CN105962549A - Silver-white metal zipper and manufacturing method thereof - Google Patents
Silver-white metal zipper and manufacturing method thereof Download PDFInfo
- Publication number
- CN105962549A CN105962549A CN201610288481.XA CN201610288481A CN105962549A CN 105962549 A CN105962549 A CN 105962549A CN 201610288481 A CN201610288481 A CN 201610288481A CN 105962549 A CN105962549 A CN 105962549A
- Authority
- CN
- China
- Prior art keywords
- teeth
- slide fastener
- silvery white
- white metal
- metal zip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B19/00—Slide fasteners
- A44B19/24—Details
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B19/00—Slide fasteners
- A44B19/42—Making by processes not fully provided for in one other class, e.g. B21D53/50, B21F45/18, B22D17/16, B29D5/00
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Slide Fasteners (AREA)
Abstract
The invention discloses a silver-white metal zipper, which comprises aluminum alloy teeth and a silver-white oxide layer on the surfaces of the teeth, wherein the oxide layer is either aluminum phosphate or aluminum dihydrogen phosphate. According to the zipper which is manufactured by the silver-white metal zipper manufacturing method disclosed by the invention, the layer of aluminum phosphate or aluminum dihydrogen phosphate covers the surfaces of the teeth, so that the teeth are oxidation-resistant and corrosion-resistant, and the metal zipper has silver-white metallic luster.
Description
Technical field
The present invention relates to a kind of slide fastener and preparation method thereof, espespecially a kind of silvery white metal zip fastener and preparation method thereof.
Background technology
Along with making rapid progress of Garment Industry, for slide fastener outward appearance and structure, there is more requirement, metal zip fastener
Be the one in slide fastener, there is the advantage such as visual sensory of the metallic luster of top grade, high-quality, be commonly used for case and bag, sportswear,
Jeans, children's garment etc..The Technology restrictions such as dye are moved owing to aluminium alloy teeth slide fastener aluminum alloy material itself exists easily oxidation,
Make on market the application for this kind of slide fastener the most little.
Summary of the invention
It is an object of the invention to solve the problem that existing aluminium alloy teeth slide fastener easily aoxidizes.
The technical scheme used for solving technical problem proposed by the invention is: a kind of silvery white metal zip fastener includes
Aluminium alloy teeth and the argenteous oxide layer of tooth surface, described oxide layer is aluminum phosphate or aluminium dihydrogen phosphate.
The manufacture method of the silvery white metal zip fastener of the present invention, comprises the following steps that
A: slide fastener teeth are mechanically polished with polisher；
B: slide fastener teeth are carried out electrochemical deoiling: slide fastener is pulled open, puts in alkaline solution and soaks, to remove in slide fastener teeth
Greasy dirt, the weight proportion of described alkaline solution is: sodium hydroxide: tertiary sodium phosphate: sodium carbonate: water=1:(1～2): (1～2):
100；
C: in polishing fluid, slide fastener teeth are carried out chemical polishing process, zipper teeth tooth surface formed indissoluble there is silvery white
The aluminum phosphate of metallic luster or aluminium dihydrogen phosphate: described polishing fluid is 85% phosphoric acid solution, reaction temperature is 95～110 DEG C；
Slide fastener teeth are passivated processing in chromium-free passivation liquid by D: under room temperature；
E: be dried after slide fastener is cleaned；
F: coat protection against oxidation layer at zipper teeth tooth surface.
The technical scheme being further qualified the present invention includes:
The aluminum alloy materials of described aluminium alloy teeth includes such as the component of following percentage by weight: Si:0.1-0.2, Mg:
0.4-0.5, surplus is aluminum.
Epoxy resin protective layer is also coated in the oxide layer of described metal zip fastener.
Described epoxy resin protective layer thickness is 0.05-0.30mm.
The oil removing time described in step B is 1～2min.
The polishing time described in step C is 0.5～1min.
In step D, passivating solution uses passivating solution: using after water=1:5 dilution, the process time is 1～2min.
Protective layer described in step F is resin material.
By technique scheme, the invention have the benefit that the silvery white metal zip fastener making side according to the present invention
The tooth surface of the slide fastener that method makes has one layer of aluminum phosphate or aluminium dihydrogen phosphate, so that teeth resistance to oxidation is corrosion-resistant, and tool
There is silvery white metallic luster.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
The silvery white metal zip fastener of the present invention includes the argenteous oxide layer of aluminium alloy teeth and tooth surface.Oxidation
Being deposited upon tooth surface makes teeth resistance to oxidation corrosion-resistant, and has silvery white metallic luster.In the present embodiment, teeth material is
Aluminium alloy, includes such as the component of following percentage by weight: Si:0.1-0.2, Mg:0.4-0.5, and surplus is aluminum.The present embodiment
In, the oxide layer of metal zip fastener also coats epoxy resin protective layer, epoxy resin protective layer thickness is 0.05-0.30mm, enters
One step prevents teeth oxidation stain.
The manufacture method of the silvery white metal zip fastener of the present invention, comprises the following steps that
A: slide fastener teeth are mechanically polished with polisher；In the present embodiment, mechanical polisher uses Fushan City, Guangdong Province tool
The model of power Scientific and Technical Industry Co., Ltd is that the 24 of JL-PP124 takes turns polisher.Designed by slide fastener teeth directional and rotation direction,
Nothing throws stricture of vagina process makes the slide fastener flank of tooth smooth and band gloss, and slide fastener surface is polished by the thickest rear essence, plays subsequent treatment
To crucial effect.
B: slide fastener teeth are carried out electrochemical deoiling: slide fastener is pulled open, puts in alkaline solution and soaks, to remove slide fastener teeth
On greasy dirt, the weight proportion of described alkaline solution is: sodium hydroxide: tertiary sodium phosphate: sodium carbonate: water=1:(1～2): (1～
2): 100；In the present embodiment, operating procedure is: clean water oil removing clean water, and the oil removing time is 1～2min, removes
Remaining oil stain and spot in slide fastener teeth and strap, this process is drawn at three maos, the Dongguan new automatic line of mechanical Science and Technology Ltd.
Carrying out on chain machine, traction frequency is 35～50HZ.
C: in polishing fluid, slide fastener teeth are carried out chemical polishing process, zipper teeth tooth surface formed indissoluble there is silver
The aluminum phosphate of white metal gloss or aluminium dihydrogen phosphate: described, polishing fluid is 85% phosphoric acid solution, and reaction temperature is 95～110
℃.In the present embodiment, slide fastener is inserted in 85% phosphoric acid solution, polishing fluid temperature controller design temperature 95～110 DEG C, high temperature
Under the conditions of remove the oxidation film layer of aluminium alloy teeth itself, form new aluminum phosphate or aluminium dihydrogen phosphate protecting film layer, thus must
To a kind of aluminium alloy teeth slide fastener with silvery white metal glossy surface effect.In the present embodiment, operating procedure is: flowing is clear
Water cleaning polishing liquid polishing flowing clean water.This process device uses the mechanical Science and Technology Ltd. in three maos, Dongguan new
Type full automatic line slide fastener polishing machine, the process time is 0.5～1min, and traction frequency is 35～50HZ.
Slide fastener teeth are passivated processing in chromium-free passivation liquid by D: under room temperature；In the present embodiment, passivating solution uses deep
The chromium-free passivation liquid of ditch between fields Ou get Mei Science and Technology Ltd., forms one layer of water white passivation protecting film at slide fastener surface, effectively
Preventing slide fastener in use easy oxidation discoloration, device therefor uses three maos, the Dongguan new automatic line of mechanical Science and Technology Ltd. to draw
Chain machine, technological parameter is: passivation temperature is room temperature, and proportioning is passivating solution: water=1:5, and the process time is 1～2min, traction frequency
It is 35～50HZ.
E: be dried after slide fastener is cleaned；In the present embodiment, slide fastener cleans through rinse bath transfer matic flowing water, this process
It is a continuous process, three maos, Dongguan mechanical Science and Technology Ltd. new automatic line slide fastener cleaning machine is carried out, traction frequency
Rate is 35～50HZ.Meanwhile, the slide fastener after cleaning removes residual moisture on slide fastener by vacuum pump.
F: coat protection against oxidation layer at zipper teeth tooth surface；In the present embodiment, coating organic resin material uses
Crystal Singapore frame oil (use proportioning is 1:1) that Zhuhai Fu Bang new material Science and Technology Ltd. produces, use equipment is Guangdong Province's Buddhist
The JL-SJLJ type metal zip fastener that Ju Li Scientific and Technical Industry Co., Ltd of mountain city produces scalds band machine, and technological parameter is set to: temperature 100
～150 DEG C, under traction rotating speed 600-800r/min, baking is dry.Coating organic resin is protection against oxidation layer, enables aluminum alloy to teeth
Slide fastener surface forms a floor height brightness and has relief Singapore rack-layer, effectively ensures the processing afterwards of aluminium alloy teeth slide fastener
In using, the most easy to change being difficult to aoxidizes.
Be below salt spray test and the experiment parameter of strength test and result as follows:
Experiment conclusion: aluminium alloy teeth slide fastener is to use aluminum alloy material, its slide fastener horizontal drawing strength is significantly more than industry standard, same
Time through chemical polishing process after with without chemical polishing process slide fastener contrast, its decay resistance be improved significantly, warp
Cross the salt spray test under 1% neutral salt spray, 5% neutral salt spray, 5% acid salt fog different condition, the aluminum after chemical polishing processes
Alloy teeth slide fastener outward appearance the most all occurs in various degree without significant change or corrosion, the slide fastener surface processed without chemical polishing
Corrosion, aluminium alloy teeth slide fastener outward appearance and strength all meet zipper industry standard.
Following table is the physicochemical property test table (note: draw of the silvery white metal zip fastener made according to the manufacture method of the present invention
Chain teeth be processed by shot blasting after test).
According to the tooth surface of the slide fastener of the silvery white metal zip fastener manufacture method making of the present invention, there is one layer of aluminum phosphate
Or aluminium dihydrogen phosphate, there is silvery white metallic luster, use aluminum alloy materials, aluminum alloy materials density is little, more lightweight, full
The market demand of foot lightweight clothing, and meet the various physical and chemical performance indexs of conventional aluminum alloys teeth metal zip fastener, full
The development of foot zipper industry and environmental requirement, reduce metal zip fastener cost of manufacture.
Although the detailed description of the invention of the present invention is described in detail, but should not be construed as the protection to the present invention
The restriction of scope.In the scope described by claims, those skilled in the art can make without creative work
Various amendments and deformation still fall within protection scope of the present invention.
Claims (9)
1. a silvery white metal zip fastener, it is characterised in that: described metal zip fastener includes aluminium alloy teeth and tooth surface
Argenteous oxide layer, described oxide layer is aluminum phosphate or aluminium dihydrogen phosphate.
2. silvery white metal zip fastener as claimed in claim 1, it is characterised in that: the aluminum alloy materials of described aluminium alloy teeth
Including such as the component of following percentage by weight: Si:0.1-0.2, Mg:0.4-0.5, surplus is aluminum.
3. silvery white metal zip fastener as claimed in claim 1, it is characterised in that: also coat epoxy resin in described oxide layer
Protective layer.
4. silvery white metal zip fastener as claimed in claim 3, it is characterised in that: described epoxy resin protective layer thickness is
0.05-0.30mm 。
5. the manufacture method of the arbitrary described silvery white metal zip fastener of claims 1 to 3, it is characterised in that: described method bag
Include and have the following steps:
A: slide fastener teeth are mechanically polished with polisher；
B: slide fastener teeth are carried out electrochemical deoiling: slide fastener is pulled open, puts in alkaline solution and soaks, to remove in slide fastener teeth
Greasy dirt, the weight proportion of described alkaline solution is: sodium hydroxide: tertiary sodium phosphate: sodium carbonate: water=1:(1～2): (1～2):
100；
C: in polishing fluid, slide fastener teeth are carried out chemical polishing process, zipper teeth tooth surface formed indissoluble there is silvery white
The aluminum phosphate of metallic luster or aluminium dihydrogen phosphate: described polishing fluid is 85% phosphoric acid solution, reaction temperature is 95～110 DEG C；
Slide fastener teeth are passivated processing in chromium-free passivation liquid by D: under room temperature；
E: be dried after slide fastener is cleaned；
F: coat protection against oxidation layer at zipper teeth tooth surface.
6. the manufacture method of silvery white metal zip fastener as claimed in claim 5, it is characterised in that: during oil removing described in step B
Between be 1～2min.
7. the manufacture method of silvery white metal zip fastener as claimed in claim 5, it is characterised in that: at the polishing described in step C
The reason time is 0.5～1min.
8. the manufacture method of silvery white metal zip fastener as claimed in claim 5, it is characterised in that: in step D, passivating solution uses
Passivating solution: using after water=1:5 dilution, the process time is 1～2min.
9. the manufacture method of silvery white metal zip fastener as claimed in claim 5, it is characterised in that: the protective layer described in step F
For resin material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610288481.XA CN105962549A (en) | 2016-05-04 | 2016-05-04 | Silver-white metal zipper and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610288481.XA CN105962549A (en) | 2016-05-04 | 2016-05-04 | Silver-white metal zipper and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105962549A true CN105962549A (en) | 2016-09-28 |
Family
ID=56993689
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610288481.XA Pending CN105962549A (en) | 2016-05-04 | 2016-05-04 | Silver-white metal zipper and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105962549A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107460384A (en) * | 2017-08-23 | 2017-12-12 | 广州市哈根德斯皮具有限公司 | Case and bag special-purpose metal connector formula and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252963A (en) * | 1998-11-02 | 2000-05-17 | 朱国光 | Technology for manufacturing metallic zipper plated by metal |
| CN1523126A (en) * | 2003-02-21 | 2004-08-25 | Ykk株式会社 | Aluminum alloy with excellent decorativeness |
| CN101457362A (en) * | 2009-01-07 | 2009-06-17 | 湖南鑫美格新型装饰材料有限公司 | Aluminum section bar three acid polishing and leveling fog inhibitor for furniture and finishing method thereof |
| CN102834551A (en) * | 2011-03-08 | 2012-12-19 | 纳米及先进材料研发院有限公司 | Method for producing white anodized aluminum oxide |
| CN104911608A (en) * | 2015-04-30 | 2015-09-16 | 深圳市联星服装辅料有限公司 | Metal zipper with double-side color effect and production method thereof |
-
2016
- 2016-05-04 CN CN201610288481.XA patent/CN105962549A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252963A (en) * | 1998-11-02 | 2000-05-17 | 朱国光 | Technology for manufacturing metallic zipper plated by metal |
| CN1523126A (en) * | 2003-02-21 | 2004-08-25 | Ykk株式会社 | Aluminum alloy with excellent decorativeness |
| CN101457362A (en) * | 2009-01-07 | 2009-06-17 | 湖南鑫美格新型装饰材料有限公司 | Aluminum section bar three acid polishing and leveling fog inhibitor for furniture and finishing method thereof |
| CN102834551A (en) * | 2011-03-08 | 2012-12-19 | 纳米及先进材料研发院有限公司 | Method for producing white anodized aluminum oxide |
| CN104911608A (en) * | 2015-04-30 | 2015-09-16 | 深圳市联星服装辅料有限公司 | Metal zipper with double-side color effect and production method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107460384A (en) * | 2017-08-23 | 2017-12-12 | 广州市哈根德斯皮具有限公司 | Case and bag special-purpose metal connector formula and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104561876B (en) | A kind of hot dip galvanizing process method | |
| CN106562520A (en) | Metal zipper and manufacture method for same | |
| CN105734574B (en) | Polishing fluid | |
| CN102601025B (en) | Powder spraying technique for aluminum die-cast alloy part | |
| CN107587123A (en) | A kind of phone housing process of surface treatment | |
| WO2018040536A1 (en) | Method for preparing composite hot-galvanized steel wire | |
| CN103352216B (en) | The coloring treatment process of a kind of copper or copper alloy surface | |
| CN104530772B (en) | A kind of composite pigment and preparation method thereof | |
| CN105803438B (en) | A kind of ferrous metal slide fastener and preparation method thereof | |
| CN104911608B (en) | Metal zip fastener with two-sided color effects and preparation method thereof | |
| CN102953101B (en) | Chrome plated zinc alloy zipper and electroplating method thereof | |
| CN102991264A (en) | Manufacturing method of antique copper | |
| CN105962549A (en) | Silver-white metal zipper and manufacturing method thereof | |
| CN104593726B (en) | Wire drawing nickel outward appearance, the surface treatment method of Anti- tarnishing are imitated on a kind of metal base | |
| CN104178718A (en) | Production method of prestressed hot-galvanized steel wire for bridge | |
| CN105112988A (en) | Process of mechanical copper plating and mechanical copper alloy plating | |
| CN106086790A (en) | A kind of kirsite antique copper vacuum coating method | |
| CN103966590A (en) | Monosilane composited chromate-free passivation liquid and method for passivating galvanized steel wire surface coating | |
| CN107268003A (en) | Whiten deashing agent and zinc die casting alloys pre-treating method | |
| CN104799505A (en) | Metal zipper with spaced colors, manufacturing method and special mould | |
| CN103243325A (en) | Surface treatment method of metal product | |
| CN109778270A (en) | Mist gold process is electroplated | |
| CN109182834A (en) | Seam dew salad chain and preparation method thereof in a kind of metal | |
| CN106498455B (en) | A kind of mechanical zinc-plating-copper process deposition copper additive | |
| KR101573187B1 (en) | Process for corrosion protection of iron containing materials |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160928 |
|
| RJ01 | Rejection of invention patent application after publication |