willow aerial parts, thus reach effectively to process the content of heavy metal in waste water, carry out harvesting afterwards to be uniformly processed, be a kind of method of effective process heavy metal pollution.
Dyeing waste water biomass processes technique of the present invention, uses single filter, reproducibility decolouring, cistern sand filtration, activated carbon adsorption, cation-adsorption, processes dyeing waste water;Printing and dyeing sludge is applied to willow plantation, had both provided the benefit materials such as the calcium needed for willow plantation, magnesium, and also utilized the high adsorption of willow heavy metal, thus reduce the processing cost to weaving heavy metal, turn waste into wealth;Use polyster fibre leftover pieces and the spun-laced nonwoven fabric of bamboo fibre leftover pieces blending, both decreased waste, and also improved the absorbability of the element such as magnesium, calcium in water.
Embodiment 1
A kind of dyeing waste water biomass processes technique, comprises the following steps:
A, the waste water introducing filtering ponds discharged by printing and dyeing workshop, add filter aid in waste water, filter, float therein filtered out after sewage flocculation, obtain precipitate, remaining containing coloured fine suspension and solute;
B, waste water after single filter add reproducibility decolorising agent, processes direct dyeing waste water, be allowed to react with direct dyes generation reduction-decolor therein, so that the dye molecule formation deoxidization, degradation product in waste water;
C, being passed through by tap water in sealing cistern, described sealing columns base is Sand Filtration System, is ceaselessly passed through in cistern by carbon dioxide, processes 7min, and installs gas recovery system and reclaim carbon dioxide;
D, the water processed in cistern is passed through activated carbon adsorption system, is 0.3m/min by flow rate set, is set as 4min by the time;
E, the water that activated carbon adsorption system processed is passed through cation-adsorption resin;
F, by water resin processed for cation-adsorption, be re-used in dyeing and printing process.
The described precipitate in step A is as the main component in the plantation base manure of cottonwood or base manure;
In the described water in the cistern in step C, the concentration of EDTA is set as 1.0-1.2g/L, and the concentration of sodium gluconate is set as 2-3g/L, sodium tert-butoxide 0.8-1.0g/L;
Consisting of of the described Sand Filtration System in step C, upper strata is fine sand, and middle level is the spun-laced nonwoven fabric of polyster fibre leftover pieces and bamboo fibre leftover pieces blending, and lower floor is gravel;
The described upper strata in Sand Filtration System and middle level, changed once every February, and the Sand Filtration System changed can be as the main component in the base manure of plantation cottonwood or base manure.
Embodiment 2
A kind of dyeing waste water biomass processes technique, comprises the following steps:
A, the waste water introducing filtering ponds discharged by printing and dyeing workshop, add filter aid in waste water, filter, float therein filtered out after sewage flocculation, obtain precipitate, remaining containing coloured fine suspension and solute;
B, waste water after single filter add reproducibility decolorising agent, processes direct dyeing waste water, be allowed to react with direct dyes generation reduction-decolor therein, so that the dye molecule formation deoxidization, degradation product in waste water;
C, being passed through by tap water in sealing cistern, described sealing columns base is Sand Filtration System, is ceaselessly passed through in cistern by carbon dioxide, processes 5min, and installs gas recovery system and reclaim carbon dioxide;
D, the water processed in cistern is passed through activated carbon adsorption system, is 0.5m/min by flow rate set, is set as 3min by the time;
E, the water that activated carbon adsorption system processed is passed through cation-adsorption resin;
F, by water resin processed for cation-adsorption, be re-used in dyeing and printing process.
The described precipitate in step A is as the main component in the plantation base manure of cottonwood or base manure.
In the described water in the cistern in step C, the concentration of EDTA is set as 1.2-1.5g/L, and the concentration of sodium gluconate is set as 0.8-1g/L, sodium tert-butoxide 1.2-1.5g/L;
Consisting of of the described Sand Filtration System in step C, upper strata is fine sand, and middle level is the spun-laced nonwoven fabric of polyster fibre leftover pieces and bamboo fibre leftover pieces blending, and lower floor is gravel;
The described upper strata in Sand Filtration System and middle level, changed once every January, and the Sand Filtration System changed can be as the main component in the base manure of plantation cottonwood or base manure.
Embodiment 3
A kind of dyeing waste water biomass processes technique, comprises the following steps:
A, the waste water introducing filtering ponds discharged by printing and dyeing workshop, add filter aid in waste water, filter, float therein filtered out after sewage flocculation, obtain precipitate, remaining containing coloured fine suspension and solute;
B, waste water after single filter add reproducibility decolorising agent, processes direct dyeing waste water, be allowed to react with direct dyes generation reduction-decolor therein, so that the dye molecule formation deoxidization, degradation product in waste water;
C, being passed through by tap water in sealing cistern, described sealing columns base is Sand Filtration System, is ceaselessly passed through in cistern by carbon dioxide, processes 8min, and installs gas recovery system and reclaim carbon dioxide;
D, the water processed in cistern is passed through activated carbon adsorption system, is 0.2m/min by flow rate set, is set as 5min by the time;
E, the water that activated carbon adsorption system processed is passed through cation-adsorption resin;
F, by water resin processed for cation-adsorption, be re-used in dyeing and printing process.
The described precipitate in step A is as the main component in the plantation base manure of cottonwood or base manure.
In the described water in the cistern in step C, the concentration of EDTA is set as 0.5-0.8g/L, and the concentration of sodium gluconate is set as 1-2g/L, sodium tert-butoxide 0.1-0.3g/L.
Consisting of of the described Sand Filtration System in step C, upper strata is fine sand, and middle level is the spun-laced nonwoven fabric of polyster fibre leftover pieces and bamboo fibre leftover pieces blending, and lower floor is gravel.
The described upper strata in Sand Filtration System and middle level, changed once every March, and the Sand Filtration System changed can be as the main component in the base manure of plantation cottonwood or base manure.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; according to technical scheme and inventive concept equivalent or change in addition thereof, all should contain within protection scope of the present invention.

Claims (5)

1. a dyeing waste water biomass processes technique, it is characterised in that comprise the following steps:
A, the waste water introducing filtering ponds discharged by printing and dyeing workshop, add filter aid in waste water, filter, float therein filtered out after sewage flocculation, obtain precipitate, remaining containing coloured fine suspension and solute;
B, waste water after single filter add reproducibility decolorising agent, processes direct dyeing waste water, be allowed to react with direct dyes generation reduction-decolor therein, so that the dye molecule formation deoxidization, degradation product in waste water;
C, being passed through by tap water in sealing cistern, described sealing columns base is Sand Filtration System, is ceaselessly passed through in cistern by carbon dioxide, processes 5-8min, and installs gas recovery system and reclaim carbon dioxide;
D, the water processed in cistern is passed through activated carbon adsorption system, is 0.2-0.5m/min by flow rate set, is set as 3-5min by the time;
E, the water that activated carbon adsorption system processed is passed through cation-adsorption resin;
F, by water resin processed for cation-adsorption, be re-used in dyeing and printing process.
Dyeing waste water biomass processes technique the most according to claim 1, it is characterised in that the described precipitate in step A is as the main component in the plantation base manure of cottonwood or base manure.
Dyeing waste water biomass processes technique the most according to claim 1, it is characterised in that in the described water in the cistern in step C, the concentration of EDTA is set as 0.5-1.5g/L, and the concentration of sodium gluconate is set as 1-6g/L, sodium tert-butoxide 0.1-1.5g/L.
Dyeing waste water biomass processes technique the most according to claim 1, it is characterized in that, consisting of of the described Sand Filtration System in step C, upper strata is fine sand, middle level is the spun-laced nonwoven fabric of polyster fibre leftover pieces and bamboo fibre leftover pieces blending, and lower floor is gravel.
Dyeing waste water biomass processes technique the most according to claim 4, it is characterised in that the described upper strata in Sand Filtration System and middle level, changed once every the 1-3 month, and the Sand Filtration System changed is as the main component in the plantation base manure of cottonwood or base manure.
CN201610480672.6A 2016-06-28 2016-06-28 Dyeing wastewater biomass treatment technique Pending CN105984979A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112023905A (en) * 2020-04-10 2020-12-04 朱晴 Composite material for treating heavy metal ions in wastewater

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07124569A (en) * 1993-11-08 1995-05-16 Wasen Kogyo Kk Decoloration treatment of printing/dyeing waste water
CN101700938A (en) * 2009-11-19 2010-05-05 浙江新成染纱有限公司 Purification and softening method for printing and dyeing technology water
CN102040313A (en) * 2010-09-27 2011-05-04 常熟市福亿印花炼染有限公司 Process for treating high-concentration printing and dying waste water
CN102583886A (en) * 2012-02-21 2012-07-18 海南农丰宝肥料有限公司 Artificial wetland for treating sewage
CN104071920A (en) * 2014-08-07 2014-10-01 南通润启时装有限公司 Printing and dyeing wastewater treatment process
CN104986894A (en) * 2015-07-02 2015-10-21 长沙华时捷环保科技发展有限公司 Method and device for softening high-hardness waste water through gas and liquid combination

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07124569A (en) * 1993-11-08 1995-05-16 Wasen Kogyo Kk Decoloration treatment of printing/dyeing waste water
CN101700938A (en) * 2009-11-19 2010-05-05 浙江新成染纱有限公司 Purification and softening method for printing and dyeing technology water
CN102040313A (en) * 2010-09-27 2011-05-04 常熟市福亿印花炼染有限公司 Process for treating high-concentration printing and dying waste water
CN102583886A (en) * 2012-02-21 2012-07-18 海南农丰宝肥料有限公司 Artificial wetland for treating sewage
CN104071920A (en) * 2014-08-07 2014-10-01 南通润启时装有限公司 Printing and dyeing wastewater treatment process
CN104986894A (en) * 2015-07-02 2015-10-21 长沙华时捷环保科技发展有限公司 Method and device for softening high-hardness waste water through gas and liquid combination

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112023905A (en) * 2020-04-10 2020-12-04 朱晴 Composite material for treating heavy metal ions in wastewater
CN112044407A (en) * 2020-04-10 2020-12-08 朱晴 Application of composite material in treatment of heavy metal ions in wastewater

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Application publication date: 20161005