CN105968654A - High-temperature-resisting injection molding material - Google Patents

High-temperature-resisting injection molding material Download PDF

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Publication number
CN105968654A
CN105968654A CN201610587853.9A CN201610587853A CN105968654A CN 105968654 A CN105968654 A CN 105968654A CN 201610587853 A CN201610587853 A CN 201610587853A CN 105968654 A CN105968654 A CN 105968654A
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CN
China
Prior art keywords
high temperature
parts
plastics material
temperature resistant
injected plastics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610587853.9A
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Chinese (zh)
Inventor
刘丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Innovation Reach Plastic Mold Co Ltd
Original Assignee
Suzhou Innovation Reach Plastic Mold Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Innovation Reach Plastic Mold Co Ltd filed Critical Suzhou Innovation Reach Plastic Mold Co Ltd
Priority to CN201610587853.9A priority Critical patent/CN105968654A/en
Publication of CN105968654A publication Critical patent/CN105968654A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a high-temperature-resisting injection molding material. The high-temperature-resisting injection molding material is prepared from, by mass, 60-80 parts of PVC resin, 30-40 parts of polycarbonate, 8-12 parts of plasticizer, 4-6 parts of lubricant and 8-22 parts of heat stabilizer, wherein the heat stabilizer is prepared from, by mass, 31-35% of zinc stearate, 41-49% of calcium carbonate and the balance hydrotalcite in a mixed mode. In this way, the material has high high-temperature-resisting performance, and the service life of the material at the high-temperature environment is prolonged.

Description

A kind of high temperature resistant injected plastics material
Technical field
The present invention relates to a kind of injected plastics material, particularly to a kind of high temperature resistant injected plastics material.
Background technology
So-called injection mo(u)lding refers to inject in mould by the injection of material adding heat fusing, cooled is become after solidifying The method of type product, its detailed process is: send into the barrel of heating by granular or powdered plastic from the hopper of injection machine, heated Plastify into molten condition, then press and injected by nozzle in the mold cavity of Guan Bi, keep die cavity institute by hardening by cooling The shape given, die sinking takes out after colloid, and the injected plastics material of present stage there is also following defect during use: Resistance to elevated temperatures is poor, causes easy deliquescing under the use environment that temperature is higher, thus affects it and use quality.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of high temperature resistant injected plastics material, it is possible to possesses and has stronger resistance to height Warm nature energy, thus improve service life in high temperature environments.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of high temperature resistant injected plastics material, Composition including following mass fraction:
Polyvinyl chloride resin 60-80 part;
Merlon 30-40 part;
Plasticizer 8-12 part;
Lubricant 4-6 part;
Heat stabilizer 8-22 part;
Wherein, described heat stabilizer is made up of zinc stearate, calcium carbonate and brucite mixing, calculates according to mass percent, institute The content stating zinc stearate accounts for 31-35%, and the content of described calcium carbonate is 41-49%, and surplus is brucite.
In a preferred embodiment of the present invention, the content ratio of described plasticizer and described lubricant is 2:1.
In a preferred embodiment of the present invention, described plasticizer be phthalate, aliphatic dibasic acid ester, Any one or more mixing of phosphoric acid ester.
In a preferred embodiment of the present invention, described lubricant is any one or more of silicone oil, fatty acid, polyester Mixing.
The invention has the beneficial effects as follows: a kind of high temperature resistant injected plastics material of the present invention possesses and has stronger resistance to elevated temperatures, from And improve service life in high temperature environments.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
A kind of high temperature resistant injected plastics material, including the composition of following mass fraction:
Polyvinyl chloride resin 60 parts;
Merlon 30 parts;
Plasticizer 8 parts;
Lubricant 4 parts;
Heat stabilizer 8 parts;
Described heat stabilizer is made up of zinc stearate, calcium carbonate and brucite mixing, calculates according to mass percent, described tristearin The content of acid zinc accounts for 31%, and the content of described calcium carbonate is 49%, and the content of described brucite is 10%.
Embodiment 2:
A kind of high temperature resistant injected plastics material, including the composition of following mass fraction:
Polyvinyl chloride resin 80 parts;
Merlon 40 parts;
Plasticizer 12 parts;
Lubricant 6 parts;
Heat stabilizer 22 parts;
Described heat stabilizer is made up of zinc stearate, calcium carbonate and brucite mixing, calculates according to mass percent, described tristearin The content of acid zinc accounts for 35%, and the content of described calcium carbonate is 41%, and the content of described brucite is 14%.
Embodiment 3:
A kind of high temperature resistant injected plastics material, including the composition of following mass fraction:
Polyvinyl chloride resin 70 parts;
Merlon 35 parts;
Plasticizer 10 parts;
Lubricant 5 parts;
Heat stabilizer 15 parts;
Described heat stabilizer is made up of zinc stearate, calcium carbonate and brucite mixing, calculates according to mass percent, described tristearin The content of acid zinc accounts for 33%, and the content of described calcium carbonate is 45%, and the content of described brucite is 12%.
Wherein, described plasticizer be phthalate, aliphatic dibasic acid ester, phosphoric acid ester any one or Multiple mixing.
Described lubricant is any one or more mixing of silicone oil, fatty acid, polyester.
The preparation method of a kind of high temperature resistant injected plastics material of the present invention is as follows:
(1), according to aforementioned proportion weigh polyvinyl chloride resin, Merlon, plasticizer, lubricant, carry out in being put into high-temperature smelting pot High temperature merges, and obtains mixed liquor,
(2), according to aforementioned proportion zinc stearate, calcium carbonate and brucite carried out proportioning, and stirs in being put into blender Uniformly, heat stabilizer is obtained;
(3), above-mentioned heat stabilizer is gradually put into above-mentioned mixed liquor, subsequently by screw extruder extrusion molding, finally Obtain high temperature resistant injected plastics material.
Being different from prior art, a kind of high temperature resistant injected plastics material of the present invention is by adding heat stabilizer, and optimizes each composition Between proportioning such that it is able to possess and have stronger resistance to elevated temperatures, thus improve service life in high temperature environments.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (4)

1. a high temperature resistant injected plastics material, it is characterised in that include the composition of following mass fraction:
Polyvinyl chloride resin 60-80 part;
Merlon 30-40 part;
Plasticizer 8-12 part;
Lubricant 4-6 part;
Heat stabilizer 8-22 part;
Wherein, described heat stabilizer is made up of zinc stearate, calcium carbonate and brucite mixing, calculates according to mass percent, institute The content stating zinc stearate accounts for 31-35%, and the content of described calcium carbonate is 41-49%, and surplus is brucite.
High temperature resistant injected plastics material the most according to claim 1, it is characterised in that containing of described plasticizer and described lubricant Amount ratio is 2:1.
High temperature resistant injected plastics material the most according to claim 1, it is characterised in that described plasticizer is phthalic acid ester Class, aliphatic dibasic acid ester, any one or more mixing of phosphoric acid ester.
High temperature resistant injected plastics material the most according to claim 1, it is characterised in that described lubricant is silicone oil, fatty acid, gathers Any one or more mixing of ester.
CN201610587853.9A 2016-07-25 2016-07-25 High-temperature-resisting injection molding material Pending CN105968654A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610587853.9A CN105968654A (en) 2016-07-25 2016-07-25 High-temperature-resisting injection molding material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610587853.9A CN105968654A (en) 2016-07-25 2016-07-25 High-temperature-resisting injection molding material

Publications (1)

Publication Number Publication Date
CN105968654A true CN105968654A (en) 2016-09-28

Family

ID=56953471

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610587853.9A Pending CN105968654A (en) 2016-07-25 2016-07-25 High-temperature-resisting injection molding material

Country Status (1)

Country Link
CN (1) CN105968654A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111019192A (en) * 2019-12-31 2020-04-17 广东胜达塑胶科技有限公司 Calcium-zinc heat stabilizer for PVC (polyvinyl chloride) pipes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101497725A (en) * 2009-02-26 2009-08-05 安徽华电线缆集团有限公司 Composite material for electric wire and cable insulation and sleeve
CN101555337A (en) * 2008-04-09 2009-10-14 上海天原集团胜德塑料有限公司 Low-precipitation type environmentally-friendly transparent soft polyvinyl chloride granules
CN102746598A (en) * 2012-07-27 2012-10-24 天津市利顺塑料制品有限公司 Oxidation-resistant and anti-cracking night-luminescent plastic product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555337A (en) * 2008-04-09 2009-10-14 上海天原集团胜德塑料有限公司 Low-precipitation type environmentally-friendly transparent soft polyvinyl chloride granules
CN101497725A (en) * 2009-02-26 2009-08-05 安徽华电线缆集团有限公司 Composite material for electric wire and cable insulation and sleeve
CN102746598A (en) * 2012-07-27 2012-10-24 天津市利顺塑料制品有限公司 Oxidation-resistant and anti-cracking night-luminescent plastic product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111019192A (en) * 2019-12-31 2020-04-17 广东胜达塑胶科技有限公司 Calcium-zinc heat stabilizer for PVC (polyvinyl chloride) pipes

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PB01 Publication
C10 Entry into substantive examination
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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160928

WD01 Invention patent application deemed withdrawn after publication