CN105952106A - Electric heating solid wood composite floor with built-in heating layers and method for manufacturing electric heating solid wood composite floor - Google Patents

Electric heating solid wood composite floor with built-in heating layers and method for manufacturing electric heating solid wood composite floor Download PDF

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Publication number
CN105952106A
CN105952106A CN201610478722.7A CN201610478722A CN105952106A CN 105952106 A CN105952106 A CN 105952106A CN 201610478722 A CN201610478722 A CN 201610478722A CN 105952106 A CN105952106 A CN 105952106A
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China
Prior art keywords
electric heating
built
parts
heating solid
compound floor
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Granted
Application number
CN201610478722.7A
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Chinese (zh)
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CN105952106B (en
Inventor
庞秋龙
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Zhejiang Ruicheng Wood Industry Co Ltd
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Zhejiang Ruicheng Wood Industry Co Ltd
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Priority to CN201610478722.7A priority Critical patent/CN105952106B/en
Publication of CN105952106A publication Critical patent/CN105952106A/en
Application granted granted Critical
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
    • E04F15/041—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members with a top layer of wood in combination with a lower layer of other material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
    • E04F15/041—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members with a top layer of wood in combination with a lower layer of other material
    • E04F15/042—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members with a top layer of wood in combination with a lower layer of other material the lower layer being of fibrous or chipped material, e.g. bonded with synthetic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/02—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets
    • E04F2290/023—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets for heating

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Floor Finish (AREA)
  • Central Heating Systems (AREA)

Abstract

The invention discloses an electric heating solid wood composite floor with built-in heating layers and a method for manufacturing the electric heating solid wood composite floor. The electric heating solid wood composite floor sequentially comprises a surface plate (1), a finger joint upper-layer plate (2), a heat conducting core plate (3), an electric heating fiber plate (4) and a bottom plate (5) from top to bottom. Battens (5) are adhered and spliced with one another in an end-to-end manner to form the finger joint upper-layer plate (2), and surfaces of iron sheets (7) and wood blocks (8) are adhered with one another to form the heat conducting core plate (3). The electric heating solid wood composite floor and the method have the advantages that wood wastage can be effectively reduced, wood resources can be saved, the electric heating solid wood composite floor and the method have superior economic benefits, and the heat conducting property can be greatly improved.

Description

Built-in heating layer electric heating solid wooden compound floor and preparation method thereof
Technical field
The present invention relates to a kind of timber floor and preparation method thereof, particularly relate to a kind of built-in heating layer Electric heating solid wooden compound floor and preparation method thereof.
Background technology
Ground heating system the most quickly incorporates the life of people as current most popular heating system, And increasingly liked by people.Wherein electrothemic floor is substantially better than common hot-water heating system System, have that maintenance rate is low, length in service life, the race occurred without water-heating system, emit, leak, droplet The advantages such as phenomenon and popular.Chinese patent literature " a kind of electric heating floor and the side of mating formation thereof Method " (application number: CN200910306209.X) electric heating floor body interior of disclosing offers Having some through holes penetrating floor layer, the shape of through hole can be circular, square or rectangular Deng, it is provided with the heating extended along through hole length direction in each through hole.Heating Outer surface contacts with through-hole wall, thus ensures that heating adstante febre transfers heat to ground Plate surface.Then the heat conductivility of this electric heating floor system is unsatisfactory.
Summary of the invention
It is an object of the invention to, it is provided that a kind of built-in heating layer electric heating solid wooden compound floor and Preparation method.The present invention can efficiently reduce the waste of timber, saves timber resources, simultaneously There is superior economic benefit.Meanwhile, the present invention can be greatly improved heat conductivility.
For solving above-mentioned technical problem, the technical scheme that the present invention provides is as follows: a kind of from up to Under include dash board, finger top plate, heat conduction central layer, fibre electroheating plate and base plate successively, described Finger top plate by batten head and the tail paste be spliced, described heat conduction central layer is by iron plate and wood Face, block face is pasted and is formed.
Above-mentioned built-in heating layer electric heating solid wooden compound floor, the bottom of described base plate offers Stress groove.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described iron plate and wooden unit interval are handed over For arranging.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described stickup finger top plate and leading Adhesive used by hot central layer includes ethylene-vinyl acetate copolymer 10-50 part, polyvinyl alcohol 20-40 part, acetamide 10-50 part in the sixth of the twelve Earthly Branches, cross-linking agent 5-10 part, potassium peroxydisulfate 5-10 part, Stearic acid 1-10 part, fibrous silicate magnesium 1-10 part, toughener 1-5 part, filler 0-20 part.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described adhesive includes ethylene-vinegar Acid ethylene copolymer 40 parts, polyvinyl alcohol 30 parts, acetamide in the sixth of the twelve Earthly Branches 30 parts, cross-linking agent 8 parts, Potassium peroxydisulfate 8 parts, stearic acid 5 parts, 5 parts of fibrous silicate magnesium, toughener 3 parts, filler 10 parts.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described cross-linking agent is metal-oxide Class cross-linking agent, including one or more in zinc oxide, lead oxide, magnesium oxide.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described toughener is polysulfide rubber One or more in glue, polybutadiene rubber, nitrile rubber.
Aforesaid built-in heating layer electric heating solid wooden compound floor, described filler is aluminium nitride or nitrogen Change boron
The production method of aforesaid built-in heating layer electric heating solid wooden compound floor, specifically includes following Step；
A, by ethylene-vinyl acetate copolymer, polyvinyl alcohol, acetamide in the sixth of the twelve Earthly Branches, cross-linking agent, mistake Potassium sulfate, stearic acid, fibrous silicate magnesium, toughener, filler mix and blend obtain adhesive；
B, fast growing wood stamping-out being become batten, by batten head and the tail splicing, blend compounds stick is pasted To long stuff then long stuff is horizontally-spliced, stick with glue agent stickup and obtain finger top plate；
C, fast growing wood stamping-out is become wooden unit, wooden unit and iron plate are spaced be arranged alternately, blend compounds Face, stick face is pasted into heat conduction central layer；
D, dash board, finger top plate, heat conduction central layer, iron plate and base plate are sticked with glue agent successively It is pasted together, obtains finished product.
Compared with prior art, finger top plate of the present invention is pasted by batten head and the tail and is spelled Connect and form, the waste of timber can be efficiently reduced, save timber resources, have superior simultaneously Economic benefit.Additionally, the present invention can be effectively improved the viscosity of timber floor, and improve Floor strength.The performance of built-in heating layer electric heating solid wooden compound floor is tried by applicant Testing, result of the test is as follows:
The present invention is at aspects such as comprcssive strength, tensile strength, impermeability pressure as can be seen from the above table, It is respectively provided with superior effect.
The present invention arranges heat conduction central layer on fibre electroheating plate simultaneously, and heat conduction central layer is by iron plate and wood Face, block face is pasted and is formed, and the setting of iron plate is possible not only to improve the intensity on floor, and can also It is greatly improved the capacity of heat transmission of heat conduction central layer, improves electric heating effect.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1: a kind of built-in heating layer electric heating solid wooden compound floor, as shown in Figure 1, Include dash board 1, finger top plate 2, heat conduction central layer 3, fibre electroheating plate 4 the most successively With base plate 5, described finger top plate 2 is pasted by batten 6 head and the tail and is spliced, described Heat conduction central layer 3 is pasted formed by iron plate 7 and 8 face of wooden unit.The bottom of described base plate 5 is opened It is provided with stress groove 9.Described iron plate 7 and wooden unit 8 interval are arranged alternately.In Fig. 1 centre circle it is The partial enlarged drawing of stress groove, stress groove can be perpendicular to the groove in floor length direction.
Embodiment 2: described finger top plate is pasted by batten head and the tail and is spliced, described Reinforcing central layer to be formed by bamboo chip and the stickup of face, wooden unit face, adhesive used includes ethyl vinyl acetate Ethylene copolymer 30 parts, polyvinyl alcohol 35 parts, acetamide in the sixth of the twelve Earthly Branches 10 parts, cross-linking agent 10 parts, Potassium peroxydisulfate 6 parts, stearic acid 8 parts, 2 parts of fibrous silicate magnesium, toughener 2 parts, filler 5 Part.Described cross-linking agent is 1/2 zinc oxide and 1/2 lead oxide, and described toughener is polysulfide rubber Glue, described filler is aluminium nitride.Above-mentioned component only need to be mixed by the preparation method of this adhesive Stir.
Embodiment 3: described adhesive includes ethylene-vinyl acetate copolymer 40 parts, polyethylene Alcohol 30 parts, acetamide in the sixth of the twelve Earthly Branches 30 parts, cross-linking agent 8 parts, potassium peroxydisulfate 8 parts, stearic acid 5 Part, 5 parts of fibrous silicate magnesium, toughener 3 parts, filler 10 parts.Described cross-linking agent is 1/3 Lead oxide and 2/3 magnesium oxide, described toughener is nitrile rubber, and described filler is nitridation Boron.
Embodiment 4: described adhesive includes ethylene-vinyl acetate copolymer 50 parts, polyethylene Alcohol 20 parts, acetamide in the sixth of the twelve Earthly Branches 40 parts, cross-linking agent 7 parts, potassium peroxydisulfate 5 parts, stearic acid 2 Part, 7 parts of fibrous silicate magnesium, toughener 2 parts.Described cross-linking agent is 1/3 lead oxide and 2/3 Magnesium oxide, described toughener is nitrile rubber, and described filler is boron nitride.
Embodiment 5: the production method of built-in heating layer electric heating solid wooden compound floor, specifically includes Following steps；
A, by ethylene-vinyl acetate copolymer, polyvinyl alcohol, acetamide in the sixth of the twelve Earthly Branches, cross-linking agent, mistake Potassium sulfate, stearic acid, fibrous silicate magnesium, toughener, filler mix and blend obtain adhesive；
B, fast growing wood stamping-out being become batten, by batten head and the tail splicing, blend compounds stick is pasted To long stuff then long stuff is horizontally-spliced, stick with glue agent stickup and obtain finger top plate；
C, fast growing wood stamping-out is become wooden unit, wooden unit and iron plate are spaced be arranged alternately, blend compounds Face, stick face is pasted into heat conduction central layer；
D, dash board, finger top plate, heat conduction central layer, iron plate and base plate are sticked with glue agent successively It is pasted together, obtains finished product.

Claims (9)

1. built-in heating layer electric heating solid wooden compound floor, it is characterized in that: include dash board (1), finger top plate (2), heat conduction central layer (3), fibre electroheating plate (4) and base plate (5) the most successively, described finger top plate (2) is pasted by batten (6) head and the tail and is spliced, and described heat conduction central layer (3) is pasted by iron plate (7) and wooden unit (8) face, face and formed.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 1, it is characterised in that: the bottom of described base plate (5) offers stress groove (9).
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: described iron plate (7) and wooden unit (8) interval are arranged alternately.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: the adhesive used by described stickup finger top plate and heat conduction central layer includes ethylene-vinyl acetate copolymer 10-50 part, polyvinyl alcohol 20-40 part, acetamide 10-50 part in the sixth of the twelve Earthly Branches, cross-linking agent 5-10 part, potassium peroxydisulfate 5-10 part, stearic acid 1-10 part, fibrous silicate magnesium 1-10 part, toughener 1-5 part, filler 0-20 part.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: described adhesive includes ethylene-vinyl acetate copolymer 40 parts, polyvinyl alcohol 30 parts, acetamide in the sixth of the twelve Earthly Branches 30 parts, cross-linking agent 8 parts, potassium peroxydisulfate 8 parts, stearic acid 5 parts, 5 parts of fibrous silicate magnesium, toughener 3 parts, filler 10 parts.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: described cross-linking agent is metal oxide-type cross-linking agent, including one or more in zinc oxide, lead oxide, magnesium oxide.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: described toughener is one or more in thiorubber., polybutadiene rubber, nitrile rubber.
Built-in heating layer electric heating solid wooden compound floor the most according to claim 2, it is characterised in that: described filler is aluminium nitride or boron nitride.
9. according to the production method of the built-in heating layer electric heating solid wooden compound floor described in any one of claim 1 to 6, it is characterised in that: specifically include following steps；
A, ethylene-vinyl acetate copolymer, polyvinyl alcohol, acetamide in the sixth of the twelve Earthly Branches, cross-linking agent, potassium peroxydisulfate, stearic acid, fibrous silicate magnesium, toughener, filler mix and blend are obtained adhesive；
B, fast growing wood stamping-out being become batten, by batten head and the tail splicing, blend compounds stick is pasted and is obtained long stuff, then long stuff is horizontally-spliced, sticks with glue agent and pastes and obtain finger top plate；
C, fast growing wood stamping-out is become wooden unit, wooden unit and iron plate are spaced be arranged alternately, face, blend compounds stick face is pasted into heat conduction central layer；
D, dash board, finger top plate, heat conduction central layer, iron plate and base plate are sticked with glue agent it is pasted together successively, obtain finished product.
CN201610478722.7A 2016-06-23 2016-06-23 Built-in heating layer electric heating solid wooden compound floor and preparation method thereof Active CN105952106B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108818781A (en) * 2018-06-01 2018-11-16 东莞市全屋荟家居用品科技有限公司 A kind of spun gold solid wood board and preparation method thereof
CN110966645A (en) * 2018-09-28 2020-04-07 台山市长发木业有限公司 Splicing geothermal board

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185796A (en) * 1995-05-26 1998-06-24 杨秀拨 Two-component polymer composition
WO2005030895A1 (en) * 2003-09-26 2005-04-07 Basf Aktiengesellschaft Binding agent system containing aminoplastic resins, copolymers from n-functionalized ethylenically unsaturated monomers and optionally vinyl alcohol and acid
CN201053190Y (en) * 2007-05-22 2008-04-30 赖作良 Composite type electric heating wood floor structure
CN202064590U (en) * 2010-12-02 2011-12-07 田红丰 Floor base material with heat conductive effect
WO2012126258A1 (en) * 2011-03-18 2012-09-27 Celanese International Corporation Adhesive composition and use thereof
CN203375520U (en) * 2013-05-09 2014-01-01 傅亮 Waterproof carbon-fiber infrared heating floor tile
CN104910859A (en) * 2015-05-29 2015-09-16 柳州市东汇木业有限公司 Method for preparing sheet material adhesive
CN105115016A (en) * 2015-09-10 2015-12-02 浙江康辉木业有限公司 Novel filament carbon fiber face heating floor and processing technique thereof
CN205822677U (en) * 2016-06-23 2016-12-21 浙江瑞澄木业有限公司 Built-in heating layer electric heating solid wooden compound floor

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185796A (en) * 1995-05-26 1998-06-24 杨秀拨 Two-component polymer composition
WO2005030895A1 (en) * 2003-09-26 2005-04-07 Basf Aktiengesellschaft Binding agent system containing aminoplastic resins, copolymers from n-functionalized ethylenically unsaturated monomers and optionally vinyl alcohol and acid
CN201053190Y (en) * 2007-05-22 2008-04-30 赖作良 Composite type electric heating wood floor structure
CN202064590U (en) * 2010-12-02 2011-12-07 田红丰 Floor base material with heat conductive effect
WO2012126258A1 (en) * 2011-03-18 2012-09-27 Celanese International Corporation Adhesive composition and use thereof
CN103443232A (en) * 2011-03-18 2013-12-11 国际人造丝公司 Adhesive composition and use thereof
CN203375520U (en) * 2013-05-09 2014-01-01 傅亮 Waterproof carbon-fiber infrared heating floor tile
CN104910859A (en) * 2015-05-29 2015-09-16 柳州市东汇木业有限公司 Method for preparing sheet material adhesive
CN105115016A (en) * 2015-09-10 2015-12-02 浙江康辉木业有限公司 Novel filament carbon fiber face heating floor and processing technique thereof
CN205822677U (en) * 2016-06-23 2016-12-21 浙江瑞澄木业有限公司 Built-in heating layer electric heating solid wooden compound floor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108818781A (en) * 2018-06-01 2018-11-16 东莞市全屋荟家居用品科技有限公司 A kind of spun gold solid wood board and preparation method thereof
CN108818781B (en) * 2018-06-01 2023-06-27 东莞市全屋荟家居用品科技有限公司 Gold wire solid wood board and manufacturing method thereof
CN110966645A (en) * 2018-09-28 2020-04-07 台山市长发木业有限公司 Splicing geothermal board

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Denomination of invention: Electric heating solid wood composite floor with built-in heating layer and its preparation method

Effective date of registration: 20210813

Granted publication date: 20180925

Pledgee: Zhejiang Mintai Commercial Bank Co.,Ltd. Huzhou Nanxun small and micro enterprise franchise sub branch

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