CN105968938B - A kind of ultraviolet light solidification acid-resistant glass protection ink and preparation method thereof - Google Patents
A kind of ultraviolet light solidification acid-resistant glass protection ink and preparation method thereof Download PDFInfo
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- CN105968938B CN105968938B CN201610369805.2A CN201610369805A CN105968938B CN 105968938 B CN105968938 B CN 105968938B CN 201610369805 A CN201610369805 A CN 201610369805A CN 105968938 B CN105968938 B CN 105968938B
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- Prior art keywords
- acid
- parts
- acrylic ester
- resistant glass
- ester prepolymer
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- 239000002253 acid Substances 0.000 title claims abstract description 51
- 239000011521 glass Substances 0.000 title claims abstract description 49
- 238000007711 solidification Methods 0.000 title claims abstract description 13
- 230000008023 solidification Effects 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- -1 acrylic ester Chemical class 0.000 claims abstract description 65
- 239000003112 inhibitor Substances 0.000 claims abstract description 19
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 19
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000003085 diluting agent Substances 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000004593 Epoxy Substances 0.000 claims description 39
- 238000003756 stirring Methods 0.000 claims description 20
- 229920000728 polyester Polymers 0.000 claims description 17
- VOOLKNUJNPZAHE-UHFFFAOYSA-N formaldehyde;2-methylphenol Chemical compound O=C.CC1=CC=CC=C1O VOOLKNUJNPZAHE-UHFFFAOYSA-N 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 6
- 150000008064 anhydrides Chemical group 0.000 claims description 6
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical group [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 4
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 4
- 229940091853 isobornyl acrylate Drugs 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 4
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 claims description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 claims description 2
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 claims description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 2
- 159000000013 aluminium salts Chemical class 0.000 claims description 2
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 claims description 2
- VJMJYBVERHZATL-UHFFFAOYSA-N (2,4,6-trimethylbenzoyl)phosphonoyl-(2,4,6-trimethylphenyl)methanone Chemical class CC1=CC(C)=CC(C)=C1C(=O)P(=O)C(=O)C1=C(C)C=C(C)C=C1C VJMJYBVERHZATL-UHFFFAOYSA-N 0.000 claims 1
- ODRLUQGNINLIRR-UHFFFAOYSA-N 1-propylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCC ODRLUQGNINLIRR-UHFFFAOYSA-N 0.000 claims 1
- 125000006181 4-methyl benzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])C([H])([H])* 0.000 claims 1
- QIAIOFAECXPNLI-UHFFFAOYSA-N CCCC(C1(CCCCC1)C(C1=CC=CC=C1)=O)O Chemical group CCCC(C1(CCCCC1)C(C1=CC=CC=C1)=O)O QIAIOFAECXPNLI-UHFFFAOYSA-N 0.000 claims 1
- IPLSEXAJUSLMIQ-UHFFFAOYSA-N CNC(C(CC)=O)C1=CC=C(C=C1)N1CCOCC1 Chemical compound CNC(C(CC)=O)C1=CC=C(C=C1)N1CCOCC1 IPLSEXAJUSLMIQ-UHFFFAOYSA-N 0.000 claims 1
- 235000017858 Laurus nobilis Nutrition 0.000 claims 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims 1
- 244000125380 Terminalia tomentosa Species 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 claims 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract description 46
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 42
- 239000000853 adhesive Substances 0.000 abstract description 18
- 230000001070 adhesive effect Effects 0.000 abstract description 18
- 239000005357 flat glass Substances 0.000 abstract description 2
- 238000007650 screen-printing Methods 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000000034 method Methods 0.000 description 15
- 239000003513 alkali Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 238000007639 printing Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- 238000001514 detection method Methods 0.000 description 5
- 235000021050 feed intake Nutrition 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- RDHSUTIDSFVNJL-UHFFFAOYSA-N OC(=O)C=C.CCCCCCCCCCCC(O)=O Chemical compound OC(=O)C=C.CCCCCCCCCCCC(O)=O RDHSUTIDSFVNJL-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000013799 ultramarine blue Nutrition 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000002633 protecting effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- PTPLXVHPKMTVIW-FPLPWBNLSA-N (Z)-hydroxyimino-oxido-phenylazanium Chemical compound O\N=[N+](/[O-])c1ccccc1 PTPLXVHPKMTVIW-FPLPWBNLSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 1
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical compound PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
Abstract
A kind of ultraviolet light solidification acid-resistant glass protection ink; it by weight include following components: 30~70 parts of acrylic ester prepolymer; 5~25 parts of diluent; 0.1-2 parts of levelling agent; 0.2~3 part of defoaming agent, 2~10 parts of Photoepolymerizationinitiater initiater, 0.1~2 part of toner; 0.02~0.5 part of polymerization inhibitor, 10~50 parts of filler.Ink provided by the invention is that a kind of flexibility is good, adhesive force is good, be resistant to high concentration of hydrofluoric acid, sulfuric acid etc.; and protectiveness is good, demoulding is easy, the cured glass protection ink of easy to operate ultraviolet light; 100~250 mesh silk-screen printings are adaptable to, interim protection of cover-plate glass etc. is mainly used in.
Description
Technical field
The invention belongs to glass protection ink areas more particularly to a kind of ultraviolet light (UV) solidification acid-resistant glass to protect ink
And preparation method thereof.
Background technique
Existing cover-plate glass processing technology imitates type from sliver, and CNC is easy to until processes such as polishings in board
Or a degree of scratch is caused to glass in other operations.These scratches generally require in subsequent handling using plain grinding technique
Polished elimination；It, just can only be by scrap of the product, so to cover board when can not be eliminated with the method for plain grinding for serious scratch
The protection of glass in process is particularly important.The mode of the ink of printing protection so far is optimal protected mode, is fitted
For scale of mass production, protecting effect is good.
As CN 103160169A discloses a kind of UV glass protection ink and preparation method thereof., which includes following weight
Component: polyurethane acrylic resin 25-50 is measured, propylene is acidified acrylic resin 20-45, hydroxyethyl methacrylate 1-10,1.6
Glycol diacrylate 1-10, dipentaerythritol hexaacrylate 1-8, photoinitiator 6-12, toner 3-8, meteorological titanium dioxide
Silicon 1-4, defoaming agent 2-5, dispersing agent 2-5, silanes adhesion promoter 1-3.It is added by the way that mentioned component successively to be pressed to number, and
Constant speed stirs when sufficient, is then ground using three-roller, can be obtained after last filtering solution.Make in touched panel glass processing technology
Glass surface is carried out after silk-screen is protected with the present invention, the final serviceability rate of glass product is than unused glass protecting measure
When improve 27%-40%, the wasting of resources can be reduced significantly, low enterprise's manufacturing cost of drop improves enterprise's production capacity.
However, above-mentioned ink and UV curing glass protection ink performance currently on the market are immature, in particular resistance to height
Concentration hydrofluoric acid and sulfuric acid performance are poor, be easy to cause and are not easy to take off film, and cleaning is difficult, in high volume production process, can largely disappear
The production time is consumed, and increases human and material resources cost.
Summary of the invention
To solve the above problems, the object of the present invention is to provide a kind of ultraviolet light solidification acid-resistant glass to protect ink.This hair
The ink of bright offer is filled out by acrylic ester prepolymer, diluent, levelling agent, defoaming agent, Photoepolymerizationinitiater initiater, polymerization inhibitor, toner
The composition such as material is that a kind of flexibility is good, adhesive force is good, is resistant to high concentration of hydrofluoric acid, sulfuric acid etc., and protectiveness is good, demoulding is easy,
The cured glass protection ink of easy to operate ultraviolet light, is adaptable to 100~250 mesh silk-screen printings, is mainly used in lid
Interim protection of glass sheet etc..
In order to achieve the above object, the present invention adopts the following technical scheme:
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components: acrylic ester prepolymer 30 by weight
~70 parts, for example, 32 parts, 36 parts, 38 parts, 41 parts, 44 parts, 48 parts, 52 parts, 56 parts, 59 parts, 63 parts, 68 parts etc., diluent 5
~25 parts, for example, 7 parts, 9 parts, 11 parts, 13 parts, 16 parts, 19 parts, 22 parts etc., 0.1-2 parts of levelling agent, for example, 0.2 part, 0.4
Part, 0.7 part, 0.9 part, 1.2 parts, 1.4 parts, 1.7 parts etc., 0.2~3 part of defoaming agent, for example, 0.2 part, 0.4 part, 0.7 part, 0.9
Part, 1.2 parts, 1.4 parts, 1.7 parts, 2.3 parts, 27 parts etc., 2~10 parts of Photoepolymerizationinitiater initiater, for example, 4 parts, 6 parts, 8 parts etc., color
0.1~2 part of powder, for example, 0.2 part, 0.4 part, 0.7 part, 0.9 part, 1.2 parts, 1.4 parts, 1.7 parts etc., polymerization inhibitor 0.02~0.5
Part, for example, 0.04 part, 0.07 part, 0.11 part, 0.15 part, 0.22 part, 0.28 part, 0.34 part, 0.39 part, 0.45 part, 0.48
Part etc., 10~50 parts of filler, for example, 12 parts, 16 parts, 19 parts, 23 parts, 28 parts, 32 parts, 36 parts, 38 parts, 41 parts, 44 parts, 48
Part etc.；
Wherein, the acrylic ester prepolymer is pre- by o-cresol formaldehyde type epoxy acrylic ester prepolymer, epoxy acrylate
Polymers, polyester acrylic ester prepolymer composition.
Wherein o-cresol formaldehyde type epoxy acrylic ester prepolymer can rapid curing, obtain after hardening superelevation resistance to chemical reagents with
Heat resistant polymer, to improve the resistances to chemical reagents such as resisting high-concentration hydrofluoric acid, sulfuric acid；Epoxy acrylic ester prepolymer is high after hardening
Adhesive force, especially high ply adhesion, flexibility is good, and resistance to chemical reagents is good；Polyester acrylic ester prepolymer has well after hardening
Adhesive force and high-flexibility.O-cresol formaldehyde type epoxy acrylic ester prepolymer, epoxy acrylic ester prepolymer, polyester acrylic
Three kinds of substances of ester prepolymer with the use of that can make, ink flexibility obtained is good, adhesive force is good, is resistant to high concentration of hydrofluoric acid, sulphur
Acid etc..
Preferably, acid-resistant glass of the invention protects ink, it by weight include following components: acrylic ester prepolymer
40~70 parts, 5~15 parts of diluent, 0.3~1 part of levelling agent, 0.5~2 part of defoaming agent, 3~10 parts of Photoepolymerizationinitiater initiater, toner
0.3~1 part, 0.05~0.3 part of polymerization inhibitor, 15~40 parts of filler.
Preferably, acid-resistant glass of the invention protects ink, it by weight include following components: acrylic ester prepolymer
45~70 parts, 10~15 parts of diluent, 0.5 part of levelling agent, 1~1.5 part of defoaming agent, 5~8 parts of Photoepolymerizationinitiater initiater, toner 0.5
Part, 0.1 part of polymerization inhibitor, 20~30 parts of filler.
Preferably, the epoxy acrylic ester prepolymer is bisphenol A epoxy acrylate prepolymer, Bisphenol F epoxy third
The a combination of one or more of olefin(e) acid ester prepolymer, bisphenol S epoxy acrylic ester prepolymer.
Preferably, the epoxy acrylic ester prepolymer is anhydride modified epoxy acrylic ester prepolymer.Generally Malaysia
The modification of the acid anhydrides such as acid anhydrides, methyl hexahydrophthalic anhydride, methyl tetrahydro phthalic anhydride, succinic anhydride.It can be used known to those skilled in the art
Method be modified.
Preferably, the o-cresol formaldehyde type epoxy acrylic ester prepolymer dosage is 2-15 parts, for example, 4 parts, 7 parts, 11
Part, 14 parts etc., more preferably 5~10 parts.
Preferably, the epoxy acrylic ester prepolymer dosage be 7~40 parts, for example, 9 parts, 12 parts, 16 parts, 20 parts,
24 parts, 28 parts, 33 parts, 37 parts etc., preferably 15~25 parts.
Preferably, the polyester acrylic ester prepolymer dosage is 10~50 parts, for example, 12 parts, 16 parts, 20 parts, 24
Part, 28 parts, 33 parts, 37 parts, 42 parts, 46 parts, 49 parts etc., preferably 25~35 parts.
Preferably, the epoxy acrylic ester prepolymer acid value is 50~200mgKOH/g, for example, 52mgKOH/
g、56mg·KOH/g、60mg·KOH/g、65mg·KOH/g、80mg·KOH/g、90mg·KOH/g、110mg·KOH/g、
125mgKOH/g, 140mgKOH/g, 160mgKOH/g, 180mgKOH/g, 195mgKOH/g etc., preferably 100
~150mgKOH/g.
Preferably, the polyester acrylic ester prepolymer elongation percentage be 50~150%, for example, 55%, 68%, 72%,
81%, 89%, 95%, 105%, 125%, 135%, 140%, 147% etc., preferably 80~120%；Acid value be 15~
50mgKOH/g, for example, 17mgKOH/g, 19mgKOH/g, 22mgKOH/g, 28mgKOH/g, 33mgKOH/
G, 39mgKOH/g, 43mgKOH/g, 48mgKOH/g etc., preferably 25-40mgKOH/g.
Preferably, the diluent is acrylate monomer, preferably lauric acid acrylate, two propylene of dipropylene glycol
The a combination of one or more of acid esters, tripropylene glycol diacrylate, iso-bornyl acrylate.Above-mentioned diluent is attached
Put forth effort, low viscosity, dilution effect are good, curing rate is fast, flexibility is good.
Preferably, the levelling agent is esters of acrylic acid levelling agent, can be taken off under alkaline condition with resin,
It is specifically as follows a combination of one or more of BYK-354 or BYK-355 or the like.
Preferably, the defoaming agent has organic silicon defoaming agent to be non-, can take off under alkaline condition with resin
It goes, is specifically as follows a combination of one or more of BYK-053 or BYK-057 or the like.
Preferably, the Photoepolymerizationinitiater initiater can be 1- hydroxycyclohexyl phenyl ketone, 2- methyl-1-[4- (methyl
It is thio) phenyl] -2- (4- morpholinyl) -1- acetone, 2- benzyl -2- dimethylamino -1- (4- morpholinyl phenyl) butanone, 2- (4- first
Base benzyl) -2- (dimethylamino) -1- (4- morpholinyl phenyl) -1- butanone, the oxidation of 2,4,6- trimethylbenzoy-dipheny
Bis- (2,4, the 6- trimethylbenzoyl) phosphine oxides of phosphine, phenyl, 2- isopropyl thioxanthone, the fluoro- 3- pyrroles's phenyl of double 2,6- bis-
Titanocenes, 2- hydroxy-2-methyl -1- phenylacetone.
The above Photoepolymerizationinitiater initiater as commercially available product, such as can enumerate BASF AG production IRGACURE 184,
IRGACURE 907、IRGACURE 369、IRGACURE379、LUCIRIN TPO、IRGACURE 819、IRGACURE ITX、
The a combination of one or more of IRGACURE 784, DAROCUR 1173 etc..
Preferably, the toner is phthalocyanine blue or ultramarine blue.
Preferably, the polymerization inhibitor is three (N- nitroso-N-Phenylhydroxylamine) aluminium salts, it is commercially available such as 510UV polymerization inhibitor.
Preferably, the filler is talcum powder or alumina powder.
The present invention is by o-cresol formaldehyde type epoxy acrylic ester prepolymer to improve the drug resistances such as resisting high-concentration hydrofluoric acid, sulfuric acid
Moral character improves adhesive force especially ply adhesion by epoxy acrylic ester prepolymer, and polyester acrylate improves flexibility,
Diluent, Photoepolymerizationinitiater initiater, defoaming agent, levelling agent, polymerization inhibitor and filler is cooperated to can get resisting high-concentration hydrofluoric acid, sulphur again
Acid, flexibility is good, adhesive force is good, easily takes off the not remaining ultraviolet light solidification acid-resistant glass protection ink of film.
An object of the present invention also resides in the system that a kind of ultraviolet light of the invention solidifies acid-resistant glass protection ink that provides
Preparation Method, includes the following steps: to weigh acrylic ester prepolymer, diluent, levelling agent, excellent after being dispersed with stirring uniformly after defoaming agent
Side is selected to be added with stirring Photoepolymerizationinitiater initiater, toner, polymerization inhibitor and filler, until after being dispersed with stirring uniformly.It is preferred that institute
Stirring is stated to carry out by dispersion machine.
Preferably, the time being dispersed with stirring be 30min or more, for example, 35min, 40min, 60min, 80min,
100min, 120min, 140min, 160min, 180min, 200min etc., preferably 90~150min.
Preferably, the revolving speed being dispersed with stirring be 300-1000r/min, for example, 350r/min, 500r/min,
650r/min, 800r/min, 950r/min, 1100r/min, 1300r/min etc., preferably 600r/min.
Ink provided by the invention has the advantages that
(1) it is resistant to high concentration of hydrofluoric acid, sulfuric acid, > 30 minutes hardness, adhesive force etc. under 40% concentration hydrofluoric acid, sulfuric acid
Performance does not change, injury-free in high concentration of hydrofluoric acid, sulfuric acid operating environment to protect；
(2) adhesive force of film or interlayer is fine, and adhesive force grade is 5B；
(3) can cutting fluid, polishing fluid in resistance to CNC technique for a long time, > 2 hours, the performances such as hardness, adhesive force did not became
Change, it is injury-free in CNC processing technology to protect；
(4) it is short to take off the film time, and at 80 DEG C of 5% sodium hydroxide solution, the alkali of printed monolayer film takes off the time and most reaches fastly
In 50s；The alkali for printing the double-deck film takes off the time and most reaches in 100s fastly；Film is taken off not remain completely.
Specific embodiment
In order to better illustrate the present invention, it is easy to understand technical solution of the present invention, of the invention is typical but non-limiting
Embodiment is as follows:
Embodiment 1
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components by weight:
By o-cresol formaldehyde type epoxy acrylic ester prepolymer, anhydride modified epoxy acrylic ester prepolymer, polyester acrylic
Ester prepolymer, lauric acid acrylate, dipropylene glycol diacrylate, BYK-057, BYK-354 weighing feed intake after mixing evenly
It is stirred evenly after IRGACURE 184, LUCIRIN TPO, phthalocyanine blue, 510 polymerization inhibitors, talcum powder is added while stirring.
Gained ink detection parameters result is as follows:
Adhesive force 5B
Hardness 3H
9000 ± 2000mpas of viscosity
Resistance to CNC technique > 2 hours
Alkali takes off time < 60s (printed monolayer film)；< 120s (printing the double-deck film) is at 80 DEG C of 5% sodium hydroxide solution
Hydrofluoric acid resistant, sulfuric acid > 30 minutes (40% concentration hydrofluoric acid, sulfuric acid).
Embodiment 2
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components by weight:
By o-cresol formaldehyde type epoxy acrylic ester prepolymer, anhydride modified epoxy acrylic ester prepolymer, polyester acrylic
Ester prepolymer, tripropylene glycol diacrylate, iso-bornyl acrylate, BYK-053, BYK-355 weighing feed intake and stir evenly
IRGACURE ITX, 907 IRGACURE, LUCIRIN TPO, ultramarine blue, 510 polymerization inhibitors, alumina powder is added while stirring afterwards
After stir evenly.
Gained ink detection parameters result is as follows:
Adhesive force 5B
Hardness 3H
9000 ± 2000mpas of viscosity
Resistance to CNC technique > 1.5 hours
Alkali takes off time < 50s (printed monolayer film)；< 100s (printing the double-deck film) is at 80 DEG C of 5% sodium hydroxide solution
Hydrofluoric acid resistant, sulfuric acid > 20 minutes (40% concentration hydrofluoric acid, sulfuric acid)
Embodiment 3
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components by weight:
By o-cresol formaldehyde type epoxy acrylic ester prepolymer, anhydride modified epoxy acrylic ester prepolymer, polyester acrylic
Ester prepolymer, iso-bornyl acrylate, BYK-057, BYK-355 weighing feed intake and are added while stirring after mixing evenly
It is stirred evenly after IRGACURE 184, phthalocyanine blue and ultramarine blue, 510 polymerization inhibitors, talcum powder and alumina powder.
Gained ink detection parameters result is as follows:
Adhesive force 5B
Hardness 3H
9000 ± 2000mpas of viscosity
Resistance to CNC technique > 2 hours
Alkali takes off time < 100s (printed monolayer film)；< 200s (printing the double-deck film) is in 5% sodium hydroxide solution 80
℃
Hydrofluoric acid resistant, sulfuric acid > 45 minutes (40% concentration hydrofluoric acid, sulfuric acid)
Comparative example 1
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components by weight:
By anhydride modified epoxy acrylic ester prepolymer, polyester acrylic ester prepolymer, lauric acid acrylate, dipropyl two
Alcohol diacrylate, BYK-057, BYK-354 weighing feed intake and IRGACURE184, LUCIRIN are added while stirring after mixing evenly
It is stirred evenly after TPO, phthalocyanine blue, 510 polymerization inhibitors, talcum powder.
Gained ink detection parameters result is as follows:
Adhesive force 5B
Hardness 3H
9000 ± 2000mpas of viscosity
Resistance to CNC technique > 2 hours
Alkali takes off time < 60s (printed monolayer film)；< 120s (printing the double-deck film) is at 80 DEG C of 5% sodium hydroxide solution
Hydrofluoric acid resistant, sulfuric acid < 10 minutes (40% concentration hydrofluoric acid, sulfuric acid)
This comparative example is free of o-cresol formaldehyde type epoxy acrylic ester prepolymer.From the performance test results as can be seen that by this
Ink made from comparative example not hydrofluoric acid resistant, sulfuric acid substantially.
Comparative example 2
A kind of ultraviolet light solidification acid-resistant glass protection ink, includes following components by weight:
By o-cresol formaldehyde type epoxy acrylic ester prepolymer, polyester acrylic ester prepolymer, lauric acid acrylate, dipropyl
Omega-diol diacrylate, BYK-057, BYK-354 weighing feed intake after mixing evenly while stirring be added IRGACURE184,
It is stirred evenly after LUCIRIN TPO, phthalocyanine blue, 510 polymerization inhibitors, talcum powder.
Gained ink detection parameters result is as follows:
Adhesive force 3B
Hardness 3H
9000 ± 2000mpas of viscosity
Resistance to CNC technique > 2 hours
Alkali takes off time < 120s (printed monolayer film)；< 240s (printing the double-deck film) is in 5% sodium hydroxide solution 80
℃
Hydrofluoric acid resistant, sulfuric acid > 30 minutes (40% concentration hydrofluoric acid, sulfuric acid)
This comparative example is free of epoxy acrylic ester prepolymer.From the performance test results as can be seen that being made by the comparative example
Although ink hydrofluoric acid resistant, sulfuric acid increase, its adhesive force be deteriorated, alkali take off the time growth.
Only o-cresol formaldehyde type epoxy acrylic ester prepolymer, epoxy acrylate it can be seen from above-mentioned comparison result
Prepolymer, three kinds of substances of polyester acrylic ester prepolymer combination made from ink could obtain relatively good comprehensive performance,
Guarantee while adhesive force, alkali take off the time with good hydrofluoric acid resistant, sulfuric acid performance.
The Applicant declares that the present invention is explained by the above embodiments method detailed of the invention, but the present invention not office
Be limited to above-mentioned method detailed, that is, do not mean that the invention must rely on the above detailed methods to implement.Technical field
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to each raw material of product of the present invention
Addition, selection of concrete mode etc., all of which fall within the scope of protection and disclosure of the present invention.
Claims (26)
- By weight include following components 1. a kind of ultraviolet light solidification acid-resistant glass protects ink: acrylic ester prepolymer 30~ 70 parts, 5~25 parts of diluent, 0.1-2 parts of levelling agent, 0.2~3 part of defoaming agent, 2~10 parts of Photoepolymerizationinitiater initiater, toner 0.1~ 2 parts, 0.02~0.5 part of polymerization inhibitor, 10~50 parts of filler；Wherein, the acrylic ester prepolymer by o-cresol formaldehyde type epoxy acrylic ester prepolymer, epoxy acrylic ester prepolymer, Polyester acrylic ester prepolymer composition, the epoxy acrylic ester prepolymer acid value are 50~200mgKOH/g, the polyester Acrylic ester prepolymer elongation percentage is 50~150%, and acid value is 15~50mgKOH/g；Wherein, the o-cresol formaldehyde type epoxy acrylic ester prepolymer dosage is 2~15 parts；The epoxy acrylic ester prepolymer Dosage is 7~40 parts；The polyester acrylic ester prepolymer dosage is 10~50 parts.
- 2. acid-resistant glass according to claim 1 protects ink, which is characterized in that by weight include following components: third 40~70 parts of olefin(e) acid ester prepolymer, 5~15 parts of diluent, 0.3~1 part of levelling agent, 0.5~2 part of defoaming agent, Photoepolymerizationinitiater initiater 3~10 parts, 0.3~1 part of toner, 0.05~0.3 part of polymerization inhibitor, 15~40 parts of filler.
- 3. acid-resistant glass according to claim 2 protects ink, which is characterized in that by weight include following components: third 45~70 parts of olefin(e) acid ester prepolymer, 10~15 parts of diluent, 0.5 part of levelling agent, 1~1.5 part of defoaming agent, Photoepolymerizationinitiater initiater 5 ~8 parts, 0.5 part of toner, 0.1 part of polymerization inhibitor, 20~30 parts of filler.
- 4. acid-resistant glass according to claim 1 protects ink, which is characterized in that the epoxy acrylic ester prepolymer is One kind of bisphenol A epoxy acrylate prepolymer, Bisphenol F epoxy acrylic ester prepolymer, bisphenol S epoxy acrylic ester prepolymer Or two or more combination.
- 5. acid-resistant glass according to claim 1 protects ink, which is characterized in that the epoxy acrylic ester prepolymer is Anhydride modified epoxy acrylic ester prepolymer.
- 6. acid-resistant glass according to claim 1 protects ink, which is characterized in that the o-cresol formaldehyde type epoxy acrylic Ester prepolymer dosage is 5~10 parts.
- 7. acid-resistant glass according to claim 1 protects ink, which is characterized in that the epoxy acrylic ester prepolymer is used Amount is 15~25 parts.
- 8. acid-resistant glass according to claim 1 protects ink, which is characterized in that the polyester acrylic ester prepolymer is used Amount is 25~35 parts.
- 9. acid-resistant glass according to claim 1 protects ink, which is characterized in that the epoxy acrylic ester prepolymer acid Value is 100~150mgKOH/g.
- 10. acid-resistant glass according to claim 1 protects ink, which is characterized in that the polyester acrylic ester prepolymer Elongation percentage is 80~120%；Acid value is 25~40mgKOH/g.
- 11. acid-resistant glass according to claim 1 protects ink, which is characterized in that the diluent is acrylate list Body.
- 12. acid-resistant glass according to claim 11 protects ink, which is characterized in that the diluent is laurel acid propylene The one or more of acid esters, dipropylene glycol diacrylate, tripropylene glycol diacrylate, iso-bornyl acrylate Combination.
- 13. acid-resistant glass according to claim 1 protects ink, which is characterized in that the levelling agent is esters of acrylic acid Levelling agent.
- 14. acid-resistant glass according to claim 13 protects ink, which is characterized in that the levelling agent be BYK-354 or/ And BYK-355.
- 15. acid-resistant glass according to claim 1 protects ink, which is characterized in that the defoaming agent has organosilicon to be non- Class defoaming agent.
- 16. acid-resistant glass according to claim 15 protects ink, which is characterized in that the defoaming agent be BYK-053 or/ And BYK-057.
- 17. acid-resistant glass according to claim 1 protects ink, which is characterized in that the Photoepolymerizationinitiater initiater is 1- hydroxyl Butylcyclohexyl phenyl ketone, 2- methyl-1-[4- (methyl thio) phenyl]-2- (4- morpholinyl)-1- acetone, 2- benzyl-2- two Methylamino -1- (4- morpholinyl phenyl) butanone, 2- (4- methylbenzyl) -2- (dimethylamino) -1- (4- morpholinyl phenyl) -1- fourth Bis- (2,4,6- trimethylbenzoyl) phosphine oxides of ketone, 2,4,6- trimethylbenzoy-dipheny phosphine oxide, phenyl, 2- are different Propyl thioxanthone, the fluoro- 3- pyrroles's phenyl titanocenes of double 2,6- bis-, the one or two of 2- hydroxy-2-methyl -1- phenylacetone Above combination.
- 18. acid-resistant glass according to claim 1 protects ink, which is characterized in that the Photoepolymerizationinitiater initiater is BASF Company production IRGACURE 184, IRGACURE 907, IRGACURE 369, IRGACURE 379, LUCIRIN TPO, IRGACURE 819, IRGACURE ITX, 784 IRGACURE, DAROCUR 1173 a combination of one or more.
- 19. acid-resistant glass according to claim 1 protects ink, which is characterized in that the toner is phthalocyanine blue or ultramarine It is blue.
- 20. acid-resistant glass according to claim 1 protects ink, which is characterized in that the polymerization inhibitor is three (N- nitrous Base-N-Phenylhydroxylamine) aluminium salt.
- 21. acid-resistant glass according to claim 1 protects ink, which is characterized in that the filler is talcum powder or/and oxygen Change aluminium powder.
- 22. the described in any item ultraviolet lights of claim 1-21 solidify the preparation method of acid-resistant glass protection ink, including as follows Step: it weighs and is added with stirring Photoepolymerizationinitiater initiater, color after dispersing after acrylic ester prepolymer, diluent, levelling agent, defoaming agent Powder, polymerization inhibitor and filler are dispersed with stirring uniformly.
- 23. preparation method according to claim 22, which is characterized in that the time being dispersed with stirring is 30min or more.
- 24. preparation method according to claim 23, which is characterized in that the time being dispersed with stirring be 90~ 150min。
- 25. preparation method according to claim 22, which is characterized in that the revolving speed being dispersed with stirring is 300-1000r/ min。
- 26. preparation method according to claim 25, which is characterized in that the revolving speed being dispersed with stirring is 600r/min.
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| CN107418300B (en) * | 2017-09-15 | 2021-09-17 | 广州双科新材料有限公司 | Acid-resistant etching protection ink and preparation method and construction method thereof |
| CN107502042A (en) * | 2017-09-15 | 2017-12-22 | 广州双科新材料有限公司 | Cover-plate glass UV protection ink and preparation method thereof and construction method |
| CN108196426A (en) * | 2018-01-05 | 2018-06-22 | 潍坊星泰克微电子材料有限公司 | For the photoresist of GPP techniques, preparation method and its photoetching process |
| CN108003699B (en) * | 2018-01-11 | 2021-08-06 | 广州亦盛环保科技有限公司 | Protective printing ink for glass acid etching process and preparation method and application thereof |
| CN110079150A (en) * | 2018-01-26 | 2019-08-02 | 蓝思科技（长沙）有限公司 | A kind of UV protection ink and its preparation method and application |
| CN108929591B (en) * | 2018-07-17 | 2021-04-27 | 广州市红太电子科技有限公司 | Light-cured liquid photosensitive ink |
| CN111218004B (en) * | 2018-11-26 | 2021-06-18 | 比亚迪股份有限公司 | Polyoxysilane, preparation method thereof, glass protection composition and application thereof |
| CN112011259A (en) * | 2020-09-08 | 2020-12-01 | 台玻太仓工程玻璃有限公司 | Temporary protective film capable of reducing glass heat treatment cost and heat treatment method thereof |
| CN112724848A (en) * | 2020-12-24 | 2021-04-30 | 东莞市品佳光学科技有限公司 | Frosted toughened film and preparation process thereof |
| CN114989718B (en) * | 2022-06-08 | 2023-04-07 | 广东希贵光固化材料有限公司 | Coating for light film removal and application thereof |
| CN115627096A (en) * | 2022-11-04 | 2023-01-20 | 广东科鼎功能材料有限公司 | Hot water strippable protective ink and method for improving glass processing protective performance |
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Denomination of invention: A UV curable acid resistant glass protective ink and its preparation method Effective date of registration: 20200916 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Registration number: Y2020440000279 |
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Date of cancellation: 20210917 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Registration number: Y2020440000279 |
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Denomination of invention: The invention relates to an ultraviolet curing acid resistant glass protective ink and a preparation method thereof Effective date of registration: 20210918 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Registration number: Y2021980009645 |
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Date of cancellation: 20220930 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2021980009645 |
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Denomination of invention: UV curable acid resistant glass protective ink and its preparation method Effective date of registration: 20221012 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2022440000270 |
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Date of cancellation: 20230915 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2022440000270 |
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Denomination of invention: A UV curable acid resistant glass protective ink and its preparation method Effective date of registration: 20230919 Granted publication date: 20190614 Pledgee: Bank of China Limited Guangzhou Development Zone Branch Pledgor: GUANGZHOU 1S ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Registration number: Y2023980057423 |