CN105957985B - A kind of accumulator with corrosion resistance - Google Patents
A kind of accumulator with corrosion resistance Download PDFInfo
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- CN105957985B CN105957985B CN201610571585.1A CN201610571585A CN105957985B CN 105957985 B CN105957985 B CN 105957985B CN 201610571585 A CN201610571585 A CN 201610571585A CN 105957985 B CN105957985 B CN 105957985B
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- polyaniline
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- composite coating
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- 238000005260 corrosion Methods 0.000 title claims abstract description 93
- 230000007797 corrosion Effects 0.000 title claims abstract description 93
- 239000011248 coating agent Substances 0.000 claims abstract description 141
- 238000000576 coating method Methods 0.000 claims abstract description 141
- 238000003466 welding Methods 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims description 131
- 239000000835 fiber Substances 0.000 claims description 77
- 229920000767 polyaniline Polymers 0.000 claims description 73
- 239000000243 solution Substances 0.000 claims description 64
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 50
- 239000004917 carbon fiber Substances 0.000 claims description 50
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- AHADSRNLHOHMQK-UHFFFAOYSA-N methylidenecopper Chemical compound [Cu].[C] AHADSRNLHOHMQK-UHFFFAOYSA-N 0.000 claims description 38
- 239000002105 nanoparticle Substances 0.000 claims description 36
- 238000013019 agitation Methods 0.000 claims description 29
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 26
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000012153 distilled water Substances 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 23
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 20
- 239000003822 epoxy resin Substances 0.000 claims description 19
- 229920000647 polyepoxide Polymers 0.000 claims description 19
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 229920002292 Nylon 6 Polymers 0.000 claims description 12
- 230000009471 action Effects 0.000 claims description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 12
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 8
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 238000002848 electrochemical method Methods 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000005457 ice water Substances 0.000 claims description 6
- 150000007522 mineralic acids Chemical class 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000020477 pH reduction Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 26
- 239000011159 matrix material Substances 0.000 description 25
- 230000000694 effects Effects 0.000 description 15
- 150000002500 ions Chemical class 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
- 230000002528 anti-freeze Effects 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 10
- 239000003973 paint Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000012752 auxiliary agent Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 241000186216 Corynebacterium Species 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 230000005518 electrochemistry Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000012216 screening Methods 0.000 description 5
- 229910052979 sodium sulfide Inorganic materials 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/1245—Primary casings; Jackets or wrappings characterised by the material having a layered structure characterised by the external coating on the casing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Prevention Of Electric Corrosion (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
This application involves a kind of accumulators with corrosion resistance, including battery jar, it is provided with electrolytic cell in the battery jar, it is equipped with upper cover on the electrolytic cell, it is characterized in that, the electrolytic cell is integral type welding structure, and electrode is provided in the electrolytic cell, and the battery jar outer surface is equipped with corrosion-resistant coating.
Description
Technical field
This application involves battery field more particularly to a kind of accumulators with corrosion resistance.
Background technology
In daily life, the use of accumulator is very extensive, such as applied to automobile, illumination, emergency power supply etc., while by
Complex in the use environment of accumulator, shell is easy in use by corrosion such as gas, liquid, to influence it
Service life.
However, cladding process is usually used in existing anticorrosion technique, one layer of anticorrosive coating is coated in target object surface,
Still suffer from the problems such as anticorrosive coating protection effect is bad.
Invention content
The present invention is intended to provide a kind of accumulator with corrosion resistance, set forth above to solve the problems, such as.
A kind of accumulator with corrosion resistance is provided in the embodiment of the present invention,
A kind of accumulator with corrosion resistance, including battery jar are provided with electrolytic cell in the battery jar, institute
It states and is equipped with upper cover on electrolytic cell, the electrolytic cell is integral type welding structure, and electrode is provided in the electrolytic cell.
The technical solution that the embodiment of the present invention provides can include the following benefits：
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has preferable anticorrosion ability,
Can with effective protection accumulator not in by environment gas, liquid etc. corrosion, or corrosion it is influenced it is smaller, to solve
Problem set forth above.
The additional aspect of the application and advantage will be set forth in part in the description, and will partly become from the following description
It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only
It is exemplary and explanatory, the application can not be limited.
Description of the drawings
Using attached drawing, the invention will be further described, but the embodiment in attached drawing does not constitute any limit to the present invention
System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings
Other attached drawings.
Fig. 1 is the structural schematic diagram of accumulator of the present invention.
Fig. 2 is the production flow diagram of anticorrosion composite coating of the present invention.
Specific implementation mode
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to
When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment
Described in embodiment do not represent and the consistent all embodiments of the present invention.On the contrary, they be only with it is such as appended
The example of the consistent device and method of some aspects being described in detail in claims, of the invention.
Metal is under the action of surrounding medium, since corruption can occur for chemical reaction, electrochemical reaction or physical dissolution etc.
Erosion.Corrosion of metal problem spread economic every field, in life, day commonly used home appliance surface can occur corrosion and
The reduction service life equally faces the various problems that metal erosion is brought, the anticorrosion to metal in fields such as traffic, machinery, chemical industry
Technology has become the very important problem of Material Field.
Currently, mainly metal material and corrosive environment are kept apart, and then avoid metal using the method for surface covering
Be corroded.According to the difference of covering material, surface covering is divided into metal covering and nonmetallic covering.It is to work as using anticorrosive paint
One of preceding most widely used, most effective anticorrosion technique.The chief component of coating has film forming matter, solvent, color stuffing
And auxiliary agent.
Polyaniline has many advantages, such as synthesis material at low cost, scratch resistance, anticorrosive, is a kind of commonly used anticorrosive to have
Machine conducting polymer, studies have shown that polyaniline, which is added in epoxy resin, can be obviously improved its mechanical performance and antiseptic property,
However, polyaniline compound anticorrosive paint still has the problems such as indissoluble, anticorrosion ability is poor at present, therefore develop and expand polyaniline
Application in corrosion-resistant field has very important significance.
Application scenarios one：
Fig. 1 shows a kind of accumulator with corrosion resistance that embodiments herein is related to, including battery jar
1, electrolytic cell is provided in the battery jar, upper cover 2 is equipped on the electrolytic cell, and the electrolytic cell is integral type weldering
Binding structure is provided with electrode in the electrolytic cell；
Preferably, 1 outer surface of the battery jar is equipped with corrosion-resistant coating 3, and 3 thickness of the corrosion-resistant coating is 400~600 μ
M, the corrosion-resistant coating 3 are that anticorrosion composite coating cures 15h shapes coated in 1 outer surface of the battery jar after drying
At.
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has suitable thickness, have
Preferable anticorrosion ability, can with effective protection accumulator not in by environment gas, liquid etc. corrosion, to extend accumulator
Service life.
Preferably, using epoxy resin as film forming matter, polyaniline/Al nano-particles are used as and fill out the anticorrosion composite coating
The composite fibre of material, copper carbon fiber and polyaniline fiber composition is as network layer.
In the anticorrosion composite coating of the application, using the composite fibre that copper carbon fiber and polyaniline fiber form as net
Network layers, on the one hand, copper carbon fiber has excellent flexibility and electric conductivity, is conducive to the transmission of conductive ion；Coppered carbon simultaneously
Fiber is used in mixed way with polyaniline fiber, and the two interacts to form network structure so that the application composite coating is in mechanical performance side
Face enhances suppleness, the impact resistance of coating, while the composite network structure enhances the wear-resisting of composite coating composite coating
Property, increase service life；In terms of electrochemistry, corynebacterium copper carbon fiber mutually splices, and forms conductive network, for corrosion electricity
Conductive ion has electric screening action in solution solution, enhances the corrosion resistance of coating；On the other hand, the application anticorrosion is compound
In coating network layer be effectively isolated matrix and corrode electrolyte contact, have physical shielding effect, obstruction corrosive ion to
The diffusion of matrix improves matrix corrosion resistance.
Preferably, the anticorrosion composite coating is using normal propyl alcohol as antifreeze.
In the application anticorrosion composite coating, normal propyl alcohol is added as antifreeze so that at low temperature, the anticorrosion is compound
Paint film still has comparable corrosion resistance, meanwhile, frost resistance and composite fibre synergistic effect, anticorrosion is compound at low temperature
The mechanical performance decline of paint film is relatively low, produces good effect.
It is further preferred that by Fig. 2, the preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper as electrode, using electrochemical method on its surface
Film, copper film thickness are 5 μm, are then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, surpasses
It under sound, is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, by FeCl36H2O
It is dissolved in distilled water, forms solution B, be then uniformly mixed A, B, wherein A, B volume ratio are 2:3, A, B mixed solution are existed
Reaction 10h is stood under the conditions of ice-water bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water into
Property, then with ethyl alcohol to be washed till filtrate colourless, and product is dried to 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, constantly stirs
It mixes, while acidification 2h, is then washed with deionized water to neutrality, 5h is dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in water
78 DEG C of processing 30min, are then added 0.5g Al nano-particles in bath, and magnetic agitation 1h obtains the uniform suspension of Al particles；
The ammonium persulfate of 10g is dissolved in 100ml hydrochloric acid solutions, magnetic agitation 1h, then utilizes separatory funnel by ammonium persulfate solution
It is added drop-wise in aniline solution, being stirred continuously makes it react 4h, is then allowed to stand filtering, will pulverize after filtrate washing drying
End is to get polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
The application anticorrosion composite coating is using epoxy resin as film forming matter, and polyaniline/Al nano-particles are as filler, phosphorus
Sour zinc, aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre of copper carbon fiber and polyaniline fiber composition
As network layer, as mixed solvent, silane coupling agent is made as auxiliary agent, polyamide 6 50 for n-butanol and N-Methyl pyrrolidone
For curing agent, normal propyl alcohol is as antifreeze；
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones is added,
Magnetic agitation 30min, is then sonicated 2h；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, by solution in two beakers
Mixing stirs 2h, sequentially adds 3 parts of 4 parts of normal propyl alcohol, 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, then
2 parts of 50 curing agent of polyamide 6 are added after stirring 1h, the anticorrosion composite coating of the application is obtained after mechanical agitation 2h；
The anticorrosion composite coating is coated in target object surface, cures 15h after dry, after solidification, coating layer thickness is
400~600 μm.
Preferably, in terms of the experiment effect of the application anticorrosion composite coating, the anti-corruption of the application anticorrosion composite coating
Corrosion energy：Corrosion resistance is evaluated by electrochemical means, and the matrix for coating different-thickness composite coating of the present invention is placed on
In the Na2S solution of 4wt%, 300h, test resistance change rate are stood, it is found that the corrosion of the application composite coating is smaller from electric current,
It can be effectively prevent corrosion of the corrosion electrolyte to matrix, and the anti-freezing property of the anticorrosion composite coating is good.
Application scenarios two：
Fig. 1 shows a kind of accumulator with corrosion resistance that embodiments herein is related to, including battery jar
1, electrolytic cell is provided in the battery jar, upper cover 2 is equipped on the electrolytic cell, and the electrolytic cell is integral type weldering
Binding structure is provided with electrode in the electrolytic cell；
Preferably, 1 outer surface of the battery jar is equipped with corrosion-resistant coating 3, and 3 thickness of the corrosion-resistant coating is 400~600 μ
M, the corrosion-resistant coating 3 are that anticorrosion composite coating cures 15h shapes coated in 1 outer surface of the battery jar after drying
At.
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has suitable thickness, have
Preferable anticorrosion ability, can with effective protection accumulator not in by environment gas, liquid etc. corrosion, to extend accumulator
Service life.
Preferably, using epoxy resin as film forming matter, polyaniline/Al nano-particles are used as and fill out the anticorrosion composite coating
The composite fibre of material, copper carbon fiber and polyaniline fiber composition is as network layer.
In the anticorrosion composite coating of the application, using the composite fibre that copper carbon fiber and polyaniline fiber form as net
Network layers, on the one hand, copper carbon fiber has excellent flexibility and electric conductivity, is conducive to the transmission of conductive ion；Coppered carbon simultaneously
Fiber is used in mixed way with polyaniline fiber, and the two interacts to form network structure so that the application composite coating is in mechanical performance side
Face enhances suppleness, the impact resistance of coating, while the composite network structure enhances the wear-resisting of composite coating composite coating
Property, increase service life；In terms of electrochemistry, corynebacterium copper carbon fiber mutually splices, and forms conductive network, for corrosion electricity
Conductive ion has electric screening action in solution solution, enhances the corrosion resistance of coating；On the other hand, the application anticorrosion is compound
In coating network layer be effectively isolated matrix and corrode electrolyte contact, have physical shielding effect, obstruction corrosive ion to
The diffusion of matrix improves matrix corrosion resistance.
It is further preferred that by Fig. 2, the preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper as electrode, using electrochemical method on its surface
Film, copper film thickness are 5 μm, are then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, surpasses
It under sound, is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, by FeCl36H2O
It is dissolved in distilled water, forms solution B, be then uniformly mixed A, B, wherein A, B volume ratio are 2:3, A, B mixed solution are existed
Reaction 10h is stood under the conditions of ice-water bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water into
Property, then with ethyl alcohol to be washed till filtrate colourless, and product is dried to 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, constantly stirs
It mixes, while acidification 2h, is then washed with deionized water to neutrality, 5h is dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in water
78 DEG C of processing 30min, are then added 0.5g Al nano-particles in bath, and magnetic agitation 1h obtains the uniform suspension of Al particles；
The ammonium persulfate of 10g is dissolved in 100ml hydrochloric acid solutions, magnetic agitation 1h, then utilizes separatory funnel by ammonium persulfate solution
It is added drop-wise in aniline solution, being stirred continuously makes it react 4h, is then allowed to stand filtering, will pulverize after filtrate washing drying
End is to get polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
The application anticorrosion composite coating is using epoxy resin as film forming matter, and polyaniline/Al nano-particles are as filler, phosphorus
Sour zinc, aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre of copper carbon fiber and polyaniline fiber composition
As network layer, as mixed solvent, silane coupling agent is made as auxiliary agent, polyamide 6 50 for n-butanol and N-Methyl pyrrolidone
For curing agent；
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones is added,
Magnetic agitation 30min, is then sonicated 2h；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, by solution in two beakers
Mixing stirs 2h, sequentially adds 3 parts of 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, adds after being stirred for 1h
Enter 2 parts of 50 curing agent of polyamide 6, the anticorrosion composite coating of the application is obtained after mechanical agitation 2h；
The anticorrosion composite coating is coated in target object surface, cures 15h after dry, after solidification, coating layer thickness is
400~600 μm.
Preferably, in terms of the experiment effect of the application anticorrosion composite coating, the anti-corruption of the application anticorrosion composite coating
Corrosion energy：Corrosion resistance is evaluated by electrochemical means, and the matrix for coating different-thickness composite coating of the present invention is placed on
In the Na2S solution of 4wt%, 300h, test resistance change rate are stood, it is found that the corrosion of the application composite coating is smaller from electric current,
It can effectively prevent corrosion of the corrosion electrolyte to matrix.
Application scenarios three：
Fig. 1 shows a kind of accumulator with corrosion resistance that embodiments herein is related to, including battery jar
1, electrolytic cell is provided in the battery jar, upper cover 2 is equipped on the electrolytic cell, and the electrolytic cell is integral type weldering
Binding structure is provided with electrode in the electrolytic cell；
Preferably, 1 outer surface of the battery jar is equipped with corrosion-resistant coating 3, and 3 thickness of the corrosion-resistant coating is 0~200 μm,
The corrosion-resistant coating 3 cures 15h coated in 1 outer surface of the battery jar for anticorrosion composite coating after drying and is formed.
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has suitable thickness, have
Preferable anticorrosion ability, can with effective protection accumulator not in by environment gas, liquid etc. corrosion, to extend accumulator
Service life.
Preferably, using epoxy resin as film forming matter, polyaniline/Al nano-particles are used as and fill out the anticorrosion composite coating
The composite fibre of material, copper carbon fiber and polyaniline fiber composition is as network layer.
In the anticorrosion composite coating of the application, using the composite fibre that copper carbon fiber and polyaniline fiber form as net
Network layers, on the one hand, copper carbon fiber has excellent flexibility and electric conductivity, is conducive to the transmission of conductive ion；Coppered carbon simultaneously
Fiber is used in mixed way with polyaniline fiber, and the two interacts to form network structure so that the application composite coating is in mechanical performance side
Face enhances suppleness, the impact resistance of coating, while the composite network structure enhances the wear-resisting of composite coating composite coating
Property, increase service life；In terms of electrochemistry, corynebacterium copper carbon fiber mutually splices, and forms conductive network, for corrosion electricity
Conductive ion has electric screening action in solution solution, enhances the corrosion resistance of coating；On the other hand, the application anticorrosion is compound
In coating network layer be effectively isolated matrix and corrode electrolyte contact, have physical shielding effect, obstruction corrosive ion to
The diffusion of matrix improves matrix corrosion resistance.
Preferably, the anticorrosion composite coating is using normal propyl alcohol as antifreeze.
In the application anticorrosion composite coating, normal propyl alcohol is added as antifreeze so that at low temperature, the anticorrosion is compound
Paint film still has comparable corrosion resistance, meanwhile, frost resistance and composite fibre synergistic effect, anticorrosion is compound at low temperature
The mechanical performance decline of paint film is relatively low, produces good effect.
It is further preferred that by Fig. 2, the preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper as electrode, using electrochemical method on its surface
Film, copper film thickness are 5 μm, are then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, surpasses
It under sound, is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, by FeCl36H2O
It is dissolved in distilled water, forms solution B, be then uniformly mixed A, B, wherein A, B volume ratio are 2:3, A, B mixed solution are existed
Reaction 10h is stood under the conditions of ice-water bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water into
Property, then with ethyl alcohol to be washed till filtrate colourless, and product is dried to 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, constantly stirs
It mixes, while acidification 2h, is then washed with deionized water to neutrality, 5h is dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in water
78 DEG C of processing 30min, are then added 0.5g Al nano-particles in bath, and magnetic agitation 1h obtains the uniform suspension of Al particles；
The ammonium persulfate of 10g is dissolved in 100ml hydrochloric acid solutions, magnetic agitation 1h, then utilizes separatory funnel by ammonium persulfate solution
It is added drop-wise in aniline solution, being stirred continuously makes it react 4h, is then allowed to stand filtering, will pulverize after filtrate washing drying
End is to get polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
The application anticorrosion composite coating is using epoxy resin as film forming matter, and polyaniline/Al nano-particles are as filler, phosphorus
Sour zinc, aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre of copper carbon fiber and polyaniline fiber composition
As network layer, as mixed solvent, silane coupling agent is made as auxiliary agent, polyamide 6 50 for n-butanol and N-Methyl pyrrolidone
For curing agent, normal propyl alcohol is as antifreeze；
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones is added,
Magnetic agitation 30min, is then sonicated 2h；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, by solution in two beakers
Mixing stirs 2h, sequentially adds 3 parts of 4 parts of normal propyl alcohol, 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, then
2 parts of 50 curing agent of polyamide 6 are added after stirring 1h, the anticorrosion composite coating of the application is obtained after mechanical agitation 2h；
The anticorrosion composite coating is coated in target object surface, cures 15h after dry, after solidification, coating layer thickness 0
~200 μm.
Preferably, in terms of the experiment effect of the application anticorrosion composite coating, the anti-corruption of the application anticorrosion composite coating
Corrosion energy：Corrosion resistance is evaluated by electrochemical means, and the matrix for coating different-thickness composite coating of the present invention is placed on
In the Na2S solution of 4wt%, 300h, test resistance change rate are stood, it is found that the corrosion of the application composite coating is smaller from electric current,
It can be effectively prevent corrosion of the corrosion electrolyte to matrix, and the anti-freezing property of the anticorrosion composite coating is good.
Application scenarios four：
Fig. 1 shows a kind of accumulator with corrosion resistance that embodiments herein is related to, including battery jar
1, electrolytic cell is provided in the battery jar, upper cover 2 is equipped on the electrolytic cell, and the electrolytic cell is integral type weldering
Binding structure is provided with electrode in the electrolytic cell；
Preferably, 1 outer surface of the battery jar is equipped with corrosion-resistant coating 3, and 3 thickness of the corrosion-resistant coating is 200~400 μ
M, the corrosion-resistant coating 3 are that anticorrosion composite coating cures 15h shapes coated in 1 outer surface of the battery jar after drying
At.
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has suitable thickness, have
Preferable anticorrosion ability, can with effective protection accumulator not in by environment gas, liquid etc. corrosion, to extend accumulator
Service life.
Preferably, using epoxy resin as film forming matter, polyaniline/Al nano-particles are used as and fill out the anticorrosion composite coating
The composite fibre of material, copper carbon fiber and polyaniline fiber composition is as network layer.
In the anticorrosion composite coating of the application, using the composite fibre that copper carbon fiber and polyaniline fiber form as net
Network layers, on the one hand, copper carbon fiber has excellent flexibility and electric conductivity, is conducive to the transmission of conductive ion；Coppered carbon simultaneously
Fiber is used in mixed way with polyaniline fiber, and the two interacts to form network structure so that the application composite coating is in mechanical performance side
Face enhances suppleness, the impact resistance of coating, while the composite network structure enhances the wear-resisting of composite coating composite coating
Property, increase service life；In terms of electrochemistry, corynebacterium copper carbon fiber mutually splices, and forms conductive network, for corrosion electricity
Conductive ion has electric screening action in solution solution, enhances the corrosion resistance of coating；On the other hand, the application anticorrosion is compound
In coating network layer be effectively isolated matrix and corrode electrolyte contact, have physical shielding effect, obstruction corrosive ion to
The diffusion of matrix improves matrix corrosion resistance.
Preferably, the anticorrosion composite coating is using normal propyl alcohol as antifreeze.
In the application anticorrosion composite coating, normal propyl alcohol is added as antifreeze so that at low temperature, the anticorrosion is compound
Paint film still has comparable corrosion resistance, meanwhile, frost resistance and composite fibre synergistic effect, anticorrosion is compound at low temperature
The mechanical performance decline of paint film is relatively low, produces good effect.
It is further preferred that by Fig. 2, the preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper as electrode, using electrochemical method on its surface
Film, copper film thickness are 5 μm, are then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, surpasses
It under sound, is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, by FeCl36H2O
It is dissolved in distilled water, forms solution B, be then uniformly mixed A, B, wherein A, B volume ratio are 2:3, A, B mixed solution are existed
Reaction 10h is stood under the conditions of ice-water bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water into
Property, then with ethyl alcohol to be washed till filtrate colourless, and product is dried to 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, constantly stirs
It mixes, while acidification 2h, is then washed with deionized water to neutrality, 5h is dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in water
78 DEG C of processing 30min, are then added 0.5g Al nano-particles in bath, and magnetic agitation 1h obtains the uniform suspension of Al particles；
The ammonium persulfate of 10g is dissolved in 100ml hydrochloric acid solutions, magnetic agitation 1h, then utilizes separatory funnel by ammonium persulfate solution
It is added drop-wise in aniline solution, being stirred continuously makes it react 4h, is then allowed to stand filtering, will pulverize after filtrate washing drying
End is to get polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
The application anticorrosion composite coating is using epoxy resin as film forming matter, and polyaniline/Al nano-particles are as filler, phosphorus
Sour zinc, aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre of copper carbon fiber and polyaniline fiber composition
As network layer, as mixed solvent, silane coupling agent is made as auxiliary agent, polyamide 6 50 for n-butanol and N-Methyl pyrrolidone
For curing agent, normal propyl alcohol is as antifreeze；
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones is added,
Magnetic agitation 30min, is then sonicated 2h；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, by solution in two beakers
Mixing stirs 2h, sequentially adds 3 parts of 4 parts of normal propyl alcohol, 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, then
2 parts of 50 curing agent of polyamide 6 are added after stirring 1h, the anticorrosion composite coating of the application is obtained after mechanical agitation 2h；
The anticorrosion composite coating is coated in target object surface, cures 15h after dry, after solidification, coating layer thickness is
200~400 μm.
Preferably, in terms of the experiment effect of the application anticorrosion composite coating, the anti-corruption of the application anticorrosion composite coating
Corrosion energy：Corrosion resistance is evaluated by electrochemical means, and the matrix for coating different-thickness composite coating of the present invention is placed on
In the Na2S solution of 4wt%, 300h, test resistance change rate are stood, it is found that the corrosion of the application composite coating is smaller from electric current,
It can be effectively prevent corrosion of the corrosion electrolyte to matrix, and the anti-freezing property of the anticorrosion composite coating is good.
Application scenarios five：
Fig. 1 shows a kind of accumulator with corrosion resistance that embodiments herein is related to, including battery jar
1, electrolytic cell is provided in the battery jar, upper cover 2 is equipped on the electrolytic cell, and the electrolytic cell is integral type weldering
Binding structure is provided with electrode in the electrolytic cell；
Preferably, 1 outer surface of the battery jar is equipped with corrosion-resistant coating 3, and 3 thickness of the corrosion-resistant coating is 600~800 μ
M, the corrosion-resistant coating 3 are that anticorrosion composite coating cures 15h shapes coated in 1 outer surface of the battery jar after drying
At.
Corrosion-resistant coating is arranged in the outer surface of battery jar in the present invention, which has suitable thickness, have
Preferable anticorrosion ability, can with effective protection accumulator not in by environment gas, liquid etc. corrosion, to extend accumulator
Service life.
Preferably, using epoxy resin as film forming matter, polyaniline/Al nano-particles are used as and fill out the anticorrosion composite coating
The composite fibre of material, copper carbon fiber and polyaniline fiber composition is as network layer.
In the anticorrosion composite coating of the application, using the composite fibre that copper carbon fiber and polyaniline fiber form as net
Network layers, on the one hand, copper carbon fiber has excellent flexibility and electric conductivity, is conducive to the transmission of conductive ion；Coppered carbon simultaneously
Fiber is used in mixed way with polyaniline fiber, and the two interacts to form network structure so that the application composite coating is in mechanical performance side
Face enhances suppleness, the impact resistance of coating, while the composite network structure enhances the wear-resisting of composite coating composite coating
Property, increase service life；In terms of electrochemistry, corynebacterium copper carbon fiber mutually splices, and forms conductive network, for corrosion electricity
Conductive ion has electric screening action in solution solution, enhances the corrosion resistance of coating；On the other hand, the application anticorrosion is compound
In coating network layer be effectively isolated matrix and corrode electrolyte contact, have physical shielding effect, obstruction corrosive ion to
The diffusion of matrix improves matrix corrosion resistance.
Preferably, the anticorrosion composite coating is using normal propyl alcohol as antifreeze.
In the application anticorrosion composite coating, normal propyl alcohol is added as antifreeze so that at low temperature, the anticorrosion is compound
Paint film still has comparable corrosion resistance, meanwhile, frost resistance and composite fibre synergistic effect, anticorrosion is compound at low temperature
The mechanical performance decline of paint film is relatively low, produces good effect.
It is further preferred that by Fig. 2, the preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper as electrode, using electrochemical method on its surface
Film, copper film thickness are 5 μm, are then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, surpasses
It under sound, is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, by FeCl36H2O
It is dissolved in distilled water, forms solution B, be then uniformly mixed A, B, wherein A, B volume ratio are 2:3, A, B mixed solution are existed
Reaction 10h is stood under the conditions of ice-water bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water into
Property, then with ethyl alcohol to be washed till filtrate colourless, and product is dried to 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, constantly stirs
It mixes, while acidification 2h, is then washed with deionized water to neutrality, 5h is dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in water
78 DEG C of processing 30min, are then added 0.5g Al nano-particles in bath, and magnetic agitation 1h obtains the uniform suspension of Al particles；
The ammonium persulfate of 10g is dissolved in 100ml hydrochloric acid solutions, magnetic agitation 1h, then utilizes separatory funnel by ammonium persulfate solution
It is added drop-wise in aniline solution, being stirred continuously makes it react 4h, is then allowed to stand filtering, will pulverize after filtrate washing drying
End is to get polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
The application anticorrosion composite coating is using epoxy resin as film forming matter, and polyaniline/Al nano-particles are as filler, phosphorus
Sour zinc, aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre of copper carbon fiber and polyaniline fiber composition
As network layer, as mixed solvent, silane coupling agent is made as auxiliary agent, polyamide 6 50 for n-butanol and N-Methyl pyrrolidone
For curing agent, normal propyl alcohol is as antifreeze；
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones is added,
Magnetic agitation 30min, is then sonicated 2h；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, by solution in two beakers
Mixing stirs 2h, sequentially adds 3 parts of 4 parts of normal propyl alcohol, 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, then
2 parts of 50 curing agent of polyamide 6 are added after stirring 1h, the anticorrosion composite coating of the application is obtained after mechanical agitation 2h；
The anticorrosion composite coating is coated in target object surface, cures 15h after dry, after solidification, coating layer thickness is
600~800 μm.
Preferably, in terms of the experiment effect of the application anticorrosion composite coating, the anti-corruption of the application anticorrosion composite coating
Corrosion energy：Corrosion resistance is evaluated by electrochemical means, and the matrix for coating different-thickness composite coating of the present invention is placed on
In the Na2S solution of 4wt%, 300h, test resistance change rate are stood, it is found that the corrosion of the application composite coating is smaller from electric current,
It can be effectively prevent corrosion of the corrosion electrolyte to matrix, and the anti-freezing property of the anticorrosion composite coating is good.
Those skilled in the art after considering the specification and implementing the invention disclosed here, will readily occur to its of the present invention
Its embodiment.This application is intended to cover the present invention any variations, uses, or adaptations, these modifications, purposes or
Person's adaptive change follows the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques.The description and examples are only to be considered as illustrative, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be understood that the invention is not limited in the precision architectures for being described above and being shown in the accompanying drawings, and
And various modifications and changes may be made without departing from the scope thereof.The scope of the present invention is limited only by the attached claims.
Claims (2)
1. a kind of accumulator with corrosion resistance, including battery jar, it is provided with electrolytic cell in the battery jar, it is described
Upper cover is equipped on electrolytic cell, which is characterized in that the electrolytic cell is integral type welding structure, is arranged in the electrolytic cell
There is electrode；
The battery jar outer surface is equipped with corrosion-resistant coating, and the corrosion-resistant coating is that anticorrosion composite coating is coated in the electric power storage
Pond shell outer surface cures 15h after drying and is formed；
The anticorrosion composite coating using epoxy resin as film forming matter, polyaniline/Al nano-particles as filler, trbasic zinc phosphate,
Aluminium triphosphate, talcum powder and barium sulfate are as color stuffing, the composite fibre conduct of copper carbon fiber and polyaniline fiber composition
Network layer, n-butanol and N-Methyl pyrrolidone are used as curing agent as mixed solvent, polyamide 6 50, and normal propyl alcohol is as freeze proof
Agent；Above-mentioned substance mass fraction is followed successively by：10 parts of epoxy resin, polyaniline/5 parts of Al nano-particles, 1 part of trbasic zinc phosphate, trimerization phosphorus
2 parts of sour aluminium, 1 part of talcum powder, 3 parts of barium sulfate, 7 parts of composite fibre, 6 parts of n-butanol, 60 parts of N-Methyl pyrrolidone, polyamide
650 2 parts, 4 parts of normal propyl alcohol；
The preparation process of the anticorrosion composite coating is as follows：
Step 1 prepares copper carbon fiber：
Carbon fiber is taken, a diameter of 20~50 μm, carbon fiber plates one layer of copper film as electrode, using electrochemical method on its surface,
Copper film thickness is 5 μm, is then cut to 2~3mm length；
Step 2 prepares polyaniline fiber：
It is 1 to take volume ratio:Aniline, is dissolved in distilled water by 60 aniline and distilled water under the action of inorganic acid, under ultrasound,
It is uniformly mixed, forms solution A, it is 1 then to take mass ratio:50 FeCl36H2O and distilled water, FeCl36H2O is dissolved
In distilled water, solution B is formed, is then uniformly mixed A, B, wherein A, B volume ratio are 2:3, by A, B mixed solution in ice water
Reaction 10h is stood under the conditions of bath, obtains bottle green product, and reaction acquired solution filtering is first washed with deionized water to neutrality, then
It is colourless it to be washed till filtrate with ethyl alcohol, product is dried 30h in drying box, obtains polyaniline fiber；
Then, copper carbon fiber and polyaniline fiber, mass ratio 3 are taken:2, it puts it into dilute hydrochloric acid solution, is stirred continuously, together
When acidification 2h, be then washed with deionized water to neutrality, 5h be dried in drying box, obtain composite fibre；
Step 3 prepares polyaniline/Al nano-particles：
It takes the neopelex of 3g to be dissolved into 200ml deionized waters first, the aniline of 3ml is added, in a water bath
78 DEG C of processing 30min, are then added 0.5g Al nano-particles, magnetic agitation 1h obtains the uniform suspension of Al particles；By 10g
Ammonium persulfate be dissolved in 100ml hydrochloric acid solutions, then ammonium persulfate solution is added drop-wise to by magnetic agitation 1h using separatory funnel
In aniline solution, be stirred continuously make its react 4h, be then allowed to stand filtering, by filtrate washing dry after grind into powder to get
Polyaniline/Al nano-particle powders；
Step 4 prepares anticorrosion composite coating：
It takes 5 parts of polyanilines/Al nano-particles and 7 parts of composite fibre to be placed in beaker, 60 parts of N-Methyl pyrrolidones, magnetic force is added
30min is stirred, 2h is then sonicated；
Then 10 parts of epoxy resin and 6 parts of n-butanols are put into another beaker, magnetic agitation 1h, solution in two beakers is mixed
It closes, stirs 2h, sequentially add 3 parts of 4 parts of normal propyl alcohol, 1 part of trbasic zinc phosphate, 2 parts of aluminium triphosphate, 1 part of talcum powder and barium sulfate, then stir
2 parts of 50 curing agent of polyamide 6 are added after mixing 1h, the anticorrosion composite coating is obtained after mechanical agitation 2h.
2. accumulator according to claim 1, which is characterized in that the corrosion-resistant coating thickness is 400~600 μm.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6887613B2 (en) * | 2002-12-04 | 2005-05-03 | General Motors Corporation | Corrosion resistant PEM fuel cell |
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|---|---|---|---|---|
| CN105531841A (en) * | 2013-06-04 | 2016-04-27 | 通用汽车环球科技运作有限责任公司 | Plasma coating for corrosion protection of light-metal components in battery fabrication |
| CN203398218U (en) * | 2013-07-09 | 2014-01-15 | 马鞍山市海鹰蓄电池配件厂 | High-capacity traction lead-acid storage battery |
| CN203536542U (en) * | 2013-10-22 | 2014-04-09 | 大连爱镁瑞电池有限公司 | Empty battery of magnesium |
| CN204315633U (en) * | 2014-08-28 | 2015-05-06 | 安徽龙钢金属制品有限公司 | Battery cell case |
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